新疆北部大地构造演化阶段与斑岩－浅成低温热液矿床的构造环境类型

本文系统总结了新疆北部斑岩-浅成低温热液矿床的成矿时代,按构造环境将该类矿床归为三大类型:洋-陆俯冲型、碰撞造山型、板内型,其中碰撞造山型又可分为碰撞型和后碰撞型。4类矿床的差别主要在于矿床金属元素组合,以及同期相伴出现的矿床类型不同:俯冲型斑岩矿床以斑岩Cu-Au矿-浅成低温热液Au矿组合为主,以伴有海相火山岩有关的VMS矿床和铁矿为特征;碰撞型和后碰撞型矿床以斑岩Cu-Mo-Au组合为主,伴有构造蚀变岩型复合/叠加的浅成低温热液型Au矿出现;板内型矿床以斑岩型单Mo(或Mo-Re)组合为主。斑岩矿床与浅成低温热液矿床虽为同一成矿系统,但二者基本不共生,且后者成矿时代一般晚于前者10～20 Ma。斑岩-浅成低温热液矿床的含矿岩石和成矿特征并不随构造环境类型不同而出现特征性差别。不同时期的斑岩矿床在分布上具有继承性和"同位成矿"特点,并表现出一定的分带性,从早到晚逐渐由靠近缝合带向外扩展、由线型分布逐渐趋于面型分布。     

中亚成矿域斑岩铜矿床基本特征

中亚成矿域发育许多大型和超大型斑岩铜矿床,是世界上重要的斑岩铜矿成矿域。我们对9个大型和超大型斑岩铜矿床进行了研究,包括地质特征、含矿岩体地球化学、SIMS锆石U-Pb定年和成矿流体成分等,结合前人成果,我们认为中亚成矿域斑岩铜矿床具有如下特点:(1)成矿时代为古生代和中生代,成矿高峰期为泥盆纪和石炭纪;(2)含矿岩浆为钙碱性中酸性岩浆和少量的碱性岩浆,含矿岩体为花岗闪长岩、闪长岩、英云闪长岩和少量的二长岩;(3)含矿岩浆大多数源于新生的洋壳,少量有古老的基底物质和围岩物质参与;(4)成矿构造背景主要为岛弧,少量为陆缘弧和岛弧向陆缘弧过渡的环境;(5)矿床可分为三类,包括斑岩型Cu-Au、Cu(Au,Mo)和Cu-Mo矿床;(6)成矿流体可分为两类,包括氧化性H2O-Na Cl-CO2-SO2体系和少量的还原性H2O-Na Cl-CH4-CO2体系;(7)成矿系统可分为三类,包括简单的斑岩系统和少量的斑岩-矽卡岩成矿系统和斑岩-浅成低温热液成矿系统。     

