西藏羌塘地区戈木错渐新世钾质火山岩的地球化学特征及其构造意义

羌塘戈木错出露一套30Ma的钾质火山岩,岩石类型包括橄榄碱玄岩、橄榄粗面玄武岩、霓辉粗面岩和舍白榴石响岩.火山岩的SiO2含量变化于46%～60%之间,Al2O3含量在13%～21%之间,Mg#介于0.14和0.63之间,K2O/Na2O＞1.岩石强烈富集轻稀土元素(LREE),亏损相容元素(Cr、Ni)和高场强元素(Nb、Ta、Ti),全岩εHf(t)值变化于-1.28～-6.20之间.研究表明,戈木错火山岩母岩浆起源于软流圈流体交代的古俯冲地幔楔的低程度熔融.同源岩浆经历了AFC作用.戈木错火山岩和区域上的鱼鳞山、火车头山钾质一超钾质火山岩共同组成了羌塘渐新世钾质一超钾质火山岩带.综合南羌塘新生代火山岩岩浆性质的演化,认为岩浆的产生可能与35Ma左右羌塘陆内俯冲板片断离导致的软流圈上涌一岩石圈减薄作用有关.     

西藏羌塘戈木错渐新世钾质火山岩的地球化学特征及其构造意义

羌塘戈木错出露一套30Ma的钾质火山岩,岩石类型包括橄榄碱玄岩、橄榄粗面玄武岩、霓辉粗面岩和含白榴石响岩。火山岩的SiO2含量变化于46%~60%之间,Al2O3含量在13%~21%之间,Mg#介于0.14和0.63之间,K2O/Na2O>1。岩石强烈富集轻稀土元素（LREE）,亏损相容元素（Cr、Ni）和高场强元素（Nb、Ta、Ti）,全岩εHf(t)值变化于-1.28~-6.20之间。研究表明,戈木错火山岩母岩浆起源于软流圈流体交代的古俯冲地幔楔的低程度熔融,同源岩浆经历了AFC作用。戈木错火山岩和区域上的鱼鳞山、火车头山钾质—超钾质火山岩共同组成了羌塘渐新世钾质—超钾质火山岩带。综合南羌塘新生代火山岩岩浆性质的演化,认为岩浆的产生可能与35Ma左右羌塘陆内俯冲板片断离导致的软流圈上涌-岩石圈减薄作用有关。     

西昆仑塔什库尔干苦子干碱性杂岩体的成因及其构造意义

苦子干碱性杂岩体是塔什库尔干新生代碱性岩带的主要组成之一,主要由霓辉正长岩、石英霓辉正长岩和碱性花岗岩组成。霓辉正长岩、石英霓辉正长岩和碱性花岗岩的SiO2含量差别较大,分别为50．26％～54．11％、59．74％～60．43oA、69．59％～72．13％;霓辉正长岩与石英霓辉正长岩的里特曼指数相近,分别为7．83～10．97、8．51～9．05,明显不同于碱性花岗岩（2．49～3．71）。这3种碱性岩石都表现出富集轻稀土,以及K、Rb、Sr、Ba等大离子亲石元素（LILE）,亏损Nb、Ta、Ti等高场强元素（HFSE）的特征。其中异常高的Sr、Ba和∑REE含量暗示可能还有富集地幔物质的加入。利用原位锆石LA—ICP—MS同位素测试方法,获得石英霓辉正长岩和碱性花岗岩的锆石U—Pb年龄分别为10．9±0．1Ma和11．9土0．4Ma,代表了岩石的结晶年龄;石英霓辉正长岩锆石εHf（t）值为-9．78～3．24,碱性花岗岩中锆石εHf（t）值为-13．54～5．78,均显示岩浆源区具有壳幔混合的特点。依据这些资料,并结合区域地质研究的综合分析,笔者初步提出西昆仑塔什库尔干苦子干碱性杂岩体的形成是由于青藏高原在～25Ma期间主体拆沉作用发生后,造成软流圈物质向北逃逸,并受到北面塔里木克拉通岩石圈山根阻挡而上涌,进而发生壳幔混合作用的产物。因此,该杂岩体是青藏高原大规模拆沉后浆活动的远程效应,且标志着研究区在～11Ma期间已处于伸展构造背景。     

