新疆东准噶尔贝勒库都克锡矿床成矿时代及成矿作用

贝勒库都克锡矿床赋存于正长花岗岩中,矿化类型主要为蚀变花岗岩型、云英岩型和石英脉型。对云英岩型锡矿石中的白云母进行了40Ar39Ar年龄测定,获得坪年龄为306.8 ± 2.4 Ma～309.7 ± 2.4 Ma,与正长花岗岩306 ±5 Ma在误差范围内一致。这组坪年龄不仅精确地反应出成矿的时间限制,而且表明了正长花岗岩与锡成矿的密切关系。锡矿石中石英流体包裹体划分为NaCl—H2O型和NaCl—H2O—CO2—CH4型。成矿温度主要集中在160～250℃和280～390℃,峰值在210℃和330℃,流体盐度为1.22%～7.86% NaCleq,流体密度为0.55～0.96g/cm3。锡矿石中石英的δDSMOW介于-128‰～-95‰,δ18OSMOW值介于9.6‰～14.‰,δ18OH2O值为1.56～8.09‰,表明成矿流体主要为岩浆水,混合少量大气降水。物理化学条件改变、水—岩交换作用及CO2—CH4和NaCl—H2O 的不混溶作用在锡成矿过程中起着重要作用。     

华北地块南缘中段中生代花岗质岩石的40Ar-39Ar年代学研究

对华北地块南缘4个中生代花岗质岩体中的角闪石和黑云母进行了40Ar-39Ar定年研究。结果表明,陕西黑山村岩体黑云母花岗闪长岩中黑云母的40Ar-39Ar坪年龄为126. 6±0. 3Ma,河南马家湾岩体细粒黑云母花岗闪长岩中黑云母的40Ar-39Ar坪年龄为126. 6±0. 2Ma,河南洛宁南八百坡岩体黑云母二长花岗岩中角闪石的40Ar-39Ar坪年龄为128. 3±0. 3Ma,山西蚕坊岩体花岗闪长岩中角闪石的40Ar-39Ar坪年龄为129. 2±0. 2Ma。上述结果显示华北地块南缘中生代的岩浆活动主要发生在早白垩世。该期岩浆的产生应与中国东部早白垩世的伸展环境相联系。     

塔里木盆地塔参1井底部花岗闪长岩的^40Ar-^39Ar年代学研究

我国陆上最深的钻井——塔参1井,井深7200m,其底部钻遇的是一分布有闪长岩捕虏体的花岗闪长岩体。我们采集花岗闪长岩样品和闪长岩样品,分选角闪石单矿物进行~(40)Ar-~(39)Ar定年。花岗闪长岩的加~(40)Ar-~(39)Ar坪年龄为932.3±0.6Ma和891.0±1.9Ma,相应的等时年龄分别为933.8±6.8Ma和892.2±32.7Ma;闪长岩~(40)Ar-~(39)Ar坪年龄为1195.7±1.0Ma,等时年龄为1199.4±6.4Ma。本项研究结果表明,塔参1井底部的火成岩为一花岗闪长岩岩体,侵位时代为新元古宙早期;闪长岩形成于中元古宙晚期,是花岗闪长岩中的捕虏体。塔里木盆地腹地存在前寒武纪古老陆壳基底,该岩体就是其重要的组成部分。     

甘肃南金山金矿床的40Ar-39Ar同位素年龄及其地质意义

南金山金矿是我国西北地区最重要的金矿床之一,矿床产于下石炭统白山组浅变质海相火山碎屑岩中.本文通过对金矿床中的蚀变绢云母进行了40Ar-39Ar同位素年龄测定,获得了两组数据,分别为250.6±2.8 Ma和232.7±4.1Ma,说明南金山金矿的形成经历了两期成矿作用.     

辽东青城子矿集区金、银成矿时代及地质意义

为确定辽宁青城子矿集区金、银的成矿时代 ,分别以含金硅化岩和含银网脉状石英晶体内流体包裹体为对象 ,应用Rb_Sr法测得金、银成矿的等时线年龄为 (2 33± 31)Ma～ (2 34± 14 )Ma ;作为对Rb_Sr法测年结果的验证 ,又以与贵金属矿石矿物共生的热液石英为对象 ,用40 Ar/3 9Ar快中子活化法测得坪年龄tp=(2 38.78± 0 .74 )Ma～ (2 38.80± 0 .6 0 )Ma,等时线年龄ti=(2 39.4 6± 1.13)Ma～ (2 4 0 .35± 0 .88)Ma。Rb_Sr和40 Ar/3 9Ar两种方法的测年结果基本一致 ,与本区印支期岩浆活动时代〔2 17.6Ma～ (2 30 .7± 5 )Ma〕吻合。     

新疆阿克提什坎金矿床石英^40Ar／39Ar快中子活化年龄及其意义

对新疆北阿尔泰诺尔特地区阿克提什坎金矿床主成矿阶段的石英样品进行40Ar/39Ar快中子活化法测年,其坪年龄为138.5±2.1Ma, 等时年龄为135.4±4.2Ma,坪年龄代表石英的形成年龄.结合本区及邻区其他年代学测试结果认为,新疆北阿尔泰地区可能存在燕山期金的成矿作用,且燕山期可能是诺尔特地区金成矿的主要时期.     

