内蒙古北山造山带百合山地区350 Ma石英闪长岩的成因及对红石山-百合山洋俯冲时限的制约

对内蒙古白山岩浆弧内百合山石英闪长岩进行了LA-ICP-MS锆石U-Pb测年、Hf同位素及岩石地球化学分析。结果显示,该岩体的形成年龄为350.8±1.5 Ma,岩浆锆石的ε_(Hf)(t)值在5.28～9.88之间,模式年龄为724～1018 Ma。地球化学数据显示,百合山石英闪长岩为一套I型钙碱性系列岩石,富碱(Na_2O+K_2O=6.03%～6.96%),富钠(Na_2O/K_2O2),较低的Mg~#(35.48～39.78)、Ni(2.06×10~(-6)～5.54×10~(-6))和Cr(2.11×10~(-6)～7.93×10~(-6))含量。相对富集轻稀土元素,重稀土分馏不明显,较低的(La/Yb)_N值(4.28～5.60),无明显Eu异常,相对富集Rb、K、U等大离子亲石元素,亏损Nb、Ta、P、Ti等高场强元素等,地球化学成分表明,石英闪长岩具有俯冲带成因的特征。石英闪长岩的锆石U-Pb年龄和岩石成因证明了350 Ma石英闪长岩是晚古生代白山岩浆弧内首次发现的可以明确与红石山-百合山洋俯冲消减作用有关的最早的弧岩浆记录。表明红石山-百合山洋于约350 Ma之前就已经开始发生俯冲消减,比前人一般认为的俯冲开始的时间提前了22 Ma。     

东北三江盆地始新世花岗闪长岩的发现及其地质意义:锆石U-Pb年代学、地球化学和Sr-Nd-Hf同位素证据

本文报道了三江盆地富锦地区临山花岗质岩体的锆石LA-ICP-MS U-Pb年龄、全岩地球化学和Sr-Nd同位素与锆石Hf同位素资料,以确定其形成时代、岩石成因、源区性质及其构造属性。花岗闪长岩中的锆石均呈半自形-自形晶,震荡环带发育,Th/U比值=0.31~1.92,指示其岩浆成因。对岩浆锆石的定年结果显示,临山花岗闪长岩形成于~54Ma,这是目前东北地区报道的最年轻的花岗质岩浆作用。该期花岗闪长岩的SiO_2含量主要在68.71%~72.42%之间,Na_2O=3.29%~4.41%,K_2O=2.79%~3.47%,Na_2O/K_2O=0.95~1.58,A/CNK=0.99~1.12;该区花岗闪长岩富集轻稀土元素(LREEs)和大离子亲石元素(LILEs),亏损重稀土元素(HREEs)和高场强元素(HFSEs),且轻重稀土元素分馏较强[(La/Yb)N=21.8~34.1]。样品无明显Eu异常(δEu=0.84~1.19)。它们的(87Sr/86Sr)i=0.7068~0.7071,εNd(t)介于-2.4~-2.3之间;锆石εHf(t)值介于+1.7~+5.7之间,二阶段Hf模式年龄(tDM2)介于765~1020Ma之间。上述特征表明,该期花岗闪长岩属于弱过铝质高钾钙碱性I型花岗岩,其原始岩浆起源于中元古代末-新元古代期间增生的陆壳物质的部分熔融。对三江盆地与佳木斯地块东缘已发表锆石Hf同位素资料进行总结和时空对比发现,佳木斯地块东缘和三江盆地具有相似的地壳增生历史,暗示三江盆地之下的基底物质可能仍归属于佳木斯地块范畴。另外,新生代临山岩体的识别,限制了富锦隆起的时限为始新世之后,并非前人认为的中生代。     

