豫西登封地区寒武系第二统朱砂洞组生物成因的豹斑构造

豫西登封地区寒武系第二统朱砂洞组发育了大量形态极具特色的豹斑状构造。豹斑为灰-深灰色,呈管状、斑块状或网状分布,主要成分为半自形-自形的白云石;而基质为灰白-浅灰色,主要成分为微晶方解石,与豹斑界限明显。根据其形态及发育特征,这些豹斑构造可分为条带状、花斑状、网格状3种类型。根据白云石及方解石含量,含有这3类豹斑构造的岩性分别定名为云斑状灰岩、灰质斑状白云岩、斑状白云岩。研究表明,豹斑是由Thalassinoides造迹生物对沉积物扰动改造形成复杂的潜穴系统,并在成岩期优先发生白云岩交代作用所致。朱砂洞组发育的豹斑自下而上从条带状经花斑状演化为网格状,反映其沉积时的水动力逐渐降低、环境更加稳定,潜穴系统趋于复杂化、生物扰动强度增大,后期白云化程度也逐渐增强。     

关于“豹皮灰岩”的成因

襄汾县浪泉乡中奥陶统马家沟组灰岩中豹皮灰岩的豹斑是虫孔内的碳酸盐物质在成岩期经白云岩化作用而成,在碳酸盐沉积物的形成和改造过程中,生物起了巨大作用。豹斑的整体形状保留了遗迹化石的形态。     

恒山中东部灰色片麻岩剪切变形初探

恒山高级变质岩区是中国早前寒武纪变质岩研究的经典地区之一。通过对区内露头尺度的构造研究,识别出恒山灰色片麻岩在新太古代晚期发生了2期剪切变形,2期剪切变形形成的构造形迹在空间分布、岩石的变形习性、变形组构等方面均存在差异。重点分析了早期构造变形形成的各种构造形迹的特点,认为恒山中东部的灰色片麻岩早期形成的自北而南由网结状分布的强变形带向均匀带状展布的强变形带的变化是构造变形分解的结果,代表了岩石在中深构造层递进变形的过程,具有时空演变的意义。这一过程是由均匀的岩石、各向异性不均匀的岩石向强烈定向的岩石转变的过程。     

滇西上寒武统保山组瘤状灰岩成因

从瘤体与基质的矿物组成、岩石的结构构造出发,深入探讨了滇西施甸地区保山组瘤状灰岩的沉积环境及其形成机理。研究表明,滇西施甸地区上寒武统保山组瘤状灰岩存在3种成因:一种是呈互层状的泥质和灰质沉积物在半固结或弱固结状态下,经差异压实-压溶作用而形成瘤状构造,岩石中各组分含量及后期压溶作用强度的差异导致了瘤状灰岩不同的存在形式;另一种是泥质和灰质沉积物在半固结或弱固结状态下经斜坡滑塌作用形成串珠状、砾屑状灰岩;第三种则是泥灰质沉积层间歇性地暴露干裂,移位磨蚀,并被后期沉积物充填胶结形成瘤状灰岩。      

试论皖北奥陶纪豹皮灰岩的古岩溶成因

本文通过对安徽北部两个奥陶系剖面豹皮灰岩(俗称豹斑)的宏观、微观及地球化学特征研究,认为豹皮灰岩的形成与奥陶纪灰岩沉积过程中的古岩溶作用及其后生改造密切相关。其形成演化模式可概括为4个阶段:①碳酸盐岩沉积间断暴露地表发育裂隙;②各种裂隙淋滤溶蚀形成沉积岩溶洞穴体系;③海侵导致海相沉积物充填岩溶洞穴;④回流渗透或混合作用使充填物白云石化而形成“斑”。     

河北张宣地区糜棱岩的特征及找金的初步研究

近年来我们对张宣地区的研究发现,该区韧性剪切构造十分发育,呈东西向狭长带状分布于尚义—赤城—平泉韧性剪切带及两侧,宽约1～5km,长约60～70km。根据韧性剪切带构造岩的宏观、微观特征、重结晶程度、组构特征及矿物组合,将糜棱岩分为糜棱岩化岩石,糜棱岩及变晶糜棱岩三类。 1.区内糜棱岩分类及特征糜棱岩化岩石:主要分布在西水沟、四道沟等地、韧性剪切带的边部或弱变形中,变形较弱,具残斑(碎斑)结掏,斑晶粒径0.3～1.5mm,残斑为圆形、椭圆形具定向排列,成分为长石、石英、角闪石、黑云母、磷灰石、石榴石等。长石以条纹长石、斜长石为主,其条纹及聚片双晶多发生弯曲,石英破裂纹发育,具波状消光,糜棱岩化岩石的基质为细粒或微粒,粒径0.01～0.1mm,由石英,长石、绿帘石及云母、绿泥     