华北地台北缘中段金矿床成矿年代学研究

华北地台北缘中段是我国重要的金矿化集中区。文中采用石英的4 0 Ar - 39Ar法和单颗粒锆石的U -Pb测年法 ,结合前人资料 ,提出本区绿岩带初生型金矿床的成矿时代为古元古代—新太古代 ,其中辽西排山楼金矿的成矿时代为 (2 10 5 .2± 10 .4)Ma ,金厂峪金矿的成矿时代为 (2 5 39± 2 3)Ma ,小营盘金矿的成矿时代为180 0Ma左右。构造期后再生型金矿床的成矿时代为燕山晚期—华力西中期 ,其中东坪金矿床的成矿时代为(35 0 .9± 0 .9)Ma ,冀东头道门子沟金矿的成矿时代为 (2 17.32± 2 .0 4)Ma ,峪耳崖金矿床的成矿时代为燕山早期 ,金厂沟梁和二道沟金矿的成矿时代为燕山晚期。     

华北地台北缘中段金矿床成矿年代学研究

华北地台北缘中段是我国重要的金矿化集中区.文中采用石英的(40)Ar-(39)Ar法和单颗粒锆石的U-Pb测年法,结合前人资料,提出本区绿岩带初生型金矿床的成矿时代为古元古代—新太古代,其中辽西排山楼金矿的成矿时代为(2 105.2±10.4)Ma,金厂峪金矿的成矿时代为(2 539±23)Ma,小营盘金矿的成矿时代为1 800Ma左右.构造期后再生型金矿床的成矿时代为燕山晚期—华力西中期,其中东坪金矿床的成矿时代为(350.9±0.9)Ma,冀东头道门子沟金矿的成矿时代为(217.32±2.04)Ma,峪耳崖金矿床的成矿时代为燕山早期,金厂沟梁和二道沟金矿的成矿时代为燕山晚期.     

吉林延边地区浅成热液金(铜)矿床的~(40)Ar/~(39)Ar激光探针测年与成矿时代讨论

延边地区是中国东北部陆缘浅成热液金铜矿床发育的地区之一,广泛发育着浅成热液金矿床、中温热液金(铜)矿床和中深成中高温热液富金铜矿床(类斑岩型);富金铜矿床的成矿时代发生在105～102 Ma,为了进一步确定浅成热液金矿床与中深成中高温热液富金铜矿床的成矿动力学背景,采用流体包裹体的~(40)Ar/~(39)Ar激光探针定年法,对该区典型浅成热液金矿床进行了精细的年代学测定,获得刺猬沟金矿床、五星山金矿床和杜荒岭金矿床的脉石矿物石英流体包裹体的~(40)Ar/~(39)Ar等时线年龄分别为(141±7)Ma、(123±7)Ma和(107±6)Ma,其中刺猬沟金矿床((141±7)Ma)和五星山金矿床((123±7)Ma)的脉石矿物石英流体包裹体含有过剩放射性成因~(40)Ar,而杜荒岭金矿床((107±6)Ma)的脉石矿物石英流体包裹体几乎不含或含极少量过剩放射性成因~(40)Ar。结合最新获得的相关地质体的精细年代学成果,认定该区浅成热液金矿床成矿作用均发生在早白垩世晚期,或发生在早白垩世晚期火山喷发、浅成岩浆就位之后,其形成环境与富金铜矿床一致,为古太平洋板块向亚洲大陆正北向俯冲转入Izanagi-Farallon板块西向俯冲的构造转换期。     

甘肃北山南金山金矿床流体包裹体研究

包裹体研究表明,南金山金矿含金矿化体及石英脉中流体包裹体发育一般,且粒度偏小,主要为CO2包裹体和气液2相包裹体.南金山金矿床成矿流体以中低温(160～240℃)、中低盐度(w(NaCl)=6％～7％)、富含CO2为特征,成矿流体属于Na+(K+,Ca2+)-Cl--(F-)-H2O体系.石英矿物氢氧同位素测试结果,δ...     

Wavelength-dispersive X-ray fluorescence spectrometric determination of Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites

Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.     

高压微波消解法测定醋酸纤维过滤器采集的微尘粒子中的砷镉钴铬铜铁锰镍铅钒锌

最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提     

硅酸盐类样品中硅、铁、铝、钛、锰、钙、镁、钾、钠和磷的x射线荧光光谱测定

本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.     

Viscous, cohesive, non-Newtonian, depositing, radial slurry flow

Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.     