滇西梁河勐养花岗闪长岩LA-ICP-MS锆石U-Pb年龄、地球化学特征及其构造意义

勐养花岗闪长岩体位于滇西腾冲地块梁河县南勐养镇一带。用LA-ICP-MS技术测得花岗闪长岩锆石U-Pb年龄为115.2±1.0Ma,该年龄被解释为花岗闪长岩的形成年龄,表明该区花岗闪长岩体的形成时代为早白垩世。岩石地球化学特征表明,花岗闪长岩中SiO_2含量为62.39%~67.97%,Na_2O+K_2O为6.26%~7.80%,K_2O为1.98%~4.11%,具有贫钾(K_2O/Na_2O值为0.45~1.11)、低P2O5(0.09%~0.38%)的特征;MgO为1.78%~1.98%,Mg~#为34.90~48.40,属于准铝质-弱过铝质钙碱性系列。微量元素具有相对富集大离子亲石元素(U、Th、Rb、Ba)、亏损高场强元素(Tb、Nb、Zr、Hf)的特点。该花岗闪长岩具有I型花岗岩的特征,同时兼有S型花岗岩之特点,具有明显的岩浆混合作用特征。岩石具有岛弧或活动陆缘岩系的微量元素分布特征。地球化学特征和微量元素构造判别图解揭示,勐养早白垩世花岗闪长岩形成于碰撞后岩浆弧环境。花岗闪长岩为幔源岩浆与高黎贡山群古老地壳部分熔融的岩浆混合的产物。该区早白垩世花岗闪长岩是腾冲地块早白垩世侵入岩与班公湖-怒江-泸水-瑞丽洋盆的闭合、洋壳向南西俯冲及板块间的碰撞造山作用的产物。     

北山独龙包地区晚石炭世陆缘弧岩浆作用——花岗闪长岩锆石U Pb年龄及地球化学证据

本文报道了北山地区独龙包南花岗闪长岩的LA-ICP-MS锆石U-Pb年龄与全岩地球化学,以确定其形成时代、岩石成因及构造环境。花岗闪长岩中的锆石呈短柱状或近等轴粒状,具典型的振荡环带,Th/U值介于0.42~0.75之间,指示岩浆成因。对岩浆锆石的定年结果显示,独龙包南花岗闪长岩形成于303.4±2.1 Ma。该期花岗闪长岩的Si O2含量为63.73%~69.12%,Na_2O=3.69%~4.03%,K_2O=2.23%~2.73%,全碱(Na_2O+K_2O)为6.08%~6.44%,Al2O3含量较高(14.83%~15.89%),K2O/Na2O为0.58~0.74,A/NCK=0.91~0.99;该区花岗闪长岩富集轻稀土(LREEs)和大离子亲石元素(LILE)Rb、Th、U、Pb,亏损重稀土元素(HREEs)和高场强元素(HFSE)Nb、Ta、P、Ti,且轻重稀土元素分馏较强,(La/Yb)N变化于4.77~6.35,具有弱的负铕异常,δEu为0.79~0.94。上述特征表明,该期花岗闪长岩属于准铝质钙碱性I型花岗岩,岩浆源区为下地壳,受到地幔物质的混染,形成构造背景为陆缘弧。结合邻区特征,得出红石山—百合山—蓬勃山蛇绿岩带代表的洋盆于晚石炭世可能发生了南北双向俯冲。     

北祁连中段毛藏寺花岗闪长岩U-Pb年龄及岩石地球化学特征

笔者研究了北祁连中段毛藏寺花岗闪长岩体的岩石学、年代学和地球化学特征。毛藏寺岩体主要岩石类型为花岗闪长岩,锆石SHRIMP U-Pb测年获得花岗闪长岩结晶年龄为(456±3)Ma。花岗闪长岩的SiO_2含量较高,介于65.1%～73.0%,较低的Mg#值(18～32),K_2O/Na_2O介于0.82～1.37,A/NKC=0.9～1.1,总体为高钾钙碱性准铝质花岗岩;岩石微量元素组成具富集LILE元素,亏损HFSE元素,轻重稀土分异明显[(La/Yb)N=11.1～34.1],具弱负Eu异常。综合地球化学特征和区域构造演化表明,花岗闪长岩岩浆源区为下地壳变玄武岩石,形成于同碰撞构造背景。     

