庞西垌‐金山银金矿田构造演化及控矿特征分析

<正>庞西垌-金山银金矿田位于钦杭带南段云开地块内(周永章,2012)。云开地块一般被认为是扬子和华夏地块的结合带(覃小锋等,2008),东西两侧分别以吴川-四会断裂、博白-岑溪断裂为界,呈北东向展布,自元古代起经历了多期的构造、岩浆作用。区内出露的地层主要有新元古代云开群变质岩、加里东期混合岩及下古生界地层,岩浆活动频繁,以燕山期花岗岩浆为主。庞西垌-金山银金矿田地处粤东桂西交界,包括了庞西垌、金山、中苏、竹根坡、高村等银金矿床及一     

云开地区不同变形期次岩石的显微—超显微变形分析及其成因意义

地云开地区不同变形期次岩石的显微－超显微变形研究，提出：（１）云开地块中的条带状混合岩一片麻状花岗岩－眼球状花岗岩（侵入花岗岩）岩石组合序列，是晋宁期、加里东期中深层次流变剪切作稆部分熔融的产物。（２）海西－印支期桂东南地体与云开地体碰撞拼贴，形成由ＮＮＷ→ＳＳＥ逆冲推覆构造系统，并在其根据带形成同碰撞期花岗岩，发生韧－脆性变形。（３）燕山期以平移剪切为主，在断裂带中形成对称分布的超糜棱岩（中心）     

云开地块印支期变质-深熔作用:混合岩、片麻岩锆石U-Pb年代学和Hf同位素证据

云开地块中生代构造演化是华南地区的研究热点之一.通过对云开地块变质基底中的混合岩、片麻岩（5个样品）和花岗岩（1个样品）开展锆石LA-ICP-MS U-Pb定年,获得440.3±3.3 Ma、230.2±2.9 Ma、230.7±1.3 Ma、459.5±2.7 Ma、431.5±4.3 Ma、229.2±5.4 Ma、229.7±2.7 Ma 7组变质（深熔）或岩浆年龄和2组（样品1432-1和ID7-3）碎屑锆石年龄,碎屑锆石年龄范围均为太古代-新元古代,且具有~1.0 Ga年龄主峰,与天堂山岩群和云开群碎屑锆石年龄谱相似.区域资料表明云开地块天堂山岩群和云开群具有相似的物质组成,均形成于早古生代-新元古代,存在变质程度和物质面貌的差异;在加里东期构造-热事件的基础上,广泛叠加了印支期区域变质（深熔）-构造-流体作用影响.4个样品中（1431-1、1432-1、D116-3和ID7-3）锆石原位Lu-Hf同位素组成显示,加里东期变质和深熔锆石Lu/Hf同位素组成基本一致,应继承了原岩的同位素组成特征.印支期变质和深熔锆石Lu/Hf同位素组成不同,可能主要由变质作用和深熔作用的差异所致.以古-中元古代为主的地壳物质参与了加里东期和印支期变质-深熔作用,在加里东期和印支期深熔作用过程中,均有少量幔源物质的加入,印支期幔源物质的贡献相对显著.      

云开地块印支期构造热事件叠加改造:来自片麻岩中多矿物U-Pb年代学的证据

云开地块显生宙的构造演化一直是华南板块的研究热点之一.通过对云开地块变质基底中片麻岩进行独居石、磷灰石和锆石LA-ICP-MS U-Pb定年,获得了434±6 Ma（MSWD=3.0）和437±12 Ma（MSWD=6.0）的岩浆锆石年龄,结合镜下观察,认为其代表的是片麻岩原岩（花岗质岩石）的形成时代,与区域上加里东期构造-岩浆-变质-深熔事件的时限基本一致,为武夷-云开加里东造山作用的产物;磷灰石经过普通铅校正后分别给出了241±13 Ma（MSWD=2.2）和242±6 Ma（MSWD=1.4）的变质年龄,独居石则分别获得了236.2±0.8 Ma（MSWD=0.66）和229.4±1.2 Ma（MSWD=2.4）的变质年龄,这些年龄结果与云开地块构造岩云母Ar-Ar年龄相一致,暗示云井地块经历了印支期（230~240 Ma）构造热事件的叠加改造.对片麻岩中黑云母电子探针数据分析显示其具有相对高的Al、Ti和Mg含量,X_Mg值为0.37~0.45,属于铁质黑云母,其Ti饱和温度计给出温度范围为650~700℃（±50℃）,与独居石估算温度580~640℃（±25℃）在误差范围内基本一致,暗示印支期构造热事件对云开地块的叠加改造温度达到了700℃.综上所述,认为云开地块现今的构造格局是在加里东期造山作用基础上叠加了印支期构造塑造而成,叠加温度可能达到了700℃;此外,在利用矿物对温压计恢复加里东期变质作用P-T轨迹时应着重考虑印支期构造热事件对矿物成分的再造作用.      

