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1.
云南丽江苦橄岩Re-Os同位素地球化学初步研究   总被引:5,自引:0,他引:5  
报导了云南丽江地区大具和仕满剖面12个苦橄岩和6个玄武岩的Re,Os含量和Os同位素组成。苦橄岩和玄武岩具有明显不同的Re-Os体系的特征。苦橄岩具有高的Os元素丰度[(1.5~3)×10-9]和低的Re元素丰度(<0.05×10-9);共生的玄武岩具有低的Os元素丰度(<0.5×10-9)和相对高的Re元素丰度(<0.8×10-9);苦橄岩具有低放射成因的 187Os/188Os 比值(0.123 3~0.126 6),而玄武岩具有高放射成因的187Os/188Os比值(0.133 8~0.157 7)。苦橄岩的Re-Os同位素特征与越南西北部二叠—三叠纪科马提岩具有低放射成因Os同位素特征相似,而玄武岩的Re-Os同位素特征与峨眉山大火成岩省(LIP)其他地区玄武岩的高放射成因的Os同位素特征相似。苦橄岩的Re-Os同位素特征表明,形成峨眉山LIP的地幔柱可能来自对流上地幔而不是深部的核-幔界面。换言之,峨眉山LIP的形成受控于岩石圈地幔过程而不是地幔柱过程。  相似文献   

2.
从浙东、闽东南的早白垩世“双峰式火山岩”和“复合岩体”中选择了有代表性的玄武岩和角闪辉长岩,分离出钛-磁铁矿,进行Re—Os同位素分析。角闪辉长岩的γos(130Ma)为-83.7~ -47.1,其(^187 Os/^188 Os)。过低,为0.0667和0.0205。这低得不合理的(^187 Os/^188 Os)i表明成岩之后Re-Os体系可能受到扰动,某些地质过程导致外加Re的进入,使岩石的^187 Re/^188 Os比值偏高、(^187 Os/^188 Os);及γOs(t)值偏低。玄武岩的γOs(130Ma)=21.4—267.8,其(^187 Os/^188 Os)。为0.1531~0.4639。Re—Os、Sm—Nd同位素及微量元素地球化学研究表明,早白垩世玄武岩浆不是来自富集地幔,而是来自亏损的地幔源区,在其演化过程中经受了地壳岩石和熔体的混染。晚中生代时期,东南沿海“大陆弧”下的地幔可能不是富集的岩石圈地幔,具有亏损特性,因而是软流圈地幔。  相似文献   

3.
本文报道了在青藏高原东南木里地区发现的二叠纪苦橄岩和与其共生玄武岩的主微量元素地球化学特征以及Os-Sr-Nd同位素组成。苦橄岩和与其共生玄武岩受地壳混染作用影响较小。根据苦橄岩的Ti/Y比值和初始的Os同位素组成,将木里苦橄岩分为两类:高Ti/Y型苦橄岩和低Ti/Y型苦橄岩,其中高Ti/Y型苦橄岩具有高的γ_(Os)= 5.3~ 10.7和ε_(Nd)= 5.9~ 6.4,与全球典型洋岛玄武岩的Os和Nd同位素组成接近,代表了地幔柱源区的同位素特征;而低Ti/Y型苦橄岩具有低的γ_(Os)=-4.1~ 1.2和ε_(Nd)= 3.2~ 5.0,可能表明受到了SCLM(大陆岩石圈地幔)源区物质的混染。与其共生的玄武岩具有低的γ_(Os)=-3.5~-1.6和ε_(Nd)=-0.6~ 0.7,表明其来自于不同于低Ti/Y型苦橄岩也有异于高Ti/Y型苦橄岩的地幔源区,但是也可能受到了SCLM物质的混染。基于Nd-Os同位素的地幔柱与SCLM的二端元混合模型显示:低Ti/Y型苦橄岩可能是SCLM物质组分与地幔柱起源的苦橄质原始岩浆混合形成的;与苦橄岩共生的玄武岩可能是由地幔柱来源的玄武质岩浆与SCLM小比例熔融的熔体混合形成的。  相似文献   

