广西花山-姑婆山燕山期花岗岩的地球化学特征及成因研究

广西花山-姑婆山燕山期花岗岩体以高硅、高钾、富碱、低磷、准铝质为特征，具有较高的TFeO/MgO值，富集大离子亲石元素、高场强元素和稀土元素，普遍出现褐帘石，应归属于富钾的钙碱性花岗岩（KCG）系列岩石，相当于高钾钙碱性I型花岗岩。产生于后造山陆内挤压向拉张转换的地球动力学背景下，其形成与岩石圈伸展-减薄、亏损地幔岩浆的上涌和富含金云母-钾质碱镁闪石的岩石圈地幔的部分熔融有关。     

粤北花山岩体地球化学特征及成因研究

通过对花山岩体主量元素、微量元素和稀土元素等方面详细的综合研究、以及分析对比可知,岩体Si O2含量在69.9%⁷2.96%,属于酸性岩体,(中)高钾钙碱性系列岩石,具硅过饱和、过铝的特征。岩石属富轻稀土型花岗岩,Eu亏损不明显。花山岩体属I型花岗岩(同熔型),是活动大陆边缘-陆弧的产物。     

粤北花山岩体地球化学特征及成因研究

通过对花山岩体主量元素、微量元素和稀土元素等方面详细的综合研究、以及分析对比可知,岩体Si O2含量在69.9%~72.96%,属于酸性岩体,(中)高钾钙碱性系列岩石,具硅过饱和、过铝的特征。岩石属富轻稀土型花岗岩,Eu亏损不明显。花山岩体属I型花岗岩(同熔型),是活动大陆边缘-陆弧的产物。     

与内蒙哈达特陶勒盖铅锌矿有关的花岗岩成因探讨

哈达特陶勒盖铅锌矿床处于华北板块与西伯利亚板块交汇部位,是二连浩特-东乌珠穆沁旗多金属成矿带中新发现 的一个中型铅锌矿床。矿区内与Pb-Zn矿化有关的花岗岩为隐伏岩体,LA-ICP-MS 锆石U-Pb 定年显示,花岗岩侵入时间为 （125±4.3）Ma,属于燕山期岩浆活动产物。岩石地球化学分析表明,花岗岩具有高硅、高碱（大部分Na相似文献   

华北地块南缘花山、五丈山岩体LA-ICP-MS锆石U-Pb年龄、地球化学特征及成因

花山复式岩体位于华北地块南缘,采用LA-ICP-MS技术测得复式岩体中的中细粒似斑状黑云二长花岗岩的锆石U-Pb年龄为128±1Ma,此年龄被解释为成岩年龄。该岩体及邻近的五丈山岩体中花岗岩具有高硅、富碱特征,为准铝-弱过铝质高钾钙碱性系列;在稀土和微量元素上,富集LREE、Rb、Ba、K、Sr等大离子亲石元素,亏损HREE、Zr、Hf、Ta、Nb、P、Ti等高场强元素,总体上Eu异常不明显,显示出I-A过渡型花岗岩的特征。锆石Lu-Hf同位素组成表明,花山花岗岩的ε_Hf(t)主要变化于-25.8~-19.6之间,t_DM2为2.81~2.43Ga,显示源区物质以古老的壳源物质为主,有年轻组分的参与。与岩体外围多金属成矿年龄的对比分析发现,外围金、钼矿床与花山复式岩体的年龄一致,比五丈山岩体晚20~25Ma,表明金、钼矿的形成与花山岩体在时空上联系密切,该岩体可能为成矿提供了热源。     

河南熊耳山地区花山花岗岩与金矿化的关系

熊耳山地区是豫西重要的金矿化集中区。通过对该区花山花岗岩的化学组成、微量元素、稀土元素、稳定同位素特征及与金矿化关系的研究,得出如下主要研究成果：（1）在R型聚类分析谱系图上表明岩体中Au、Ag、Pb、Cu、Ba元素与金矿床微量元素相关性趋于一致;（2）在稀土元素配分模式图上表现出花岗岩和蚀变岩具有相似的右倾配分曲线的特征;（3）在流体包裹体的w(Na⁺)-w(K⁺)-w(Ca²⁺+Mg²⁺)成分三角图上表明金成矿流体和岩浆热液具亲缘关系;（4）岩体线性构造控制了花山地区构造蚀变岩型和爆破角砾岩型金矿床的时空分布;（5）金矿床的成矿时代为燕山期,花山花岗岩的成岩时间集中于81～159 Ma;（6）S、H、O、Pb同位素组成表明成矿物质和成矿流体来自岩浆热液。     

