地壳中的岩浆储库

岩浆储库是地壳内岩浆储存和演化的主要场所，是地球内外部圈层能量和物质交换的桥梁。对岩浆储库的研究贯穿在整个岩浆岩的研究历史中，并逐渐形成了多种理论假说。本文介绍了岩浆、晶粥等基本概念，总结了地球物理、岩石学和地球化学、数值模拟三种常用的研究手段及其适用范围，重点探讨了大岩浆房模型、晶粥模型和多层岩浆系统模型的主要内容和重要进展，系统比较了不同模型的异同点。这些假说模型并非是非此即彼的，可能反映了岩浆储库在不同演化阶段的状态。最后，本文探讨了岩浆储库模型对岩浆过程、火山喷发和地壳生长等科学问题带来的新的认识和挑战。     

河南桐柏老湾花岗岩岩浆动力学与成矿

基于岩浆岩岩石学、流体动力学、热力学研究。本文计算了河南桐伯老湾花岗岩岩浆过程的上升速度、冷凝速度及岩浆熔体的密度、粘度、含水量等物理参数，探讨了熔体中晶体的成核密度和生长速度以及岩浆对流形式等动力学行为，并分析了它们与成矿作用的联系。研究表明，老湾花岗岩岩浆含水量为4．76％，在侵位的温度和压力下是饱和的，较高的水含量有利于矿化。老湾花岗岩熔体上升较快而冷却缓慢，晶体成核密度和生长速度较低，以挥发分为迁移形式的成分对流是熔体中成矿物质迁移、富集的主要方式。老湾花岗岩特殊的岩浆物理性质和动力学行为指示其岩浆作用与老湾金矿床的形成具有密切的成因联系。     

地壳硅质岩浆演化的动力学机制SCIEI北大核心CSCD

硅质岩浆的成因及演化机制研究是认识大陆地壳成分结构演化机制的关键途径。地壳硅质岩浆储库的基本性质及其演化的动力学过程是制约硅质岩浆演化及其多样性的根本原因,也是受到广泛关注的前沿和热点问题。本文总结了硅质岩浆储库的基本性质及其演化机制研究的相关进展,重点探讨了岩浆体系演化的动力学机制,即其物质成分及温度压力条件的动态演化过程,亦即岩浆储库在补给驱动下的存留、活化、分异、喷发过程。经由累积生长的方式形于地壳浅部的硅质岩浆储库以晶粥为主要赋存形式,具有较低的温度压力范围和高硅高结晶度高粘度的特征。岩浆储库的基本性质导致其自身不具有持续演化的能力,只有在基性岩浆补给的驱动下才能长时间存留分异或快速活化喷发。基性岩浆的补给及其携带的热及流体/挥发份深刻地改变了岩浆储库的物质成分及物理条件,是导致硅质岩浆分异演化或喷发的根本原因。本文还结合研究进展探讨了东南沿海地区中生代火山-侵入岩的成因演化机制及相关问题。     

陆内穿地壳岩浆系统及其去气作用和环境效应SCIEI北大核心CSCD

岩浆作用是联系地球深部与表层碳储库的桥梁,是全球碳循环的重要一环。揭示岩浆作用与碳循环之间的关系对理解地球系统演化过程中的环境效应和气候变化有重要意义。本文综述了前人在岩浆系统研究的重要进展,介绍了陆内穿地壳岩浆系统,梳理了从幔源岩浆底侵和地壳熔融,到岩浆上升、累积、混合、分异直至喷出等物理化学过程,构建了地壳岩浆活动的统一框架。岩浆过程同时控制着挥发分行为,岩浆自身的去气作用将地球深部挥发分带到地表,而接触热变质作用可改造围岩并将其中的碳脱出。基于穿地壳岩浆系统,本文系统阐述了岩浆挥发分的来源、组成、行为,及其释放到大气中对气候与环境产生的潜在影响。尤其是针对中国华南地区分布的大量陆内中生代的侵入岩和火山岩,结合同期广泛分布的巨厚碳酸盐岩,介绍和展望了陆内岩浆系统和去气作用的联系及环境效应,提出该时期的岩浆活动及其与碳酸盐岩的反应很可能对局部乃至全球的气候造成了显著的影响,该领域有较大研究潜力。     

