阴山—燕山北麓富碱侵入岩体的岩石地球化学特征、锆石SHRIMP U-Pb年龄及构造意义

本文研究的达茂旗黄合少、察哈尔右后旗古城和河北尚义县八道沟岩体位于华北克拉通北缘阴山—燕山北麓,索伦缝合带以南,沿近东西方向展布。主要岩石类型为正长岩、二长岩和石英二长岩。岩石地球化学研究表明其SiO2含量59. 08%~66. 52%, Al2O3= 15. 34%~21. 67%,A/CNK<1。属于准铝质中性岩范畴。全碱含量（Na2O+K2O）均在8%以上,在岩石的碱度率AR—SiO2图解上大多数样品落入碱性与过碱性区域,里特曼指数σ值从3. 73~10. 83均位于碱性或过碱性系列,属于碱性岩。岩体的微量元素以富集大离子亲石元素（LILE）如Rb、Ba和Sr等,亏损高场强元素（HFSE）如Ti、P、Nb和Ta等为特征。岩石稀土元素特征显示富集轻稀土元素（LREE）,亏损重稀土元素（HREE）并且轻重稀土元素分馏比较明显的特征。除极个别样品外,岩石具有Eu负异常（δEu= 0. 35~0. 91）。通过对察哈尔右后旗古城正长岩体和河北尚义县八道沟富碱侵入岩体的高精度测年研究,获得其SHRIMP锆石U- Pb年龄分别为413. 2±3. 3~415. 0±5. 9 Ma和366. 8±5. 2~372. 3±4. 7 Ma,表明其均为古生代泥盆纪富碱侵入岩浆活动的产物。结合前人关于阴山—燕山北麓其它富碱侵入岩体（内蒙古固阳东高家村碱性正长岩体、黄合少碱性正长岩和冀北水泉沟碱性杂岩体 ）的研究成果,推断在华北克拉通北缘阴山—燕山北麓一带,可能存在一条东西方向展布的晚古生代泥盆纪富碱侵入岩带。根据该岩带岩石地球化学特征,以及Ta/Yb—Th/Yb与Zr/Nb—Zr/Nb—Y/Nb判别图推测其岩浆物质来源可能与富集地幔有关,按照成岩温压环境指示,其形成深度位置约为下地壳,岩浆上升侵位过程中明显受到地壳物质的混染。依据前人关于碱性岩特征的研究,结合本文研究岩体的岩石化学特征和及Rb—Nb+Y构造判别图解指示,推测岩体形成于张性构造环境,可能与古生代志留纪末兴蒙造山带南部发育的白乃庙岛弧带和华北克拉通发生弧—陆碰撞后的伸展背景相关。     

云南中甸甭哥正长斑岩成矿性探讨

<正>1地质背景研究区处于特提斯-喜马拉雅造山带和扬子克拉通两大构造单元接合地带,属三江复合造山带。中甸甭哥碱性杂岩体位于三江地区蜂腰地带,属特提斯-喜马拉雅构造域东缘义敦岛弧带的南延部分。甭哥岩体呈岩株、岩枝集群式出露,最大的不足1 km2;主体近南北向展布于碧塔海-甭哥与纳帕海-土官村两组深大断裂,岩石以正     

湖北竹溪蔓荆沟碱性正长岩地球化学特征及其构造环境分析

在南秦岭造山带中发现的竹溪蔓荆沟碱性正长岩,呈透镜状侵入于辉绿岩体内,个别呈独立岩体侵入于早古生代地层中。单个正长岩体规模较小。通过对其进行岩相学及岩石地球化学特征研究,表明其为全碱(Na_2O~+K_2O)含量较高的钾质碱性正长岩;岩石中Mg~#值较低,明显低于原始岩浆Mg~#值,说明其为原始岩浆经历较高程度演化的产物;岩体中稀土元素总量ΣREE较高,轻稀土元素LREE富集明显,重稀土元素HREE亏损;通过微量元素构造环境判别分析认为,研究区正长岩形成于大陆裂谷环境,且形成于大陆裂谷早期阶段,其形成时代为早志留世。     

Magmatic evolution and rare earth element enrichment of Saima alkaline complex,Liaoning, ChinaSCIEI北大核心CSCD