东秦岭磨沟碱性岩体年代学、地球化学及岩石成因

河南嵩县磨沟碱性岩体位于华北陆块南缘,其主体岩性为霓辉正长岩,局部出露正长岩和少量似斑状(霓辉)正长岩,发育岩浆暗色包体。LA-ICP-MS锆石U-Pb定年结果显示,霓辉正长岩和正长岩成岩年龄分别为210.4±2.0Ma(MSWD=0.39)和237.6±2.9Ma(MSWD=0.95),结合前人研究成果,认为该岩体是中三叠世和晚三叠世两期岩浆活动的产物。岩石地球化学特征显示,霓辉正长岩的σ值为8.93~11.08,K2O含量为10.70%~13.76%,K2O/Na2O值为3.87~10.35,属于过碱性岩石系列的钾质碱性岩;在微量元素组成上,富集轻稀土和大离子亲石元素,亏损高场强元素,具有弱或不明显的负铕异常。在同位素组成上,霓辉正长岩具有偏高的、变化范围很大的(87Sr/86Sr)i值和显著偏低的εNd(t)值;锆石的εHf(t)值变化于-21.6~-4.5之间,两阶段Hf模式年龄为1 555~2 629 Ma。磨沟岩体是由含金云母的富集地幔部分熔融产生的幔源岩浆与壳源岩浆混合并经一定程度的分异演化形成的,岩石中高含量的K来源于这种含金云母的富集地幔。磨沟岩体早期岩浆活动发生于秦岭造山带主碰撞峰期的局部伸展环境,晚期岩浆活动则发生于后碰撞伸展环境。     

滇西腾冲地区龙川江河谷上新世火山岩SHRIMP锆石U-Pb年龄及其地球化学特征

报道了应用SHRIMP技术测定云南腾冲地区龙川江河谷附近上新世粗面安山岩和粗面岩的年龄结果。该区粗面安山岩与粗面岩的喷发时代接近,形成时代为2.81Ma±0.11Ma,属上新世。该区火山岩具高钾钙碱性的特点,富集大离子亲石元素、稀土元素和高场强元素（如Zr、Th、Hf）的特征明显不同于典型的岛弧钙碱性火山岩,而与遭受地壳混染的软流圈源大陆玄武岩相类似,是在板内拉张环境下地幔岩浆混染了大量下地壳物质的产物。     

中国东部新生代火山作用时代与构造环境变迁

中国东部新生代火山岩K-Ar年龄与岩石化学研究表明,早第三纪(40—55Ma)均为拉斑与钙-碱性岩浆喷发,代表了弧后引张环境。渐新世期间火山作用处于相对平静阶段。中新世以后表现出拉斑与碱性玄武岩的交替喷发,在不同的构造带上表现出19—21Ma、14—15 Ma、5—8Ma与<1Ma期间的强碱性玄武岩喷发,大约7Ma为一周期。这种火山作用的时空与岩性变化特征与全球板块构造环境的重大变迁密切相联。     

山西临县紫金山碱性杂岩内二长岩锆石U-Pb年代学及其意义

山西临县紫金山杂岩主要由深成相岩瘤、浅成相岩墙和岩基、喷出相熔岩和火山角砾岩等岩石单元组成。对该杂岩体内的浅成相次透辉二长岩、霞辉正长岩进行了锆石LA-ICP-MS原位U-Pb同位素测年。结果显示,次透辉二长岩锆石边部U-Pb年龄加权平均值为(136.7±6.5)Ma,Th/U比值0.781～2.559,明显呈三段性,表明岩浆同化混染过程中岩浆成分变化的岩浆混合过程信息;锆石核部U-Pb年龄加权平均值为(1937±37)Ma,Th/U比值为0.339～0.669,显示岩浆成因特征;(霓)霞(次透)辉正长岩的锆石U-Pb加权平均年龄为(137±2.7)Ma,Th/U比值1.484～5.0,反映岩浆富Th且与二长岩互补的特征,揭示出这2期岩浆之间存在有限混合现象。2个样品年龄均显示紫金山碱性杂岩体最早的二长岩与霞辉正长岩浆活动在早白垩世。二长岩的2个孤点年龄(222±4)Ma和(323±3)Ma可能代表了霓霞钛辉岩、正霞正长岩及白霞正长岩包体岩石岩浆底侵的年龄。     

