赣南金竹坪钨矿床多期成矿作用特征及地质意义

金竹坪矿床是南岭东段赣南地区钨多金属成矿带内一处典型的石英脉型钨矿床。燕山期隐伏中粗粒(或似斑状)黑云母二长花岗岩与成矿作用密切相关,早期矿体受后期热液交代作用改造强烈而表现多世代成矿的特征。关于隐伏岩体与多期成矿活动的时间,目前依然缺乏精确的年代学制约。本文利用锆石和黑钨矿LA-ICP-MS U-Pb测年方法对矿床内似斑状黑云母二长花岗岩及3个世代的黑钨矿进行定年,揭示成矿多期演化史,并探讨成矿作用过程。结果显示,似斑状黑云母二长花岗岩岩浆锆石年龄为(155.2±0.7) Ma, 3个世代黑钨矿年龄分别为(164.9±2.4) Ma、(157.4±1.0) Ma和(144.8±1.8) Ma。综合分析认为金竹坪钨矿床隐伏岩体侵位于159～155 Ma,三期热液钨矿化作用形成于164.9～144.8 Ma,它们均系燕山期南岭钨锡多金属成矿带大规模成岩成矿作用的产物。前两个世代钨矿化年龄与花岗岩体侵位时代在误差范围内基本一致,处于南岭中—晚侏罗世成矿高峰期;而第三个世代钨矿化则较岩体形成晚约10 Ma,可能代表中晚侏罗世成矿作用后新发生的一期早白垩世钨矿化作用。     

再论东天山白山铼钼矿区成岩成矿时代

东天山白山铼钼矿区的成岩成矿时代尚存在海西期和印支期之争.最新的同位素年代学研究表明,矿区南部斜长花岗斑岩的锆石U-Pb年龄为235～245Ma,矿区东部黑云母斜长花岗岩的锆石SHRIMP U-Pb年龄为239Ma±8Ma,矿石中辉钼矿的Re-Os等时线年龄为229Ma±2Ma.结合笔者已报道的燕山期岩浆侵位与成矿的年代学证据,首次提出白山铼钼矿区具有印支期和燕山期2期成岩成矿作用,早期成岩成矿作用发生于中三叠世,晚期成岩成矿作用发生于早侏罗世.     

马兰峪背斜核部中生代侵入岩体锆石U-Pb年龄、地球化学特征及其构造意义

利用LA-MC-ICP-MS锆石U-Pb测年获得马兰峪背斜核部前分水岭二长花岗岩、茅山二长花岗岩、王坪石二长花岗岩、高家店石英闪长岩、肖营子花岗闪长岩及钾长花岗岩的结晶年龄分别为(153.8±2.7)Ma、(162.7±1.5)Ma、(162.3±1.3)Ma、(170.5±1.8)Ma、(164.6±2.2)Ma和(186.8±1.3)Ma,同时获得180~175 Ma和201~186 Ma的继承岩浆锆石年龄,时代上分属于印支期和燕山期,以燕山期为主;岩石地球化学特征表明其岩浆来源于上地幔物质底侵引起下地壳部分熔融。结合区域地质资料分析,本文认为:1)马兰峪背斜开始形成于印支期,完成于燕山期;2)印支—燕山期强烈构造运动不但使地台基底与盖层同步卷入褶皱作用,地壳缩短加厚,而且使上地幔物质底侵,下地壳物质部分熔融,从而形成了一系列发育于背斜核部的侵入岩体;3)燕山地区中生代造山作用,并不只是地壳表层的物质运动,而是涉及全地壳以至上地幔的物质运动,它使中朝地块北部由原来稳定克拉通状态进入一个全面活化的新阶段。     