豫西花山花岗岩基岩石学和地球化学特征及其成因

花山花岗岩岩基是燕山期在华北地台南缘发生的陆内挤压俯冲作用的产物。组成该岩基的万村、蒿坪和金山庙岩体的矿物学、岩石化学、稀土及微量元素地球化学特征均可以与Ⅰ型（或华南同熔型）花岗岩相类比，反映出该地壳重熔成因的花岗岩对源岩──变质的中基性火山岩（太华群）的继承作用。因此，在划分花岗岩类的成因类型时，应考虑到其形成的地质背景、源岩性质及成岩方式等因素。     

山东沂水紫苏花岗岩特征-形成时代及成因探讨

通过对山东沂水地区紫苏花岗岩野外地质特征、岩相学及地球化学特征等的研究,认为山东沂水地区紫苏花岗岩为变质表壳岩经深熔作用形成．其主要证据为：（１）紫苏花岗岩与变质表壳岩在空间上密切伴生,二者多为渐变过渡接触关系,且他们的片麻理协调一致;（２）在变质表壳岩中发育大量长英质或花岗质脉体,这些脉体的矿物成分、地球化学特征与紫苏花岗岩一致;（３）紫苏花岗岩与变质表壳岩具有相似的稀土配分型式;（４）紫苏花岗岩亏损大离子亲石元素及生热元素,其原岩应为经历了深变质作用的岩石;（５）紫苏花岗岩中锆石多为圆粒状和椭球状,并发育磨蚀坑,说明其原岩主要为变沉积岩;（６）麻粒岩相变质作用时间与紫苏花岗岩形成时间基本一致．     

云南个旧神仙水岩体锆石U—Pb年代学及岩石地球化学研究

云南个旧地区花岗岩极其发育,且与锡成矿关系密切。其中个旧西区神仙水花岗岩体呈岩株状,岩性主要为碱长花岗岩和正长岩。岩石地球化学研究表明,神仙水花岗岩具有高硅、贫钙镁、富碱的特征;ω（TFeO）／ω（MgO）和ω（Na2O＋K2O）／ω（A12：O3）比值高。富集大离子亲石元素Rb、n、u、K、La、Nd和高场强元素zr、Hf,亏损Ba、sr、Ta、P、Ti。Eu负异常较强,轻稀土富集,重稀土相对亏损,稀土配分模式呈右倾海鸥型,岩石类型属于A型花岗岩。锆石LA—ICP．Ms定年结果表明神仙水花岗岩体形成于81Ma左右,相当于晚白垩世。根据区域地质和花岗岩地球化学特征,判断其形成于伸展构造环境。     

南岭稀土花岗岩、钨锡花岗岩及其成矿作用的对比

南岭地区的钨锡和稀土矿床都与花岗岩类有直接成因联系,但二者的成矿作用有许多不同之处.钨锡是典型的热液成矿,而稀土则主要形成于风化作用.随着花岗岩类的分异演化,岩石中的W、Sn等元素含量逐渐增加,因此钨锡等矿床主要与高度分异演化的晚阶段小岩体有关;但是稀土的表现与钨锡不同,由于花岗岩类的分异演化导致稀土栽体黑云母及许多副矿物的减少,因此稀土元素含量在晚阶段岩体中反而降低.赣南的五里亭-大吉山岩体、桂东北的花山-姑婆山岩体等提供了很好的范例.因此,南岭地区与风化壳型稀土矿床有关的岩石主要有:印支期准铝质花岗岩,燕山期A型花岗岩,燕山中-晚期黑云母二长花岗岩等.     

西藏冈底斯带阿索构造混杂岩南侧亚布努马花岗斑岩地球化学特征及锆石U-Pb年龄

西藏中冈底斯北部尼玛县阿索乡亚布努马地区东侧出露一处花岗斑岩岩脉,LA-ICP-MS锆石U-Pb测年结果显示,该花岗斑岩的形成时代为晚侏罗世(161.2±5.9Ma)。全岩地球化学数据显示其高硅、富碱、富铝的特征,属于碱性准铝质花岗斑岩;富集轻稀土元素,轻、重稀土元素分异明显,具有明显的负Eu异常,富集Rb、Pb等大离子亲石元素,亏损Ba、Sr元素及Nb、Ta、Ti、U等高场强元素,形成于岛弧环境。其源区可能为来自俯冲带增厚下地壳的深熔作用,结合区域上同时代的岩浆事件,亚布努马花岗斑岩应该形成于以班公湖-怒江洋南向俯冲为动力背景的陆缘弧环境。     