Discovery of the Late Carboniferous alkaline volcanic rocks in the Guyang area,eastern Yinshan Block,and its geological implicationsSCIEI北大核心CSCD

在华北克拉通北缘阴山地块东部固阳地区发现了假白榴石粗面玄武岩和钾质粗面岩两种高钾准铝质碱性火山岩。地质年代学数据显示,假白榴石粗面玄武岩的磷灰石U-Pb年龄为322±14Ma,钾质粗面岩的锆石U-Pb年龄为315.6±7.5Ma,说明其形成时代均为晚石炭世。岩石地球化学特征显示,二者均富Al、Fe,贫Mg;富集大离子亲石元素(如Rb、Ba和K),相对亏损高场强元素(如Ta、Nb和Ti),轻重稀土分异明显,富集轻稀土,相对亏损重稀土,Eu异常不明显;高(87Sr/86Sr)i比值(0.710028~0.714745),低εNd(t)值(-9.0~-17.2),表现出相似的交代岩石圈地幔源区和地壳混染特征。将该碱性火山岩与兴蒙造山带晚石炭世-早二叠世中基性火山岩和阴山地块白垩纪中基性火山岩进行岩石类型对比,发现华北克拉通北缘产出的火山岩多为高钾碱性系列,而兴蒙造山带中产出的火山岩则多为钙碱性系列;与兴蒙造山带晚石炭世-早二叠世中基性火山岩进行岩石成因对比,发现它们的岩浆源区和混染程度并不相同,即固阳地区碱性火山岩为受到早古生代俯冲沉积物交代的岩石圈地幔部分熔融所形成的岩浆在上升过程中混染华北克拉通TTG片麻岩后喷发的产物,而兴蒙造山带中火山岩的产出则多为亏损地幔部分熔融所形成的岩浆在上升过程中轻度混染地壳物质后喷发的结果。在固阳地区发现晚石炭世碱性火山岩,代表着古亚洲洋在该时期的后造山伸展作用范围已延伸至华北克拉通北缘。     

峨眉山大火成岩省晚期酸性火山岩的岩石地球化学特征

峨眉山大火成岩省出露有少量酸性火山岩,它们与基性火山岩共生,表现出双峰式的特征,为研究峨眉山地幔柱晚期岩浆活动提供了重要的窗口。本文通过对双峰式火山岩主、微量元素和斑晶电子探针分析研究表明,基性火山岩属于碱性玄武岩,酸性火山岩主要由粗面岩组成;相对玄武岩,粗面岩中MgO、Fe2O3、P2O5、TiO2、CaO含量明显降低;粗面岩与玄武岩具有相互平行的REE配分模式,但粗面岩出现明显的Eu负异常,以及Sr、Ti等元素的强烈亏损;粗面岩与玄武岩具有同源的特征,通过稀土元素模拟计算表明粗面岩可以由玄武质岩浆经过80%分离结晶作用(辉石、斜长石和Fe-Ti氧化物)而形成。在峨眉山大火成岩省晚期出现双峰式火山岩,可能与地幔柱活动晚期岩浆供给少,在地壳岩浆房中停留时间长,岩浆发生强烈分离结晶作用有关。     

四川攀枝花二叠纪双峰式火山岩地球化学特征及其地质意义

攀枝花二叠纪火山岩发育有玄武岩和粗面岩的基性和碱性两个端元,区域上明显缺失中间过渡类型。玄武岩SiO_2含量处于45.65%~49.32%范围内,粗面岩SiO_2含量介于64.39%~69.17%之间,构成经典的"双峰式"火山岩特征组合。两者均具有富Na、贫K、轻稀土富集、轻重稀土明显分馏的特征。特征微量元素Nb/Ta、Th/Ta、Th/U比值变化相对较小,玄武岩分别为15.16、2.70和4.13,粗面岩分别为15.40、2.55和4.12,显示两者具有相似的地球化学属性。微量元素特征显示,除了Ti和Y等少数高场强元素不协调以外,玄武岩与粗面岩绝大多数微量元素变化规律相似,且Rb、Ce、Y、Nb、Hf、Ta等元素与洋岛玄武岩(OIB)特征一致,说明它们具有地幔柱构造系统下的岩浆属性,岩浆源于石榴石二辉橄榄岩岩石圈地幔的部分熔融。结合前人资料,攀枝花二叠纪双峰式火山岩的厘定,不仅暗示了岩浆形成于拉张的裂谷构造环境,也为西南地区二叠纪峨眉山大火成岩地幔柱成因提供支撑。     