湘南王仙岭花岗岩体的锆石U-Pb年代学、地球化学、锆石Hf同位素特征及其地质意义

湘南王仙岭岩体由主体电气石黑云母花岗岩和侵入其内部的黑云母二长花岗岩组成,LA-MC-ICPMS锆石U-Pb定年显示电气石黑云母花岗岩形成于印支期(235.0±1.3Ma),黑云母二长花岗岩形成于燕山期(155.9±1.0Ma),表明该岩体是两期岩浆活动的产物。这两期岩石均为高钾钙碱性系列,A/CNK值为1.07～1.66,属过铝-强过铝质花岗岩类。稀土元素显示LREE富集,HREE亏损,Eu负异常明显(0.01～0.38)的特征。早期电气石黑云母花岗岩和晚期黑云母二长花岗岩的εHf(t)值分别为-7.92～+4.61和-10.66～-5.35;两阶段Hf模式年龄(tDM2)分别为1758～967Ma和1875～1538Ma。两期花岗岩均来自于古中元古代地壳物质重熔,其中早期电气石黑云母花岗岩在侵位上升过程中捕获了部分幔源老锆石,成岩过程中有少量地幔物质参与,且其源区具有高εHf(t)值的特点。综合前人研究成果,本文认为华南中生代印支期和燕山期均有钨锡矿化作用,印支期花岗质岩浆形成于碰撞挤压作用间隙伸展环境,而燕山期花岗质岩浆可能形成于大陆边缘弧后伸展环境。     

锡田印支-燕山期复式花岗质岩浆-热液活动时限和物质来源

锡田钨锡多金属矿田位于湘赣两省交界,南岭成矿带的北部。锡田花岗岩体是一个复式岩体。本文利用LA-MC-ICP MS技术对8个样品的锆石进行了原位微区U-Pb定年和Lu-Hf同位素测试,结果显示其中有4个为印支期(226~225Ma)、另外4个为燕山期(166~158Ma)。印支期花岗岩锆石的εHf(t)值为-4.6~-10.8,两阶段模式年龄TDM2值为2011~1534Ma,根据是否呈正态分布可分为7组;燕山期花岗岩锆石的εHf(t)值为-4.3~-10,TDM2值为1896~1429Ma,可分为5组。相似的Hf同位素组成表明两期花岗岩具有同源性,均源自古元古代晚期至中元古代早期地壳物质的部分熔融。而εHf(t)值变化范围较大且分成很多组可能更主要受控于源区Hf同位素的不均一性。此外,本文利用40 Ar-39 Ar定年方法测得花岗岩顶部石英脉和云英岩中4个白(金)云母的年龄为150~148Ma,这期与成矿有关的热液作用应该与最晚一期岩浆活动有关。通过本次获得的定年数据和对已有的成岩成矿定年数据的总结,本文认为锡田岩体可以分为三个期次,印支期(226~225Ma),燕山期第一阶段(166~158Ma)和燕山期第二阶段(151~141Ma)。     

河北省四拨子-六拨子钼铜矿区侵入岩 LA-ICP-MS锆石U-Pb定年及成矿意义

河北省青龙满族自治县四拨子-六拨子钼铜矿位于燕辽成矿带东部,是近年来发现的中型钼铜矿床。矿化多沿层面、裂隙充填、交代,呈脉状赋存于大红峪组的石英砂岩、长石石英砂岩及白云岩夹层和高于庄组的白云岩内,地质特征表明成矿主要与硅化关系密切。文章对矿区6个侵入岩进行了锆石LA-ICP-MS U-Pb年代学研究,结果表明,矿区存在4期岩浆侵入活动:第一期为晚三叠世(211~206 Ma),形成六柱坪和三拨子西沟细粒似斑状二长花岗岩;第二期为早侏罗世早期(196~190 Ma),形成老商家和五拨子花岗斑岩;第三期为早侏罗世晚期(177Ma),形成达子沟细粒似斑状二长花岗岩;第四期为晚侏罗世早期(160 Ma),形成七拨子粗中粒二长花岗岩。矿区辉钼矿的Re-Os加权平均年龄为(194±1)Ma,成矿时代为早侏罗世,与花岗斑岩形成时代一致(196~190 Ma),表明钼铜成矿可能与花岗斑岩岩浆期后热液活动有关。     

黑龙江鹿鸣钼矿床地质特征及成矿年龄

黑龙江鹿鸣钼矿床位于小兴安岭-张广才岭多金属成矿带翠宏山-二股成矿亚带中南段。矿化发生在花岗岩体内,矿石为石英细脉浸染状的花岗斑岩、二长花岗岩,围岩蚀变具有岩浆热液蚀变的分带特征。成矿作用与花岗岩浆侵入活动密切相关,矿床成因类型为斑岩型。岩石地球化学研究表明,矿区花岗斑岩、二长花岗岩具有同一岩浆来源,属于"A"型花岗岩,是在伸展大地构造环境背景下岩浆侵入形成的岩体。通过锆石SHRIMP U-Pb年龄测定,获得二长花岗岩年龄为(201.1±3.90) Ma和(176.2±4.3) Ma,获得花岗斑岩年龄为(182.3±4.0) Ma,确定鹿鸣钼矿床的成矿年龄在182～176 Ma之间,成矿时代为燕山早期。     