晶粥储存、侵入体累积组装与花岗岩成因

花岗质岩浆在地壳内的储存、迁移和分异,是导致大陆地壳生长演化的基本过程.有关地壳岩浆冷储存的新发现,挑战了数十年来深部存在以熔融体为主要组成的大岩浆房的观点.对活火山区的地球物理探测、岩石矿物学研究以及热历史模拟都一致证明,岩浆储库中的物质以晶粥为主,它们长时间处于固相线下的温度条件,属于冷储存状态.今天出露地表的大型侵入岩体,是古岩浆储库的代表,它们大都是在数百万年甚至更长的时间跨度内,多幕式的岩浆输运、累积侵位和多次添加组装而成的.侵入体的累积组装,可以通过岩石单元间接触关系的观察、岩石和矿物成分的不均一性研究以及侵入体内大的结晶时间跨度来证明.地壳浅部大型侵入体的形成,大体积的火山喷发,都要求存在穿地壳的岩浆通道系统,该系统中岩浆主要以岩墙形式将不同深度的岩浆储库串联起来,并通过无数岩床的堆垛而形成巨大的岩株或岩基等侵入体.高分异花岗岩和高硅流纹岩的存在,尤其是火山的超级喷发现象,要求岩浆储库的晶粥体发生活化和分异,而晶粥的解体往往是由于从下部侵入的新岩浆注入了额外的热和流体.保留在岩石中的晶体种群蕴含了侵入体累积组装、晶粥活化和岩浆分异的线索.尤其是再循环晶可以提供岩浆通道系统结构和演变的新信息.未来,在花岗岩成因研究中,重点要从晶粥活化与岩浆分异演化过程、岩浆上升和组装机制、火山岩与侵入岩的成因联系等方面入手,开展岩浆通道系统的跨学科研究,构建花岗岩岩浆过程研究的新范式,深入认识大陆地壳的生长和演化机理.      

卧龙湖煤矿岩浆蚀变煤层中汞的分布与赋存特征

系统采集淮北卧龙湖煤矿岩浆蚀变煤层中岩浆岩、煤及顶底板岩石样品,测试分析了样品中汞、灰分、挥发分、水 分以及各形态硫的含量,探讨了岩浆蚀变煤层中汞的分布与赋存特征。结果表明：（1） 岩浆侵入导致煤中灰分升高,挥发 分降低,煤中硫主要以黄铁矿硫和有机硫存在;（2） 岩浆侵入导致煤中汞的富集,卧龙湖煤矿岩浆蚀变煤层中汞的平均含 量高达0.23×10-6,是华北石炭-二叠纪煤、中国煤以及美国煤中汞的平均含量的1.4 倍,1.2 倍和1.3 倍;（3） 煤中汞的含量 随离岩浆侵入体距离增大有逐渐降低的趋势,但在煤岩接触带附近,汞在岩浆侵入体上方和下方的煤中呈现不同的分布特 征;（4） 煤中的汞主要以无机结合态的形式存在,且大部分赋存在煤中的黄铁矿中,同时亦存在与有机硫结合的汞。岩浆 热液对煤层的侵入,导致煤质以及煤中汞的含量和赋存方式发生了显著变化。     

