西乌珠穆沁旗巴彦呼舒花岗闪长岩锆石U-Pb LA-ICP-MS年龄、地球化学、Hf同位素特征及其地质意义

本文报道的花岗闪长岩位于内蒙古巴彦呼舒以东10 km处。大地构造位于中亚造山带中段的锡林浩特晚古生代褶皱带。LA-ICP-MS锆石U-Pb测年获得该岩体的侵位年龄为236.1±3.4Ma。花岗闪长岩Si O2为66.93%~67.22%,Al2O3为15.13%~15.53%,K2O为2.47%~2.56%,Na2O为4.35%~4.46%,A/CNK值为0.94~0.95,显示该地区花岗闪长岩属于偏铝质钙碱性岩;亏损高场强元素,Sr达416.6×10-6~425.7×10-6,Sr/Y值为42~49,显示出高Sr低Y的典型特征,具有Adakite(高锶低钇中酸性岩)或者高Sr花岗岩的特点。花岗闪长岩的锆石εHf(t)值介于13.3~15.7之间;两阶段模式年龄分别为249~356Ma和258~422Ma。综合分析表明,花岗闪长岩为西伯利亚板块和华北板块碰撞闭合后,加厚的下地壳部分熔融作用的产物。     

东昆仑卡而却卡铜矿区花岗闪长岩及其暗色微粒包体成因:锆石U-Pb年龄、岩石地球化学及Sr-Nd-Hf同位素证据

卡而却卡铜多金属矿区花岗闪长岩体中广泛分布具有似斑状结构的闪长质包体,包体主要为椭圆形,定向排列,具有与寄主岩石相似的矿物组合,但角闪石含量明显比寄主岩石高,具有明显的不平衡反应结构,发育针状磷灰石。LA-MC-ICP-MS锆石U-Pb测试表明,暗色微粒包体形成于(234.1±0.6)Ma,寄主花岗闪长岩形成于(234.4±0.6)Ma,为岩浆混合作用的存在提供了有力证据。地球化学特征显示,暗色包体Si O2、Mg O含量较寄主岩石高,更偏基性;均富集大离子亲石元素和轻稀土元素,亏损高场强元素,但寄主花岗闪长岩LaN/YbN值(11.6~19.0)明显高于暗色包体(5.0~9.7),Nb/Ta值(10.6~11.7)低于暗色包体(11.6~14.8)。二者具有相近的Sr-Nd-Hf同位素组成,花岗闪长岩的εNd(t)值为-5.3~-4.2,(87Sr/86Sr)i值为0.71110~0.71125,εHf(t)为-5.8~-3.4,tDM(Hf)为1012~1102 Ma;暗色包体的εNd(t)值为-5.2~-5.0,(87Sr/86Sr)i值为0.71114~0.71171,εHf(t)为-6.3~-1.6,tDM(Hf)为937~1129 Ma。综上推测,在中三叠世俯冲—碰撞转换阶段,EMⅡ型富集岩石圈地幔在上涌软流圈物质的作用下发生部分熔融产生基性岩浆,并底侵下地壳物质局部熔融形成长英质岩浆房,进而由基性岩浆注入长英质岩浆房后,经过演化形成微粒包体,演化了的基性岩浆与长英质岩浆混合,最终形成含微粒包体的均一岩浆,这种岩浆结晶后形成含暗色包体花岗闪长岩。     

新疆希勒库都克铜钼矿区岩浆混合作用: 来自锆石U-Pb年代学的证据

新疆北部富蕴县内希勒库都克铜钼矿区的花岗闪长岩及其包体岩相学、矿物化学和岩石地球化学特征及野外地质特征显示其为岩浆混合作用的结果。本文获得花岗闪长岩及其中暗色微粒包体玄武安山玢岩、细粒辉长闪长岩锆石U-Pb年龄为326.8±2.1Ma、327.6±2.4Ma、329.3±2.3Ma,年龄值基本一致,这一结果从年代学角度为花岗闪长岩及其中暗色微粒包体的岩浆混合作用成因提供证据。偏酸性的花岗闪长质与偏基性玄武安山质岩浆混合作用形成了331.9±2.1Ma的安山玢岩脉。     