湖南塔山花岗岩SHRIMP锆石U-Pb年龄及其地质意义

塔山花岗岩体位于湘南阳明山-塔山东西向构造-岩浆带东端,为呈近东西向延伸的岩基,出露面积约200km~2。岩体侵入于古生代地层中,接触面倾向围岩,倾角30°~50°,由四侵入次岩体组成,之间多为脉动接触关系,主要岩性为黑云母二长花岗岩。第二侵入次岩体SHRIMP锆石U-Pb年龄为218±3Ma,第三侵入次岩体SHRIMP锆石U-Pb年龄为215±3Ma。由此表明,塔山花岗岩形成于晚三叠世,相邻单元之间的时间间隔为3~5Ma。阳明山-塔山东西向构造-岩浆带主要形成于印支期。区内钨、锡、铜、铅、锌等多金属矿床丰富,找矿潜力较大,亦表明南岭地区不仅存在燕山期花岗岩成矿,印支期花岗岩也可成矿。     

南秦岭桂林沟斑岩型钼矿Re-Os同位素年代学及其构造意义研究

陕西省镇安县桂林沟斑岩型钼矿床位于南秦岭多金属成矿带内,其成矿围岩主要为细粒花岗岩、钾长花岗岩和蚀变的粗粒花岗岩。本文通过对桂林沟斑岩型钼矿床中辉钼矿Re-Os同位素定年以及围岩中锆石U-Pb年代学研究,旨在探讨成矿成岩的关系及其构造意义。结果表明,6件辉钼矿的Re-Os同位素年龄在195.9~198.5Ma之间,加权平均年龄为197.2±1.3Ma,表明桂林沟钼矿形成于早侏罗世。围岩细粒花岗岩、钾长花岗岩和粗粒花岗岩的锆石U-Pb年龄分别为199±1.4Ma、201±3.1Ma和198±11Ma,这说明其成岩和成矿年龄基本一致。值得注意的的是,桂林沟钼矿床的形成年龄不同于前人已报导的秦岭钼矿的三个主要成矿期,即238~213Ma、145~126Ma和116~110Ma,其稍晚于第一成矿期。200~190Ma可能代表了秦岭成矿带一期尚未认识的重要成矿事件,对于南秦岭找矿具有重要意义。该期钼矿形成于秦岭印支期碰撞之后,是在造山带垮塌引起的岩浆-热液事件过程中形成的。     

西南天山科桑溶洞新元古代-早奥陶世花岗岩锆石U-Pb年代学研究

在新疆西南天山科桑溶洞地区,新厘定出一套斜长角闪岩-花岗岩地质单元:侵入斜长角闪岩中的新元古代白云母花岗岩(片麻状构造)、以及侵入上述古老岩石单元的早奥陶世花岗岩(块状构造)。片麻状白云母花岗岩中锆石具有热液锆石边、岩浆锆石幔和碎屑锆石核(边-幔-核结构),剔除被热液锆石和碎屑锆石混染的SHRIMP测点,获得岩浆锆石幔的加权平均年龄752.3±5.1Ma(MSWD=0.95),代表岩浆的结晶年龄。块状花岗岩的锆石具有边-核结构,热液锆石边的U-Pb年龄(419.5±5.7Ma)明显偏低。剔除热液锆石和碎屑锆石,获得岩浆锆石的平均U-Pb年龄481.1±4.4Ma(MSWD=0.88),代表花岗岩的结晶年龄。早奥陶世早期,岩浆侵入新元古代片麻状白云母花岗岩中。在晚志留世或者更晚时期,两类花岗岩共同经受了变质热液改造,变质流体交代岩浆锆石,导致锆石溶蚀再生长。     

Wavelength-dispersive X-ray fluorescence spectrometric determination of Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites

Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.     

高压微波消解法测定醋酸纤维过滤器采集的微尘粒子中的砷镉钴铬铜铁锰镍铅钒锌

最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.     