赛马碱性杂岩体位于我国辽东半岛,是一个典型的铀-铌和稀土多金属矿化杂岩体,富含重稀土,其复杂的演化过程和稀土元素富集机制仍没有得到有效约束。本文对该碱性杂岩体中角闪辉石正长岩、正长岩、黑云正长岩、云霓霞石正长岩和异霞正长岩5类岩石及锆石的元素地球化学特征进行了系统研究,并开展了特征矿物包裹体的显微岩相学研究,旨在限定杂岩体母岩浆的演化路径,揭示稀土元素的富集机制。研究结果显示,赛马碱性杂岩体的母岩浆经历了由钾质碱性(角闪辉石正长岩、正长岩和黑云正长岩),到钾质过碱性(云霓霞石正长岩),向钠质过碱性(异霞正长岩)的充分演化。在演化过程中赛马碱性杂岩体母岩浆的体系状态发生了明显变化,碱性岩浆演化受流体不饱和的纯岩浆体系的控制,而过碱性岩浆岩则形成于流体过饱和的岩浆体系,且异霞正长岩母岩浆流体的饱和程度明显高于云霓霞石正长岩的母岩浆。研究还显示,钾质碱性岩浆稀土元素的地球化学行为主要受控于磷灰石等矿物的分离结晶,而成矿的钠质过碱性岩浆稀土、锆和铌等元素的富集成矿则主要受富CO_(2)的高盐度岩浆热液的控制。     

云南省香格里拉县甭哥碱性杂岩体岩石地球化学特征及其地质意义

云南省香格里拉地区发育一套以甭哥碱性杂岩体为代表的富碱高钾岩浆岩。该岩体SiO_2变化范围较宽,高FeO~T和碱质,低Al_2O_3、MgO和CaO;富集LILE和LREE,相对亏损HFSE并显著亏损Cr、Co、Ni等过渡族元素,同时还具有从弱负异常至强正异常的δEu及δCe,表现出埃达克质与岛弧型火山岩双重特征。岩石地球化学研究表明,甭哥岩体并非单一岩浆经简单结晶分异而来,其岩浆来源具有多样性与多期性,它们主要代表了晚三叠印支期俯冲洋片和地幔楔与下地壳部分熔融及新生代含金云母相的交代富集地幔低程度部分熔融的岩浆作用。其形成和演化大致经历了晚印支期初始岩浆形成和燕山期后续岩浆逐步叠加及新生代喜山期岩浆侵位三个阶段,在整个岩浆作用过程中,伴随有地幔流体交代作用及由此引发的壳幔物质混染现象。而与甭哥碱性杂岩体有关的金成矿作用主要受制于该区多阶段岩浆与含矿地幔流体的相互作用及地幔流体交代叠加混染作用,其金成矿的富矿体可能定位于深部,据此提出甭哥碱性杂岩体具有深部成矿的勘探开发远景。     

桂东南富钾岩浆岩岩的Nd同位素组成：华南中生代地幔物质上涌事件

广西东南部罗容杂岩体由辉长岩－闪长岩－二长岩－正长岩组成，马山由碱性辉长岩－正长岩－花岗闪长岩－花岗岩组成。它们富K、富大离子亲石元素（LIL），无Nb、Ta负异常等特征表明它们是形成于板内环境的钾玄质侵入岩。罗容杂岩体的各种岩石和马山的基性岩的εNd(T)稍低，为－0．6，此岩石单元是由幔源岩浆加热地壳使之熔融的壳源岩浆形成的，并伴有幔源岩浆的混合或交换。此二杂岩体形成于拉张构造环境。地幔物质上涌导致了中生代华南地壳张裂以及华南大规模花岗岩和相关矿床的形成。     

吉林省第三纪火山岩年代地层及构造环境

本文对吉林省第三纪年代地层、岩石地层、火山事件地层提出了新的划分方案。建立了15个火山事件地层序列。依据区域性地层角度不整合及构造岩浆活动的性质,划分出三个构造发展阶段。对比吉林省及邻区与日本列岛各阶段主要地质事件的特征,获得了第三纪的火山活动构造环境新认识：第一阶段（62～34Ma）总体上为挤压造山环境,由初期的弧后拉张转为后期的挤压,与太平洋板块的俯冲和斜冲地球动力学机制有关。第二阶段（34～5.2Ma）为拉张环境,受日本海盆的打开和演化直接控制。第三阶段（5.2～1.64Ma）为挤压抬升环境,对应着菲律宾海板块向日本岛弧下的俯冲。     