火成岩中的超临界流体晶及其研究意义

流行火成岩理论中,岩浆被默认为自然熔体,因而火成岩中的矿物晶体都形成于熔体的结晶作用,可称为熔体晶。许多证据表明,火成岩中也可以含有从超临界流体析出的晶体,被称为超临界流体晶(文中简称为流体晶)。根据三个典型实例分析,流体晶既可以从超临界流体直接析出,类似于从热液析出晶体的过程;也可以由超临界流体浓缩产生的熔体结晶形成。不管是哪一种晶出方式,流体晶产生的前提都是岩浆达到流体过饱和态;而满足这一前提的基本条件则是透岩浆流体过程和岩浆快速上升。结合前人关于熔体流体平衡条件的研究进展,以及熔体黏度对挥发分含量和岩浆上升速度对熔体黏度的依赖,发现透岩浆流体过程与岩浆上升过程之间具有耦合关系,这种关系可以用来阐明岩浆系统行为非线性变化的原因。流体晶的研究具有重要意义,可用于：(1)提供一种研究岩浆系统流体条件的新途径;(2)揭示岩浆系统偏离理想态的程度;(3)为反演岩浆系统动力学过程提供新的约束;(4)为识别致矿侵入体和评估侵入体的找矿潜力提供新的矿物学标志;(5)理解火成岩理论中一些长期得不到解决的问题,如岩浆中挥发分溶解度问题、冻结岩浆的活化问题、岩浆成矿专属性问题。     

岩浆不混溶作用过程中的岩浆动力学条件

岩浆不混溶作用过程中的岩浆动力学研究是岩石学研究领域中的一个空白。本文以粘性流体力学，流变学理论为基础，结合某些岩浆动力学实验结果，首次探讨了在岩浆发生不混溶作用过程中，某些岩浆的物理性质及贵浆运动的动力学的约束条件，主要包括：不混溶作用产生的两液相的分离速率，球体的沉浮条件，分布特征及雷诺数的计算方法，并探讨了这些参数在研究岩浆不混溶作用过程中的地质意义。     

锡的地球化学性质与华南晚白垩世锡矿成因

锡在地质过程中表现出亲氧、亲硫和亲铁三重特性。在地幔岩浆过程中,锡是一种中等不相容的金属元素。锡成矿主要与酸性岩浆活动有关,其地球化学性质决定了其成矿主要受源区性质、氧逸度以及挥发分含量、岩浆结晶分异等因素控制。高度结晶分异可使锡在岩浆中进一步富集,是锡成矿相关花岗岩的普遍特征;锡为变价元素,岩浆体系氧逸度影响源区中锡的迁移能力和分离结晶过程中锡的元素行为,还原性岩浆体系有利于锡富集成矿。富含F、Cl和B等挥发组分对锡元素的迁移和富集起积极的作用。全球锡矿床分布与俯冲带关系密切,特提斯和环太平洋构造域是主要蕴藏区。重要的锡成矿事件表现出区域性和阶段性的特征。结合锡的地球化学特性以及锡矿分布特征,我们认为最有利锡成矿的动力学机制是俯冲板片后撤机制。俯冲板片后撤引发深部软流圈地幔上涌,导致强烈的壳幔相互作用,形成低氧逸度、富F、Cl和B等花岗岩,有利于锡成矿。对于华南晚白垩世锡成矿事件,新特提斯洋俯冲板片发生后撤是其成矿地球动力学背景。     

熔体包裹体挥发分应用的研究进展

挥发分(例如H2O、CO2、F、Cl和S)是地幔的重要组成部分,虽然它们在地幔中的含量很低,但是在地幔熔融和熔体演化、地幔不均一、地幔流变学、地幔地震特性和电导率等研究方面具有重要作用。对矿物熔体包裹体和玻璃挥发分的研究已经成为当前的研究热点。其中,熔体包裹体研究凭借其独特的优势成为研究地幔和岩浆挥发分组成的重要手段。熔体包裹体直接捕获了矿物形成时岩浆中的成分,且由于寄主矿物的存在使得熔体包裹体能够保持独立演化而不受外界环境影响,因此能够较为完整地保存岩浆中的挥发分信息。同时,研究熔体包裹体中的挥发分是恢复岩浆喷发前挥发分含量最直接的途径。如果通过现代分析方法(如扫描电镜、电子探针和离子探针等)对熔体包裹体进行详细的岩相学观察以及对后期可能影响熔体包裹体原始挥发组分的作用(地壳混染、岩浆去气、扩散和水化作用)进行评估,并结合实验研究熔体包裹体被捕获后发生的变化而对数据进行矫正,那熔体包裹体对研究岩浆体系中的挥发分将大有可为。基于此,本文系统介绍了熔体包裹体挥发分研究的现状及主要研究内容,主要包括熔体包裹体挥发分的测试方法、挥发分在岩浆中的溶解度、判断挥发分数据可靠性和挥发分研究的经典应用等4个方面。     