Paleozoic alkaline volcanism: geochemistry and petrogenesis of Um Khors and Um Shaghir trachytes of the central Eastern Desert, Egypt

The Um Khors and Um Shaghir trachyte (UKT and UST) plugs and sheets represent two conspicuous outcrops of Paleozoic alkaline volcanism in the central Eastern Desert of Egypt. The trachyte magmatisms erupted along the Pan-African NW-trending shear zone (302?±?15 and 273?±?15?Ma, respectively) and intruded the Late Proterozoic rocks of the studied area. The trachyte rocks consist mainly of sanidine, anorthoclase, albite, and quartz with a noticeable amount of aegirine?Caugite, aegirine, hedenbergite, and arvedsonite. The studied trachytes are moderately evolved in composition (with 62?C67.5?wt.% SiO₂) and exhibit a limited compositional range in most of the major elements. They are alkaline in nature and considered as silica-oversaturated rocks. The rare earth elements (REE) patterns are somewhat uniform and highly fractionated, being enriched in light REE over heavy REE and show prominent negative Eu anomalies. The UKT and UST are enriched in high field strength elements Nb, Zr, and Y, consistent with typical within-plate alkaline magmatisms of extensional tectonic regimes. They were generated through the fractional crystallization of mantle-derived magmas. Although the UST is younger than the UKT, they show approximately similar chemical compositional ranges of the most major and trace elements, with somewhat higher MgO, Cr, Ni, and Ba contents in the former. This may argue against the evolution of the UST via a continuous fractional crystallization of the residual magmatic melt of the UKT. Thus, the UKT and UST are genetically related but could be emplaced through two various magmatic pulses of the same parent source (i.e., asthenospheric mantle source) at different times. The ascending magmatisms were subjected to variable significant degrees of crustal contamination during their generation.     

U-Pb age of zircon from mantle peridotite nodules in Cenozoic alkali basalts of the Vitim Plateau,Transbaikal region

The U-Pb (SHRIMP-II) age of zircons from garnet-spinel peridotite nodules in Cenozoic alkali basalts of the Vitim Plateau, Transbaikal region were determined. Most of the zircons are euhedral and subhedral prismatic crystals with an elongation of 1.5–2.0. Fragments of crystals and nearly equant crystals with rounded edges are present as well. Rounded or irregular cores are observed in some grains. None of the zircons yielded an age that would correspond to the time of basalt eruption (21–2.35 Ma or younger). The youngest dates range from 135.2 ± 2.7 Ma to 141 ± 3 Ma (Early Cretaceous). Both concordant values and the lower intersection of discordia with concordia (138.8 ± 5.7 Ma) are within this age interval. The upper intersection corresponds to 1891 ± 26 Ma. A considerable part of the concordant values are grouped within the intervals (164.6 ± 1.6)–(183.4 ± 2.0) and (264.0 ± 7.3)–(295.7 ± 0.76) Ma (Early-Middle Jurassic and Early Permian, respectively). The older concordant values fall in the interval 1462 ± 19 to 1506 ± 4 Ma (Mesoproterozoic). Proterozoic age was obtained for cores of composite zircon grains. Zircons pertaining to all age intervals are enriched in REE relative to chondrite (except La). The chondrite-normalized REE patterns are positively sloped with an increase in contents from LREE to HREE. The LREE and HREE contents and the depth of the Eu minimum tend to increase with age. In composite zircons of Proterozoic age, cores are somewhat enriched in REE. It has been suggested that crystallization of zircon as a separate phase in peridotites extremely depleted in Zr was related to a low degree of partial melting. The melt that formed in the intergranular space and that was repeatedly enriched in Zr was not extracted from the solid framework of rock and crystallized in situ under the changed thermodynamic conditions in the upper mantle. The occurrence of zircons of several age intervals in peridotites testifies to the multistage evolution of the upper mantle and recurrent partial melting under various physicochemical conditions.     

