铑作基体改进剂石墨炉原子吸收法测定海洋生物样品中的痕量砷

采用铑作基体改进剂,消除样品中共存磷酸盐基体的干扰,实现了用塞曼石墨炉原子吸收法测定贻贝、虾粉、牡蛎等海洋生物样品中痕量砷。方法的ＬＤ为２５ｐｇ（１０μＬ进样）,线性范围在０～１２５μｇ／ＬＡｓ。标准加入法测定砷的回收率为８５％～１０２％,１０－６水平Ａｓ的测定ＲＳＤ（ｎ＝６）小于７％,分析结果与标准样品的标准值和氢化物原子吸收法测定结果相符。     

浙江泰顺洋滨黄玉斑岩地球化学特征和成因

浙江泰顺洋滨斑岩锡矿成矿母岩为黄玉斑岩类岩脉，长约２ｋｍ，宽２－２０ｍ，岩性可分黄玉钾长花岗斑岩、黄玉二长花岗斑岩和黄英斑岩三种。黄玉含量占１０％－２０％，具火成斑状结构。岩石为强过铝质（Ａ／ＮＫＣ＝１．５７４－１２．９４），高Ｆ／Ｃｌ值（１４６－３０３），高Ｒｂ／Ｓｒ值（５－１２２），高的不相容元素丰度（Ｓｎ＝３１３×１０－６－１０４２×１０－６）而相容元素丰度较低（Ｓｒ＝１０×１０－６－２８×１０－６），稀土配分呈海鸥型，成因上应是Ｓ型含锡斑岩。     

横岭关铜矿床地球化学研究

对横岭关铜矿床中稀土元素、同位素和矿物包裹体地球化学研究表明，矿床形成温度为３５０℃±３０℃；压力为３８×１０~５Ｐａ～２４０×１０~５Ｐａ；盐度为３０ｗｔ％～４２ｗｔ％；ｌｏｇｆｏ_２为－３０．４１～－３１．４７；ｌｏｇｆｓ_２为－５．４～－８；ｐＨ值为７．３；ｌｏｇｆｃｏ_２为－２．４９；铜的溶解度（ｌｏｇｍ_（Ｃｕ））为－５．８７～－２．２１。围岩的铅－铅同位素年龄为１７７５×１０~６ａ，矿石的铅－铅同位素年龄为１８４５×１０~６ａ；矿石硫同位素组成，δ~（３４）Ｓ为－８．１‰～３６．９‰，显示出硫同位素为非平衡特征；碳酸盐岩的碳同位素组成，δ~（１３）Ｃ为－７．１‰～－２．６‰，δ~（１３）Ｃ_（∑Ｃ）为－５．３‰；成矿流体的氢氧同位素组成具有变质热卤水的特点，认为该矿床属于变质热卤水成矿。     

流动注射夹层带进样方式分光光度法测定溴

采用流动注射夹层带进样方式研究了酚红法测定溴的化学条件和流路参数，所建立的方法具有灵敏度高、精密度好、试剂消耗量少和分析速度快的特点。在所选实验条件下，Ｂｒ－的质量浓度为０２～１００ｍｇ／Ｌ时有良好的线性关系，检出限和相对标准偏差（２０ｍｇ／ＬＢｒ－，ｎ＝１１）分别为０１１ｍｇ／Ｌ和０８８％，测定速度为６０～９０／ｈ。对化学试剂ＫＣｌ和ＮａＣｌ中的杂质溴进行了测定，加标回收率为９５％～１０５％。     

邻硝基苯基萤光酮－溴化十六烷基三甲铵二阶导数光度法同时测定微量钨和钼

研究了邻硝基苯基萤光酮（ｏ－ＮＰＦ）－溴化十六烷基三甲铵（ＣＴＭＡＢ）与Ｗ（Ⅵ）和Ｍｏ（Ⅵ）共同显色条件及其吸收光谱和导数光谱行为。选择二阶导数光谱用基线相交法同时测定Ｗ和Ｍｏ，对１：１０或１０：１的Ｗ和Ｍｏ互不干扰，回收完全。测定范围为４～１６０ｎｇ／ｍｌ的Ｗ，４～１２０ｎｇ／ｍｌ的Ｍｏ。对１０￣（－６）水平的Ｗ和Ｍｏ测定的ＲＳＤ（ｎ＝８）均小于１０％，对国家一级地质标样测定结果符合要求。     

