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1.
张艳飞  周永恒  董洋  李琛  王刚 《地球科学》2022,47(4):1234-1252
为探讨内蒙古拜仁达坝岩体岩浆来源与构造环境,进而限制古亚洲洋闭合时间,锆石U-Pb年代学、岩石地球化学及Sr-Nd同位素地球化学研究结果表明,岩体由花岗闪长岩和石英闪长岩组成,岩石侵位年龄为327±2 Ma(MSWD=1.4).岩体具有偏铝质-弱过铝质钙碱性特征,富集Rb、Th、U、K,亏损Ba、Sr、P及Nb、Ta、...  相似文献   

2.
桑桑地区林子宗群火山岩Sr、Nd同位素地球化学特征和SHRIMP锆石U-Pb地质年代学数据表明:①林子宗火山岩以高钾流纹岩为主,属于高钾钙碱性系列岩石,形成于49.8Ma±0.92 Ma,属于帕那组火山岩地层;②林子宗火山岩稀土元素配分模式较为一致,相对于HREE,强烈富集LREE;③林子宗火山岩具有相对低的初始Sr同位素值(87Sr/86Sr(i)=0.70488~0.70569)和较高的初始Nd值(εNd(i)=-1.38~-1.58);④总体上富集大离子亲石元素,亏损高场强元素,与岛弧型火山岩的地球化学特征类似。桑桑地区林子宗火山岩在形成过程中明显受到角闪石和斜长石分离结晶作用的影响。可能是俯冲的新特提斯洋板片断离或变陡,进而导致经历过俯冲交代作用的富集岩石圈地幔甚至局部下地壳发生部分熔融,形成的初始岩浆发生混合作用,并在近封闭条件下发生高度分离结晶作用的产物。结合已有的结果,认为冈底斯带南带普遍经历了50Ma左右的岩浆作用。  相似文献   

3.
桑桑地区林子宗群火山岩Sr、Nd同位素地球化学特征和SHRIMP锆石U-Pb地质年代学数据表明:①林子宗火山岩以高钾流纹岩为主,属于高钾钙碱性系列岩石,形成于49.8Ma± 0.92 Ma,属于帕那组火山岩地层;②林子宗火山岩稀土元素配分模式较为一致,相对于HREE,强烈富集LREE;③林子宗火山岩具有相对低的初始Sr同位素值(87Sr/86Sr(i)=0.70488~0.70569)和较高的初始Nd值(εNd(i)=-1.38~-1.58);④总体上富集大离子亲石元素,亏损高场强元素,与岛弧型火山岩的地球化学特征类似。桑桑地区林子宗火山岩在形成过程中明显受到角闪石和斜长石分离结晶作用的影响。可能是俯冲的新特提斯洋板片断离或变陡,进而导致经历过俯冲交代作用的富集岩石圈地幔甚至局部下地壳发生部分熔融,形成的初始岩浆发生混合作用,并在近封闭条件下发生高度分离结晶作用的产物。结合已有的结果,认为冈底斯带南带普遍经历了50Ma左右的岩浆作用。  相似文献   

4.
华北克拉通东部中生代岩石圈减薄已经取得了大量进展,相比之下对克拉通中部岩石圈演化认识不足。本文对华北克拉通中部狐偃山杂岩体中科头正长岩进行了锆石U-Pb年代学、主量和微量元素、Sr-Nd-Hf同位素地球化学研究。LA-ICP-MS锆石U-Pb定年结果显示,科头正长岩侵位于早白垩世晚期(~111Ma)。岩石样品均为钾质—超钾质,属于碱性系列岩石。这些岩石相对富集轻稀土,亏损重稀土和中稀土,具有明显的正Eu异常(Eu/Eu~*=1.22~1.96)、富集大离子亲石元素LILE(Rb、Sr、Ba),亏损高场强元素HFSE(Nb、Ta、Ti)。所有岩石样品具有相对高的初始~(87)Sr/~(86)Sr比值(0.7058~0.7062)和低的ε_(Nd)(t)(-10.4~—11.1),ε_(Hf)(t)介于—12.2~—5.2之间。详细的元素和同位素地球化学研究表明科头正长岩的原始岩浆可能来源于富集岩石圈地幔中富金云母的尖晶石二辉橄榄岩源区的部分熔融,岩浆演化过程中经历了地壳混染与结晶分异(AFC)过程。结合华北克拉通中部岩浆资料,将华北克拉通中部早白垩世岩浆作用分为早晚两期:早期(123~135Ma)为岩浆作用高峰期,晚期(~114Ma)为最后一期弱的岩浆期;华北克拉通中部陆下岩石圈地幔是富集的、不均一的,其至少在早白垩世(138~111Ma)一直处于减薄状态。  相似文献   