Structure,age, and ore potential of the Burpala rare-metal alkaline massif,northern Baikal region

The Burpala alkaline massif is a unique geological object. More than 50 Zr, Nb, Ti, Th, Be, and REE minerals have been identified in rare-metal syenite of this massif. Their contents often reach tens of percent, and concentrations of rare elements in rocks are as high as 3.6% REE, 4% Zr, 0.5% Y, 0.5% Nb, 0.5% Th, and 0.1% U. Geological and geochemical data show that all rocks in the Burpala massif are derivatives of alkaline magma initially enriched in rare elements. These rocks vary in composition from shonkinite, melanocratic syenite, nepheline and alkali syenites to alaskite and alkali granite. The extreme products of magma fractionation are rare-metal pegmatites, apatite-fluorite rocks, and carbonatites. The primary melts were related to the enriched EM-2 mantle source. The U-Pb zircon ages of pulaskite (main intrusive phase) and rare-metal syenite (vein phase) are estimated at 294 ± 1 and 283 ± 8 Ma, respectively. The massif was formed as a result of impact of the mantle plume on the active continental margin of the Siberian paleocontinent.     

班- 怒带东段丁青蛇绿岩中镁铁质岩石年代学及构造背景

丁青蛇绿岩位于班公湖-怒江缝合带东段,分为东、西两个蛇绿岩体,丁青西蛇绿岩体缺乏基性岩年代学研究。对丁青西地质填图显示,蛇绿岩主要由方辉橄榄岩、纯橄榄岩、辉绿岩、玄武岩及辉长岩组成。其中玄武岩、辉长岩及辉绿岩出露在宗白区域,玄武岩和辉绿岩与下侏罗统沉积岩呈构造接触,辉长岩呈岩脉侵入到下侏罗统沉积岩中。岩石地球化学研究表明,玄武岩和辉长岩同属于碱性基性岩石,其中玄武岩具有典型洋岛玄武岩的稀土和微量元素特征,可能形成于与地幔柱有关的洋岛环境。在玄武质凝灰岩中挑选出的锆石测年,获得U-Pb年龄为198.7±3.8Ma,属早侏罗世。辉长岩的稀土和微量元素含量低于典型洋岛玄武岩,但其REE和微量元素具有OIB的特征,与典型OIB相比,辉长岩的HREE发生了一定程度富集。辉长岩锆石的U-Pb年龄为164.3±2.6Ma,认为辉长岩在形成过程中受到了软流圈地幔和岩石圈下部LVZ中富集熔体的共同作用,其形成于大陆边缘裂谷环境;辉绿岩成分属于拉斑系列岩石,其REE和微量元素曲线显示辉绿岩同时具有N-MORB和E-MORB的特征。辉绿岩锆石U-Pb年龄为114.2±1.3Ma,其形成晚于玄武岩。结合区域地质,认为辉绿岩形成于受地幔柱影响的弧后扩张脊环境。本研究提供了丁青西蛇绿岩新的年代学和岩石学证据,为探讨丁青蛇绿岩的形成和演化历史提供了新的证据。     

Mobility of Rare Earth Elements in Basalt‐Derived Laterite at the Bolaven Plateau,Southern Laos

Geochemical and geochronological studies were conducted on basalts and laterites from the Bolaven Plateau in southern Laos in order to evaluate the mobility and mineralization of REE, Y and Sc during laterization. The basalts are classified into three categories: (i) small volumetric alkali basalt (eruption age: 15.7 Ma), large volumetric olivine tholeiite (1.2 Ma) and quartz tholeiite with olivine tholeiite (younger than 0.5 ± 0.2 Ma). Formation of REE minerals during laterization result in mobilization and fractionation of REE and Y in laterite profiles. Occurrence of florencite‐(Ce) in a laterite profile derived from alkali basalt immobilizes REE (particularly LREE) and this leads the laterites to be enriched in LREE relative to the parent basalt. Few positive Ce anomalies in this profile suggest that florencite‐(Ce) [(Ce)Al₃(PO₄)₂(OH)₂] formation was followed by CeO₂ precipitation due to the change of redox condition. In tholeiite‐derived laterite profiles, florencite is not recognized and REE and Y tend to be depleted relative to the parent basalts with positive Ce anomalies. This is interpreted as scavenging REE³⁺ except for Ce⁴⁺ from the laterite profile in oxidizing conditions. Sc behaves similarly to Fe during laterization and it is more abundant in the tholeiitic laterite than that in the alkali basaltic laterite. Results of sequential extraction indicate that REE of the alkali basaltic laterite are contained in residual phase, which is dominantly florencite‐(Ce), but they are rarely present in ion‐adsorption phase. It is concluded that basaltic laterites have a low potential of REE resource in terms of low REE contents and a difficulty in REE extraction.     