南秦岭下古生界石煤的富硒性及意义

南秦岭下古生界地层中赋存着丰富的石煤资源，特别是下寒武统的鲁家坪组和下志留统的大贵坪组的石煤最为丰富，是本区下古生界的主要含煤段。这两个组的石煤均富含硒元素。下寒武统的石煤一般含硒量为（２０～５０）×１０￣（－６），最高可达３７０×１０￣（－６），下志留统的石煤含硒量一般为（２０～３０）×１０￣（－６），远远高于地壳克拉克值￣［１］。     

锍试金富集贵金属元素：I.等离子体质谱法测定地质样品中痕量铂族元素

纯化了捕集剂，用锍试金结合Ｔｅ共沉淀富集，等离子体质谱法测定了地质样品中的铂族元素，全流程铂族元素回收率大于９４％，一次熔样可同时测定了６个铂族元素，按２０ｇ取样计算，方法检出限（ｎｇ／ｇ）分别为０．０２４，Ｒｕ，０．０１３，Ｒｈ，０．２０，Ｐｄ，０．０３３，Ｏｓ０．３９，Ｉｒ０．１２Ｐｔ；对标准ＧＰｔ－６平行测定５次，铂族元素相对标准偏差为１％（Ｏｓ）～８％（Ｐｔ）对不同类型标样进行测定，测得结     

光度法测定痕量钛的研究

基于痕量Ｔｉ（Ⅳ）在稀Ｈ２ＳＯ４介质中对ＥＤＴＡ还原Ｃｒ２Ｏ２－７褪色反应的抑制作用，建立了测定痕量Ｔｉ（Ⅳ）的光度法。测定范围为２４～２４μｇ／Ｌ，检出限为１０６×１０－７ｇ／ＬＴｉ（Ⅳ）。结合萃取分离富集技术，方法用于测定人发及茶叶样品中的痕量Ｔｉ（Ⅳ），结果与标准值相符，加标回收率在９５％～１００％，ＲＳＤ（ｎ＝６）为１１％～２０％。     

激光采样─电感耦合等离子体原子发射光谱分析系统的研制及其分析性能

报道了一个连续激光采样，连接电感耦合等离子体原子发射光谱仪（ＩＣＰＡＥＳ）作检测的分析系统。其结构简单、稳定性好，适合于进行直接固体粉末分析。由于激光采样时间短，靶点温度高于５６６０℃，故基体效应较小。检出限可达１０－６级，分析重现性（ＲＳＤ）一般可达３％～５％     

2，4－二溴－6－羧基苯重氮氨基偶氮苯光度法测定痕量铊的研究

研究了新试剂２，４－二溴－６－羧基苯重氮氨基偶氮苯与Ｔｌ（Ⅲ）的高灵敏显色反应。在非离子表面活性剂ＴｒｉｔｏｎＸ－１００存在下，于ｐＨ１０．５的ＮＨ＿３·Ｈ＿２Ｏ－ＮＨ＿４Ｃｌ缓冲介质中，Ｔｌ（Ⅲ’）与该试剂生成红色配合物，其配合物的最大吸收波长位于５２０ｎｍ处，摩尔吸光系数为１．８３×１０￣５Ｌ·ｍｏｌ￣－１·ｃｍ￣－１。Ｔｌ（Ⅲ’）量在０～０．６４μｇ／ｍｌ范围内符合比尔定律。方法用于废水中痕量Ｔｌ的测定，结果与其它方法结果相符。测定工业废水及粉煤灰中痕量Ｔｌ的ＲＳＤ（ｎ＝６）在１．６％～３．２％范围。     

Définition d'une limite multicritère ; stratigraphie du passage Campanien–Maastrichtien du site géologique de Tercis (Landes,SW France)Definition of a multi-criteria boundary; stratigraphy of the Campanian–Maastrichtian interval of the geological site at Tercis (Landes,SW France)