云开地区加里东期花岗岩锆石U-Pb年龄及其地质意义

对云开地区1∶25万区调中划归前寒武纪或新元古代的(片麻状)花岗岩进行了锆石LA-ICP-MS U-Pb定年,获得的年龄分别为(443.3±2.6)Ma(样品1009,陆川县陆透水库东南)、(445.7±2.3)Ma(样品1010,陆川县月垌村)、(441.1±2.0) Ma(样品1012,高州市谢鸡镇)和(443.7±1.7)Ma(样品10108,信宜市朱砂镇),表明它们属于加里东期的产物而不是以往认为的前寒武纪基底或新元古代岩石.结合前人的研究表明,这些花岗岩主要由元古宙基底岩石发生深熔作用而成,是华南地区加里东期陆内造山作用的响应.随着云开地区前寒武纪基底中大量加里东期年龄的发现,说明加里东运动对该区的影响非常强烈,1∶25万区调中划归前寒武纪基底或新元古代的部分片麻状花岗岩应归属加里东期.云开地区前寒武纪基底主要是以片麻岩类为代表的高州杂岩和以变沉积岩类为代表的云开群,高州杂岩形成时代为中新元古代,云开群形成时代可能为新元古代.从整个华夏地块来看,存在古-中元古代结晶基底,但出露可能并不像以往认为的那么广泛.     

云开地块基底演化与成矿作用

云开地块位于广东和广西两省的毗邻地带,经历了基底形成和改造两个阶段。基底形成包括了古中元古代高州杂岩的沉积与变质、晚元古代云开群的沉积与变质、震旦系和早古生代地层的沉积和变质,在早古生代晚期作为整体转化为稳定地块。基底改造发生在加里东期之后,包括海西－印支期与燕山－喜山期两个阶段,基底岩石经历了断裂变质、重熔改造和构造活动。在基底演化过程中,物质进行了重新分布,一些元素得以富集成矿,使云开地区成为     

云开地块基底演化与成矿作用

云开地块位于广东和广西两省的毗邻地带,经历了基底形成和改造两个阶段。基底形成包括了古中元古代高州杂岩的沉积与变质、晚元古代云开群的沉积与变质、震旦系和早古生代地层的沉积和变质,在早古生代晚期作为整体转化为稳定地块。基底改造发生在加里东期之后,包括海西－印支期与燕山－喜山期两个阶段,基底岩石经历了断裂变质、重熔改造和构造活动。在基底演化过程中,物质进行了重新分布,一些元素得以富集成矿,使云开地区成为我国重要的银金-多金属矿床集中区。     

两广云开隆起区基底的组成演化及其基本结构格局

云开隆起区基底具双层结构特点，深层次基底包括早—中元古代中深变质岩系和由其重熔而成的混合岩及花岗岩，其中的钾长球斑花岗岩具岩浆成因特征，结晶年龄为３９０—５１０Ｍａ。云开隆起区基底形成之后，经历了自晋宁期以来的长期而复杂的变质变形演化历史，于加里东期形成的变质核杂岩或穹隆构造，奠定了云开隆起区的基本结构格局。     

云开地块的构造演化史及其动力学特征

云开地块构造演化史可筛分为６个构造期：（１）前晋宁期（〉１４００×１０＾ａ），发生ＮＥ向超深层次的伸展型顺层滑脱，滑脱带下部发展为区域深熔混合岩和溶熔花岗岩；（２）晋宁期（１４００×１０＾６～８００×１０＾６ａ）发生ＮＮＥ向深层次伸展剪切，剪切带下部逐渐形成条带状深熔混合岩和片麻状深熔花岗岩；（３）加里东期（８００×１０＾６～３７０×１０＾６ａ）发生Ｓ→Ｎ中深层次推覆剪切，剪切带形成高侵位片麻状深     

两广云开隆起区基底的组成演化及其基本结构格局

去开隆起区基底具双层结构特点，深层次基底包包括早－中元古代中深变质岩系和由基重熔而成的混合岩及花岗岩，其中的钾长球斑花岗岩具岩浆成因特征，结晶年龄为３９００－５１０Ｍａ。云开隆起区基底形成之后，经历了自晋宁期以来的长期而复杂的变质变形演倾，地加里东期形成的变质核杂岩或穹隆构造，奠定了云开隆起区的基本结构格局。     

Wavelength-dispersive X-ray fluorescence spectrometric determination of Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites

Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.     

高压微波消解法测定醋酸纤维过滤器采集的微尘粒子中的砷镉钴铬铜铁锰镍铅钒锌

最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提     

硅酸盐类样品中硅、铁、铝、钛、锰、钙、镁、钾、钠和磷的x射线荧光光谱测定

本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.     

Viscous, cohesive, non-Newtonian, depositing, radial slurry flow

Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.     