郯庐剪切带的性质和意义

沿郯庐断裂带从大别山东麓经山东中部至辽北吉南的新宾—桦甸地区,暴露的早前寒武纪结晶岩石中存在着一系列北北东走向的大型韧性剪切带,其最大宽度达20km,走向断续延伸近2000km,它们分别在大别、鲁西和新宾地区形成了巨大的弧形牵引构造。剪切带中不同尺度组构要素的几何学,指示其中曾经发生了一致的大幅度左行位移;变形岩石的显微构造和矿物组合特征,说明这一韧性剪切带早期形成于低角闪岩相条件下,并且在抬升和冷却过程中经历了绿片岩相条件下的递进变形。山东中部晚元古代以后的沉积不整合于韧性剪切带及其变形岩石之上,中生代未期脆性的郯庐断裂系统追踪并改造了基底岩石中的韧性剪切带。     

川北早寒武世碳酸盐岩台缘斜坡沉积特征及变形构造形成机制探讨

基于对川北米仓山西部旺苍县鼓城乡唐家河下寒武统仙女洞组露头剖面的观察与镜下分析发现,仙女洞组下段由生物碎屑泥晶灰岩(L)、粉砂质泥岩(M)、似瘤状砾屑灰岩(L')、角砾灰岩(R)、藻凝块灰岩(A)和含生屑钙质砂岩(S)组合而成,其以角砾灰岩、似瘤状砾屑灰岩和藻凝块灰岩为特征,且发育异地岩块和滑塌变形构造。进一步分析认为:L-M岩石组合为正常的斜坡环境低能沉积;L'-R岩石组合中的角砾灰岩为上斜坡生物灰泥丘崩坍滑动至下部而形成的,似瘤状砾屑灰岩可能是由于L-M岩石组合快速沉积导致沉积物失稳滑动变形、上斜坡生物灰泥丘崩落角砾致使的差异压实和滑动、以及后期物质成分差异引起的压溶作用等共同作用的结果,从而使灰质层发生破碎并被泥质包围形成断续的砾屑状,甚至轻微的位移,进而形成条带特征不明显的杂乱变形构造;微生物岩(Mb)组合为上斜坡的灰泥丘沉积;S-M岩石组合为斜坡上部的浊流沉积。根据上述分析结果建立米仓山西部仙女洞组碳酸盐岩台缘斜坡沉积模式,表明仙女洞组沉积早期米仓山西部存在台缘斜坡相沉积。     

豹皮灰岩的研究现状及其意义

豹皮灰岩为不同地质时期、不同地区的碳酸盐岩地层中较常见的岩石类型,前人对其构造形态、成岩过程、成岩环境及成因机制等方面进行的研究存在较多争论和不一致。本文在分析前人的研究成果基础上,认为在豹皮灰岩的研究中应注重其岩石学特征的分析;在豹皮灰岩的成因机制研究问题上,可借鉴白云岩的研究成果和地球化学数据的运用,但不可忽视白云石和方解石共存这一基本地质现象;豹皮灰岩的岩石名称使用时存在混淆现象,建议使用构造形态+结构成因来对豹皮灰岩进行命名。     

周口店黄院东山梁构造变形特征及其地质意义

针对周口店黄院东山梁一带青白口系和下古生界构造变形进行的详细解剖分析一直未见有文献报道。通过对东山梁构造变形现象进行反复多次的详细观察,发现东山梁中段寒武系张夏组鲕粒灰岩层位重复出现,但鲕粒未发生变形,经追索表明该层位存在逆冲断层重复和破坏;同时,东山梁南段采石场掌子面可见青白口系景儿峪组薄层大理岩和寒武系府君山组灰岩构成的小型斜歪倾伏褶皱,上覆寒武系馒毛组中发育由NNE向SSW推覆的逆冲褶断,使部分层位缺失,褶断带内岩石存在韧性变形等构造现象。这一观测成果修正了前人研究认为东山梁一带只存在大量折叠层、而断层发育欠佳的认识,也为北京西山地区区域地质演化研究提供了一定的科学佐证。     

Wavelength-dispersive X-ray fluorescence spectrometric determination of Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites

Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.     

高压微波消解法测定醋酸纤维过滤器采集的微尘粒子中的砷镉钴铬铜铁锰镍铅钒锌

最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提     

硅酸盐类样品中硅、铁、铝、钛、锰、钙、镁、钾、钠和磷的x射线荧光光谱测定

本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.     

Viscous, cohesive, non-Newtonian, depositing, radial slurry flow

Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.     