东昆仑祁漫塔格乌兰拜兴地区中泥盆世花岗岩年龄、地球化学特征及其地质意义

东昆仑祁漫塔格乌兰拜兴地区花岗岩体由二长花岗岩和花岗闪长岩组成,SiO_2含量为67.47%～73.63%,全碱(Na_2O+K_2O)含量为6.74%～7.89%,K_2O/Na_2O=0.59～1.30,A/CNK=0.91～1.08,属高钾钙碱性系列和钙碱性系列,准铝质-过铝质岩石。稀土元素总量平均为137.28×10~(-6),δEu值为0.37～0.89,平均为0.57,(La/Yb)_N值为6.72～19.36,平均为10.75。稀土元素球粒陨石标准化配分曲线呈负Eu异常明显的右倾型;岩体明显富集大离子亲石元素Rb、K,不相容元素U和Th,轻稀土元素和Pb;相对亏损高场强元素Nb、Ta、P、Ti,以及大离子亲石元素Ba;岩石Rb/Sr值为0.45～1.17,平均为0.72,介于上地幔值和地壳值之间; Nb/Ta值为5.36～13.90,平均为10.93,比值总体低于地幔平均值,显示壳幔混合的特点。采用锆石U-Pb定年的方法,获得乌兰拜兴花岗闪长岩的~(206)Pb/~(238)U年龄为384.1±2.4Ma,代表该岩体的形成年龄。结合岩石地球化学、构造特征和区域地质背景,认为该岩体形成于中泥盆世晚期后碰撞陆内伸展阶段,并与铁多金属矿成矿密切相关,在矿产勘查中应引起重视。     

青海省阳康地区晚奥陶世花岗岩地球化学特征及其地质意义

青海省阳康地区花岗岩岩石组合为细粒石英闪长岩、黑云母花岗闪长岩。通过对岩石地球化学分析发现,SiO_2含量为54.36%～70.16%,Al_2O_3含量为13.08%～17.01%,K_2O含量为1.57%～3.91%,Na_2O含量为2.37%～3.75%,CaO含量为1.91%～8.09%,里特曼指数σ为1.5～2.61,属偏铝质-过铝质钙碱性花岗岩;稀土总量(∑REE)为121.7×10~(-6)～458×10~(-6),LREE/HREE值为6.81～14.72,表现为轻稀土富集型,δEu值为0.46～1.16,Eu亏损明显,δCe略亏损;富集大离子亲石元素(Rb、Ba、K)和轻稀土元素(La、Ce、Nd),亏损重稀土元素(Yb、Lu)和高场强元素(Nb、Ta),具有明显的Eu和Sr、P、Ti的亏损。在石英闪长岩和花岗闪长岩中分别获得LA-ICP-MS锆石U-Pb年龄分别为(455.5±1.1)Ma和444Ma,形成时代为晚奥陶世。通过构造环境分析,认为阳康地区花岗岩是由挤压向拉伸环境转换的张驰阶段的岩浆侵位,属同造山花岗岩。     

哀牢山构造带南段马玉花岗闪长岩地球化学特征及其锆石U-Pb年龄

对云南墨江县马玉花岗闪长岩进行了锆石U-Pb年龄和岩石地球化学分析。LA-ICP-MS锆石U-Pb测年显示,马玉花岗闪长岩年龄为263.6±2.4Ma,形成于晚二叠世。岩石地球化学显示,马玉花岗闪长岩SiO_2含量为59.56%～70.50%,全碱(Na_2O+K_2O)含量为5.16%～7.92%,且Na2OK_2O;岩石富集轻稀土元素,负Eu异常明显(δEu=0.84～1.32),相对富集Sc、Hf,相对贫化Sr、Zr、Th、U。构造环境判别图解显示,马玉花岗闪长岩形成于碰撞期后板内构造环境,说明哀牢山构造带的古特提斯支洋或弧后盆地在晚二叠世(263.6±2.4Ma)已经闭合。     

内蒙古阿拉善北缘尚丹岩体的年代学、地球化学特征及构造意义

阿拉善北缘造山带位于中亚造山带最南端,前人鲜有报道的尚丹岩体是认识其构造演化的关键。尚丹岩体中花岗闪长岩的LA-ICP-MS锆石U-Pb年龄为331. 7±0. 9Ma,是在宗乃山-沙拉扎山构造带中获得的最早的晚古生代年龄,指示了早石炭世的岩浆事件。尚丹花岗闪长岩体具有中等硅含量(SiO_2=66. 07%～68. 15%)、高Na_2O(Na_2O/K_2O 1. 6),并相对高CaO(CaO/Na_2O 1),属于准铝质(A/CNK 1,A/NK 1)和中钾钙碱性系列(σ=1. 21～1. 40,K_2O=1. 55%～2. 21%),其岩石薄片中可见角闪石,地球化学和岩相学上都显示出I型花岗岩的特征。岩石的稀土元素含量中等,轻重稀土分异较明显((La/Yb)N=5. 30～6. 62),富集Rb、Th、K、Zr、Hf等元素,亏损Ba、Nb、Ta、P、Ti等元素。样品未出现明显Eu负异常,表明其可能形成于中下地壳的部分熔融。同时,2件全岩样品具有弱负的εNd(t)值(-1. 02、-0. 91),Nd模式年龄tDM1为1. 30～1. 28Ga,1件样品的锆石εHf(t)值为+0. 30～+5. 27,Hf模式年龄tDM2为1. 32～1. 00Ga。结合地球化学分析,尚丹岩体很可能形成于中新元古代地壳的再循环。总的来说,尚丹岩体具有岛弧相关特征,构造判别图解显示其形成于俯冲相关环境,表明阿拉善北缘在早中古生代造山停歇后,晚古生代的俯冲作用至少开始于早石炭世。     