硅酸盐中铁、锰、钛、钙、钾、磷、硅、铝、镁、钠、锶、铷、钡的X-射线荧光光谱定量测定

本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。     

Bellechester,Minnesota, USA,lagoon collapses

Bellechester, Minnesota, is a small community of approximately 155 residents located on the county line between Goodhue and Wabasha counties in southeast Minnesota's karst region. Bellechester is served by a 21-year-old wastewater treatment facility (WWTF) consisting of three waste-stabilization ponds. On 28 April 1992 six sinkholes were discovered to have drained cell 2 of the WWTF resulting in the loss of approximately 8.7×10⁶ 1 of partially treated effluent and about 600 m³ of soil into previously undetected subsurface voids of unknown dimensions. In the week following the collapse, approximately 200 water wells located within a 5-km radius of the WWTF were sampled in an after-the-fact, emergency sampling program. Twelve samples with elevated fecal coliform levels, 18 samples with nitrate-nitrogen greater than the 10 mg/1 standard, and no samples with elevated chlorides were found. However, the elevated levels could not be unambiguously attributed to the WWTF collapse. This is the third WWTF to fail by sinkhole collapse in southeast Minnesota since 1974. All three collapsed lagoons have been located in similar geomorphic and stratigraphic settings. However, at least two lagoons have collapsed in the adjacent area in northeast Iowa, and these lagoons are located at different stratigraphic positions. Twenty-two WWTFs constructed in southeast Minnesota's karst region in the last 25 years have been identified as subject to potential sinkhole collapse. An unknown but significant number of manure storage lagoons, flood control structures, etc., have also been constructed in the karst region and are at risk. Public agencies are beginning to develop plans to deal with the risk associated with existing and future waste lagoons in this environment. The critical hydrogeologic parameters that can be used to prioritize the risk of collapse at existing facilities include: (1) the lithology of the first bedrock beneath each lagoon, (2) the thickness of surficial materials between the lagoon and the bedrock surface, (3) the presence and construction of liners (seepage rate), and (4) the proximity to existing sinkholes.     

Mercury,arsenic, antimony,and selenium contents of sediment from the Kuskokwim River,Bethel, Alaska,USA

The Kuskokwim River at Bethel, Alaska, drains a major mercury-antimony metallogenic province in its upper reaches and tributaries. Bethel (population 4000) is situated on the Kuskokwim floodplain and also draws its water supply from wells located in river-deposited sediment. A boring through overbank and floodplain sediment has provided material to establish a baseline datum for sediment-hosted heavy metals. Mercury (total), arsenic, antimony, and selenium contents were determined; aluminum was also determined and used as normalizing factor. The contents of the heavy metals were relatively constant with depth and do not reflect any potential enrichment from upstream contaminant sources.     

滇东南花岗岩与锡、银、铜、铅、锌多金属矿床的成因关系

滇东南锡、银、铅、锌多金属矿床主要分布在个旧、白牛厂、都龙3个矿区,而滇东南较大的3个花岗岩体又分别出露在3个矿区或附近.花岗岩体均形成于燕山晚期,岩石化学、矿物成分相似,富含锡、银、铅、锌、钨、铜等成矿元素.矿床主金属元素组合与岩体之间的距离由远而近出现由锡、钨、(铍、铌、钽)→锡、钨、(铁)、铜、铟→锡、铅、锌、银、铟、(锑)有规律的变化.花岗岩浆是成矿物质来源和成矿热源.岩浆侵入初期使上覆地层隆起产生背斜(凹陷部位成向斜);同时使地层产生一系列裂隙、压性断层或层间断裂;岩浆侵入晚期,这些断层再次活动,表现为张性,岩浆产生的含矿热液沿由其活动所造成的断裂迁移、充填、交代、沉淀而形成矿床.     

岩石密度和超高压岩石折返速率

在常温常压条件下对中国大陆科学钻CCSD主孔100-3000米岩心样品进行了密度测量,建立了密度连续剖面,并界定了不同超高压岩石的密度值。通过对比高温高压物性实验资料,岩石密度随着退变程度增强而降低,榴辉岩密度变化序列为3.52g/cm3→3.49g/cm3→3.07g/cm3→2.93g/cm3。超高压长英质岩石密度变化序列为3.00g/cm→2.80g/cm3→2.65g/cm3。上述实验资料是讨论不同折返阶段岩石所受浮力的基础,为研究折返速率大小提供了基本参数。本文通过折返板块运动平衡时,上浮力与粘滞力平衡这一关系式,定量研究了大陆俯冲板块的折返速率,认为密度差产生上浮力从而引起折返,温度对板块折返速率的影响最为显著;密度差大小、折返角度、折返板块大小对折返速率也有直接的影响。定量模拟分析表明,在温度高于850℃时,板块的折返速率可以超过100mm/a;当温度降至700℃时,折返速率则低于1.5mm/a。作者认为在折返早期,温度较高,板块快速折返至60-70km榴辉岩相深度;随着传导散热,温度降低,板块以较慢的速率折返至中下地壳。折返速率的估算表明,浮力是板块折返第一阶段(从>100km深部折返至<40km的中下地壳)的主要驱动力。