Regional Tectonic Transformation in East Kunlun Orogenic Belt in Early Paleozoic: Constraints from the Geochronology and Geochemistry of Helegangnaren Alkali-feldspar Granite

The Helegangnaren feldspar granite exposed in the eastern part of East Kunlun, is characterized by high concentrations of SiO2 and alkaline, low abundances of Fe, Mg and Ca, metaluminous-weak peraluminous. Trace elements analysis shows that the granite is depleted extremely in Ba, Sr and Eu, and rich in some large-ion lithophile elements and high field strength elements. Besides, the granite has high Ga contents, the values of 104(Ga/Al) vary from 2.50 to 2.77, which is mainly greater than the lower limit of A-type granites (2.6), and is higher than the I- and S-type granites’ average (2.1 and 2.28, respectively). Rare earth element (REE) is characterized by relatively high fractionations of light REE (LREE) and heavy REE (HREE) (LREE/HREE=9.3–13.60, (La/Yb)N=10.92–18.02), pronounced negative Eu anomalies (δEu=0.08–0.13), and exhibits right-dipping gull pattern. Major elements, rare elements and trace elements features show the granite is ascribed to A-type granite and A2 subtype in tectonic genetic type. They are plotted into post-collision or within-plate area in a variety of tectonic discriminations. Geological and geochemical data comprehensively suggest that the granite is formed in a post-collision extensive tectonic setting. Laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) zircon U-Pb dating yields a weighted mean age of 425?Ma, belonging to Middle Silurian, which is similar to the age of the post-collision geological events in the region. The differences of magmatic rocks in formation age, rocks assemblage and rocks series systematically indicate that the regional tectonic stress regime in the East Kunlun orogenic belt experienced a major transformation from compress to extension in Middle Silurianin, and the Helegangnaren feldspar granite intruded in the early stage of tectonic transformation.     

吉林省大石头镇北部青茶馆-元宝山花岗斑岩锆石U-Pb年龄及地球化学特征

青茶馆-元宝山花岗斑岩具有高硅、富铝、稀土元素含量较高、相对富集轻稀土元素、亏损重稀土元素的特征,负Eu异常明显,稀土元素配分图解具有右倾"V"字形的特征,并相对富集大离子亲石元素。锆石具有典型的岩浆振荡生长环带和较高的Th/U值(0.49~1.07),反映了岩浆成因特征。测得LA-ICP-MS锆石U-Pb年龄为116.8±1.5Ma(n=13,MSWD=1.13)。以上特征表明,青茶馆-元宝山花岗斑岩为高钾钙碱性高分异I型花岗岩,为后造山花岗岩,其形成可能与古太平洋板块俯冲作用有关。     

小兴安岭霍吉河钼矿区含矿花岗岩类特征及成矿年龄

黑龙江霍吉河钼矿区内含矿花岗岩类岩石组合为黑云母二长花岗岩、二长花岗岩和花岗细晶岩,属高钾钙碱性岩-钾玄岩系列准铝质-过铝质岩石,具有轻稀土富集、重稀土亏损分馏模式;富集不相容元素(Cs、Th)并表现为Ta和Nb负异常以及Pb、Sr正异常,显示俯冲带地球化学特征.含矿岩浆岩明显富集Mo、Cu、Pb、Zn、W、Cr等金属元素.岩石全岩铅同位素来源比较复杂,具有混合成因铅特征.辉钼矿Re-Os模式年龄为180.7±2.5Ma和181.3±2.6Ma,钼矿成矿时代为早侏罗世.霍吉河钼矿是在蒙古-鄂霍茨克洋和古太平洋相向联合俯冲作用下,导致霍吉河地区发生地壳增生和壳幔相互作用以及后来的拆沉作用,形成了该区花岗质岩石和钼矿床.高度演化的花岗岩体(脉)可以作为今后本区钼矿床的找矿方向.     