南祁连拉脊山构造带早古生代岩浆混合作用:以马场岩体为例

拉脊山构造带位于南祁连构造带北缘,发育大量早古生代岩浆岩。其南缘马场岩体主要由黑云母花岗岩和花岗闪长岩组成,花岗闪长岩中发育大量的镁铁质微粒包体。黑云母花岗岩、花岗闪长岩和镁铁质包体LA-ICP-MS锆石U-Pb年龄分别为 467±7Ma、468±6Ma、466±6Ma。黑云母花岗岩具有低 K_2O/Na_2O(0.28～0.37)、高 Sr/Y(125～168)比值特征,为埃达克质岩;同时,黑云母花岗岩还具有相对低的MgO、Cr、Ni含量和Mg~#值,富集轻稀土、大离子亲石元素(Ba、K、Pb、Sr)以及Zr、Hf,亏损重稀土和高场强元素(Nb、Ta、Ti),具有Eu正异常(Eu/Eu~*=1.30～1.58),亏损Sr-Nd和锆石Hf同位素组成((~(87) Sr/~(86)Sr)_t=0.7044～0.7046 ,ε_(Nd)(t)=+2.05～+2.21,ε_(Hf)(t)=+8.2～+10.2),指示黑云母花岗岩是新生地壳物质重熔的产物。镁铁质微粒包体与寄主花岗闪长岩之间呈过渡-截然接触界线,发育反向脉角闪石嵌晶结构、斜长石不平衡生长结构、镁铁质凝块以及刀刃状黑云母、针状磷灰石等显微结构反映典型的岩浆混合特征。镁铁质微粒包体与寄主花岗闪长岩均富集大离子亲石元素(Cs、K、Pb、Sr),亏损高场强元素(Nb、Ta、Zr、Hf),具有与黑云母花岗岩一致的Sr-Nd同位素组成,但镁铁质微粒包体具有更高的 MgO 含量(6.15%～9.12%)、Mg~#值(57～60)和 Cr(271 × 10~(-6)～424 × 10~(-6))、Ni(54.7 × 10~(-6)～86.6× 10~(-6))含量,暗示镁铁质微粒包体与花岗闪长岩是由受俯冲流体交代的地幔熔体与新生地壳物质重熔形成的熔体经岩浆混合而成。结合区域背景分析,本文认为马场岩体的形成与南祁连洋俯冲过程中幔源岩浆底侵加热新生地壳以及岩浆混合作用相关。     

内蒙古狼山地区早石炭世角闪辉长岩、花岗闪长岩的岩石成因及构造意义

内蒙古狼山山脉西侧分布有大面积的晚古生代岩浆岩,时代集中在早石炭世—晚二叠世,早石炭世角闪辉长岩、花岗闪长岩体出露于潮格温都尔镇西侧。角闪辉长岩体呈岩滴状产出,被花岗闪长岩体侵入,LA-ICP-MS锆石U-Pb年龄显示,角闪辉长岩的~(206)Pb/~(238)U加权平均年龄为329.0±2.3 Ma,花岗闪长岩的~(206)Pb/~(238)U加权平均年龄为331.1±0.9 Ma~330.0±4.2 Ma。花岗闪长岩暗色矿物以角闪石为主,富钠(Na2O=3.48%~4.46%),高钠钾比值(Na2O/K2O=1.03~2.39),钙碱性系列,P2O5-SiO_2之间存在较好的负相关性,岩石地球化学特征具Ⅰ型花岗岩的特点。Hf同位素及元素地球化学特征指示了角闪辉长岩及花岗闪长岩均来自于受地壳混染的亏损地幔,为同源岩浆演化的产物。角闪辉长岩及花岗闪长岩稀土元素配分型式一致,均为轻稀土元素富集,重稀土元素亏损,具弱的负Eu异常;角闪辉长岩富集Ba、Sr,亏损Nb、Ta、Zr、Hf;花岗闪长岩富集大离子亲石元素Rb、K、Pb、Sr,不同程度地亏损高场强元素Nb、Ta、P、Ti,总体反映了岩浆弧的地球化学特征。结合区域地质背景,早石炭世狼山地区侵入岩岩石组合为角闪辉长岩(闪长岩)+石英闪长岩+花岗闪长岩,认为狼山地区早石炭世处于大陆边缘弧构造背景。     