4.
苏皖地区发育的新生代玄武岩中富含地幔橄榄岩捕虏体,测定了25个橄榄岩全岩的锇同位素组成。结果表明大部分样品呈亏损特征,187Os/188Os=0.119~0.129.Os同位素比值与主量成分之间有显著的相关性.采用187Os/188Os-Al2O3代用等时线方法,由截距得到初始值(187Os/188Os)0=0.109,在对流地幔的187Os/188Os比值演化线上获得模式年龄t=2.5(±0.1)Ga,为晚太古-早元古代。用样品组中最低的锇同位素组成,即187Os/188Os=0.119,计算Re亏损模式年龄,t=1.2Ga,为中元古代。表明苏皖地区新生代玄武岩中的地幔橄榄岩捕虏体具有古老的形成年龄,它们是经过显生宙减薄作用后的残余地幔的碎片。大陆岩石圈地幔的古老形成年龄与上覆地壳克拉通的古老稳定年龄相耦合。  相似文献   

5.
本文报道了汉诺坝新生代碱性玄武岩中地幔橄榄岩包体的主量、微量元素和Re-Os同位素。14个尖晶石橄榄岩Re、Os含量分别为0.022~0.193ng/g和1.237~4.304ng/g,^187Os/^188Os比值为0.1183~0.1244,与^187Os/^188Os比值相关性不好,但与熔体亏损指标如重稀土元素Yb的含量、全岩Al2O3的百分含量有很好的线性关系,可能反映了地幔熔融后的Re或/和Os的活动。全岩Al2O3、CaO、TiO2含量均与MgO有很好的负相关性,全岩原始地幔标准化REE丰度模式呈现了LREE亏损,表明该区橄榄岩包体是由软流圈地幔经过部分熔融,亏损了玄武质组分后形成的。由Os同位素代理等时线得到该区陆下岩石圈地幔的形成年龄为1.7~2.0Ga,表明尖晶石相橄榄岩所代表的岩石圈地幔是中元古代的陆下岩石圈地幔减薄后的残留体。  相似文献   

6.
峨眉山大火成岩省中高Os苦橄岩的发现及地质意义   总被引:8,自引:1,他引:7  
本文对峨眉山大火成岩省中苦橄岩及其共生的玄武岩进行了铂族元素(PGE)分析,结果表明苦橄岩比玄武岩的PGE含量要高至少一个数量级,并且具有明显高的Os含量,不仅比熔融程度最高的科马提岩要高,而且比原始地幔还要高,另外,还显示出超球粒陨石的Os/Ir比值(2.84~3.88)。其高的Os/Ir比值可能与岩浆上升过程中混入黑色页岩有关。部分熔融计算表明,含有0.01%硫化物的原始地幔 0.5%的外核在7%的熔融程度下,然后又被约10%的黑色页岩混染可以模拟原始岩浆的PGE含量。其Os含量及其他地球化学特征与其同时代的西伯利亚暗色岩系的相似性可能暗示了这两个大火成岩省来自于同一个起源于核-幔边界的超级地幔柱。另外,还根据苦橄岩和玄武岩PGE的含量估算了该地区PGE的成矿潜力。  相似文献   

7.
Re-Os同位素体系在蛇绿岩应用研究中的进展   总被引:2,自引:1,他引:2  
Re-Os不同于由亲石元素构成的同位素体系,在原始上地幔(PUN)部分熔融过程中,母体Re是中等不相容元素,优先进入熔体相,子体Os是强相容元素,富集在残留相中,是研究蛇绿岩的极好示踪剂。在蛇绿岩应用研究中已经取得了4个方面的进展:(1)明确了熔体相的Re/Os和^187Os/^188Os比值高,而残留相的低;(2)铬铁矿中铂族元素矿物(PGM)的Re亏损年龄(TRD)证实了蛇绿岩中复杂的超镁铁岩体是多阶段部分熔融的产物;(3)现代大洋橄榄岩和玄武岩的Re-Os同位素研究表明熔体相和残留相的^187Os/^188Os比值在高于亏损地幔值(DMM)的部分是一致的,而低于DMM的存在不一致性,为研究蛇绿岩中熔体相与残留相是否存在“耦合”关系提供了新的制约因素;(4)揭示了蛇绿岩地幔橄榄岩中含有古大陆岩石圈地幔,这是前所未知的。虽然取得了不少进展,但是由于Re-Os同位素体系用于蛇绿岩研究的时间较短,尚存在一些问题,如显生宙蛇绿岩地幔橄榄岩的定年问题,有待进一步深化研究。  相似文献   

