白令海陆架区柱样沉积物脂类分子特征及其气候变化响应

为探究全球变暖对于高纬度海洋生态环境的影响,对中国第5次北极科学考察在白令海陆架区采集的BL16柱样沉积物中的脂类进行了研究.沉积物中检测到丰富的饱和烃和脂肪酸等化合物,其组成和分布显示,该沉积柱中有机质为陆源和海源混合输入.其中长链正构烷烃和长链饱和正构脂肪酸主要来源于陆源高等植物,饱和异构和反异构脂肪酸主要来源于海洋自生细菌,短碳链正构烷烃、反异构烷烃和烷基环戊烷烃的浓度相互间有较好的相关性,表明其来源较为一致,主要来源于海洋浮游藻类和细菌.海源短链正构烷烃与陆源长链正构烷烃的比值∑C_15-21/∑C_23-33在0.14~0.90之间,表明该沉积柱中正构烷烃主要以陆源输入为主.沉积柱中短链正构烷烃、反异构烷烃和烷基环戊烷浓度,以及脂肪酸中异构、反异构脂肪酸组分与长链饱和正构脂肪酸组分的相对变化与总有机碳含量（TOC）、总氮含量（TN）变化一致,尤其在20世纪70年代以来明显升高,可能反映了海洋初级生产力持续增加的趋势,并且对全球变暖做出了灵敏的响应.      

南海北部油气缓释环境沉积物脂类化合物组成特征

认识沉积环境有机碳留存状况是阐述油气形成过程中有机碳早期成岩的关键内容。以南海珠江口盆地及其邻近海域为背景,通过研究表层沉积物中脂类化合物的形态组成,认识脂类有机碳的来源和留存状态,阐述特征脂类分子的早期成岩特征。结果表明,研究区域表层沉积物有机碳含量为0.22%～0.66%,有机碳稳定同位素分布在-20.88‰～-22.93‰之间,表现为显著的海源特征。沉积物中共检测出21种脂肪酸、6种脂肪醇、8种甾醇和植醇;总脂肪酸、脂肪醇、甾醇和植醇含量分别为12.57～40.27μg/g、5.35～8.98μg/g、0.15～3.75μg/g和0.01～3.99μg/g干重,总体表现为靠近珠江口和台湾海峡略高。脂类化合物的存在形态以游离态(FR)和碱性水解态(BH)为主,酸性水解态(AH)贡献较低;其中植醇和甾醇呈现显著的BH优势,植醇中未检出AH组分的贡献。脂类化合物主要来自于海洋现场生产,海洋微藻和细菌的相对贡献率分别为21.18%～33.78%和11.02%～15.64%,陆源高等植物贡献低于5%。来源于硫酸盐还原菌的支链脂肪酸在靠近珠江口海域高达1.79～2.62μg/g,占总脂肪酸的5.14%～6.50%,并与硫酸盐还原过程相关的古菌分布相一致。     

Biomarkers in upper Holocene Eastern North Sea and Wadden Sea sediments

Total extracts of sediment cores from five different stations in the North Sea and Wadden Sea were analysed for their biomarker composition. Only sediments of the Skagerrak contained significant amounts of marine biomarkers (mainly alkenones), other sites contained predominantly terrestrial biomarkers. Bioturbation in the Skagerrak is, however, far too high to determine sea surface temperature (SST) changes within short time intervals. These results indicate that biomarkers contained in these sediments are not useful to reconstruct climate fluctuations during the upper Holocene. High amounts of α-, β- and ω-hydroxy fatty acids as well as small amounts of α, β-dihydroxy fatty acids were released from the insoluble organic material of the sediments from the Wadden Sea station, indicating a significant input of the eelgrass Zostera marina. This was confirmed by microscopic observations. This is the first time the α,β-dihydroxy fatty acids have been found in a sediment core and they have proven to be potential biomarkers for these seagrass species.     