硅酸盐中铁、锰、钛、钙、钾、磷、硅、铝、镁、钠、锶、铷、钡的X-射线荧光光谱定量测定

本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。     

岩石密度和超高压岩石折返速率

在常温常压条件下对中国大陆科学钻CCSD主孔100-3000米岩心样品进行了密度测量,建立了密度连续剖面,并界定了不同超高压岩石的密度值。通过对比高温高压物性实验资料,岩石密度随着退变程度增强而降低,榴辉岩密度变化序列为3.52g/cm3→3.49g/cm3→3.07g/cm3→2.93g/cm3。超高压长英质岩石密度变化序列为3.00g/cm→2.80g/cm3→2.65g/cm3。上述实验资料是讨论不同折返阶段岩石所受浮力的基础,为研究折返速率大小提供了基本参数。本文通过折返板块运动平衡时,上浮力与粘滞力平衡这一关系式,定量研究了大陆俯冲板块的折返速率,认为密度差产生上浮力从而引起折返,温度对板块折返速率的影响最为显著;密度差大小、折返角度、折返板块大小对折返速率也有直接的影响。定量模拟分析表明,在温度高于850℃时,板块的折返速率可以超过100mm/a;当温度降至700℃时,折返速率则低于1.5mm/a。作者认为在折返早期,温度较高,板块快速折返至60-70km榴辉岩相深度;随着传导散热,温度降低,板块以较慢的速率折返至中下地壳。折返速率的估算表明,浮力是板块折返第一阶段(从>100km深部折返至<40km的中下地壳)的主要驱动力。     

Bellechester,Minnesota, USA,lagoon collapses

Bellechester, Minnesota, is a small community of approximately 155 residents located on the county line between Goodhue and Wabasha counties in southeast Minnesota's karst region. Bellechester is served by a 21-year-old wastewater treatment facility (WWTF) consisting of three waste-stabilization ponds. On 28 April 1992 six sinkholes were discovered to have drained cell 2 of the WWTF resulting in the loss of approximately 8.7×10⁶ 1 of partially treated effluent and about 600 m³ of soil into previously undetected subsurface voids of unknown dimensions. In the week following the collapse, approximately 200 water wells located within a 5-km radius of the WWTF were sampled in an after-the-fact, emergency sampling program. Twelve samples with elevated fecal coliform levels, 18 samples with nitrate-nitrogen greater than the 10 mg/1 standard, and no samples with elevated chlorides were found. However, the elevated levels could not be unambiguously attributed to the WWTF collapse. This is the third WWTF to fail by sinkhole collapse in southeast Minnesota since 1974. All three collapsed lagoons have been located in similar geomorphic and stratigraphic settings. However, at least two lagoons have collapsed in the adjacent area in northeast Iowa, and these lagoons are located at different stratigraphic positions. Twenty-two WWTFs constructed in southeast Minnesota's karst region in the last 25 years have been identified as subject to potential sinkhole collapse. An unknown but significant number of manure storage lagoons, flood control structures, etc., have also been constructed in the karst region and are at risk. Public agencies are beginning to develop plans to deal with the risk associated with existing and future waste lagoons in this environment. The critical hydrogeologic parameters that can be used to prioritize the risk of collapse at existing facilities include: (1) the lithology of the first bedrock beneath each lagoon, (2) the thickness of surficial materials between the lagoon and the bedrock surface, (3) the presence and construction of liners (seepage rate), and (4) the proximity to existing sinkholes.     

Mercury,arsenic, antimony,and selenium contents of sediment from the Kuskokwim River,Bethel, Alaska,USA

The Kuskokwim River at Bethel, Alaska, drains a major mercury-antimony metallogenic province in its upper reaches and tributaries. Bethel (population 4000) is situated on the Kuskokwim floodplain and also draws its water supply from wells located in river-deposited sediment. A boring through overbank and floodplain sediment has provided material to establish a baseline datum for sediment-hosted heavy metals. Mercury (total), arsenic, antimony, and selenium contents were determined; aluminum was also determined and used as normalizing factor. The contents of the heavy metals were relatively constant with depth and do not reflect any potential enrichment from upstream contaminant sources.     

滇东南花岗岩与锡、银、铜、铅、锌多金属矿床的成因关系

滇东南锡、银、铅、锌多金属矿床主要分布在个旧、白牛厂、都龙3个矿区,而滇东南较大的3个花岗岩体又分别出露在3个矿区或附近.花岗岩体均形成于燕山晚期,岩石化学、矿物成分相似,富含锡、银、铅、锌、钨、铜等成矿元素.矿床主金属元素组合与岩体之间的距离由远而近出现由锡、钨、(铍、铌、钽)→锡、钨、(铁)、铜、铟→锡、铅、锌、银、铟、(锑)有规律的变化.花岗岩浆是成矿物质来源和成矿热源.岩浆侵入初期使上覆地层隆起产生背斜(凹陷部位成向斜);同时使地层产生一系列裂隙、压性断层或层间断裂;岩浆侵入晚期,这些断层再次活动,表现为张性,岩浆产生的含矿热液沿由其活动所造成的断裂迁移、充填、交代、沉淀而形成矿床.