8.
近期对科马提岩以及许多大火成岩省中的苦橄岩进行的水含量分析以及地幔潜能温度的研究表明,无论是太古宙还是显生宙的大火成岩省的形成都和含水的地幔柱有关。晚二叠纪的峨眉山大火成岩省(ELIP)位于扬子克拉通西缘,目前主流观点认为其是由地幔柱形成的。前人根据大量的岩石地球化学工作将ELIP分为西区、中区和东区;证明了位于西区的大理、宾川的苦橄岩和玄武岩地幔源区的水含量高于2500×10-6。然而对于其他区域玄武岩源区的含水性还不清楚。文章以位于中区的二滩剖面底部高钛型玄武岩为研究对象,采用单斜辉石斑晶反演的方法研究恢复了其原始岩浆的水含量。结果表明,单斜辉石斑晶水含量范围为76×10-6 ~424×10-6, 对应的平衡熔体水含量为3.01 wt%。在考虑分离结晶影响后,恢复的原始岩浆水含量达到2.71±0.95 wt%。该水含量略低于大理苦橄岩水含量,与宾川苦橄岩相当。而计算的地幔源区水含量最低估计为1357×10-6,该值低于大理、宾川苦橄岩的源区水含量,但仍显著高于正常洋中脊玄武岩和洋岛玄武岩源区。ELIP中不同区域的苦橄岩和玄武岩都存在高水含量,这表明在ELIP的形成和演化过程中水都扮演了很重要的角色。  相似文献   

9.
江琳  支霞臣 《岩石学报》2010,26(4):1265-1276
本文报道了采自汉诺坝玄武岩区周坝和白龙硐剖面以及白布洛张20井等地29个玄武岩样品的Re、Os含量和~(187)Os/~(188)Os比值。Os含量为11×10~(-12)~314×10~(-12),Re含量为40×10~(-12)~238×10~(-12),Re和Os含量有正相关趋势。碱性玄武岩(AK)的Re、Os含量高于拉斑玄武岩(TH)和过渡玄武岩(TR),玄武岩Os含量变化与分离结晶作用有关,玄武岩的低Re含量与地面喷发的火山岩浆脱气过程中Re的挥发性丢失作用有关。玄武岩的~(187)Os/~(188)Os比值为0.14735~0.61136,AK的~(187)Os/~(188)Os比值比TH和TR低且变化小。玄武岩的~(187)Os/~(188)Os比值与Os含量有负相关性。随着Os含量降低到小于75×10~(-12),~(187)Os/~(188)Os比值迅速升高,反映了地壳混染在TH和TR成因中的贡献。在以往的研究中没有观察到类似的地壳混染作用,说明了Re-Os同位素体系在示踪壳源物质上的优势。一些Os含量较高的TH的~(187)Os/~(188)Os比值表明其地幔源区既非亏损的又非经交代富集的SCLM,可能是混入了地壳俯冲物质的"Marble cake"型地幔。总之,汉诺坝玄武岩的Re-Os同位素地球化学研究支持了以往研究的主要成果,两类玄武岩地球化学差异性和异源成因论;分离结晶和部分熔融过程在玄武岩成因中的重要作用;碱性玄武岩的成因与地幔柱的关系等。同时揭示了一些新的现象:汉诺坝玄武岩形成中存在少量的地壳混染作用;地面喷发的火山熔岩在脱气过程中Re的挥发性丢失;拉斑玄武岩的源区更有可能为"Marble cake"型地幔。  相似文献   