博格达山东段苏吉山A型花岗岩地球化学特征、LA-ICP-MS定年及其构造意义

新疆巴里坤县苏吉山花岗岩体在构造上位于博格达造山带东段,岩性为铁浅闪石碱长花岗岩。全岩具有较高的 SiO2、K2O+Na2O、NK/A和较低的A/CNK含量;轻稀土相对富集、铕弱亏损;不同程度的富集大离子亲石元素和高场强元 素,亏损Cs、Sr、P、Ti;HFSE元素组合（Zr+Nb+Ce+Y） 介于451×10-6~674×10-6,锆石饱和温度范围841~883℃;以上特 征都表现为典型的A型花岗岩特征,判别图解进一步显示其为A2型花岗岩。造岩矿物角闪石属钙质普通角闪石,铁浅闪石 亚类,主量成分Al2O3介于2.9%~4.5%,Si/(Si+Ti+A1)为0.88~0.93,显示出壳源角闪石的特征。LA-ICP-MS 锆石U-Pb 年 龄为301.5±2.4 Ma,表明其形成时代为晚石炭世格舍尔阶。苏吉山A型花岗岩壳源角闪石特征指示其不同于A1亚型与地幔 热柱、裂谷有关的伸展机制,裂谷中晚期侵位表明其不同于A2亚型所代表的后造山环境。结合邻区花岗岩侵位时空特征, 苏吉山A型花岗岩应标志着一种裂谷作用减弱的局限伸展环境,也表明博格达裂谷作用受控于古亚洲洋沿卡拉麦里蛇绿岩 带的斜向俯冲作用。     

大兴安岭嫩江地区中生代双峰式火山岩锆石U-Pb定年、地球化学特征及其地质意义

本文对嫩江地区中生代双峰式火山岩进行了锆石LA-ICP-MSU-Pb年代学和岩石地球化学研究。测年结果显示嫩江地区中生代双峰式火山岩形成于127.5Ma的早白垩世晚期。岩石地球化学研究表明,早白垩世晚期火山岩具有双峰式组合特点,基性端员富碱,富含轻稀土元素和大离子亲石元素,亏损重稀土元素和高场强元素（Nb、Ta、Ti、Y）,形成于富集的岩石圈地幔的部分熔融和分离结晶作用,形成的过程可能含有少量的陆壳混染。酸性端员显示A型流纹岩的特征,为幔源岩浆底侵,使中下地壳岩石发生部分熔融的成因。双峰式火山岩组合的存在暗示其形成于陆内拉张的构造环境。结合区域上中生代火山岩的空间展布特征,嫩江地区早白垩世晚期双峰式火山岩的形成应与太平洋板块向欧亚大陆的俯冲作用有关。     

Zircon SHRIMP U-Pb ages and geochemistry of Late Mesozoic granitoids in Western Zhejiang and Southern Anhui: constraints on the model of lithospheric thinning of Southeast China

ABSTRACT

We report geochemical data and zircon SHRIMP U-Pb ages for Late Mesozoic granitoids from the western Zhejiang province and southern Anhui province (the WZSA region) from southeast China. In combination with published geochronological and geochemical data, the granitoids in the region can be divided into three stages: 171–141 Ma, 140–121 Ma, and 120–95 Ma. The first stage of these granitoids is mainly composed of granite porphyry and granodiorite which are similar to I-type granitoids, including having weakly negative Eu anomalies with enrichment in light rare earth elements (LREE), Rb, Th, and U. The second stage of granitoids consists of monzogranite, syenogranite, and granite with the characteristics of both A-type and I-type granitoids including strongly negative Eu anomalies; depletion of Ba, Sr, and Ti; and enrichment of K, Rb, and high field strength elements (HFSEs) (such as Th and U). The third stage of granitoids is mainly composed of granite, quartz monzonite, quartz diorite, and mafic rocks with weakly negative Eu anomalies and also enrichment in LREE, Rb, Th, U, and K. From our work, we propose a transition from compressional to extensional magmatism at ~141 Ma. Based on the geochemical characteristics of these granites and coeval mafic rocks, we propose that the formation of the A-type magmatism in the WZSA region formed as the result of lithospheric extension and asthenospheric upwelling during the Early Cretaceous.     

Petrogenesis of Late Cretaceous Jiangla’angzong I-Type Granite in Central Lhasa Terrane, Tibet, China: Constraints from Whole-Rock Geochemistry, Zircon U-Pb Geochronology, and Sr-Nd-Pb-Hf Isotopes