The stereoisomeric composition of phytanyl chains in lipids of Dead Sea sediments

Lipid extracts from five recent Dead Sea sediments were analyzed for isoprenoid compounds and the following were isolated: free and phospholipid-bound di-O-phytanylglycerol, free phytanol and free and esterifled phytanic acid. The phytanyl groups of the diether and the free phytanol were oxidized to the corresponding phytanic acid; the stereoisomeric composition of the derived phytanic acids as well as of the ester-bound phytanic acid was determined by open-tubular gas-liquid chromatography of the corresponding methyl esters on butanediolsuccinate polyester. Only the 3R,7R,11R-isomer of phytanic acid was detected in each of the phytanate samples, indicating that these phytanyl chains in the Dead Sea sediments are most likely derived from extremely halophilic bacteria rather than from phytol of chlorophyll origin. These findings also provide further evidence that the mixtures of RRR and SRR-phytanic acids previously isolated from organic-rich shales were most likely derived from the phytyl chain in chlorophyll.     

Organic geochemical characteristics of time-series settling particles in northern South China Sea and their implications

Organic carbon, total nitrogen, amino acids, sugars, and chlorophyll were determined in < 1 mm fractions of the samples collected by successive large aperture time-series sediment traps (Honjo-Mark M) in northern South China Sea during September 1987 to October 1988. The ratio of C/N and the relative abundance of amino acids and sugars show that organic matter in the settling particles from northern South China Sea is derived mainly from marine plantkon (especially phytoplankton). The organic carbon fluxes in our sediment traps are lower than those in other sediment traps. But the relative contents of C_org/total particulate matter are generally similar to those in the Panama Basin, Arabian Sea and Subarctic Pacific. It is suggested that monsoon-caused changes of physical and chemical conditions in the upper euphotic layer would control the fluxes of organic matter as well as its composition and transport in northern South China Sea. This project was financially supported by both Sino-German Scientific Cooperation Program and National Natural Science Foundation of China (No. 49070269, 49776297).     

南海始新世海相地层分布及油气地质意义

采用古生态学及沉积学方法, 对南海北部深水区BY7-1-1井及L29井特定层段进行细致研究.通过有孔虫、孢粉藻类分析及沉积学分析, 证实南海北部白云深水区在晚始新世即出现滨浅海相沉积环境, 确定了南海北部最早接受海相沉积的时间.始新世海相地层在南海北部主要分布在台西及台西南盆地中, 并在晚始新世扩展到珠江口盆地白云凹陷.在南部分布较广, 曾母盆地、北康盆地、礼乐盆地及巴拉望盆地中均有始新世海相地层分布.南海始新世海相地层的分布受制于新南海扩张及古南海的消退, 以晚始新世为时间节点发生显著变化, 总体上分布范围增大, 反映该时期南海拉张和断裂活动的加剧.南海始新世海相地层具有良好的油气潜力, 在部分盆地中形成了优质的烃源岩与储层, 珠江口盆地白云深水区晚始新世海相地层的发现, 对南海深水海相油气勘探具有积极的参考作用.      

Variability of river discharge and Atlantic-water inflow at the Laptev Sea continental margin during the past 15,000 years: implications from maceral and biomarker records

In order to reconstruct the depositional environment from the Laptev Sea continental slope and shelf during the past ~15,000 years BP maceral analysis was carried out on two sediment cores (PS2458-4, PS2725-5) and compared with organic-geochemical parameters. During the transition from the Last Glacial to the Holocene the environment of the Laptev Sea shelf was controlled by the post-glacial sea level rise, variations in river discharge, surface-water productivity, and Atlantic-water inflow along the Eurasian continental margin. Based on our results, we identify the following significant changes of the environment: (a) at approximately 13,500 years BP the first step of deglaciation (Termination 1a) is documented by the deposition of marine and fresh-water organic matter; (b) at approximately 10,400 years BP the first post-glacial influence of Atlantic-water inflow along the Eastern Laptev Sea continental margin is indicated by an increase in marine organic matter; (c) at the beginning of the Holocene an increased fluvial supply is documented by an increase in fresh-water alginite; and (d) since ~9500-8000 years BP modern marine conditions are established at the Laptev Sea continental margin as documented in increased amounts of marine macerals, biomarkers (dinosterol, brassicasterol, short-chain fatty acids), and dinoflagellate cysts.     