10.
郝艳丽  黄启帅  张晓冉  史仁灯 《岩石学报》2011,27(10):2937-2946
云南大理苦橄岩产出于峨眉山大火成岩省内带,位于峨眉山玄武岩系底部.岩石具斑状结构,斑晶占20%~40%左右,由自形-半自形的橄榄石和单斜辉石组成;基质约占60% ~ 80%,主要由长条状斜长石和颗粒状单斜辉石组成,辉绿结构;含少量尖晶石.绝大部分样品全岩SiO2低于47%,为45.94%~46.37%(1个样品达47.35%),MgO大于18%,介于19.01%~23.77%之间,Na2O+ K2O低于2%,介于1.52%~1.97%之间,具典型苦橄岩的岩相学和岩石化学特征.全岩Re含量变化范围较小,介于0.349×10-9~0.424×10-9之间;Os含量变化范围较大,介于0.889×10-9~4.276×10-9之间;187Re/188Os=0.437±0.012 ~2.708±0.025,187Os/188Os =0.1283±0.0002~0.1354±0.0004;从中分选出的橄榄石的Re、Os含量分别为0.030×10-9~0.049×10-9、0.625×10-9~0.757×10-9,1s7Re/188Os =0.191±0.038 ~0.377±0.062,187Os/188 Os=0.1254±0.0005 ~ 0.1268±0.0005,均低于全岩;尖晶石的Os含量最高,为80.5×10-9,187Os/188 Os最低,为0.1252±0.0003.经质量平衡计算,基质的187Os/188Os比值介于0.1380 ~0.1415之间,与原始上地幔相比,基质的Re-Os同位素组成具有壳层熔岩的特点,而橄榄石和尖晶石具有熔融残留相的特点,基质的γOs大于0,介于+2.0~ +3.28之间,矿物的γOs均小于O,介于-2.01~-2.59之间,显示明显的亏损特征,无核-幔边界源区信息,而全岩的介于-1.11~ -3.24之间,为基质和斑晶及尖晶石的混合结果,推测峨眉山大火成岩省是壳-幔相互作用的产物.  相似文献   

11.
The meta-basic volcanic rocks in the Tengtiaohe Zone yield zircon U–Pb ages of 258.8±2.5 Ma and 259.2±1.8 Ma, respectively which agree with the ages of flood basalts of ELIP and are similar to the basaltic rocks and komatiites from the Song Da Zone in northern Vietnam. The results suggest that the age of meta-basic volcanic rocks is Late Permian, rather than the Early Permian or Early Carboniferous ages as previously inferred. Most meta-basic volcanic rocks are strongly enriched in LREEs relative to HREEs and display trace element patterns similar to the ELIP high-Ti basalts, and are enriched in LILEs with negative Sr anomalies. Their initial ~(87)Sr/~(86) Sr ratios range from 0.705974 to 0.706188 and εNd(t) from-0.82 to-2.11. Their magmas were derived from an enriched and deep mantle source without significant crustal contamination. These meta-basic volcanic rocks formed in ELIP. Therefore, the Tengtiaohe Zone is not an ophiolite zone and can link to the Song Da Zone in northern Vietnam.  相似文献   

12.
以往学术界更多的关注科马提岩和苦橄岩的相似性,忽略其差异。通过全数据模式,采集数据库内全球的太古宙科马提岩、后太古宙低/高钛苦橄岩数据,对比三者之间的差异发现,科马提岩更富MgO、Cr、Ni、Cs、Pb、Co和Zn,其次为低钛苦橄岩(除Co和Zn),其余主量、微量元素的含量由高至低依次为高钛苦橄岩、低钛苦橄岩、科马提岩。依据元素间的差异(如Cr/Ga、MgO/Ga、MnO/Zr、Cr/Zr等),采用密度分布函数(Density Distribution)在Matlab软件中绘制出可有效区分3类岩石的等密度判别图,并用该图对若干晚古生代"科马提岩"的岩性重新厘定。结合岩相学和地球化学特征研究表明,晚古生代"科马提岩"中,印度东部为高钛苦橄岩,越南为化学成分与科马提岩类似的低钛苦橄岩,印度拉达克地区为低钛苦橄岩。  相似文献   

13.
高Ti玄武岩成因是峨眉山大火成岩省(ELIP)研究的热点问题。由于高Ti玄武岩地球化学特征在空间上存在差异,其岩石成因尚未达成共识。本文系统收集了峨眉山大火成岩省中高Ti玄武岩地球化学数据以及锆石ID-TIMS U-Pb测年结果,并进行统一处理分析与模拟。研究结果显示,峨眉山大火成岩省形成于约259~258 Ma,高Ti玄武岩在大火成岩省全区均有出露。自西向东,岩石年龄无明显变化规律,厚度逐渐变薄。高Ti玄武岩起源于具有富集地幔特征的地幔柱源区,几乎没有遭受地壳混染,经历了低程度部分熔融作用并可能混入了少量岩石圈地幔物质,发生了以单斜辉石为主的分离结晶作用。峨眉山大火成岩省深部存在一个非对称式的地幔柱,自西向东,高Ti玄武质岩浆起源深度变浅、温度降低,熔融深度和压力随之降低,熔融程度相对增大。模拟表明,源区石榴石相和尖晶石相的熔融程度分别为0.5%~2%和5%,石榴石相熔融比例自西向东由90%减小至40%,而尖晶石相熔融比例由10%增大至60%。  相似文献   