5.
曲水杂岩体位于冈底斯构造-岩浆岩带东段南缘,其岩浆活动与雅鲁藏布江新特提斯洋壳向北俯冲、消减以及印度与欧亚板块碰撞息息相关。本文以曲水县-昌果乡广泛分布的中酸性花岗岩体为研究对象,进行了系统的LA-ICP-MS锆石U-Pb年代学和岩石地球化学研究。结果表明,曲水杂岩体由3期时代和规模不同的花岗质岩体构成,其LA-ICP-MS锆石U-Pb年龄分别为95.2±1.0~88.5±1.0Ma、65.2±0.6Ma和48.5±0.5~43.3±0.7Ma;岩石地球化学研究表明,晚白垩世和古新世花岗岩以中性-中酸性为主,属钙碱性系列,具中铝特征,A/CNK比值小于1.1,属于I型花岗岩,是玄武质下地壳部分熔融产物,指示其形成于特提斯洋壳俯冲过程的岛弧构造环境。始新世花岗岩以高钾钙碱性系列为主,并出现钾玄岩系列,具偏铝-过铝质特征,指示岩浆上侵过程中遭受了不同程度的地壳物质混染,其形成于印度-欧亚板块强烈碰撞的构造环境。  相似文献   

6.
玉林花岗岩体位于东天山中段觉罗塔格构造带,对玉林花岗岩体开展了锆石U-Pb年代学及岩石地球化学研究。LA-ICP-MS锆石U-Pb测年结果为(327.1±6.6)Ma,为早石炭世岩浆活动的产物。岩石地球化学结果表明,玉林花岗岩体SiO_2含量为66.34%~67.52%,Al_2O_3含量为15.21%~15.7%,全碱含量为5.39%~7.57%,A/CNK为0.877~0.988,小于1.1,属准铝质-低钾钙碱性系列的花岗闪长岩类。岩石具有明显的轻重稀土分异,富集K,Sr等大离子亲石元素,相对亏损Nb,Th,Ti等高场强元素,为火山弧花岗岩,显示与埃达克岩相似的地球化学性质。结合岩石地球化学及同位素特征,认为玉林花岗岩体可能来源于俯冲洋壳的熔融,并在上升过程中受到地幔楔物质的影响,形成于洋壳俯冲下的岛弧环境。  相似文献   

7.
冈底斯岩浆岩带呈近东西向沿雅鲁藏布江缝合带分布,是一条巨大的构造—岩浆岩带。南冈底斯中生代的岩浆活动经历了205~152 Ma、109~80 Ma、65~41 Ma和33~13 Ma 4个阶段,均是挤压环境的产物。但其触发机制一直存在争议。争议的焦点在于新特提斯洋和班公湖—怒江洋的俯冲方式。为解释冈底斯南缘中生代中酸性岩浆岩的成因及构造环境,本文以西藏自治区扎囊县桑耶地区的石英二长岩为研究对象,通过年代学、岩石地球化学、Lu-Hf同位素分析岩浆起源、岩石成因及其构造环境。LA-ICP-MS锆石U-Pb定年结果显示,岩体形成于晚白垩世(91~88 Ma)。岩石地球化学分析揭示其属准铝质高钾钙碱性系列,富集大离子亲石元素和轻稀土元素,亏损高场强元素和重稀土元素,无明显Eu负异常,锆石εHf(t)值为+10.6~+14.2。石英二长岩形成于斜长石和石榴石的过渡带,岩浆经历了角闪石、磷灰石及黑云母的分离结晶作用。其典型的微量元素比值特征指示岩浆来源于年轻俯冲洋壳的部分熔融,并有少量新生幔源物质加入,具典型的I型花岗岩特征,推断其形成于俯冲岛弧环境,表明晚白垩世时期冈底斯南...  相似文献   