Contrasting magmatic structures between small plutons and batholiths emplaced at shallow crustal level (Sierras de Córdoba,Argentina)

Processes like injection, magma flow and differentiation and influence of the regional strain field are here described and contrasted to shed light on their role in the formation of small plutons and large batholiths their magmatic structures. The final geometric and compositional arrangement of magma bodies are a complex record of their construction and internal flow history. Magma injection, flow and differentiation, as well as regional stresses, all control the internal nature of magma bodies. Large magma bodies emplaced at shallow crustal levels result from the intrusion of multiple magma batches that interact in a variety of ways, depending on internal and external dynamics, and where the early magmatic, growth-related structures are commonly overprinted by subsequent history. In contrast, small plutons emplaced in the brittle-ductile transition more likely preserve growth-related structures, having a relatively simple cooling history and limited internal magma flow. Outcrop-scale magmatic structures in both cases record a rich set of complementary information that can help elucidate their evolution. Large and small granitic bodies of the Sierra Pampeanas preserve excellent exposures of magmatic structures that formed as magmas stepped through different rheological states during pluton growth and solidification. These structures reveal not only the flow pattern inside magma chambers, but also the rheological evolution of magmas in response to temperature evolution.     

http://www.sciencedirect.com/science/article/pii/S1674987111000429

The three most crucial factors for the formation of large and super-large magmatic sulfide deposits are: (1) a large volume of mantle-derived mafic-ultramafic magmas that participated in the formation of the deposits; (2) fractional crystallization and crustal contamination, particularly the input of sulfur from crustal rocks, resulting in sulfide immiscibility and segregation; and (3) the timing of sulfide concentration in the intrusion. The super-large magmatic Ni-Cu sulfide deposits around the world have been found in small mafic-ultramafic intrusions, except for the Sudbury deposit. Studies in the past decade indicated that the intrusions hosting large and super-large magmatic sulfide deposits occur in magma conduits, such as those in China, including Jinchuan (Gansu), Yangliuping (Sichuan), Kalatongke (Xinjiang), and Hongqiling (Jilin). Magma conduits as open magma systems provide a perfect environment for extensive concentration of immiscible sulfide melts, which have been found to occur along deep regional faults. The origin of many mantle-derived magmas is closely associated with mantle plumes, intracontinental rifts, or post-collisional extension. Although it has been confirmed that sulfide immiscibility results from crustal contamination, grades of sulfide ores are also related to the nature of the parental magmas, the ratio between silicate magma and immiscible sulfide melt, the reaction between the sulfide melts and newly injected silicate magmas, and fractionation of the sulfide melt. The field relationships of the ore-bearing intrusion and the sulfide ore body are controlled by the geological features of the wall rocks. In this paper, we attempt to demonstrate the general characteristics, formation mechanism,tectonic settings, and indicators of magmatic sulfide deposits occurring in magmatic conduits which would provide guidelines for further exploration.     

The magmatic to hydrothermal transition and its bearing on ore-forming systems

The exsolution of volatile phases from silicate magmas controls physical and chemical magma properties and influences large-scale geologic phenomena and processes having major societal and economic implications including the release of climate-altering gases to the atmosphere, the explosivity of volcanic eruptions, hydrothermal alteration, and the generation of magmatic–hydrothermal mineralization. These volatile phases exsolve from a wide variety of magmas and cover a very broad spectrum of compositions.

