“寨背式”离子吸附型稀土矿床多类型稀土矿化及其成因

赣南寨背离子吸附型稀土矿床产于寨背复式花岗岩体的风化壳中,自20世纪80年代发现以来一直以轻稀土型开采,近年在轻稀土型花岗岩风化壳中发现了重稀土矿。为了探讨轻稀土型花岗岩风化过程中重稀土元素的迁移、分馏和富集机制,本文选择了区内三个具有代表性的风化壳钻孔(ZK1、ZK2和ZK4)对其进行了全相和离子交换相稀土元素地球化学研究。结果显示：钻孔ZK4中离子交换相稀土含量介于14.90×10^-6～835.8×10^-6之间,并富集轻稀土(LREE/HREE=2.28～10.78);钻孔ZK1中离子交换相稀土含量达1470×10^-6(9件样品均值),具有从轻稀土型向重稀土型过渡的配分特征(LREE/HREE=1.30～1.65),并且剖面自上而下显示轻、重稀土逐渐富集的趋势;钻孔ZK2中离子交换相稀土含量为492.4×10^-6(8件样品均值),自上而下稀土配分类型从轻稀土型过渡至重稀土型(LREE/HREE=0.43～2.25),且轻稀土富集在全风化层上部而重稀土则富集在下部。三个钻孔的Nb/Ta和Zr/Hf...     

新疆包尔图铜矿稀土元素地球化学特征及其地质意义

包尔图铜矿床位于南天山库米什洋盆俯冲变质带的边缘,矿体受断裂构造控制。矿区围岩为一套中深变质岩,其稀土元素组成具有如下特征:∑REE较高,LREE/HREE=2.46～16.86,轻重稀土元素明显分异,且轻稀土相对富集,负铕异常,配分模式曲线向右倾斜。矿石的∑REE相对较低,LREE/HREE=0.06～0.97,轻重稀土元素明显分异,重稀土相对富集,配分曲线向左倾斜,与混合岩脉体的稀土元素配分模式相近。稀土元素组成特征指示矿床的成矿过程可能与混合岩化作用有关。结合矿床地质特征,认为包尔图铜矿床为变质热液型铜矿床。     

新疆且日克其菱铁矿床稀土元素地球化学特征

新疆且日克其菱铁矿床赋存于下志留统温泉沟群中低级变质岩系中,由三个矿段组成,总体呈层状、似层状、透镜状.矿石稀土含量较高(∑REE=740.97 ×10-6～820.21×10-6),轻稀土富集(LREE/HREE=13.17～14.74)的特征暗示了矿床形成于弱-中碱性的含矿溶液;明显的Ce正异常(δCe=3.25～...     

浙江八面山萤石矿床稀土元素地球化学特征及成因探讨

对浙江八面山萤石矿床中不同类型萤石矿石和围岩样品的稀土元素的系统分析表明,细粒萤石矿石的ΣREE〈39×10-6,LREE为14.36×10-6～34.24×10-6,HREE0.96×10-6～2.04×10-6,Y〈3×10-6;巨晶萤石矿石中的ΣREE3.62×10-6～20.81×10-6,LREE2.71×10-6～17.67×10-6,HREE0.24×10-6～1.49×10-6;而围岩花岗岩的ΣREE460.29×10-6,LREE225.97×10-6,HREE91.32×10-6,Y＆gt;140×10-6;沉积岩中的ΣREE20.22×10-6、LREE16.11×10-6、HREE1.61×10-6。矿石与围岩中沉积岩的稀土总量、轻稀土、重稀土和Y的含量接近,与花岗岩的稀土总量、轻稀土、重稀土和Y元素含量相差悬殊。萤石矿石的稀土分布型式主要为轻稀土富集型,（La/Yb）N通常多数大于8,在8.07～17.26间,δEu值在0.45～1.30,δCe在0.89～1.14间,Ce、Eu基本不显异常。矿石与围岩的稀土地球化学研究显示,八面山萤石矿床为受地层、岩体与断裂共同控制＂三位一体＂的低温热液型矿床。     

贵州道真县还打岩地区铝土矿床地球化学特征

贵州道真县还打岩——陈家榜铝土矿研究区为中国地质调查局铝土矿远景调查项目的新发现矿产地之一,该铝土矿产于石炭系黄龙组（C：h）灰岩侵蚀面上的二叠系大竹园组（P2d）;地球化学研究显示,矿床中Al2O3与TiO2含量成正相关关系,与SiO2含量成负相关关系;不同岩矿石的稀土总量（EREE）含量变化大,LREE／HREE均大于1,轻稀土较富集,重稀土存在不同程度的亏损;铝土矿中Al2O3含量和稀土总量（EREE）呈负相关关系;矿床成因属古风化壳沉积型铝土矿。     