甘肃省南祁连化石沟地区发现中二叠世埃达克质岩:大地构造及成矿意义

南祁连地区化石沟花岗闪长岩位于化石沟铜矿附近,东距阿克塞县城约120 km。花岗闪长岩LA-ICP-MS锆石U-Pb年龄为261.1±3.8 Ma,形成于中二叠世晚期。岩石属钙碱性系列,具有埃达克岩的地球化学特征,SiO_2含量在68.35%~69.14%之间,高铝(Al_2O_3=15.83%~16.06%)、Sr(367×10~(–6)~381×10~(–6))、低Y(15.12×10~(–6)~19×10~(–6))和Yb(1.34×10~(–6)~1.85×10~(–6)),富Na贫K(Na_2O=4.3%~4.47%,K_2O=2.22%~2.46%,Na_2O/K2O=1.75~2.01),MgO介于0.79%~0.89%之间,Mg~#为0.35左右。岩石富集强不相容元素Ba、Rb、Sr、Th、U和LREE,强烈亏损高场强元素Nb、Ta、Ti以及HREE,(La/Yb)_N=8.3~11.77,具轻微的Eu负异常(δEu=0.76~0.86),高Rb/Sr(≈0.2)值。化石沟花岗闪长岩的(~(87)Sr/~(86)Sr)i、ε_(Nd)(t)、(~(176)Hf/~(177)Hf)_i、δ~(18)O_(V-SMOW)分别为0.7065~0.7068、–1.45~–0.78、0.282765、12.1‰~12.5‰。综合以上特征,认为化石沟花岗闪长岩源于新生地壳物质在玄武岩浆底侵作用下发生的部分熔融,在岩浆作用过程中可能发生过轻微的分离结晶作用,形成于板内背景,处于造山挤压向后造山伸展的构造体制转变阶段。花岗闪长岩的Nd和Hf模式年龄(分别为1.1 Ga和0.9 Ga)指示玄武质岩浆上侵的时间应为中元古代晚期。化石沟埃达克质岩显示了良好的斑岩型Cu、Au成矿潜力,寻找与埃达克岩有关的斑岩型Cu、Au矿应是下一步找矿的重点方向。     

Wavelength-dispersive X-ray fluorescence spectrometric determination of Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites

Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.     

高压微波消解法测定醋酸纤维过滤器采集的微尘粒子中的砷镉钴铬铜铁锰镍铅钒锌

最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提     

硅酸盐类样品中硅、铁、铝、钛、锰、钙、镁、钾、钠和磷的x射线荧光光谱测定

本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.     

Viscous, cohesive, non-Newtonian, depositing, radial slurry flow

Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.     