北祁连冷龙岭地区宁缠河花岗岩体的地球化学特征及大地构造意义

宁缠河花岗岩岩体位于北祁连中段,由两阶段侵入体构成,第一阶段侵入体具I型花岗岩特征,第二阶段侵入体为S型花岗岩。微量和稀土元素地球化学特征表明,岩体具有轻稀土富集型的球粒陨石标准化模式,两阶段侵入体形成于不同的构造环境,清阳河单元可能是在弧陆发生软碰撞时,岛弧型岩浆房中富含硅质的残余岩浆,在挤压应力下,快速上升侵入形成,下夹石及上池沟单元形成于同碰撞造山阶段。     

天津蓟县孙各庄碱性杂岩体年代学和岩石地球化学特征

通过对天津蓟县孙各庄碱性杂岩体开展系统的主量、稀土和微量元素岩石地球化学研究和高精度的锆石SHRIMP U-Pb测年研究,厘定岩体的形成时代,全面认识该区碱性岩浆活动的性质、物质来源和构造背景,并探讨其重要的地质意义。研究表明:孙各庄碱性杂岩体中正长岩的锆石SHRIMP U-Pb年龄为(225.6±1.1)Ma,形成于晚三叠世,为印支期碱性岩浆活动的产物。岩体主要岩石类型为碱性正长岩和正长辉石岩:前者高Al,富碱,贫Ca、Mg和Fe,为铝过饱和岩石;后者富碱,高Ca、Mg、Fe;均属于碱性-强碱性岩石,且相对富K。稀土元素总量高,轻、重稀土元素分馏明显,具极微弱的负Eu异常。微量元素富集大离子亲石元素Sr、Ba和轻稀土元素La、Ce、Pr、Nd、Sm,相对亏损高场强元素Nb、Ta、Hf和Th,正长辉石岩富集过渡族元素Cr、Ni和Co。由此表明:孙各庄碱性杂岩体形成于由挤压向伸展转变的引张型后碰撞构造环境,其岩浆物质来源与富集地幔相关,进而推测华北克拉通北缘早中生代岩石圈地幔具富集性。综合对比研究结果显示,华北克拉通北缘早中生代碱性岩浆活动的时间为238～220Ma。华北克拉通早中生代大规模的碱性岩浆活动可能与华北克拉通的破坏特别是岩石圈减薄具有相同的深部地球动力学背景。可以认为:华北克拉通北缘印支期碱性岩体的侵位时代238～220Ma可能代表华北克拉通岩石圈伸展减薄的起始时间,而且,岩石圈伸展减薄是从华北克拉通北缘西部开始的。     

华北克拉通减薄的岩浆岩响应:来自河北武安洪山含霓石斑状正长岩的证据

洪山碱性杂岩体出露于河北省邯郸市永年县,地处太行山南段,出露面积约53 km²,岩性以正长岩类为主体,侵位于晚古生代—中生代地层中。洪山碱性杂岩体中正长岩属于钾质的碱性系列岩石,形成于拉张环境,其形成年龄为(120.1±4.6) Ma,是华北克拉通岩浆作用峰期的产物。岩体稀土元素配分图中无Eu异常,表现为轻稀土元素富集的配分型式。富集Rb、K、Sr等大离子亲石元素,亏损Nb、Ta、Ti等高场强元素,具有大陆地壳特征。野外观察到岩石具有从深成到浅成-超浅成的特征,电子探针发现长石出现反环带,正长岩中不含继承锆石等特征,结合若要使地壳内岩石部分熔融产生无铕异常的正长质岩浆,那么压力应大于20 kbar,说明洪山碱性杂岩体形成于加厚地壳局部熔融,后经历了少量幔源岩浆混合及地幔流体的注入等过程,导致正长岩出现一定的地幔Hf、Nd同位素印记,而未改变其主微量元素特征,随后在拉张环境下快速上升至地表浅处。     