硅酸盐中铁、锰、钛、钙、钾、磷、硅、铝、镁、钠、锶、铷、钡的X-射线荧光光谱定量测定

本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。     

Bellechester,Minnesota, USA,lagoon collapses

Bellechester, Minnesota, is a small community of approximately 155 residents located on the county line between Goodhue and Wabasha counties in southeast Minnesota's karst region. Bellechester is served by a 21-year-old wastewater treatment facility (WWTF) consisting of three waste-stabilization ponds. On 28 April 1992 six sinkholes were discovered to have drained cell 2 of the WWTF resulting in the loss of approximately 8.7×10⁶ 1 of partially treated effluent and about 600 m³ of soil into previously undetected subsurface voids of unknown dimensions. In the week following the collapse, approximately 200 water wells located within a 5-km radius of the WWTF were sampled in an after-the-fact, emergency sampling program. Twelve samples with elevated fecal coliform levels, 18 samples with nitrate-nitrogen greater than the 10 mg/1 standard, and no samples with elevated chlorides were found. However, the elevated levels could not be unambiguously attributed to the WWTF collapse. This is the third WWTF to fail by sinkhole collapse in southeast Minnesota since 1974. All three collapsed lagoons have been located in similar geomorphic and stratigraphic settings. However, at least two lagoons have collapsed in the adjacent area in northeast Iowa, and these lagoons are located at different stratigraphic positions. Twenty-two WWTFs constructed in southeast Minnesota's karst region in the last 25 years have been identified as subject to potential sinkhole collapse. An unknown but significant number of manure storage lagoons, flood control structures, etc., have also been constructed in the karst region and are at risk. Public agencies are beginning to develop plans to deal with the risk associated with existing and future waste lagoons in this environment. The critical hydrogeologic parameters that can be used to prioritize the risk of collapse at existing facilities include: (1) the lithology of the first bedrock beneath each lagoon, (2) the thickness of surficial materials between the lagoon and the bedrock surface, (3) the presence and construction of liners (seepage rate), and (4) the proximity to existing sinkholes.     

Mercury,arsenic, antimony,and selenium contents of sediment from the Kuskokwim River,Bethel, Alaska,USA

The Kuskokwim River at Bethel, Alaska, drains a major mercury-antimony metallogenic province in its upper reaches and tributaries. Bethel (population 4000) is situated on the Kuskokwim floodplain and also draws its water supply from wells located in river-deposited sediment. A boring through overbank and floodplain sediment has provided material to establish a baseline datum for sediment-hosted heavy metals. Mercury (total), arsenic, antimony, and selenium contents were determined; aluminum was also determined and used as normalizing factor. The contents of the heavy metals were relatively constant with depth and do not reflect any potential enrichment from upstream contaminant sources.     

滇东南花岗岩与锡、银、铜、铅、锌多金属矿床的成因关系

滇东南锡、银、铅、锌多金属矿床主要分布在个旧、白牛厂、都龙3个矿区,而滇东南较大的3个花岗岩体又分别出露在3个矿区或附近.花岗岩体均形成于燕山晚期,岩石化学、矿物成分相似,富含锡、银、铅、锌、钨、铜等成矿元素.矿床主金属元素组合与岩体之间的距离由远而近出现由锡、钨、(铍、铌、钽)→锡、钨、(铁)、铜、铟→锡、铅、锌、银、铟、(锑)有规律的变化.花岗岩浆是成矿物质来源和成矿热源.岩浆侵入初期使上覆地层隆起产生背斜(凹陷部位成向斜);同时使地层产生一系列裂隙、压性断层或层间断裂;岩浆侵入晚期,这些断层再次活动,表现为张性,岩浆产生的含矿热液沿由其活动所造成的断裂迁移、充填、交代、沉淀而形成矿床.     

岩石密度和超高压岩石折返速率

在常温常压条件下对中国大陆科学钻CCSD主孔100-3000米岩心样品进行了密度测量,建立了密度连续剖面,并界定了不同超高压岩石的密度值。通过对比高温高压物性实验资料,岩石密度随着退变程度增强而降低,榴辉岩密度变化序列为3.52g/cm3→3.49g/cm3→3.07g/cm3→2.93g/cm3。超高压长英质岩石密度变化序列为3.00g/cm→2.80g/cm3→2.65g/cm3。上述实验资料是讨论不同折返阶段岩石所受浮力的基础,为研究折返速率大小提供了基本参数。本文通过折返板块运动平衡时,上浮力与粘滞力平衡这一关系式,定量研究了大陆俯冲板块的折返速率,认为密度差产生上浮力从而引起折返,温度对板块折返速率的影响最为显著;密度差大小、折返角度、折返板块大小对折返速率也有直接的影响。定量模拟分析表明,在温度高于850℃时,板块的折返速率可以超过100mm/a;当温度降至700℃时,折返速率则低于1.5mm/a。作者认为在折返早期,温度较高,板块快速折返至60-70km榴辉岩相深度;随着传导散热,温度降低,板块以较慢的速率折返至中下地壳。折返速率的估算表明,浮力是板块折返第一阶段(从>100km深部折返至<40km的中下地壳)的主要驱动力。