8.
胡振华 《地质与勘探》2020,56(2):359-371
白音高老组火山岩在大兴安岭地区广泛分布,本文对大兴安岭中南部贺斯格乌拉牧场白音高老组酸性火山岩进行了锆石U-Pb年代学、岩石地球化学和Sr-Nd同位素分析,探讨其岩石成因及构造背景。位于大兴安岭中南段东乌旗地区的白音高老组火山岩,主要岩性为流纹岩、流纹质凝灰岩等,LA-ICP-MS锆石U-Pb年龄分别为129. 8±0. 8 Ma、128. 2±2. 8 Ma,属早白垩世早期;从岩石地球化学特征上看,其主量元素SiO_2含量68. 76%~76. 18%、Al_2O_3含量11. 84%~13. 38%,属高钾钙碱性岩石;稀土总量较高,(La/Yb)N 6,(La/Sm)_N 3,显示为轻稀土富集型,δEu显示负铕异常(0. 4~0. 6),微量元素以富集大离子亲石元素K、Rb、Ba,贫高场强元素Nb、P、Ti为特征; Sr-Nd同位素组成上具有低I_(Sr)、高ε_(Nd)(t)和低t_(DM)的特征(I_(Sr)=0. 7039~0. 7045,ε_(Nd)(t)=2. 65~4. 39)。火山岩浆来源于下地壳基性物质的部分熔融,综合研究并结合前人资料认为,白音高老组流纹岩形成于滨太平洋板块俯冲后伸展及蒙古-鄂霍次克洋闭合后的综合效应下。  相似文献   

9.
西藏冈底斯中部广泛发育中新生代岩浆活动,而其岩石成因及岩浆源区仍存争议。早白垩世岩浆作用既是探究冈底斯带大规模的岩浆成矿作用的关键要素,又是认识其地球动力学过程的关键窗口。本文以中冈底斯带确角弄地区出露的早白垩世花岗质岩体为对象,进行了详细的LA-ICP-MS锆石U-Pb年代学、全岩地球化学和Sr-Nd同位素研究。花岗质岩体岩石类型以黑云母花岗闪长岩为主,其次为石英二长岩、正长花岗岩等,属I型偏铝质高钾钙碱性系列花岗岩。确角弄岩体黑云母花岗闪长岩侵位年龄为127±1.6Ma,(~(87)Sr/~(86)Sr)_i值高(0.70926~0.71424),负全岩ε_(Nd)(t)值(-7.0~-9.1),微量元素表现出消减带富集大离子亲石元素、亏损高场强元素的特征,显示岛弧花岗岩的亲缘性。岩浆源区主要来自古老基底岩石的部分重熔并可能有少量幔源物质的参与,经历了强烈分离结晶作用。岩石成因可能与早白垩世时受到班公湖-怒江洋壳岩石圈向南俯冲过程中发生的板片断离有关。确角弄岩体是中冈底斯早白垩世带状岩浆大爆发事件在中部的延续。岩体与围岩接触带发生了强烈的热液蚀变,具有很高的铁钨物化探异常值,局部地方发现了磁铁矿矿化点,成矿岩体锆石都具较高的Ce~(4+)/Ce~(3+)比值(450~769),锆石Ti饱和温度较高为776℃左右,显示成矿岩浆为高温岩浆热液体系并具有高氧逸度特征,化探趋势剩余异常的空间展布受地层岩性、断裂构造、岩浆岩控制明显,指示了良好的铁钨找矿前景。  相似文献   

10.
洋陆转换岩石学证据(洋内弧)的发现使识别、重建、研究洋盆转化为大陆成为可能.对中亚造山带东缘迪彦庙俯冲增生杂岩带内蛇绿岩开展岩石地球化学、Sr-Nd同位素以及锆石U-Pb年代学研究,识别出一套洋内弧火成岩组合.MORB-Like玄武岩锆石U-Pb谐和年龄为286.1±6.1 Ma,代表洋内初始俯冲时代;HMA锆石U-Pb谐和年龄为283.7±4.7 Ma,代表首次岩浆作用后、俯冲程度加深的岩浆作用时代;岛弧拉斑玄武岩(IAT)锆石U-Pb谐和年龄为241±5 Ma,指示古亚洲洋早三叠世逐渐向着正常岛弧岩浆作用转换的大陆化方向发展.从MORB-Like玄武岩到HMA再到IAT的岩石组合序列代表了洋内俯冲作用由浅到深的递进演变以及洋盆向大陆边缘岛弧逐步演化的洋陆转换过程.   相似文献   

11.
Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.  相似文献   

12.
最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提  相似文献   

13.
本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。  相似文献   

14.
This paper reports the first results of a study of 11 isotope systems (3He/4He, 40Ar/36Ar, 34S/32S, 65Cu/63Cu, 62Ni/60Ni, 87Sr/86Sr, 143Nd/144Nd, 206–208Pb/204Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.  相似文献   