东海表层沉积物黏土粒级中多态脂肪酸组成与地球化学特征

对东海陆架泥质沉积区两个代表性站位表层沉积物开展了黏土粒级分离提取,并对其依次进行溶剂萃取、碱解和酸解处理,得到结合程度不同的三种脂肪酸组分：有机溶剂抽提的游离态脂肪酸、碱解得到的碱解酸和酸解得到的酸解酸。三种赋存态酸的存在表明它们所联结的宏观分子的结构不同或所吸附黏土矿物的保护作用不同。不同赋存态酸的数量、组成和分布有一定差异,两站位相同赋存态酸的数量与组成也存在明显差异。组成与分布特征表明东海陆架泥质区超细颗粒物中脂肪酸以海洋内源藻类来源为主（〉70％）,陆源高等植物贡献相对较低,并有少量的细菌源贡献。各赋存态酸的降解程度为碱解酸高于酸解酸高于游离酸,可能与其在黏土中的赋存状态和吸附过程有关。靠近长江河口的表层沉积物样品（24站）海洋内源藻类贡献略低于远离河口的站位（30站）,陆源高等植物的输入稍高于后者,是受两泥质区沉积环境综合影响的结果。     

Prospective prediction and exploration situation of marine Mesozoic-Paleozoic oil and gas in the South Yellow Sea

The South Yellow Sea Basin is a large sedimentary basin superimposed by the Mesozoic-Paleozoic marine sedimentary basin and the Mesozoic-Cenozoic terrestrial sedimentary basin, where no oil and gas fields have been discovered after exploration for 58 years. After the failure of oil and gas exploration in terrestrial basins, the exploration target of the South Yellow Sea Basin turned to the marine Mesozoic-Paleozoic strata. After more than ten years’ investigation and research, a lot of achievements have been obtained. The latest exploration obtained effective seismic reflection data of deep marine facies by the application of seismic exploration technology characterized by high coverage, abundant low-frequency components and strong energy source for the deep South Yellow Sea Basin. In addition, some wells drilled the Middle-Upper Paleozoic strata, with obvious oil and gas shows discovered in some horizons. The recent petroleum geological research on the South Yellow Sea Basin shows that the structure zoning of the marine residual basin has been redetermined, the basin structure has been defined, and 3 seismic reflection marker layers are traceable and correlatable in the residual thick Middle-Paleozoic strata below the continental Meso-Cenozoic strata in the South Yellow Sea Basin. Based on these, the seismic sequence of the marine sedimentary strata was established. According to the avaliable oil and gas exploration and research, the marine Mesozoic-Paleozoic oil and gas prospects of the South Yellow Sea were predicted as follows. (1) The South Yellow Sea Basin has the same sedimentary formation and evolution history during the sedimentary period of the Middle-Paleozoic marine basin with the Sichuan Basin. (2) There are 3 regional high-quality source rocks. (3) The carbonate and clastic reservoirs are developed in the Mesozoic-Paleozoic strata. (4) The three source-reservoir-cap assemblages are relatively intact. (5) The Laoshan Uplift is a prospect area for the Lower Paleozoic oil and gas, and the Wunansha Uplift is one for the marine Upper Paleozoic oil and gas. (6) The Gaoshi stable zone in the Laoshan Uplift is a favorable zone. (7) The marine Mesozoic-Paleozoic strata in the South Yellow Sea Basin has the geological conditions required to form large oil and gas fields, with remarkable oil and gas resources prospect. An urgent problem to be addressed now within the South Yellow Sea Basin is to drill parametric wells for the Lower Paleozoic strata as the target, to establish the complete stratigraphic sequence since the Paleozoic period, to obtain resource evaluation parameters, and to realize the strategic discovery and achieve breakthrough in oil and gas exploration understanding.©2019 China Geology Editorial Office.     

我国南海海鱼中有机氯农药残留分析

建立了凝胶渗透色谱前处理,毛细管气相色谱测定我国南海海鱼中11种有机氯农药的方法。分析了油鲽鱼块、鲷鱼片、银鳕鱼、哈哈鱼块、海鳗鱼中的有机氯农药残留情况,发现在禁用20多年后,六六六(HCHs)、滴滴涕(DDTs)、狄氏剂、环氧七氯在鱼肉中均有不同程度的检出,其中滴滴涕的残留水平最高达到26.73μg/kg。研究发现我国南海海鱼中4种HCH的总残留量高于北京市场上的淡水鱼的残留水平;多数有机氯农药残留污染的平均水平也高于英国和巴西等国鱼类的水平。南海海鱼中有机氯农药残留水平具有指示环境污染的意义。     