Petrography and mineral chemistry of Alkaline-Carbonatite Complex in Singhbhum Crustal Province,Purulia region,Eastern India

The variant rock types of an Alkaline-Carbonatite Complex (ACC) comprising alkali pyroxenite, nepheline syenite, phoscorite, carbonatite, syenitic fenite and glimmerite along with REE and Nb-mineralization are found at different centres along WNW-ESE trending South Purulia Shear Zone (SPSZ) in parts of Singhbhum Crustal Province. The ACC occurs as intrusions within the Mesoproterozoic Singhbhum Group of rocks. Alkali pyroxenite comprises of aegirine augite, magnesiotaramite, magnesiokatophorite as major constituents. Pyrochlore and eucolite are ubiquitous in nepheline syenite. Phoscorite contains fluorapatite, dahllite, collophane, magnetite, hematite, goethite, phlogopite, calcite, sphene, monazite, pyrochlore, chlorite and quartz. Coarse fluorapatite shows overgrowth of secondary apatite (dahllite). Secondary apatite is derived from primary fluorapatite by solution and reprecipitation. The primary fluorapatite released REE to crystallize monazite grains girdling around primary apatite. Carbonatite is composed dominantly of Srcalcite along with dolomite, tetraferriphlogopite, phlogopitic biotite, aegirine augite, richterite, fluorapatite, altered magnetite, sphene and monazite. The minerals comprising of the carbonatite indicate middle stage of carbonatite development. Fenite is mineralogically syenite. Glimmerite contains 50–60% tetraferriphlogopite. An alkali trend in the evolution of amphiboles (magnesiotaramite-magnesiokatophorite-richterite) and chinopyroxenes (aegirine augite, aegirine) during the crystallization of the suite of rocks is noted. Monazite is the source of REE in phoscorite and carbonatite. Fluorapatite has low contents of REE, PbO, ThO₂ and UO₂. Pyrochlore reflects Nb-mineralization in nepheline syenite and it is enriched in Na₂O, CaO, TiO₂, PbO and UO₂. Pyrochlore containing UO₂ (6.605%) and PbO (0.914%) in nepheline syenite has been chemically dated at 948 ± 24 Ma by EPMA.     

西准噶尔达尔布特蛇绿混杂岩中碱性玄武岩的成因:晚泥盆世地幔柱的产物？

西准噶尔是巨型中亚造山带的重要组成部分。该地区分布有多条蛇绿混杂岩带,其中达尔布特蛇绿混杂岩带被认为是西准噶尔规模最大的蛇绿混杂岩带,主要是以方辉橄榄岩为主的超镁铁质岩、镁铁质橄长岩、辉长(绿)岩,枕状熔岩、块状玄武岩及硅质岩。对达尔布特蛇绿混杂岩带中的块状玄武岩进行详细的岩石学、岩相学、同位素年代学及地球化学分析。结果表明,块状玄武岩的LA ICP MS锆石U Pb(加权平均206Pb/238U)年龄为(375±2) Ma,时代属于晚泥盆世。岩石SiO2质量分数为45.24%~49.86%,具有高镁、钛和碱的特征(w(MgO)=2.45%~6.85%,w(TiO2)=1.68%~3.74%,w(Na2O+K2O)=2.37%~5.34%),属于碱性玄武岩系列。碱性玄武岩具有典型洋岛玄武岩的稀土元素和微量元素模式,且相对富集轻稀土元素和大离子亲石元素Rb、Ba、Th等。高场强元素Zr、Hf、Nb、Ta没有明显负异常,显示其来源于富集地幔,主要组成为尖晶石和石榴石二辉橄榄岩,并发生了5%~10%的部分熔融。结合研究区与碱性玄武岩伴生的沉积岩特征、前人资料及对比邻区同期火山岩,可知达尔布特蛇绿混杂岩碱性玄武岩形成于大洋板内与地幔柱有关的洋岛环境,即碱性玄武岩是晚泥盆世地幔柱活动的产物,暗示中亚造山带在晚泥盆世就有地幔柱活动。假若这里提出的晚泥盆世地幔柱模式是正确的,将意味着地幔柱活动在显生宙中亚造山带地壳增生过程中起到重要作用。     