云南个旧似长石正长岩类及其岩石成因

云南个旧碱性岩体主要的岩石类型有碱性正长岩和似长石正长岩,其中,似长石正长岩中出现大量似长石矿物霞石、方钠石和碱性暗色矿物。本文根据矿物成分及特征,将这些似长石正长岩进一步划分为黑榴霞石方钠正长岩、霞石方钠正长岩、霞石正长岩及方钠霞石正长岩4类。岩石地球化学结果表明,4类岩石的地球化学行为整体表现出过碱质岩的特征,K2O+Na2O含量很高,为钾玄岩系列,同时表现出钾质的特点。分异指数高,呈现高度分异演化特点。稀土元素变化大,轻重稀土元素分异明显,富集轻稀土元素,亏损重稀土元素。微量元素富集大离子亲石元素Th、U及Zr、Hf等高场强元素,亏损Ba、Sr大离子亲石元素,而P和高场强元素Ta、Ti亏损,同时Cr、Co、Ni含量非常低,具有中等的负Eu异常和微弱的负Ce异常。研究表明,似长石正长岩在岩浆演化过程中表现出明显的分离结晶作用特征,且岩浆起源温度较高,约为835℃,起源较深。个旧似长石正长岩为A型岩套A1亚型,结合构造判别图解,认为其可能来自角闪石或者金云母相矿物存在的富集地幔,形成于燕山晚期伸展的构造背景,岩浆在较高温度下高度结晶分异,并在侵位过程中伴随陆壳成分的混染。     

西南三江甭哥金矿床磷灰石地球化学特征及地质意义

甭哥金矿床位于西南三江造山带北段的义敦弧南缘,属于与富碱侵入岩有关的金矿床。目前,对其成矿机理认识仍较为薄弱,制约了资源评价和找矿勘查进展。本文选取甭哥金矿床强矿化的正长斑岩和弱矿化的黑云辉石正长岩中的磷灰石作为研究对象,详细剖析磷灰石的地球化学特征,探讨其记录的成岩成矿信息。结果表明,磷灰石的稀土元素含量特征及配分模式显示富碱岩浆主要来自于壳幔混合的源区,黑云辉石正长岩中磷灰石的(La/Sm)N、(La/Yb)N、(Sm/Yb)N值和Sr含量呈正相关,说明长石结晶对岩浆结晶分异有重要的影响;正长斑岩中磷灰石具有高Sr/Y、Ce/Pb值,而Th/U、(Sm/Yb)N值较低,指示强烈的流体活动参与了岩浆结晶过程;磷灰石挥发分(F、Cl)含量及比值特征指示金矿成矿流体主要来自地幔源区,成矿与富碱、高氯的成矿流体有关。磷灰石Mn氧逸度计估算结果显示,甭哥富碱侵入岩具有高氧逸度特性,但两种不同岩性岩石的氧逸度具有差异性。其中,正长斑岩的logf_(O_2)值为-12～-10. 3,黑云辉石正长岩的logf_(O_2)值为-15. 5～-11. 1,磷灰石中SO_3含量及Ga含量也暗示正长斑岩的氧逸度高于黑云辉石正长岩的特征;结合磷灰石低Mn、Ga含量和高的Cl、SO_3含量,反映甭哥金矿床金的成矿是在高氧逸度条件下金氯络合物迁移、富集而沉淀的结果。因而,磷灰石的地球化学特征对金矿床成矿过程示踪和勘查评价具有重要的指示意义。     

Late Ediacaran post-collisional A-type syenites with shoshonitic affinities,northern Arabian-Nubian Shield: a possible mantle-derived A-type magma

The Abu Rumeil syenitic rocks represent the inner ring dyke of the Katherina Ring complex, southern Sinai, Egypt. They are divided petrologically into two types, alkali feldspar syenite and quartz syenite. The mineralogy and geochemistry of the syenites indicate an alkaline nature with a shoshonitic affinity. Although rare mafic xenocrysts overgrown by primary K-feldspars and overlapping rare earth element (REE) patterns indicate some role for crustal contamination, the trace element chemistry shows a dominant mantle contribution. The geochronology and field relations imply that the Abu Rumeil syenites were emplaced in a post-collisional, within-plate tectonic setting, yet they express the enrichments in large-ion lithophile elements relative to high field strength elements generally characteristic of subduction influence. We suggest that this signature is inherited from partial melting of a lithospheric mantle source previously affected by subduction during assembly of the Arabian-Nubian Shield. Little evidence of the early evolution of the suite is preserved; there are no associated mafic rocks. We therefore restrict our attention to a petrogenetic model that can explain the relations among the observed felsic composition. The REE patterns of all samples are enriched in light REE and fractionated, but it is notable that there are small positive Eu anomalies in the alkali-feldspar syenites contrasting with small negative Eu anomalies in the quartz syenites. Positive Eu anomalies suggest a cumulate nature for the alkali-feldspar syenites; there are also breaks in the slopes of most variation trends between the alkali-feldspar syenites and the quartz syenites. The general trends in all major oxides and trace elements within the suite can be modeled by fractional crystallization of feldspars—with smaller roles for pyroxene, biotite, apatite, and Fe-Ti oxides—from an intermediate liquid to form the quartz syenites and by assimilation of the near-liquidus phases into the same starting liquid to form the alkali feldspar syenites. The geothermobarometry of pyroxenes and amphiboles suggests shallow emplacement (<10 km depth) and crystallization temperatures ranging from 1100 °C down to 800 °C.     