The transition from the orthomagmatic to the hydrothermal stages has important bearing on these fundamentally important geologic phenomena, and this report summarizes the published results of a dozen scientific investigations on the magmatic–hydrothermal transition as applied to volcanic eruption and magmatic–hydrothermal mineralization. These studies involve a variety of analytical and experimental methodologies, and many focus on fluid and melt inclusions from mineralized magmatic systems. A primary goal of each study is to better understand the role of magmatic volatiles and the importance of the magmatic–hydrothermal transition on these geologic processes.     

对岩浆过程的进一步解析

对于岩浆作用来说,岩石地球化学方法更多地用来探讨岩浆的起源、不同岩浆的相互混合、围岩对岩浆的混染及岩浆自身的演化和团结等。实验岩石学与岩相学研究相结合至今已构成了基本的岩石学理论框架,近些年来的工作一般是为不多见的岩石学现象、难以解决的岩理学问题及有关的岩浆过程进行更加深化和补充的实验。岩浆动力学利用流体力学的方法定量描述岩浆过程,建立理论模型。本文从这三方面简要叙述新近对岩浆过程分析研究的某些进展。     

岩浆运移动力学及其研究进展

岩浆运移动力学是岩浆动力学的重要分支领域，研究内容包括5个方面：运移方式、运移通道、运移途径、运移动力与运移过程的成矿作用。就这5方面的研究进展进行了系统回顾，对尚待进一步研究的科学问题进行了归纳与总结，指出浮力不是弹性岩石圈岩浆运移上升的驱动力，而上地幔岩浆运移方式、弹性岩石圈岩浆往上运移驱动力、岩浆自主破裂形成的动力学机制、中途停歇岩浆重起动再运移的驱动机制、岩浆再停歇和运移过程的结晶与分异及其与围岩相互作用和伴生的元素富集与成矿作用等问题是岩浆运移动力学是尚待进一步攻关与研究的关键性科学问题。     

花岗岩体的累积生长与高结晶度岩浆的分异

花岗岩成因研究是认识大陆地壳形成和分异的有效方式。野外地质和地球物理观测、岩石学和地质年代学研究以及热演化模拟证明,很多花岗岩体是在数百万年甚至更长的时间跨度内、由多次岩浆累积添加侵位而成的。地壳内可能不存在岩基尺度的大岩浆房,具有流动能力的岩浆体一般规模很小(宽度1000m)。1000m宽的岩浆体冷凝到固相线只需要数千年时间。复式岩体的形成一般要经历三个阶段,即源区岩浆沿岩墙的上升、在脆-韧性地层界面处岩墙转化为岩床以及无数的岩床的垂向堆垛导致侵入体长大。存在于上地壳的岩浆储库,特别是多次先后侵位产生的岩浆体,主体上是晶粥体,其晶体含量高,粘度大,活动性弱,不利于发生对流、分异和混合。当幔源镁铁质岩浆大规模注入到地壳时,使粘稠的晶粥状岩浆受到加热,熔体含量增大,岩浆的粘度降低,引起岩浆体内部的成分分异和不同成分的岩浆之间的混合;当逐渐加厚的熔体层产生了足够大的浮力后,特别是有挥发份加入后,就会快速上升,甚至穿透上部的晶粥体,触发大规模的火山喷发。幔源岩浆的通量越大,地壳岩浆的活动性也越强,大规模的长英质岩浆聚集就可能发生大喷发,形成超级火山。本文提出,只有将侵入岩与火山岩相结合、长英质岩石与镁铁质岩石相结合,重点从侵入体形成的时间长短、岩浆相互作用的规模和频率、岩浆通量的演变、高结晶度的岩浆分异机理、侵入岩与火山岩的关系、地幔热和物质的贡献、挥发份在岩浆分异和火山喷发中的作用等方面入手,开展野外地质、岩石学、地球化学、同位素年代学及岩浆动力学的综合研究,才能深入认识花岗岩的成因机制,深化对大陆地壳形成和演化过程的理解。     