14.
The Sula Mountains greenstone belt is the largest of the late-Archaean greenstone belts in the West African Craton. It comprises a thick (5 km) lower volcanic formation and a thinner (2 km) upper metasedimentary formation. Komatiites and basalts dominate the volcanic formation and komatiites form almost half of the succession. All the volcanic rocks are metamorphosed to amphibolite grade and have been significantly chemically altered. Two stages of alteration are recognised and are tentatively ascribed to hydrothermal alteration and later regional amphibolite facies metamorphism. Ratios of immobile trace elements and REE patterns preserve, for the most part, original igneous signatures and these are used to identify five magma types. These are: low-Ti komatiites – depleted in light REE; low-Ti komatiites – with flat REE patterns; high-Ti komatiitic basalts – with flat REE; low-Ti basalts – depleted in light REE; high-Ti basalts – with flat REE patterns. Much of the variation between the magma types can be explained in terms of different melt fractions of the mantle source, although there were two separate mantle sources one light REE depleted, the other not. The interleaving of the basalts and komatiites produced by this melting indicates that the two mantle sources were melted simultaneously. The simplest model with which to explain these complex melting processes is during melting within a rising mantle plume in which there were two different mantle compositions. The very high proportion of komatiites in the Sula Mountains relative to other greenstone belts suggests either extensive deep melting and/or the absence of a thick pre-existing crust which would have acted as a “filter” to komatiite eruption. Received: 10 February 1998 / Accepted: 28 July 1998  相似文献   

15.
The evolution of the mantle''s chemical structure   总被引:10,自引:0,他引:10  
I.H. Campbell  R.W. Griffiths 《Lithos》1993,30(3-4):389-399
The geochemistry of flood basalts and their associated picrites, and of komatiites and their associated basalts, combined with a theoretical model for the structure of mantle starting plumes, can be used to decipher key elements of the geochemical structure of the deep mantle and show how it has varied through time. We argue that the thermal boundary layer above the core consisted mainly of depleted mantle similar to the present MORB source during the Archaean and this was largely replaced between 2.7 and 2.0 billion years ago by enriched mantle to form the OIB source. We suggest that this change in the nature of the hotspot source reflects a fundamental change in the dominant component of downward convection: from cold plumes breaking away from beneath a stable lithosphere during the pre-Archaean to subduction of lithosphere in the Archaean and post-Archaean mantles.  相似文献   

16.
Greenstone basalts and komatiites provide a means to track both mantle composition and magma generation temperature with time.Four types of mantle are characterized from incompatible element distributions in basalts and komatiites:depleted,hydrated,enriched and mantle from which komatiites are derived.Our most important observation is the recognition for the first time of what we refer to as a Great Thermal Divergence within the mantle beginning near the end of the Archean,which we ascribe to thermal and convective evolution.Prior to 2.5 Ga,depleted and enriched mantle have indistinguishable thermal histories,whereas at 2.5-2.0 Ga a divergence in mantle magma generation temperature begins between these two types of mantle.Major and incompatible element distributions and calculated magma generation temperatures suggest that Archean enriched mantle did not come from mantle plumes,but was part of an undifferentiated or well-mixed mantle similar in composition to calculated primitive mantle.During this time,however,high-temperature mantle plumes from dominantly depleted sources gave rise to komatiites and associated basalts.Recycling of oceanic crust into the deep mantle after the Archean may have contributed to enrichment of Ti,Al,Ca and Na in basalts derived from enriched mantle sources.After 2.5 Ga,increases in Mg~# in basalts from depleted mantle and decreases in Fe and Mn reflect some combination of growing depletion and cooling of depleted mantle with time.A delay in cooling of depleted mantle until after the Archean probably reflects a combination of greater radiogenic heat sources in the Archean mantle and the propagation of plate tectonics after 3 Ga.  相似文献   