Petrology of the Permian Yellow Sands of northeastern England and their North Sea Basin equivalents

The Permian Yellow Sands of northeastern England and the Permian Weissliegendes of the English North Sea Basin are petrologically defined as multicycle, moderately sorted, subrounded graywackes, subgraywackes and subarkoses with post-depositionally etched and overgrown grains. These sandstones were derived by the marine reworking of the Permian Rotliegendes and transported from the east to the southwest. Petrologic data show that these Upper Permian sandstones were deposited in a shallow marine environment and that the commonly held aeolian dune interpretation for them should be rejected. Their formation during the transgression of the Zechstein Sea places them within the Zechstein sequence and therefore they are Thuringian in age rather than Saxonian.     

中国东南海域中生界油气地质条件与勘探前景

中国东南海域中生代地处欧亚板块东南缘, 夹持于欧亚板块、太平洋板块与印度澳大利亚板块之间。以往对于该区域的油气勘探多集中于新生代。笔者在前人研究的基础之上, 结合新近获得的地震资料, 开展了中国东南海域及周缘油气地质条件研究。结果表明:中国东南海域中生界分布广, 东海南部、台湾岛以及台西南盆地发育中生界深海相硅质岩, 可能与冲绳缝合带和菲律宾巴拉望缝合带形成有关;南海北部及周缘陆区发育上三叠统下侏罗统海相和海陆交互相碎屑岩及上侏罗统白垩系陆相碎屑岩, 可能与印支期缝合带的形成有关。从海域钻井及周缘陆区沉积层序资料推断, 中国东南海域有两套发育良好的烃源岩, 具有较强的生烃潜力:上三叠统下侏罗统海相泥页岩, 有机碳质量分数为0.28%~14.96%, 干酪根类型主要以Ⅱ₂型和Ⅲ型为主;下白垩统海相泥页岩, 有机碳质量分数为0.60%~2.00%, 干酪根类型以偏Ⅱ₂Ⅲ型为主。该海域发育两套生储盖组合:一套以上三叠统下侏罗统泥页岩为烃源岩, 中、上侏罗统砂岩为储层, 下白垩统泥页岩为盖层;另一套以下白垩统泥页岩为烃源岩, 白垩系砂岩为储层, 上白垩统泥页岩为盖层。它们相互可以形成"古生新储"、"自生自储"油气藏组合。因此, 中国东南海域中生界是值得关注的油气勘探新领域。     

南海长链烯酮化合物的检测及U37^k值的应用

首次系统地在南海大面积站位中检测出长链烯酮化合物。通过长链烯酮指标Ｕ３７ｋ与实测表层海水温度（ＳＳＴ）的对比研究,发现海洋沉积物样品在室温下长期（１７ａ）密封保存,长链烯酮指标Ｕ３７ｋ值无明显变化。Ｕ３７ｋ值在南海海区指示的表层海水温度与季节有关,主要反映秋、冬两季,即１０月至次年３月间的ＳＳＴ。     

Late Weichselian glaciation history of the northern North Sea

Based on new data from the Fladen, Sleipner and Troll areas, combined with earlier published results, a glaciation curve for the Late Weichselian in the northern North Sea is constructed. The youngest date on marine sedimentation prior to the late Weichselian maximum ice extent is 29.4 ka BP. At this time the North Sea and probably large parts of southern Norway were deglaciated (corresponding to the Alesund interstadial in western Norway). In a period between 29.4 and c. 22 ka BP, the northern North Sea experienced its maximum Weichselian glaciation with a coalescing British and Scandinavian ice sheet. The first recorded marine inundation is found in the Fladen area where marine sedimentation started close to 22 ka BP. After this the ice fronts receded both to the east and west. The North Sea Plateau, and possibly parts of the Norwegian Trench, were ice-free close to 19.0 ka, and after this a short readvance occurred in this area. This event is correlated with the advance recorded at Dimlington, Yorkshire, and the corresponding climatostratigraphic unit is denoted the Dimlington Stadial (18.5 ka to 15.1 ka). The Norwegian Trench was deglaciated at 15.1 ka in the Troll area. The data from the North Sea, together with the results from Andwa, northern Norway (Vorren et al . 1988; Møller et al . 1992), suggest that the maximum extent of the last glaciation along the NW-European seaboard from the British Isles to northern Norway was prior to c . 22 ka BP.     