REE mineralogy and geochemistry of the Western Keivy peralkaline granite massif,Kola Peninsula,Russia

The authors have studied the geology, geochemistry, petrology and mineralogy of the rare earth elements (REE) occurring in the Western Keivy peralkaline granite massif (Kola Peninsula, NW Russia) aged 2674 ± 6 Ma. The massif hosts Zr- and REE-rich areas with economic potential (e.g. the Yumperuaiv and Large Pedestal Zr-REE deposits), where 25% of ΣREE are represented by heavy REE (HREE). The main REE minerals are: chevkinite-(Ce), britholite-(Y) and products of their metamict decay, bastnäsite-(Ce), allanite-(Ce), fergusonite-(Y), monazite-(Ce), and others. The areas contain also significant quantities of zircon reaching potentially economic levels. We have discovered that behavior of REE and Zr is controlled by alkalinity of melt/solution, which, in turn, is controlled by crystallization of alkaline pyroxenes (predominantly aegirine) and amphiboles (predominantly arfvedsonite) at a late magmatic stage. Crystallization of mafic minerals leads to a sharp increase of K₂O content and decrease of SiO₂ content that cause a decrease of melt viscosity and REE and Zr solubility in the liquid. Therefore, REE and zirconium immediately precipitate as zircon and REE-minerals. There are numerous pod- and lens-like granitic pegmatites within the massif. Pegmatites in the REE-rich areas are also enriched in REE, but HREE prevails over light REE (LREE), about 88% of REE sum.     

云南会泽地区玄武粗安岩年代学、地球化学及构造演化

滇东北会泽地区发现峨眉山玄武岩中沿NNE向发育的玄武粗安岩,通过详细的野外地质调查、镜下岩相学分析、锆石U-Pb定年以及岩石地球化学测试等方法,研究了该玄武粗安岩形成年龄,地球化学特征及其指示的构造演化过程。LA-ICP-MS锆石U-Pb年代学确定玄武粗安岩形成的加权年龄为(251.6±4.2)Ma(MSWD=0.20),蚀变年龄分别为(143.5±1.9)Ma和(150.5±2.4)Ma。岩石地球化学主量、稀土和微量元素测试表明,玄武粗安岩的SiO_2含量在52.09%～54.10%,属于中基性火山岩;Mg~#介于19.88～40.86,在TAS图解上整体显示为碱性玄武岩粗安岩系列;稀土元素和微量元素特征显示出会泽玄武粗安岩来自交代的富集地幔源区,岩浆演化过程中发生了一定的单斜辉石、斜长石和磁铁矿的分离结晶作用。会泽玄武粗安岩是峨眉山玄武岩的一部分,推断其为峨眉山地幔柱活动消亡期的产物。     

藏北双湖鄂柔地区变质岩和玄武岩的~(40)Ar/~(39)Ar年龄及其意义

在藏北龙木错—双湖缝合带东段双湖鄂柔地区,获得绿泥阳起石片岩中阳起石矿物的40Ar/39Ar坪年龄为(235·9±2·6)Ma和枕状玄武岩中蚀变辉石斑晶的40Ar/39Ar坪年龄为(232·5±2·4)Ma,两个年龄具有极好的一致性,记录了中三叠世晚期—晚三叠世早期沿龙木错—双湖缝合带发生俯冲碰撞作用的构造-热事件。羌塘地区中三叠世晚期—晚三叠世早期的俯冲碰撞造山事件使得龙木错—双湖缝合带及其以北的大部分地区(即北羌塘盆地)转变为前陆盆地,区域上三叠统底部不整合面和底砾岩的发育是碰撞造山作用地质记录的重要标志。绿泥阳起石片岩的原岩主要为富含玄武岩的火山-沉积岩系,绿泥阳起石片岩和蚀变枕状玄武岩具有Ti O2、P2O5、MgO含量较高和LREE富集型、无Eu异常,以及“大隆起”微量元素配分模式和富集Nb、Ta、Ti元素等地球化学特征,显示为较典型的洋岛型碱性玄武岩性质。