硅酸盐中铁、锰、钛、钙、钾、磷、硅、铝、镁、钠、锶、铷、钡的X-射线荧光光谱定量测定

本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。     

硅酸盐类样品中硅、铁、铝、钛、锰、钙、镁、钾、钠和磷的x射线荧光光谱测定

本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。     

Viscous, cohesive, non-Newtonian, depositing, radial slurry flow

Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.     

岩石密度和超高压岩石折返速率

在常温常压条件下对中国大陆科学钻CCSD主孔100-3000米岩心样品进行了密度测量,建立了密度连续剖面,并界定了不同超高压岩石的密度值。通过对比高温高压物性实验资料,岩石密度随着退变程度增强而降低,榴辉岩密度变化序列为3.52g/cm3→3.49g/cm3→3.07g/cm3→2.93g/cm3。超高压长英质岩石密度变化序列为3.00g/cm→2.80g/cm3→2.65g/cm3。上述实验资料是讨论不同折返阶段岩石所受浮力的基础,为研究折返速率大小提供了基本参数。本文通过折返板块运动平衡时,上浮力与粘滞力平衡这一关系式,定量研究了大陆俯冲板块的折返速率,认为密度差产生上浮力从而引起折返,温度对板块折返速率的影响最为显著;密度差大小、折返角度、折返板块大小对折返速率也有直接的影响。定量模拟分析表明,在温度高于850℃时,板块的折返速率可以超过100mm/a;当温度降至700℃时,折返速率则低于1.5mm/a。作者认为在折返早期,温度较高,板块快速折返至60-70km榴辉岩相深度;随着传导散热,温度降低,板块以较慢的速率折返至中下地壳。折返速率的估算表明,浮力是板块折返第一阶段(从>100km深部折返至<40km的中下地壳)的主要驱动力。     

Regional distribution of Al,B, Ba,Ca, K,La, Mg,Mn, Na,P, Rb,Si, Sr,Th, U and Y in terrestrial moss within a 188,000 km2 area of the central Barents region: influence of geology,seaspray and human activity

Five hundred and ninety-eight samples of terrestrial moss (Hylocomium splendens and Pleurozium schreberi) collected from a 188,000 km² area of the central Barents region (NE Norway, N Finland, NW Russia) were analysed by ICP-AES and ICP-MS. Analytical results for Al, B, Ba, Ca, K, La, Mg, Mn, Na, P, Rb, Si, Sr, Th, U and Y concentrations are reported here. Graphical methods of data analysis, such as geochemical maps, cumulative frequency diagrams, boxplots and scatterplots, are used to interpret the origin of the patterns for these elements. None of the elements reported here are emitted in significant amounts from the smelting industry on the Kola Peninsula. Despite the conventional view that moss chemistry reflects atmospheric element input, the nature of the underlying mineral substrate (regolith or bedrock) is found to have a considerable influence on moss composition for several elements. This influence of the chemistry of the mineral substrate can take place in a variety of ways. (1) It can be completely natural, reflecting the ability of higher plants to take up elements from deep soil horizons and shed them with litterfall onto the surface. (2) It can result from naturally increased soil dust input where vegetation is scarce due to harsh climatic conditions for instance. Alternatively, substrate influence can be enhanced by human activity, such as open-cast mining, creation of ‘technogenic deserts’, or handling, transport and storage of ore and ore products, all of which magnify the natural elemental flux from bedrock to ground vegetation. Seaspray is another natural process affecting moss composition in the area (Mg, Na), and this is most visible in the Norwegian part of the study area. Presence or absence of some plant species, e.g., lichens, seems to influence moss chemistry. This is shown by the low concentrations of B or K in moss on the Finnish and Norwegian side of the (fenced) border with Russia, contrasting with high concentrations on the other side (intensive reindeer husbandry west of the border has selectively depleted the lichen population).     

NEW SET OF LOW CONCENTRATION STANDARDS FOR LA, CE, SM, YB, LU, Y, SC, V, NB AND TA IN SILICATES

We have developed a set of four synthetic standards for the rare earth and high field strength elements designed for use in the determination of those elements in silicates. The base material is a glass nominally at the eutectic of the MgO-Al₂O₃-SiO₂ ternary system. The nominal doping level was 2 wt% of the elements as oxides. To avoid problems associated with peak interference, the elements were doped in four separate glasses.