中国大陆环境斑岩型矿床：基本地质特征、岩浆热液系统和成矿概念模型

中国大陆环境斑岩型矿床包括斑岩型Cu(-Mo、-Au)、斑岩型Mo、斑岩型Au和斑岩型Pb-Zn等矿床类型,主要产出于青藏高原大陆碰撞带、东秦岭大陆碰撞带和中国东中部燕山期陆内环境,在地球动力学背景、深部作用过程、岩浆起源演化、流体与金属来源等方面与岩浆弧环境斑岩型矿床存在重要差异.在大洋板块俯冲形成的岩浆弧,主要发育斑岩Cu-Au矿床或富金斑岩Cu矿(岛弧)和斑岩Cu-Mo及斑岩Mo矿床(陆缘弧).相比,在大陆碰撞带,晚碰撞构造转换环境发育斑岩Cu、Cu-Mo和Cu-Au矿床,矿床受斜交碰撞带的走滑断裂系统控制,后碰撞地壳伸展环境则主要发育斑岩Cu-Mo矿床,矿床受垂直于碰撞带的正断层系统控制;在陆内造山环境,早期发育斑岩Cu-Au矿床,晚期发育斑岩Pb-Zn矿床,它们主要沿古老的但再活化的岩石圈不连续带分布,受网格状断裂系统控制;在后造山(或非造山)伸展环境,则大量发育斑岩Mo矿和斑岩Au矿,它们则主要围绕大陆基底-克拉通(或地块)边缘分布,受再活化的岩石圈不连续带控制.大陆环境斑岩Cu(-Mo,-Au)矿床的含矿斑岩多为高钾钙碱性和钾玄质,以高钾为特征,显示埃达克岩地球化学特性.岩浆通常起源于加厚的新生镁铁质下地壳或拆沉的古老下地壳.上地幔通过三种可能的方式向岩浆系统供给金属Cu(和Au):①提供大批量的幔源岩浆并底垫于加厚下地壳底部,构成含Cu岩浆的源岩;②提供小批量的软流圈熔体交代和改造下地壳,并诱发其熔融;③与拆沉的下地壳岩浆熔体发生反应.大陆环境含Mo岩浆系统高SiO_2、高K_2O,岩相以花岗斑岩为主,花岗闪长斑岩次之,既不同于Climax型,又有别于石英二长斑岩型Mo矿床,岩浆起源于古老的下地壳.金属Mo主要为就地熔出,部分萃取于上部地壳.大陆环境含Pb-Zn花岗斑岩多属铝过饱和型,与S型花岗岩相当,以高δ~(18)O(>10‰)和高放射性Pb为特征,Sr-Nd-Pb同位素组成反映其来源于中下地壳的深熔作用,金属Pb-Zn主要来源于深融的壳层.大陆环境含Au岩浆系统以富B花岗闪长斑岩为主,常与矿前闪长岩密切共生.Sr-Nd-Pb同位素显示,含Au岩浆主要来源于上部地壳,但曾与幔源岩浆发生相互作用.金属Au部分来源于上地壳,部分来源于地幔岩浆.大陆环境斑岩型矿床显示各具特色的蚀变类型和蚀变分带,其中,斑岩型Cu(-Mo,-Au)矿热液蚀变遵循Lowell and Guilbert模式;斑岩型Mo矿主要发育钙硅酸盐化、钾硅酸盐化和石英-绢云母化;斑岩型Pb-Zn矿主要发育绿泥石-绢云母化和绢云母-碳酸盐化,缺乏钾硅酸盐化;斑岩型Au矿强烈发育中度泥化.斑岩型矿床的成矿流体初始为高温、高fO_2、高S、富金属的岩浆水,由浅成侵位的长英质岩浆房在应力松弛环境下出溶而来,晚期有天水不同程度地混入.Cu、Mo、Pb-Zn通常沉淀于流体分相和流体沸腾过程中,而Au则主要沉淀于岩浆-热液过渡阶段.     

云南普朗斑岩铜矿晚三叠世构造控矿条件

普朗铜矿是义敦岛弧东多金属矿带的超大型斑岩型铜矿床.成矿带内岩浆构造活动频繁,裂隙构造叠加成矿-控矿作用显著,但研究程度薄弱.在对普朗铜矿区巷道进行构造岩相学综合调查研究的基础上,结合区域成矿构造背景,厘定矿区褶皱、断裂宏观特征,对典型中段进行节理（裂隙）测量分析.研究表明：1）古特提斯洋闭合过程斑岩铜矿成矿作用与晚三叠世构造演化、岩浆活动关系密切,普朗铜矿形成于俯冲造山阶段;2）区域深大断裂控制着矿区沉积建造和岩浆岩分布,矿床总体产于普朗背形核部,次级NEE及NE向断裂控制着含矿斑岩体和节理（裂隙）的发育,矿（化）体赋存于两组断裂交汇部位;3）矿区以张节理为主的复合型节理系统,为含矿热液的运移、扩散和富集提供导矿、储矿空间,裂隙发育程度与铜矿化呈正相关.通过对矿区岩浆侵入-构造裂隙系统特征与控矿规律的研究,认为热液脉状矿（化）体严格受控于构造-裂隙系统改造富集作用,裂隙构造发育部位是探寻富"脉状矿"的有利靶区.     