硅酸盐中铁、锰、钛、钙、钾、磷、硅、铝、镁、钠、锶、铷、钡的X-射线荧光光谱定量测定

本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。     

Bellechester,Minnesota, USA,lagoon collapses

Bellechester, Minnesota, is a small community of approximately 155 residents located on the county line between Goodhue and Wabasha counties in southeast Minnesota's karst region. Bellechester is served by a 21-year-old wastewater treatment facility (WWTF) consisting of three waste-stabilization ponds. On 28 April 1992 six sinkholes were discovered to have drained cell 2 of the WWTF resulting in the loss of approximately 8.7×10⁶ 1 of partially treated effluent and about 600 m³ of soil into previously undetected subsurface voids of unknown dimensions. In the week following the collapse, approximately 200 water wells located within a 5-km radius of the WWTF were sampled in an after-the-fact, emergency sampling program. Twelve samples with elevated fecal coliform levels, 18 samples with nitrate-nitrogen greater than the 10 mg/1 standard, and no samples with elevated chlorides were found. However, the elevated levels could not be unambiguously attributed to the WWTF collapse. This is the third WWTF to fail by sinkhole collapse in southeast Minnesota since 1974. All three collapsed lagoons have been located in similar geomorphic and stratigraphic settings. However, at least two lagoons have collapsed in the adjacent area in northeast Iowa, and these lagoons are located at different stratigraphic positions. Twenty-two WWTFs constructed in southeast Minnesota's karst region in the last 25 years have been identified as subject to potential sinkhole collapse. An unknown but significant number of manure storage lagoons, flood control structures, etc., have also been constructed in the karst region and are at risk. Public agencies are beginning to develop plans to deal with the risk associated with existing and future waste lagoons in this environment. The critical hydrogeologic parameters that can be used to prioritize the risk of collapse at existing facilities include: (1) the lithology of the first bedrock beneath each lagoon, (2) the thickness of surficial materials between the lagoon and the bedrock surface, (3) the presence and construction of liners (seepage rate), and (4) the proximity to existing sinkholes.     

Mercury,arsenic, antimony,and selenium contents of sediment from the Kuskokwim River,Bethel, Alaska,USA

The Kuskokwim River at Bethel, Alaska, drains a major mercury-antimony metallogenic province in its upper reaches and tributaries. Bethel (population 4000) is situated on the Kuskokwim floodplain and also draws its water supply from wells located in river-deposited sediment. A boring through overbank and floodplain sediment has provided material to establish a baseline datum for sediment-hosted heavy metals. Mercury (total), arsenic, antimony, and selenium contents were determined; aluminum was also determined and used as normalizing factor. The contents of the heavy metals were relatively constant with depth and do not reflect any potential enrichment from upstream contaminant sources.     

滇东南花岗岩与锡、银、铜、铅、锌多金属矿床的成因关系

滇东南锡、银、铅、锌多金属矿床主要分布在个旧、白牛厂、都龙3个矿区,而滇东南较大的3个花岗岩体又分别出露在3个矿区或附近.花岗岩体均形成于燕山晚期,岩石化学、矿物成分相似,富含锡、银、铅、锌、钨、铜等成矿元素.矿床主金属元素组合与岩体之间的距离由远而近出现由锡、钨、(铍、铌、钽)→锡、钨、(铁)、铜、铟→锡、铅、锌、银、铟、(锑)有规律的变化.花岗岩浆是成矿物质来源和成矿热源.岩浆侵入初期使上覆地层隆起产生背斜(凹陷部位成向斜);同时使地层产生一系列裂隙、压性断层或层间断裂;岩浆侵入晚期,这些断层再次活动,表现为张性,岩浆产生的含矿热液沿由其活动所造成的断裂迁移、充填、交代、沉淀而形成矿床.     

岩石密度和超高压岩石折返速率

在常温常压条件下对中国大陆科学钻CCSD主孔100-3000米岩心样品进行了密度测量,建立了密度连续剖面,并界定了不同超高压岩石的密度值。通过对比高温高压物性实验资料,岩石密度随着退变程度增强而降低,榴辉岩密度变化序列为3.52g/cm3→3.49g/cm3→3.07g/cm3→2.93g/cm3。超高压长英质岩石密度变化序列为3.00g/cm→2.80g/cm3→2.65g/cm3。上述实验资料是讨论不同折返阶段岩石所受浮力的基础,为研究折返速率大小提供了基本参数。本文通过折返板块运动平衡时,上浮力与粘滞力平衡这一关系式,定量研究了大陆俯冲板块的折返速率,认为密度差产生上浮力从而引起折返,温度对板块折返速率的影响最为显著;密度差大小、折返角度、折返板块大小对折返速率也有直接的影响。定量模拟分析表明,在温度高于850℃时,板块的折返速率可以超过100mm/a;当温度降至700℃时,折返速率则低于1.5mm/a。作者认为在折返早期,温度较高,板块快速折返至60-70km榴辉岩相深度;随着传导散热,温度降低,板块以较慢的速率折返至中下地壳。折返速率的估算表明,浮力是板块折返第一阶段(从>100km深部折返至<40km的中下地壳)的主要驱动力。