15.
Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.  相似文献   

16.
本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。  相似文献   

17.
岩石密度和超高压岩石折返速率   总被引:1,自引:3,他引:1  
在常温常压条件下对中国大陆科学钻CCSD主孔100-3000米岩心样品进行了密度测量,建立了密度连续剖面,并界定了不同超高压岩石的密度值。通过对比高温高压物性实验资料,岩石密度随着退变程度增强而降低,榴辉岩密度变化序列为3.52g/cm3→3.49g/cm3→3.07g/cm3→2.93g/cm3。超高压长英质岩石密度变化序列为3.00g/cm→2.80g/cm3→2.65g/cm3。上述实验资料是讨论不同折返阶段岩石所受浮力的基础,为研究折返速率大小提供了基本参数。本文通过折返板块运动平衡时,上浮力与粘滞力平衡这一关系式,定量研究了大陆俯冲板块的折返速率,认为密度差产生上浮力从而引起折返,温度对板块折返速率的影响最为显著;密度差大小、折返角度、折返板块大小对折返速率也有直接的影响。定量模拟分析表明,在温度高于850℃时,板块的折返速率可以超过100mm/a;当温度降至700℃时,折返速率则低于1.5mm/a。作者认为在折返早期,温度较高,板块快速折返至60-70km榴辉岩相深度;随着传导散热,温度降低,板块以较慢的速率折返至中下地壳。折返速率的估算表明,浮力是板块折返第一阶段(从>100km深部折返至<40km的中下地壳)的主要驱动力。  相似文献   

18.
Bellechester, Minnesota, is a small community of approximately 155 residents located on the county line between Goodhue and Wabasha counties in southeast Minnesota's karst region. Bellechester is served by a 21-year-old wastewater treatment facility (WWTF) consisting of three waste-stabilization ponds. On 28 April 1992 six sinkholes were discovered to have drained cell 2 of the WWTF resulting in the loss of approximately 8.7×106 1 of partially treated effluent and about 600 m3 of soil into previously undetected subsurface voids of unknown dimensions. In the week following the collapse, approximately 200 water wells located within a 5-km radius of the WWTF were sampled in an after-the-fact, emergency sampling program. Twelve samples with elevated fecal coliform levels, 18 samples with nitrate-nitrogen greater than the 10 mg/1 standard, and no samples with elevated chlorides were found. However, the elevated levels could not be unambiguously attributed to the WWTF collapse. This is the third WWTF to fail by sinkhole collapse in southeast Minnesota since 1974. All three collapsed lagoons have been located in similar geomorphic and stratigraphic settings. However, at least two lagoons have collapsed in the adjacent area in northeast Iowa, and these lagoons are located at different stratigraphic positions. Twenty-two WWTFs constructed in southeast Minnesota's karst region in the last 25 years have been identified as subject to potential sinkhole collapse. An unknown but significant number of manure storage lagoons, flood control structures, etc., have also been constructed in the karst region and are at risk. Public agencies are beginning to develop plans to deal with the risk associated with existing and future waste lagoons in this environment. The critical hydrogeologic parameters that can be used to prioritize the risk of collapse at existing facilities include: (1) the lithology of the first bedrock beneath each lagoon, (2) the thickness of surficial materials between the lagoon and the bedrock surface, (3) the presence and construction of liners (seepage rate), and (4) the proximity to existing sinkholes.  相似文献   

19.
The Kuskokwim River at Bethel, Alaska, drains a major mercury-antimony metallogenic province in its upper reaches and tributaries. Bethel (population 4000) is situated on the Kuskokwim floodplain and also draws its water supply from wells located in river-deposited sediment. A boring through overbank and floodplain sediment has provided material to establish a baseline datum for sediment-hosted heavy metals. Mercury (total), arsenic, antimony, and selenium contents were determined; aluminum was also determined and used as normalizing factor. The contents of the heavy metals were relatively constant with depth and do not reflect any potential enrichment from upstream contaminant sources.  相似文献   

20.
滇东南锡、银、铅、锌多金属矿床主要分布在个旧、白牛厂、都龙3个矿区,而滇东南较大的3个花岗岩体又分别出露在3个矿区或附近.花岗岩体均形成于燕山晚期,岩石化学、矿物成分相似,富含锡、银、铅、锌、钨、铜等成矿元素.矿床主金属元素组合与岩体之间的距离由远而近出现由锡、钨、(铍、铌、钽)→锡、钨、(铁)、铜、铟→锡、铅、锌、银、铟、(锑)有规律的变化.花岗岩浆是成矿物质来源和成矿热源.岩浆侵入初期使上覆地层隆起产生背斜(凹陷部位成向斜);同时使地层产生一系列裂隙、压性断层或层间断裂;岩浆侵入晚期,这些断层再次活动,表现为张性,岩浆产生的含矿热液沿由其活动所造成的断裂迁移、充填、交代、沉淀而形成矿床.  相似文献   

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