长江中下游成矿带陆内斑岩型矿床的成岩成矿作用

陆内环境斑岩型矿床的发现对斑岩成矿理论的完善具有重要意义。长江中下游成矿带作为中国东部重要的陆内成矿带之一,成矿带内发育多个重要的斑岩型矿床,如铜山口Cu-Mo矿床、鸡冠嘴Cu-Au矿床、白云山Cu矿、城门山Cu-Mo矿床、武山Cu-Mo矿床、丰山洞Cu-Au矿床、丁家山Cu矿、洋鸡山Au矿、沙溪Cu-Au矿床、冬瓜山Cu-Au矿床、舒家店Cu矿床和安基山Cu矿床等。本文选取成矿带内典型的、具有代表性的斑岩型矿床,对其地质特征(地层、构造、含矿斑岩、脉体特征和围岩蚀变)、成岩成矿年代、成矿岩体的岩石化学和成岩成矿地球化学等方面的研究资料和成果进行了系统总结,讨论和试图阐明长江中下游成矿带陆内斑岩型矿床的成岩成矿作用与成矿模式。研究显示,长江中下游成矿带形成于燕山期陆内造山过程,成矿斑岩岩浆活动和成矿作用主要发生于149~105Ma之间,进一步可以分为早、中、晚三阶段:149~135Ma、133~125Ma和123~105Ma,三阶段岩浆活动和成矿作用主要发生于成矿带中的断隆区,早阶段(149~135Ma)和晚阶段(123~105Ma)多为斑岩-矽卡岩型矿化,中阶段(133~125Ma)矿化为典型的斑岩型矿化。长江中下游成矿带内斑岩型矿床的含矿斑岩为高钾钙碱性-钙碱性系列岩石,大部分具有埃达克岩的地球化学特征,可能为源自富集地幔的岩浆和加厚下地壳部分熔融的岩浆混合的产物,源自富集地幔的基性岩浆对成矿具有至关重要的作用,它的混入使得混合岩浆富水、硫和金属(Cu、Au)等。进一步通过与岩浆弧环境的斑岩型矿床对比研究发现,长江中下游成矿带斑岩型矿床一般不发育高级泥化岩帽(advanced argillic liithocaps)以及浅部的高-中硫矿化蚀变系统,含矿岩浆源区性质和成矿物质来源等与岩浆弧环境的斑岩型矿床明显不同。     

新疆哈图-包古图金铜矿集区锆石年龄及成矿特点

晚古生代,新疆西准噶尔地区发生了强烈的构造-岩浆活动和广泛的金、铜成矿作用,形成了哈图-包古图大型金铜矿集区。锆石SHRIMP U-Pb年龄测量表明,含矿闪长岩体形成于312.3±2.2Ma～332.0±2.8Ma,矿集区岩浆活动及其成矿作用发生在石炭纪。哈图-包古图矿集区成矿作用有4个显著特点:(1)地幔流体活动强烈;(2)构造应力转化快速;(3)拉斑系列和钙碱性系列岩浆成矿;(4)多种矿化类型集中发育等。哈图-包古图矿集区发育石英脉型-蚀变岩型金矿床、斑岩型铜矿床和同期的石英脉型-蚀变岩型金矿床以及热液脉型铜金矿床的成矿系列。     

中亚成矿域核心区斑岩铜矿地质和地球化学特征研究现状综述

中亚成矿域核心区域发育多个斑岩型铜矿床,集中分布于哈萨克斯坦环巴尔喀什、中国新疆西准噶尔和东天山地区。笔者从成矿斑岩岩石学、地球化学、岩浆性质、矿床地质和成矿流体性质等方面,对以上地区主要斑岩铜矿的研究现状进行了总结,并概括了境内外斑岩铜矿床的异同。中亚成矿域核心区斑岩铜矿含矿斑岩主要为闪长岩、闪长玢岩、花岗闪长斑岩和石英二长岩,属钙碱性或高钾钙碱性系列,除哈萨克斯努尔卡斯甘外,大多具有埃达克岩的地球化学特征。哈萨克斯坦环巴尔喀什地区和中国西准噶尔、东天山地区斑岩铜矿成矿斑岩结晶温度主要集中在668～836℃,斑晶相结晶压力为0.8～3.2kbar(对应深度2.4～8.8km),环巴尔喀什地区成矿斑岩(ΔQFM=2.9～4.8)具有明显高于西准噶尔和东天山地区(ΔQFM=0.3～1.8)的岩浆氧逸度。中亚成矿域核心地区含矿斑岩的(~(87)Sr/~(86)Sr)i=0.702 5～0.706 7,εNd(t)=4.9～8.8,显示含矿岩体主要来源于新生洋壳,可能伴随古老基底物质的参与。矿区发育以钾化、绢英岩化和青磐岩化为主的热液蚀变,努尔卡斯甘矿区发育与高级泥化有关的高硫型浅成低温热液型金矿化。矿床地球化学研究显示区内斑岩铜矿硫化物的硫主要为岩浆硫(δ~(34)S=-5‰～2‰)。环巴尔喀什地区和中国东天山土屋-延东斑岩铜矿成矿流体为氧化性的H_2O-NaCl-CO_2-SO_2体系,西准噶尔包古图为还原性的H_2O-NaCl-CO_2-CH_4体系。     