The Jiangla'angzong granite in the northern part of the Central Lhasa Terrane is composed of syenogranite and adamellite. LA-ICP-MS zircon U-Pb analyses suggest that syenogranite has a weighted mean ~(206) Pb/~(238) U age of 86±1 Ma(mean square weighted deviation=0.37), which is in accordance with the muscovite Ar-Ar age(85±1 Ma) of Cu-Au ore-bearing skarns and the zircon U-Pb age(84±1 Ma) of adamellite. This suggests that the Jiangla'angzong magmatism and Cu–Au mineralization events took place during the Late Cretaceous. The granite contains hornblende, biotite, and pyroxene, and does not contain Al-bearing minerals, such as muscovite, cordierite, and garnet. It has high contents of SiO_2(65.10–70.91 wt%), K_2O(3.44–5.17 wt%), and total K_2O+Na_2O(7.13–8.15 wt%), and moderate contents of A_(12)O_3(14.14–16.45 wt%) and CaO(2.33–4.11 wt%), with a Reitman index(σ43) of 2.18 to 2.33, and A/CNK values of 0.88 to 1.02. The P_2O_5 contents show a negative correlation with SiO_2, whereas Pb contents show a positive correlation with SiO_2. Th and Y contents are relatively low and show a negative correlation with the Rb contents. These characteristics suggest that the Jiangla'angzong granite is a high K calc–alkaline metaluminous I–type granite. It is enriched in light rare earth elements(LREE) and large ion lithofile elements(LILE), and depleted in heavy rare earth elements(HREE) and high field strength elements(HFSE), with LREE/HREE ratios of 11.7 to 18.1. The granite has negative Eu anomalies of 0.58 to 0.94 without obvious Ce anomalies(δCe=1.00–1.04). The relatively low initial 87 Sr/86 Sr ratios of 0.7106 to 0.7179, positive εHf(t) values of 1.0 to 4.1, and two-stage Hf model ages(TDM2) ranging from 889 Ma to 1082 Ma, These geochemical features indicate that the granite derived from a juvenile crust. The(~(143) Nd/~(144) Nd)_t values from the Jiangla'angzong granite range from 0.5121 to 0.5123, its εNd(t) values range from-10.17 to-6.10, its(~(206) Pb/~(204) Pb)_t values range from 18.683 to 18.746, its(~(207) Pb/~(204) Pb)_t values range from 15.695 to 15.700, and its(~(208) Pb/~(204) Pb)_t values range from 39.012 to 39.071. These data indicate that the granite was formed by melting of the upper crust with the addition of some mantle materials. We propose that the Jiangla'angzong granite was formed during the postcollision extension of the Qiangtang and Lhasa terranes.     

云南省大坪金矿区二长花岗岩的 地球化学特征及地质意义

[摘 要] 大坪金矿区岩浆活动频繁,矿区出露的二长花岗岩体规模较大,岩性为中粗粒二长花岗岩。在岩石化学组成上,SiO₂含量为67.32%～71.71%、Al₂O₃为14.54%～16.66%,属于过铝质花岗岩类。岩石富集大离子亲石元素(Sr、U、Rb 和Ba)和轻稀土元素(LREE)、相对亏损高场强元素(Ta、Nb和Ti), 且Ta、Nb 和Ti 具“TNT"负异常;啄Eu 值为0. 80～1. 44,负Eu 异常不明显;87 Sr/ 86 Sr 值范围为0.7078～0. 7436,均值0. 7256,高于原始地幔现代值0.7045;¹⁴³Nd/¹⁴⁴Nd 值范围为0. 5119～0. 5122,均值0. 5120,低于原始地幔现代值0. 512638;ε_Nd值范围为-2. 5～-4.2,均值-3.98。表明矿区二长花岗岩源区应来自于“壳-幔混合带"的部分熔融,形成于同碰撞或碰撞晚期的构造环境。二长花岗岩体与大坪金矿成矿流体具有相同源区,岩体为大坪金矿的形成提供了热源和主要成矿流体。     

Petrological and geochemical characteristics of Zhaibei granites in Nanling region,Southeast China: Implications for REE mineralization

Mineralization with ion adsorption rare earth elements (REEs) in the weathering profile of granitoid rocks from Nanling region of Southeast China is an important REE resource, especially for heavy REE (HREE) and Y. However, the Jurassic granites in Zhaibei which host the ion adsorption light REE (LREE) ores are rare. It is of peraluminous and high K calc-alkaline composition, which has similar geochemical features of high K₂O + Na₂O and Zr + Nb + Ce + Y contents and Ga/Al ratio to A-type granite. Based on the chemical discrimination criteria of Eby [Geology 20 (1992) 641], the Zhaibei granite belongs to A1-type and has similar source to ocean island basalts. The rock is enriched in LREE and contains abundant REE minerals including LREE-phosphates and halides. Minor LREE was also determined in the feldspar and biotite, which shows negligible and negative Eu anomalies, respectively. This indicates that the Zhaibei granite was generated by extreme differentiation of basaltic parent magmas. In contrast, granites associated with ion adsorption HREE ores contain amounts of HREE minerals, and show similar geochemical characteristics with fractionated felsic granites. Note that most Jurassic granitoids in the Nanling region contain no REE minerals and cannot produce REE mineralization. They belong to unfractionated M-, I- and S-type granites. Therefore, accumulation of REE in the weathering profile is controlled by primary REE mineral compositions in the granitoids. Intense fractional crystallization plays a role on REE enrichment in the Nanling granitoid rocks.