巴干贡巴晚三叠世石英闪长岩地球化学特征及成因

巴干贡巴地区主要产出有四处燕山期石英闪长岩体,SiO2较为稳定,岩石均具富钾钙的特点。里特曼组合指数σ=0.96～1.55,属于钙碱性岩石;稀土总量ΣREE为69.98～-223.68;LREE为58.71～170.86;HREE为10.95～19.12;轻重稀土比值LREE/HREE为5.21～19.43,属于轻稀土富集,重稀土亏损型;无明显Eu异常反应;Th、La、Nd、Hf具明显富集显正异常,Ba、Ta、Nb、Sr、Ti具明显亏损现象。综合分析认为该区岩体为下地壳部分熔融形成的"I"型花岗岩,属受张性断裂影响的被动侵位类型。     

邹家山铀矿床伴生重稀土元素的赋存特征

初步研究发现,相山矿田邹家山矿床中伴生有较高的重稀土元素,回收这些珍稀的资源和探索其成因具有重要的意义,而查明这些伴生稀土在铀矿床中的赋存特征是前期基础性工作。为此本文采用电子探针和激光剥蚀电感耦合等离子体质谱分析了邹家山铀矿床中稀土元素的赋存状态。结果显示：该矿床稀土矿物主要为独居石、氟碳钙铈矿和磷钇矿;独居石、氟碳钙铈矿的LREE/HREE>1,为轻稀土富集型;而磷钇矿的LREE/HREE<1,为重稀土富集型。沥青铀矿、钛铀矿、铀钍石、铀石、钍石、锆石等铀钍矿物的稀土特征为重稀土富集型;铀钍矿物稀土总量（∑REE+Y）较高,为（3 805.78~65 307.00）×10^-6,LREE/HREE<1,为0.01~0.80,平均为0.29。其他伴生矿物磷灰石、钾长石为轻稀土富集型,萤石为轻、重稀土富集型两类都有,而伊利石、黄铁矿的轻重稀土无明显相对富集。重稀土在磷钇矿和铀钍矿物中以类质同象形式存在,少量赋存于伴生矿物。     

小秦岭文峪-东闯金矿床流体包裹体的微量元素及成因意义

运用热爆法提取和ICP-MS技术,研究了小秦岭文峪-东闯金矿不同阶段脉石英流体包裹体的稀土和微量元素.数据表明,石英流体包裹体的LREE相对富集,ΣLREE/ΣHREE为3.19～8.45,且从早阶段至晚阶段该比值有增长之势.轻重稀土分馏程度不大, 存在着一定的Eu异常.流体中Cu、Zn、Mo、W、Pb等微量成矿元素的富集系数远大于1.结合太华群变质岩系、文峪花岗岩体的REE和Cu、Pb、Zn等微量元素特征,认为金矿床的成矿物质主要来自太华群变质岩系.     

云南邦棍尖山花岗岩的岩石学、地球化学和年代学特征对离子吸附型稀土成矿的制约

云南陇川龙安稀土矿是云南境内唯一开采的离子吸附型稀土(iREE)矿床,其成矿母岩为邦棍尖山花岗岩。近年来该花岗岩风化壳中相继发现了一系列iREE矿化点甚至矿床,其中不乏重稀土(HREE)矿。本文选取邦棍尖山南段的花岗岩进行岩石学、矿物学、地球化学和年代学等研究工作,并探讨其对iREE(甚至离子吸附型重稀土(iHREE))成矿的制约。邦棍尖山岩体的主要岩性为黑云母二长花岗岩,本研究测得花岗岩锆石U-Pb年龄为50.33 Ma(50.33±0.30 Ma, MSWD=0.15),形成于喜山期(古近纪),是目前发现的成矿母岩最年轻的iREE矿床。花岗岩具有以下地球化学特征：高硅高碱、低铁低镁,A/CNK>1.1,高钾-强过铝质,S型。岩体轻稀土(LREE)相对富集,轻重稀土分异较强烈(LREE/HREE为2.54～8.98),Eu负异常(δEu=0.06～0.17);微量元素显示出高Rb、Th,低Ba、Nb、Sr、Zr、Hf、Ti的特征,岩浆岩高度分异。邦棍尖山花岗岩中的(含)稀土矿物主要是榍石(∑REE=14506.24×10^-6,LREE/HREE=1.14,...     

浙江萤石矿床的稀土元素地球化学特征木

文章根据浙江14个萤石矿床(点)的94个萤石和49个赋矿岩石样品的稀土元素分布特征,将萤石矿床分为两种类型:即轻稀土富集型(萤石的∑REE=30×10~(-6)～80×10~(-6),Y=10×10~(-6)～50×10~(-6),∑Ce/∑Y≥1,La/Yb>6);重稀土富集型(萤石的∑REE=40×10~(-6)～70×10~(-6),Y=30×10~(-6)～110×10~(-6),∑Ce/∑Y<1,La/Yb<3)。前者从早阶段到晚阶段,萤石的∑REE及Y含量趋于减小,LREE/HREE及La/Yb值增大;后者从早期到晚期,萤石的∑REE和Y含量以及LREE/HREE和La/Yb比值变化则相反。轻稀土富集型萤石的矿床规模越大,萤石与未蚀变围岩的REE含量差值越大;重稀土富集型萤石的矿床规模越大,萤石与未蚀变围岩的REE含量差值越小。     