初论碰撞造山环境斑岩铜矿成矿模型

作为金属Cu最主要来源的斑岩铜矿床主要产于岛弧及陆缘弧环境.基于大量弧环境斑岩铜矿床研究而建立的经典斑岩铜矿成矿模型,在后来环太平洋成矿带斑岩型矿床的勘查中取得了重大突破,成为科学理论指导矿床勘查的典范.然而,近年来国内矿床学家发现,除经典成矿模型所记录的岛弧及陆缘弧环境外,斑岩铜矿还可产于碰撞造山带内,甚至产在陆内环境中.显然,这些斑岩铜矿的成因无法用经典的斑岩铜矿成矿模型解释.文章从弧环境斑岩铜矿成矿模型的综述人手,通过对青藏高原斑岩铜矿床的成矿环境及构造控制、含矿斑岩起源、矿床基本特征、成矿物质来源、金属富集机制以及成矿流体来源及演化等已有研究成果的综合分析,初步提出了碰撞造山环境斑岩铜矿的成矿模型.该模型强调:①碰撞造山环境斑岩铜矿含矿斑岩为强烈挤压构造背景下形成的埃达克岩,岩浆起源于加厚的新生下地壳,板块断离或岩石圈拆沉诱发的软流圈物质上涌,以及斜向碰撞导致的挤压.伸展的构造机制转换通常是引发岩浆源区发生部分熔融的外部条件;②成矿金属的深部富集是因岩浆高氧逸度所致,高氧逸度条件下,S主要以硫酸盐的形式溶解于岩浆之中,从而导致通常优先向硫化物分配的Cu、Au等开始作为不相容元素向硅酸盐熔浆中富集;③含矿斑岩的侵位既可受到因斜向碰撞诱发的大型走滑断裂系统的控制,也可受到岩石圈拆沉诱发的大型张性断层的控制;而含矿斑岩的就位则受矿区尺度的构造控制,多组构造的交汇部位或大型背斜的核部常是斑岩铜矿产出的重要位置;④大型矿床,特别是超大型矿床下部通常存在岩浆房,岩浆房的流体出溶是引发矿床大规模蚀变与矿化的根源;成矿金属与S均来自岩浆,与含矿斑岩可能具有相同的源区;⑤矿床整体上具有与弧环境类似的蚀变分带规律,从内向外依次为钾硅酸盐化、石英-绢云母、粘土化及青磐岩化;不过,因碰撞造山带环境含矿斑岩相对富K,从而导致岩浆房或浅侵的岩株/岩枝中出溶的岩浆热液常具有比弧环境斑岩铜矿床更高的K+/H+比值,从而诱发钾硅酸盐化蚀变的强烈发育;因钾硅酸盐化蚀变持续时间较长,铜钼矿化主要产于该蚀变阶段,特别是以黑云母大量发育为特征的晚期钾硅酸盐化阶段;⑥成矿物质沉淀可能因成矿过程中温度、压力、盐度、氧逸度、pH值等因素的变化所致,而这些因素的变化又直接或间接与高原的快速隆升与剥蚀有关.     