甘肃北山大豁落南地区晚二叠世花岗闪长岩成因——锆石U-Pb年龄和岩石地球化学制约

对甘肃北山大豁落南地区花岗闪长岩进行了LA-ICP-MS锆石U-Pb测年及主量和微量元素地球化学分析。结果表明,花岗闪长岩的结晶年龄为259.7±1.5Ma。花岗闪长岩SiO_2含量介于63.10%～69.69%之间,Al_2O_3介于14.86%～15.48%之间,平均15.21%,MgO含量为0.96%～3.59%,平均2.69%,岩石强烈富集轻稀土元素,(La/Yb)N为18.60～50.91,具弱Eu异常(δEu=0.83～1.06),高Sr(454×10~(-6)～862×10~(-6))、高Sr/Y值(Sr/Y=44.95～60.35),具有埃达克岩的地球化学特征。花岗闪长岩富钾、贫钠,具有较高的Cr、Ni含量和Mg~#(50.31～66.75)值,结合区域地质背景,认为花岗闪长岩是碰撞后板内热隆伸展环境壳幔交互作用的产物,暗示晚古生代北山地区地壳为垂向增生,与以天山为主的中亚造山带大范围存在的二叠纪与幔源岩浆有关的花岗岩是同期构造岩浆事件的产物。     

太行山北段王安镇杂岩体岩石学、年代学、地球化学特征及地质意义

王安镇杂岩体主要由花岗闪长岩、二长花岗岩、花岗岩、石英闪长岩、二长闪长岩组成,LA-ICP-MS锆石U-Pb测年显示,花岗闪长岩和石英闪长岩分别形成于129±2.7Ma和128.3±1.9Ma,说明该杂岩体形成于早白垩世。王安镇杂岩体具有高Sr/Y比值(3.63~83.5),和高Sr(373×10-6~821×10-6),及低Y(7.36×10-6~22.21×10-6)、Yb(0.95×10-6~1.27×10-6)含量的地球化学特征,这与埃达克岩相似。该杂岩体具有相对低的87Sr/86Sr初始比值(0.706538~0.709484)和明显偏低的εNd(128Ma)值(-18.4~-12.8)。结合太行山中生代中-基性侵入岩中地幔包体已有的研究成果,认为具有高Sr/Y特征的王安镇杂岩体是在下地壳发生大规模拆沉的基础上,随着软流圈上涌其所携带的热促使加厚基性下地壳发生部分熔融,之后熔融岩浆在上升的过程中发生了角闪石的结晶分异和岩浆混合作用形成。     