Heavy metal pollution in the Black Sea shore and offshore of Turkey

Land-locked seas were polluted mainly by land-based pollutants. The Black Sea is the largest enclosed sea in the world and widely perceived to be heavily polluted. In order to determine the impact of marine activities on heavy metal pollution, shore (500 m distance from edge)–offshore (5,555 m distance from edge) samples of various stations through the Sinop, Samsun and Ordu cities located in the Middle Black Sea region between May 2000 and October 2001 were taken. In addition, samples were taken between April–May 2000 in order to designate the heavy metal pollution of certain rivers, streams, harbor and shores in Samsun’s boundary and 32 sampling stations for the routine pollution monitoring studies are selected including rivers, streams, industrial and domestic discharge points along the Black Sea coast of Turkey in the year 1996. Heavy metal concentrations of whole samples were measured and compared with “Quality Criteria of General Marine and Continental Inside Water Sources” currently effective in Turkey so as to bring up the levels of pollution in marine, rivers and streams.     

Barite Nodules in the Japan Sea

Although barite nodules are extremely rare in the World Ocean, they are rather widespread in the Japan Sea. They were first discovered by Japanese scientists in the Honshu Island borderland (Okada et al., 1971; Sakai, 1971). They were later reported from the North Yamato Rise (Lipkina and Tsoi, 1980) and Okushiri Ridge (Astakhova et al., 1990) (Fig. 1, Table 1). All barite nodules in the Japan Sea are confined to Miocene marine sediments.     

Characteristics of marine strata distribution in South Yellow Sea based on airborne gravity and magnetic data

Based on the high accuracy airborne gravity and magnetic data of South Yellow Sea, combined with the characteristics of gravitational and magnetic field and geophysical properties, the authors analyzed the matched filtering through radially averaged logarithmic power spectrum to separate and extract the gravity and magnetic anomaly caused by the interfacial fluctuation of marine strata. And the depth of the marine strata interface of South Yellow Sea was interpreted by the tangent and Vaquier methods. The authors also compiled the depth of the bottom and top interface of the marine strata after geological and geophysical interpretations. In addition, a preliminary division of South Yellow Sea marine strata tectonic units was carried out and the strata distribution was also discussed. The central depression and southern depression of Subei- South Yellow Sea depression area were developed on the strongly magnetic basement, with weak tectonic deformation. The marine strata remain intact with a shallow depth of 4 km to 8 km. South Yellow Sea is the oil and gas exploration area with great resource potential.     

南黄海海域生储盖层特征及油气远景评价

根据近年来新取得的资料,结合前人的研究成果,对南黄海海域的生储盖层特征进行了综合研究。古生界、中生界海相地层为南黄海海域的主力烃源岩,从构造运动和沉积发育情况分析,将南黄海海域的古生界、中生界海相地层生成油气的成藏过程划分为三叠纪印支运动前、侏罗纪—白垩纪、古近纪和新近纪4个阶段。通过对生储盖层的特征分析,说明南黄海古生界、中生界海相地层油气资源具有开发前景。在对南黄海盆地海相中生界、古生界烃源条件和后期保存条件研究的基础上,预测了盆地内海相油气资源的有利运聚区,为南黄海海域的油气勘探及研究工作提供了依据,对我国新的海上油气开发及部署作出了贡献。     

基于航空重、磁数据的南黄海海相地层分布特征识别

基于南黄海海域实测高精度航空重、磁数据,结合航空重、磁场及物性特征,通过平均对数功率谱分析匹配滤波方法技术,对南黄海海相地层界面起伏引起的重、磁异常特征进行分离、提取,采用切线法和外奎尔法计算海相地层界面的深度,经地质和地球物理综合解释,编制了南黄海海相地层底界面、顶界面深度图及海相地层厚度图。在此基础上,初步划分了南黄海海相地层构造单元,探讨了南黄海海相地层的分布特征。苏北—南黄海坳陷区的中部坳陷和南部坳陷均发育在强磁性基底之上,构造变形较弱,海相地层保存完整,埋藏浅,厚度为4~8 km,是南黄海地区具有较大资源潜力的油气勘探区。     

南海中西部地貌单元划分及其特征和成因分析

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