Lithostratigraphy, physicochemical stratigraphy, biostratigraphy, and geochronology of the 77–70 Ma old series bracketing the Campanian–Maastrichtian boundary have been investigated by 70 experts. For the first time, direct relationships between macro- and microfossils have been established, as well as direct and indirect relationships between chemo-physical and biostratigraphical tools. A combination of criteria for selecting the boundary level, duration estimates, uncertainties on durations and on the location of biohorizons have been considered; new chronostratigraphic units are proposed. The geological site at Tercis is accepted by the Commission on Stratigraphy as the international reference for the stratigraphy of the studied interval. To cite this article: G.S. Odin, C. R. Geoscience 334 (2002) 409–414.     

GEOPHYSICS

正20140634 Cao Lingmin(Key Laboratory of Marine Geology and Environment,Institute of Oceanology,Chinese Academy of Sciences,Qingdao 266071,China);Xu Yi Finite Difference Tomography of the Crustal Velocity Structure in Tengchong,Yunnan Province(Chinese Journal of Geophysics,ISSN0001-5733,CN11-2074/P,56(4),2013,p.1159-1167,6illus.,35refs.,with English abstract)     

PALEOBOTANY

正20140965Jia Gaowen(School of Earth Sciences,Lanzhou University,Lanzhou 730000,China);Liu Kenan Pod and Leaflet Fossils of Dalbergia(Leguminosae)from the Upper Miocene of Lincang,Yunnan Province(Acta Palaeontologica Sinica,ISSN0001-6616,CN32-1188/Q,52(2),2013,p.213-222,6     

NONMETALS DEPOSITS

正20141520 Bo Ying(Key Laboratory of Metallogeny and Mineral Assessment,MLR,Beijing 100037,China);Liu Chenglin Saline Spring Hydrochemical Characteristics and Indicators for Potassium Exploration in Southwestern and Northern Tarim Basin,Xinjiang(Acta Geoscientica Sinica,ISSN1006-3021,CN11-3474/P,34(5),2013,p.594-602,5 illus.,3 tables,28 refs.)     

PROSPECTING EXPLORATION

正20142599Chen Sanming(Guangxi Key Laboratory of Concealed Deposits Exploration,Guilin University of Technology,Guilin541004,China);He Yuzhou Block Model and Reserves Estimation of Panzhihua Iron Deposit Based on 3D Geological Modeling(Journal of Guilin University of Technology,ISSN1674-9057,CN45-1375/N,33(4),2013,p.610-615,9illus.,1table,15refs.)     

STRUCTURAL GEOLOGY

正20140594 Bai Daoyuan(Hunan Institute of Geology Survey,Changsha 410016,China);Zhong Xiang Faults in the Jingzhou Basin and Their Tectonic Settings(Geotectonica et Metallogenia,ISSN1001-1552,CN44-1595/P,37(2),2013,p.173-183,6illus.,59refs.)Key words:basin evolution,tectonic setting,South China In the Upper Paleozoic and Jurassic se-     

MATHEMATICAL GEOLOGY

正20141243Chen Ge(Hangzhou Research Institute of Petroleum Geology,PetroChina,Hangzhou 310023,China);Si Chunsong Study on Sedimentary Numerical Simulation Method of Fan Delta Sand Body(Journal of Geology,     

QUATERNARY GEOLOGY & GEOMORPHOLOGY

正20141664 Abudoukerimu Abasi(Kashi Meteorological Bureau of Xinjiang,Kashi 844000,China);Wang Rongmei The Relationship with Woody Plants Phonological Variation Characters and Climatic Change from 1982to 2010in Kashi(Quaternary Sciences,ISSN1001-7410,CN11-2708/P,33(5),2013,p.927-935,8illus.,3 tables,48 refs.,with English abstract)     

GEOTHERMICS GEOLOGY

正20140958 Mei Huicheng(No.915GeologicalBrigade,Jiangxi Bureau of Geology and Mineral Resources,Nanchang 330002,China);Li Zhongshe Geological Features and Causes of the Huihuang Geotherm in Xiushui,Jiangxi Province(Journal of Geological Hazards and