江南造山带东段旌德岩体锆石LA-ICPMS年龄和Nd-Sr-Hf同位素地球化学

提要：旌德花岗质杂岩体位于安徽南部,由花岗闪长岩和二长花岗岩组成。本研究得到岩体中锆石U-Pb年龄为(141.0±1.0) Ma,认为该年龄代表岩体的侵位年龄。岩体全岩主量元素特征显示出中偏酸性 (SiO2＝66.01%~70.87%),富Al (Al2O3＝14.91%~16.24%),富碱 (alk = 6.64%~8.01%),K2O/Na2O变化范围在0.78~1.04,镁、铁含量较低,MgO：0.68%~1.06%,TFe2O3 (2.0%~3.34%),以及低磷 (P2O5 =0.10%~0.14%)的特点;微量元素主要富集Sr (189×10-6~452×10-6),贫Nb、Ta、P、Ti、Y、Yb,高Sr/Y比值 (23~66)和 (La/Yb)N (13~58),Eu有轻微的负异常到弱的正异常 (δEu＝0.81~1.18)。旌德岩体的地球化学特征与中国东部中生代埃达克质岩相似。ISr＝0.7096~0.7101, εNd(t)＝-6.28~-7.32,εHf(t)值变化于-6.5~-1.1,两阶段模式年龄 tDM2=1.4~1.5 Ga。较年轻的Nd同位素模式年龄、较高的εNd(t)值和εHf(t)值,以及岩体中发育有岩浆混合成因的暗色包体,指示源区可能有地幔物质的贡献。幔源岩浆底侵使下地壳发生部分熔融,并发生了岩浆混合作用,形成了旌德岩体。     

新疆东准噶尔二台北花岗岩体和包体的SHRIMP锆石U-Pb年龄及其地质意义

高精度SHRIMP锆石U-Pb定年结果表明,二台北花岗闪长岩的形成时代为299.3±8.7Ma,代表了岩浆侵入到上地壳的年龄;其中所含的暗色微粒包体形成时代为301.5±6.6Ma,与寄主岩石的时代在误差范围内完全相同。结合野外、岩相学和主量、微量元素地球化学特征分析,偏基性的暗色微粒闪长质包体与寄主花岗闪长质岩浆并非有直接成因联系,包体可能是由过冷的镁铁质岩浆混入到花岗闪长质岩浆中发生快速冷凝,然后被花岗闪长质岩浆携带、侵入到上地壳中形成的。因此,花岗闪长岩及其包体才能够具有相同的SHRIMP锆石U-Pb年龄。二台北岩体与东准噶尔广泛分布的以碱性花岗岩为代表的后碰撞花岗岩具有相同的形成时代,乌伦古-斋桑泊断裂北侧的花岗闪长岩、石英闪长岩等和断裂南侧的碱性花岗岩、钾长花岗岩等的形成时代非常相近,应该是同一期岩浆活动的产物,无法区分出先后顺序。而这些岩体普遍具有低的~(87)Sr/~(86)Sr初始比值和正的ε_(Nd)(t)值,表明它们都是新疆北部晚古生代幔源岩浆活动的产物,它们的形成和演化提供了准噶尔地区后碰撞幔源岩浆底侵作用导致大陆地壳垂向生长过程的信息。     

西藏冈底斯带西部达雄岩体的岩石成因:锆石U-Pb年龄和Hf同位素约束

对出露于冈底斯西部地区措勤北部达瓦错东侧的达雄岩体进行了锆石U-Pb定年、全岩主量元素、微量元素、Sr-Nd同位素和锆石Hf同位素研究,以约束其岩石成因。达雄岩体的主体岩性为花岗闪长岩,其中发育大量闪长质包体。花岗闪长岩的锆石LA-ICP MS年龄为107±1Ma,该年龄代表了岩体结晶年龄。花岗闪长岩锆石ε_(Hf)(t)值变化于-1.0～3.0,两阶段模式年龄变化于974～1226Ma。花岗闪长岩富硅(SiO_2=70.65%～71.10%),富钙(CaO=3.21%-3.26%)、贫钾(K_2O= 2.81%～2.99%)、低P_2O_5(0.09%),铝饱和指数(A/CNK)为1.01～1.02,属于偏铝质花岗岩或弱过铝质花岗岩。闪长质包体Sio_2含量为57.84%,与寄主岩相比,闪长质包体更富CaO、MgO、TFe_2O_3和TiO_2。花岗闪长岩和闪长质包体均属中钾钙碱性系列,ε_(Nd)(t)值分别为-4.6和-3.2,两阶段模式年龄(t_(DM2))相近(分别为1277Ma和1166Ma),并与锆石Hf同位素模式年龄一致。岩相学、年代学和地球化学研究表明闪长质包体可能是由岩浆混合作用形成的镁铁质微粒包体。我们的初步研究成果似乎表明,冈底斯中西部地区在早白垩世晚期(～110Na)很可能存在一次重要的岩浆混合作用,这一初步认识对研究冈底斯中北部地区规模宏大的白垩纪岩浆作用的深部动力学过程具有重要意义。     