Petrology,geochemistry and source characteristics of the Burpala alkaline massif,North Baikal

The Burpala alkaline massif contains rocks with more than 50 minerals rich in Zr,Nb,Ti,Th,Be and rare earth elements(REE).The rocks vary in composition from shonkinite,melanocratic syenite,nepheline and alkali syenites to alaskite and alkali granite and contain up to 10%LILE and HSFE,3.6%of REE and varying amounts of other trace elements(4%Zr,0.5%Y,0.5%Nb,0.5%Th and 0.1%U).Geological and geochemical data suggest that all the rocks in the Burpala massif were derived from alkaline magma enriched in rare earth elements.The extreme products of magma fractionation are REE rich pegmatites,apatite-fiuorite bearing rocks and carbonatites.The Sr and Nd isotope data suggest that the source of primary melt is enriched mantle(EM-Ⅱ).We correlate the massif to mantle plume impact on the active margin of the Siberian continent.     

攀西裂谷带中白马杂岩及其单矿物的稀土元素地球化学特征

稀土元素及锶同位素资料表明，形成白马杂岩体的母岩浆为玄武质岩浆，起源于上地幔，由被交代的上地慢橄榄岩经5％～10％部分熔融形成的；层状侵入体和正长岩为同源岩浆演化的产物；做榄石、单斜辉石和斜长石是岩浆演化早期最重要的堆积矿物；产于细粒辉长岩和层状辉长岩中的单斜辉石和斜方辉石，它们的Eu和Ce异常的差异，主要受控于矿物结晶时的氧化还原条件。     

辽西元古宙旧庙基性杂岩的地球化学特征及物源区讨论

辽西旧庙基性杂岩主要由二辉辉石岩、辉长苏长岩和角闪辉长岩组成。它们是由同源岩浆演化分离结晶作用为主形成的拉斑玄武系列。痕量元素、ＲＥＥ及Ｓｒ同位素的特征表明岩浆起源于富集型地幔源区。低的Ｎｉ、较高的Ｈ２Ｏ，说明初始岩浆起源于富含Ｈ２Ｏ的富集型地幔源区，在相对较低的温度下熔融形成。ｗ（Ｒｂ）／ｗ（Ｂａ）、ｗ（Ｒｂ）／ｗ（Ｓｒ）值变化较大，表明岩浆形成演化与下地壳物质曾发生强烈的混合     

Petrology of a mantle-derived rhyolite, Hokkaido, Japan

The Miocene Kitami rhyolite, consisting of orthopyroxene and plagioclase-phyric lavas and dikes, occurs on the back-arc side of the Kuril arc with coeval basalts and Fe-rich andesites. Temperatures estimated from orthopyroxene–ilmenite pairs exceed 900°C. Although the whole rock compositions of the Kitami rhyolite correspond to S-type granites (i.e., high K, Al, large ion lithophile elements, and low Ca and Sr), Sr–Nd isotope compositions are remarkably primitive, and similar to those of the coeval basalts and andesites. They are distinct from those of lower crustal metamorphic rocks exposed in the area. Comparison of chondrite-normalized rare earth element (REE) patterns between the rhyolite and the basalts and andesites show that the rhyolite is more light REE enriched, but has similar heavy REE contents than the basalts. All rhyolites show negative Eu anomalies. The geochemical data suggest that did not formed by simple dehydration melting of basaltic rocks or fractional crystallization of basaltic magmas. The features of slab-derived fluids expected from recent high pressure experimental studies indicates that mantle wedge is partly metasomatized with “rhyolitic” materials from subducted slabs; it is more likely that very low degree partial melting of the metasomatized mantle wedge formed the rhyolite magma.     