斑岩Cu-Mo-Au矿床:新认识与新进展

斑岩型矿床作为一种最重要的铜钼和铜金矿床类型一直得到人们的普遍重视 ,近些年来又取得了重要研究进展 ,主要体现在 5个方面 :①岛弧和陆缘弧是斑岩型矿床产出的重要环境 ,但大陆碰撞造山带也具有产出斑岩型矿床的巨大潜力。按矿床产出的构造环境 ,可以分为弧造山型斑岩矿床和碰撞造山型斑岩矿床 ;②弧造山型含矿斑岩主要为钙碱性和高钾钙碱性 ,而碰撞造山型含矿斑岩则主要为高钾钙碱性和橄榄安粗质 (shoshonitic)。两种环境的含矿斑岩多具有埃达克岩 (adakite)岩浆亲合性 ,但前者主要来源于俯冲的大洋板片 ,后者主要来源于碰撞加厚的下地壳。大洋板片的部分熔融缘于俯冲角度的平缓化 ,而加厚下地壳的熔融起因于俯冲大陆板片的断离 (slabbreakoff) ;③在弧造山环境 ,大洋俯冲板片的膝折 (kink)或撕裂 (slabtear)不仅导致俯冲角度变缓 ,而且引起弧地壳耦合变形 ,产生切弧断裂 ,控制斑岩铜系统的时空分布。俯冲板片撕裂引发软流圈上涌 ,诱发大洋板片熔融 ,产生含矿岩浆 ;④在碰撞造山环境 ,大陆俯冲板片的裂离导致软流圈上涌 ,向下地壳注入新生物质 ,并诱发下地壳物质熔融 ,产生含矿岩浆。碰撞后地壳伸展形成横切碰撞带的正断层系统 ,为斑岩侵位提供运移通道 ,并导致岩浆流体大量分凝和铜钼金淀积。不论     

环巴尔喀什-西准噶尔成矿省矿床类型、成矿系统和跨境成矿带对接

环巴尔喀什-西准噶尔成矿省地处中亚成矿域核心区,古生代构造和岩浆活动强烈,成矿作用丰富多样,发育许多大型-超大型乃至世界级的金属矿床,包括斑岩型铜矿床、斑岩-石英脉-云英岩型钨钼矿床、矽卡岩型铜(多金属)矿床、火山成因块状硫化物型(VMS)多金属矿床、浅成低温热液型金矿床、石英脉-蚀变岩型中温热液金矿床、与花岗岩有关的Be-U矿床、岩浆熔离型铜镍硫化物矿床和豆荚状铬铁矿等,这些矿床集中分布,形成多处成矿带,包括哈萨克斯坦的扎尔玛-萨吾尔、波谢库尔-成吉斯和北巴尔喀什等成矿带以及新疆西准噶尔的萨吾尔、谢米斯台-沙尔布提和巴尔鲁克-克拉玛依等成矿带。哈萨克斯坦包含大型-超大型和世界级金属矿床的成矿带向东是否延入新疆西准噶尔?能否实现新疆西准噶尔找矿重大突破?都是备受关注的重大地质找矿问题。本文在前人研究并结合作者工作基础上,根据成矿带的成矿构造环境、矿床类型、成矿特点和成矿时代,总结出成矿省至少发育九类成矿系统,即(1)奥陶纪-志留纪岛弧斑岩型Cu-Au成矿系统;(2)奥陶纪岛弧VMS型多金属成矿系统;(3)泥盆纪岛弧岩浆熔离型铜镍硫化物成矿系统;(4)泥盆纪与蛇绿岩有关的豆荚状铬铁矿成矿系统;(5)早石炭世岛弧斑岩-浅成低温热液型Cu-Au成矿系统;(6)石炭纪岛弧斑岩型-矽卡岩型Cu-Mo-Au成矿系统;(7)晚石炭世弧后盆地与花岗岩有关的Be-U成矿系统;(8)早二叠世岛弧或岛弧和陆缘弧过渡弧斑岩-石英脉-云英岩型Mo-W成矿系统;(9)早二叠世岛弧石英脉-蚀变岩型中温热液金成矿系统。对比研究发现境内外相邻成矿带具有相同或相似的成矿系统,二者可以对接,新疆西准噶尔三条成矿带分别是哈萨克斯坦三条成矿带的东延部分,构成了成矿省北部的扎尔玛-萨吾尔Cu-Au成矿带、中部的波谢库尔-成吉斯-谢米斯台Cu-Au-Be-U多金属成矿带和南部的北巴尔喀什-克拉玛依Cu-Mo-W-Au-Cr成矿带。新疆西准噶尔具有形成大型-超大型矿床的成矿系统和成矿条件,有望实现找矿勘探的更大突破。     

Wavelength-dispersive X-ray fluorescence spectrometric determination of Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites

Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.     

高压微波消解法测定醋酸纤维过滤器采集的微尘粒子中的砷镉钴铬铜铁锰镍铅钒锌

最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.     