Hydrochemistry of aquifers in the southern Dead Sea area,southern Jordan

 The demand for water resources in the area south of the Dead Sea due to continued development, especially at the Arab Potash Company (APC) works necessitates that water quality in the area be monitored and evaluated based on the local geology and hydrogeology. The objective of this paper is to provide information on the past and present status of the main aquifers under exploitation or planned for future development. Two main aquifers are discussed: the Safi water field, presently being operated, and the Dhiraa water field, which is being developed. The aquifer developed in the Safi water field is shallow and fed by the Hasa fault system, which drains a significant portion of the Karak mountains. This aquifer seems to be well replenished within the core, where no obvious long-term degradation in water quality can be identified. However, in the low recharge areas within the distal portions of the alluvial fan, there has been a degradation in water quality with time. The degradation is caused by the dissolution of the Lisan Marl, which is present at the outskirts of the fan system, based on hydrochemistry of water in the wells. The Dhiraa field is a deep (800–950 m) aquifer drilled specifically for the extraction of brackish water present in the Kurnub aquifer. Available data indicate that there are at least three distinct water types within this field. These water types are variable in quality, and there may be potential for mixing of these waters, thus affecting the quality of the freshest waters presently available. Tritium and oxygen isotope analysis indicate that the water is old and possibly nonrenewable. Received: 24 July 1995 · Accepted: 26 September 1995     

Charnockitic magmatism in southern India

Large charnockite massifs cover a substantial portion of the southern Indian granulite terrain. The older (late Archaean to early Proterozoic) charnockites occur in the northern part and the younger (late Proterozoic) charnockites occur in the southern part of this high-grade terrain. Among these, the older Biligirirangan hill, Shevroy hill and Nilgiri hill massifs are intermediate charnockites, with Pallavaram massif consisting dominantly of felsic charnockites. The charnockite massifs from northern Kerala and Cardamom hill show spatial association of intermediate and felsic charnockites, with the youngest Nagercoil massif consisting of felsic charnockites. Their igneous parentage is evident from a combination of features including field relations, mineralogy, petrography, thermobarometry, as well as distinct chemical features. The southern Indian charnockite massifs show similarity with high-Ba-Sr granitoids, with the tonalitic intermediate charnockites showing similarity with high-Ba-Sr granitoids with low K₂O/Na₂O ratios, and the felsic charnockites showing similarity with high-Ba-Sr granitoids with high K₂O/Na₂O ratios. A two-stage model is suggested for the formation of these charnockites. During the first stage there was a period of basalt underplating, with the ponding of alkaline mafic magmas. Partial melting of this mafic lower crust formed the charnockitic magmas. Here emplacement of basalt with low water content would lead to dehydration melting of the lower crust forming intermediate charnockites. Conversely, emplacement of hydrous basalt would result in melting at higher {ie565-01} favoring production of more siliceous felsic charnockites. This model is correlated with two crustal thickening phases in southern India, one related to the accretion of the older crustal blocks on to the Archaean craton to the north and the other probably related to the collision between crustal fragments of East and West Gondwana in a supercontinent framework.     

Groundwater investigation in the southern part of Gabes using resistivity sounding, southern Tunisia

The groundwater hydrogeology of southern Tunisia emphasizes two main groundwater bodies so-called Zeuss-Koutine and south Gabes. These groundwater bodies yielding economically important storage of useful water present complex internal architecture and heterogeneity allowing exchange flows throughout permeable or/and fractured bodies. A geophysical survey using resistivity soundings was carried out along this area to describe in detail the field structure and the 3D extent of these groundwater bodies by the hydrogeological new data and detailed subsurface mapping based on resistivity sounding and seismic data. This survey discusses also the potentialities of some permeable layer in water storage and purposes potential favorable areas for optimum groundwater mining.     