陕西商州地区丹凤变质火山岩的地球化学特征

陕西商州地区丹凤变质火山岩具有洋内岛弧火山岩地球化学特征,它们是分别来自不同源区的拉斑玄武和钙碱性2个系列共存的一套变质火山岩。其Th/Ta比值高及Ni、Ta、Ti、Y和Yb含量低,表明岩石受到消减带组分的影响。种种证据表明,丹凤变质火山岩是早古生代华北地块南缘消减带之上洋内岛弧环境的产物。     

西秦岭印支早期铁堂峡石英正长斑岩的地球化学特征及其地质意义

西秦岭东部发育大量小规模中酸性脉岩,但对这些脉岩的研究相对缺乏.在详细的野外观察和岩相学研究的基础上,对西秦岭天水铁堂峡石英正长斑岩进行了地球化学、锆石U-Pb年代学和Lu-Hf同位素研究.石英正长斑岩的锆石U-Pb定年结果表明它们的形成时代为~250 Ma,属印支早期岩浆产物.地球化学研究显示它们属于弱过铝质的高钾钙碱性岩系列,高Mg#,以富集Ba、Sr、K,强烈亏损Nb、Ta,且Eu异常不明显为特征.这些特征与埃达克岩的性质相似.铁堂峡石英正长斑岩的锆石ε_Hf（t）值介于-1.44~+3.17,一阶段Hf模式年龄（t_DM1）在765~945 Ma之间.铁堂峡石英正长斑岩形成于阿尼玛卿洋北向俯冲的大陆边缘弧环境,是俯冲洋壳及大洋沉积物熔体与上覆地幔楔作用的产物,并在浅部岩浆房中经历了轻微的分离结晶作用.      

Nd and Sr isotope signatures of the Khibina and Lovozero agpaitic centres, Kola Alkaline province, Russia

Nd and Sr compositions of the highly evolved agpaitic nepheline syenites and associated ijolites and carbonatites from the Khibina and the Lovozero alkaline centres define three magma sources. Isotopes of the voluminous nepheline syenites and ijolites of Khibina intrusions III, IV, V, VI and VII as well as of nepheline syenites of Lovozero lie on the Kola Carbonatite Mixing Line which is close to the “mantle array” defined by the components “bulk earth” and “prema” on a Sr---Nd plot. The Khibina carbonatites and associated silicate rocks of intrusion VIII, which have more radiogenic Sr, did not evolve from the same parent magma as the nepheline syenites.

Isotopic constraints exclude a pre-enrichment of Rb, Sr, Sm and Nd in the lithospheric mantle below Kola over more than 10 Ma prior to the crystallization of the magmas. A formation of the melts involving major participation of the Precambrian crust of the Baltic Shield is also excluded.

The lack of significant Eu anomalies in the Lovozero nepheline syenites gives evidence that the agpaitic magmas in the Kola region did not form from basaltic liquids by fractional crystallization of plagioclase or anorthoclase at crustal levels. A formation from nephelinite or nepheline benmoreite magmas at mantle pressures is more likely, possibly by dynamic flow crystallization.

Enrichment factors suggest that large-ion lithophile and high field-strength elements as Ta, La, Nb and Zr, which are highly concentrated in the agpaites, were scavenged from mantle volumes of some 100,000 km³. An enrichment of these elements prior to magma formation may have been performed by volatile transfer.

The well-defined whole-rock isochrons of the Khibina III–VII and the Lovozero agpaites of c. 370 Ma date the magma separation for the different intrusion, if these melts are cogenetic and formed by fractional crystallization in a Khibina and a Lovozero magma chamber. If, however, Rb and Sr were collected by a process of volatile transfer, and the initial Sr isotopic compositions of the two distinguished agpaite suites are, therefore, averages of the sampled mantle volumes, the Rb---Sr whole-rock isochron ages of c. 370 Ma would date this process of element collection. The concordance of the whole-rock ages with the mineral ages of Khibina and Lovozero samples is then further evidence for the short period between magma genesis, intrusion and crystallization.