17.
The Xinjie mafic-ultramafic layered intrusion in the Emeishan large igneous province (ELIP) hosts Cu-Ni-platinum group element (PGE) sulfide ore layers within the lower part and Fe-Ti-V oxide-bearing horizons within the middle part. The major magmatic Cu-Ni-PGE sulfide ores and spatially associated cumulate rocks are examined for their PGE contents and Re-Os isotopic systematics. The samples yielded a Re-Os isochron with an age of 262 ± 27 Ma and an initial 187Os/188Os of 0.12460 ± 0.00011 (γOs(t) = −0.5 ± 0.1). The age is in good agreement with the previously reported U-Pb zircon age, indicating that the Re-Os system remained closed for most samples since the intrusion emplacement. They have near-chondritic γOs(t) values ranging from −0.7 to −0.2, similar to those of the Lijiang picrites and Song Da komatiites. Exceptionally, two samples from the roof zone and one from upper sequence exhibit radiogenic γOs(t) values (+0.6 to +8.6), showing minor contamination by the overlying Emeishan basalts.The PGE-rich ores contain relatively high PGE and small amounts of sulfides (generally less than 2%) and the abundance of Cu and PGE correlate well with S, implying that the distribution of these elements is controlled by the segregation and accumulation of a sulfide liquid. Some ore samples are poor in S (mostly <800 ppm), which may due to late-stage S loss caused by the dissolution of FeS from pre-existing sulfides through their interaction with sulfide-unsaturated flowing magma. The combined study shows that the Xinjie intrusion may be derived from ferropicritic magmas. The sharp reversals in Mg#, Cr/FeOT and Cr/TiO2 ratios immediately below Units 2-4, together with high Cu/Zr ratios decreasing from each PGE ore layer within these cyclic units, are consistent with multiple magma replenishment episodes. The sulfides in the cumulate rocks show little evidence of PGE depletion with height and thus appear to have segregated from successive inputs of fertile magma. This suggests that the Xinjie intrusion crystallized from in an open magma system, e.g., a magma conduit. The compositions of the disseminated sulfides in most samples can be modeled by applying an R factor (silicate-sulfide mass ratio) of between 1000 and 8000, indicating the segregation of only small amounts of sulfide liquid in the parental ferropicritic magmas. Thus, continuous mixing between primitive ferropicritic magma and differentiated resident magma could lead to crystallization of chromite, Cr-bearing magnetite and subsequently abundant Fe-Ti oxides, thereby the segregation of PGE-rich Cu-sulfide.When considered in the light of previous studies on plume-derived komatiites and picrites worldwide, the close-to-chondritic Os isotopic composition for most Xinjie samples, Lijiang picrites and Song Da komatiites suggest that the ferropicritic magma in the ELIP were generated from a plume. This comprised recycled Neoproterozic oceanic lithosphere, including depleted peridotite mantle embedded with geochemically enriched domains. The ascending magmas thereafter interacted with minor (possibly <10%) subducted/altered oceanic crust. This comparison suggests that the komatiitic melts in the ELIP originated from a greater-than normal degree of melting of incompatible trace element depleted, refractory mantle components in the plume source.  相似文献   

18.
峨眉山大火成岩省出露有少量酸性火山岩,它们与基性火山岩共生,表现出双峰式的特征,为研究峨眉山地幔柱晚期岩浆活动提供了重要的窗口。本文通过对双峰式火山岩主、微量元素和斑晶电子探针分析研究表明,基性火山岩属于碱性玄武岩,酸性火山岩主要由粗面岩组成;相对玄武岩,粗面岩中MgO、Fe2O3、P2O5、TiO2、CaO含量明显降低;粗面岩与玄武岩具有相互平行的REE配分模式,但粗面岩出现明显的Eu负异常,以及Sr、Ti等元素的强烈亏损;粗面岩与玄武岩具有同源的特征,通过稀土元素模拟计算表明粗面岩可以由玄武质岩浆经过80%分离结晶作用(辉石、斜长石和Fe-Ti氧化物)而形成。在峨眉山大火成岩省晚期出现双峰式火山岩,可能与地幔柱活动晚期岩浆供给少,在地壳岩浆房中停留时间长,岩浆发生强烈分离结晶作用有关。  相似文献   

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