硅酸盐中铁、锰、钛、钙、钾、磷、硅、铝、镁、钠、锶、铷、钡的X-射线荧光光谱定量测定

本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。     

硅酸盐类样品中硅、铁、铝、钛、锰、钙、镁、钾、钠和磷的x射线荧光光谱测定

本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。     

Viscous, cohesive, non-Newtonian, depositing, radial slurry flow

Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.     

岩石密度和超高压岩石折返速率

在常温常压条件下对中国大陆科学钻CCSD主孔100-3000米岩心样品进行了密度测量,建立了密度连续剖面,并界定了不同超高压岩石的密度值。通过对比高温高压物性实验资料,岩石密度随着退变程度增强而降低,榴辉岩密度变化序列为3.52g/cm3→3.49g/cm3→3.07g/cm3→2.93g/cm3。超高压长英质岩石密度变化序列为3.00g/cm→2.80g/cm3→2.65g/cm3。上述实验资料是讨论不同折返阶段岩石所受浮力的基础,为研究折返速率大小提供了基本参数。本文通过折返板块运动平衡时,上浮力与粘滞力平衡这一关系式,定量研究了大陆俯冲板块的折返速率,认为密度差产生上浮力从而引起折返,温度对板块折返速率的影响最为显著;密度差大小、折返角度、折返板块大小对折返速率也有直接的影响。定量模拟分析表明,在温度高于850℃时,板块的折返速率可以超过100mm/a;当温度降至700℃时,折返速率则低于1.5mm/a。作者认为在折返早期,温度较高,板块快速折返至60-70km榴辉岩相深度;随着传导散热,温度降低,板块以较慢的速率折返至中下地壳。折返速率的估算表明,浮力是板块折返第一阶段(从>100km深部折返至<40km的中下地壳)的主要驱动力。     

Regional distribution of Al,B, Ba,Ca, K,La, Mg,Mn, Na,P, Rb,Si, Sr,Th, U and Y in terrestrial moss within a 188,000 km2 area of the central Barents region: influence of geology,seaspray and human activity

Five hundred and ninety-eight samples of terrestrial moss (Hylocomium splendens and Pleurozium schreberi) collected from a 188,000 km² area of the central Barents region (NE Norway, N Finland, NW Russia) were analysed by ICP-AES and ICP-MS. Analytical results for Al, B, Ba, Ca, K, La, Mg, Mn, Na, P, Rb, Si, Sr, Th, U and Y concentrations are reported here. Graphical methods of data analysis, such as geochemical maps, cumulative frequency diagrams, boxplots and scatterplots, are used to interpret the origin of the patterns for these elements. None of the elements reported here are emitted in significant amounts from the smelting industry on the Kola Peninsula. Despite the conventional view that moss chemistry reflects atmospheric element input, the nature of the underlying mineral substrate (regolith or bedrock) is found to have a considerable influence on moss composition for several elements. This influence of the chemistry of the mineral substrate can take place in a variety of ways. (1) It can be completely natural, reflecting the ability of higher plants to take up elements from deep soil horizons and shed them with litterfall onto the surface. (2) It can result from naturally increased soil dust input where vegetation is scarce due to harsh climatic conditions for instance. Alternatively, substrate influence can be enhanced by human activity, such as open-cast mining, creation of ‘technogenic deserts’, or handling, transport and storage of ore and ore products, all of which magnify the natural elemental flux from bedrock to ground vegetation. Seaspray is another natural process affecting moss composition in the area (Mg, Na), and this is most visible in the Norwegian part of the study area. Presence or absence of some plant species, e.g., lichens, seems to influence moss chemistry. This is shown by the low concentrations of B or K in moss on the Finnish and Norwegian side of the (fenced) border with Russia, contrasting with high concentrations on the other side (intensive reindeer husbandry west of the border has selectively depleted the lichen population).     

NEW SET OF LOW CONCENTRATION STANDARDS FOR LA, CE, SM, YB, LU, Y, SC, V, NB AND TA IN SILICATES

We have developed a set of four synthetic standards for the rare earth and high field strength elements designed for use in the determination of those elements in silicates. The base material is a glass nominally at the eutectic of the MgO-Al₂O₃-SiO₂ ternary system. The nominal doping level was 2 wt% of the elements as oxides. To avoid problems associated with peak interference, the elements were doped in four separate glasses.