Définition d'une limite multicritère ; stratigraphie du passage Campanien–Maastrichtien du site géologique de Tercis (Landes,SW France)Definition of a multi-criteria boundary; stratigraphy of the Campanian–Maastrichtian interval of the geological site at Tercis (Landes,SW France)

Lithostratigraphy, physicochemical stratigraphy, biostratigraphy, and geochronology of the 77–70 Ma old series bracketing the Campanian–Maastrichtian boundary have been investigated by 70 experts. For the first time, direct relationships between macro- and microfossils have been established, as well as direct and indirect relationships between chemo-physical and biostratigraphical tools. A combination of criteria for selecting the boundary level, duration estimates, uncertainties on durations and on the location of biohorizons have been considered; new chronostratigraphic units are proposed. The geological site at Tercis is accepted by the Commission on Stratigraphy as the international reference for the stratigraphy of the studied interval. To cite this article: G.S. Odin, C. R. Geoscience 334 (2002) 409–414.     

Quaternary stresses revealed by calcite twinning inversion: insights from observations in the Savonnières underground quarry (eastern France)

Calcite samples were extracted both from the rock matrix and the superficial coating of a karstified fault plane of an underground quarry, located in the eastern border of the Paris basin. The karstification is dated as Quaternary. Analysis of mechanical calcite twinning reveals that only the calcite matrix has also undergone a compression trending WNW that can be attributed to the Mio-Pliocene alpine collision. Both coating and matrix have undergone a strike-slip regime with σ₁ roughly trending north–south, that could correspond to the regional present-day state of stress, a strike-slip compression rather trending NNW, modified by local phenomena. To cite this article: M. Rocher et al., C. R. Geoscience 335 (2003).     

HYDROGEOLOGY

正20141756 Chen Ruige(Mathematical College,China University of Geosciences,Beijing100083,China);Zhou Xun Numerical Simulation of Groundwater Level Fluctuation in a Coastal Confined Aquifer with Sloping Initial Groundwater Level Induced by the Tide(Geological Bulletin of China,ISSN1671-2552,CN11-4648/P,32(7),2013,p.1099-1104,6 illus.,16 refs.) Key words:confined water,groundwater level     

METAMORPHIC PETROLOGY

正20141408 Cai Jia(Institute of Geology,Chinese Academy of Geological Sciences,Beijing100037,China);Liu Fulai Petrogenesis and Metamorphic P-T Conditions of Garnet-Spinel-Biotitebearing Paragneiss in Danangou Area,Daqingshan-Wulashan Metamorphic Complex Belt(Acta Petrologica Sinica,ISSN1000-0569,CN11-1922/P,29(7),     

SERIALS

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GEOPHYSICAL EXPLORATION

正20142386An Guoying(China Aero Geophysical Survey and Remote Sensing Center for Land and Resources,Beijing 100083,China)Application of Satellite Remote Sensing in Regional Hydrogeological Investigation:Taking Cenozoic Strata in Wenquan Sheet(1∶250 000)of Karakoram Range as an Example(Geosci-     

QUATERNARY GEOLOGY & GEOMORPHOLOGY

正20141016An Chengbang(Key Laboratory of Western China’s Environmental Systems,Ministry of Education,Lanzhou University,Lanzhou 730000,China);Zhao Yongtao Lake Records during the Last Glacial Maximum from Xinjiang,NW China and Their Climatic Impli-     

PETROLEUM GEOLOGY

正20141538 Cao Qing(School of Earth Sciences and Engineering,Xi’an Petroleum University,Xi’an 710065,China);Zhao Jingzhou Characteristics and Significance of Fluid Inclusions from Majiagou Formation,Yichuan Huangling Area,Ordos Basin(Advances in Earth Science,ISSN1001-8166,CN62-1091/P,28(7),2013,p.819-828,7 illus.,3 tables,43 refs.)     

GEOCHEMISTRY

正20142002 Wei Hualing(Institute of Geophysical and Geochemical Exploration,Chinese Academy of Geological Sciences,Langfang065000,China);Zhou Guohua Element Content and Mineral Compositions in Different Sizes of Soil in Tongling Area,Anhui Province(Geological Bulletin of China,ISSN1671-2552,CN11-4648/P,32(11),2013,p.1861     

ENGINEERING GEOLOGY

正20141768 An Shaopeng(Institute of Rock and Soil Mechannics,Chinese Academy of Sciences,Wuhan 430071,China);Wei Lide Experimental Study on Mechanical Behavior of Xigeda Formation Siltstone and Structure Interface(Journal of Engineering Geology,ISSN1004-9665,CN11-3249/P,21(5),2013,p.702-708,9illus.,1 table,16 refs.)