Analysis and simulation of magma mixing processes in 3D

Magma mixing structures from the lava flow of Lesbos (Greece) are analyzed in three dimensions using a technique that, starting from the serial sections of rock cubes, allows the reconstruction of the spatial distribution of magmas inside rocks. Two main kinds of coexisting structures are observed: (i) “active regions” (AR) in which magmas mix intimately generating wide contact surfaces and (ii) “coherent regions” (CR) of more mafic magma that have a globular shape and do not show large deformations. The intensity of mingling is quantified by calculating both the interfacial area (IA) between interacting magmas and the fractal dimension of the reconstructed structures. Results show that the fractal dimension is linearly correlated with the logarithm of interfacial area allowing discrimination among different intensities of mingling.

The process of mingling of magmas is simulated using a three-dimensional chaotic dynamical system consisting of stretching and folding processes. The intensity of mingling is measured by calculating the interfacial area between interacting magmas and the fractal dimension, as for natural magma mixing structures. Results suggest that, as in the natural case, the fractal dimension is linearly correlated with the logarithm of the interfacial area allowing to conclude that magma mixing can be regarded as a chaotic process.

Since chemical exchange and physical dispersion of one magma inside another by stretching and folding are closely related, we performed coupled numerical simulations of chaotic advection and chemical diffusion in three dimensions. Our analysis reveals the occurrence in the same system of “active mixing regions” and “coherent regions” analogous to those observed in nature. We will show that the dynamic processes are able to generate magmas with wide spatial heterogeneity related to the occurrence of magmatic enclaves inside host rocks in both plutonic and volcanic environments.     

Apatite as a monitor of late-stage magmatic processes at Volcán Irazú, Costa Rica

Apatite phenocrysts from the 1963 and 1723 eruptions of Irazú volcano (Costa Rica) record a volatile evolution history that confirms previous melt inclusion studies, and provides additional information concerning the relative and absolute timing of subvolcanic magmatic events. Measurements of H, Cl, and F by secondary ion mass spectrometry reveal multiple populations of apatite in both 1723 and 1963 magmas. Assuming nominal apatite/melt partition coefficients allows us to compare the pattern of melt inclusions and apatites in ternary space, demonstrating the fidelity of the record preserved in apatite, and revealing a complex history of magma mixing with at least two components. The preservation of heterogeneous populations of apatite and of internally heterogeneous crystals requires short timescales (days to years) for these magmatic processes to occur.     

Variable parent magmas and recharge regimes of the Parinacota magma system (N. Chile) revealed by Fe, Mg and Sr zoning in plagioclase

Zoning patterns of An content and Fe, Mg and Sr concentrations in plagioclase phenocrysts in andesites from Parinacota Volcano (N. Chile) reflect alternating recharge events with two chemically distinct mafic magmas. These magmas are characterized by low and high Sr contents, similar to two recent mafic flank eruptions. One end-member basaltic andesite shows large Sr enrichment and Heavy Rare Earth depletions and thus equilibrated with lower-crustal rocks at depth where plagioclase (high Sr) is unstable, and garnet (high HREE, Y) is stable. A second end-member magma is lower in Sr, Ba contents and has REE patterns typical for parent magmas elsewhere in the Central Andes.

The number of recorded recharge events increases after a catastrophic sector collapse and during the subsequent rebuilding of the stratocone. Variations of An, Fe and Mg contents and morphology of zones suggest also changes in water pressure, including decompression under water under-saturated and water-saturated conditions. Evidence for decompression is more present in post-collapse samples, suggesting that the change in the volcano dynamics involves changes in magma chamber location. This shows the importance of the cone collapse event in the volcano's magmatic evolution. We propose that both end-members are only seen at the surface of Parinacota Volcano because of the particular dynamics of this volcanic system and that similar processes might occur in other volcanic centres of the Central Volcanic Zone.