Perpotassic granulites from southern Bohemia

Garnetiferous, perpotassic granulites associated with voluminous, felsic calc-alkaline garnet-kyanite granulites in the Blanský les massif are described as a new rock type. A K₂O content near 13 wt%, Zr content ranging from 17 to 5877 ppm, primary Ca-Mg-Fe garnet (pyrope up to 33 mol %), and the absence of primary plagioclase and quartz characterize the new type of granulite. Calcium is incorporated only in garnet and apatite. Owing to the content of garnet the bulk syenitic compositions are metaaluminous to peraluminous. The perpotassic granulites are accompanied by subordinated melanocratic perpotassic granulite and alkali-feldspar melanocratic granulite containing up to 20 vol % quartz. These rock types also contain highly variable amounts of zircon. High-pressure, noneutectic partial melting of crustal rocks and crystallization under upper mantle conditions is suggested as the main process in generation of perpotassic granulites. A polyphase, ductile to brittle deformation and recrystallization in pyroxene granulite and later in amphibolite facies accompanied obduction of the granulite massif which carries numerous enclaves of pyrope peridotite. Euhedral equant zircon crystals up to 4 mm long enclosed in large garnet crystals and in the alkali feldspar matrix of perpotassic granulite represent a uniform, high-temperature population with a nearly concordant U-Pb system (Aftalion et al. 1989). The Hercynian age of this zircon indicates the role of the Hercynian anatexis of crustal rocks under upper mantle conditions in generation of granulites in the Moldanubian zone of the Bohemian massif.     

Neotectonics and seismicity in southern Patagonia

Research for evaluation of geologic hazards involving earthquakes and volcanic eruptions in southern Argentina seems to have historically received little attention. Nevertheless, the relatively small work done indicates a Neogene tectonic architecture in the area with capability of generating potential hazardous earthquakes in a growing population region. Seismicity and some morphotectonic evidences of Quaternary activity of the Magallanes–Fagnano left‐lateral fault system in the transform boundary between South America and Scotia plates, are analysed in this paper. This fault system is considered to be an important seismogenic source, responsible for large earthquakes that have occurred in southern Argentina. Some examples from the South and Austral Andean Volcanic Zones are also examined in order to show recent volcanic activity which also generated crustal seismicity. Preliminary hazard estimation clearly shows the presence of both potentially active volcanic centres in southern Patagonia that may also trigger seismicity and the high probability for large crustal earthquake generation. Copyright © 2015 John Wiley & Sons, Ltd.     

大别山南部天然碳硅石

根据1975年的矿点检查报告,在大别山南部董家山蛇纹岩体的人工重砂和岩石薄片中,发现确有天然碳硅石存在。大部分碳硅石单晶为六方板状,一部分为不规则形,最大粒径450μm×100μm,一般250μm×150μm。薄片中的粒径较小。单晶的拉曼光谱位移峰值稳定,薄片中碳硅石的拉曼位移峰也都在误差范围内。单晶以二轴晶(+)为主,部分为一轴晶(+),薄片中晶体几乎都为二轴晶(+)。虽然天然碳硅石可以产出于任何岩石中,但是原位的天然碳硅石只见于陨石和金伯利岩中,本文发现的很可能是首例地球蛇纹岩中的原位天然碳硅石。天然碳硅石与人工合成的碳化硅在结晶行为、光学性质和红外光谱方面有明显不同,成分也有差异,但拉曼光谱虽有差别却不明显。由于碳硅石与金刚石有类似的四面体方向sp3异化键和相同的滑动面,可能有类似的变形条件。根据碳硅石有晶内变形,推测其形成于≥300km的深度,这对认识大别山南部构造演化有重要意义。