地幔交代作用：研究进展、问题及对策

有关地幔交代作用的研究始于７０年代早期。近２０年来研究工作的贡献是使人们对与地幔演化和不均一性有关的地幔交代作用特征和交代作用机制有了更多的了解。地幔交代作用很复杂，它取决于交代作用发生的时间、构造环境、交代介质的种类以及与不同深度地幔内各种地质事件有关的流体的组成。进一步深入开展有关交代作用成因、机制及其与各种地质事件关系的研究，对于深入认识岩石圈地幔的演化和不均一特征具有十分重要的意义。对不同构造环境中的不同包体类型进行深入研究，为地幔交代作用提供广泛约束。将传统的地质学、岩石学的研究与地球化学、地球物理学以及现代测试技术相结合，很可能为解决交代作用成因、机制及交代作用与岩浆作用之间的时间先后问题，交代作用与地质事件的关系问题提供有效的方法和途径。     

地幔交代作用与地幔流体

简要综述了地幔交代作用的特征、研究现状及研究热点，阐明了地幔流体在地幔中的宏观、微观分布及其交代作用机理。地幔交代作用及地幔流体的研究，将促进我们进一步认识岩石圈地幔的演化及不均一特征。     

地幔对流及其对地壳表层拉张盆地的影响

回顾近十年来在地幔对流方面的最新研究进展,阐述了板块俯冲后在地幔中的演化特征,以及地幔上升流即地幔柱的驱动机制和地质效应。特别介绍了地幔柱对地壳表层拉张盆地形成和充填过程的影响。进一步探讨了地幔柱活动在济阳坳陷的地质表现及其引发的火山岩浆活动、碎屑充填特征。认为盆地演化的阶段性间接反映了地幔对流的阶段性。     

地壳深俯冲与富钾火山岩成因

富钾火山岩是一类兼具壳幔双重地球化学特征的特殊岩石组合 ,它们不可能由亏损或原始地幔所派生 ,成岩过程中必须有地壳物质的参与 ,将地壳物质引入富钾火山岩成岩过程的主要动力机制即是深俯冲作用。洋壳和陆壳均可以通过俯冲进入地幔 ,俯冲地壳物质析出流体对地幔岩石的交代作用是导致富钾火山岩具特殊地球化学特征的主要原因。根据对大别—苏鲁造山带南北两侧晚中生代富钾火山岩的实例研究 ,表明该区火山岩的形成均受到了俯冲洋壳析出流体的交代作用 ,但造山带北侧富钾火山岩的形成还叠加了俯冲的扬子陆壳析出流体的交代作用 ,是多次富集事件综合作用的结果。文中还对富钾火山岩成因研究中值得进一步深入探索的问题进行了讨论。     

地幔交代作用研究综述

地幔交代现象广泛发现于各地的碱性玄武岩或金伯利岩中的地幔橄榄岩包体中。地幔交代作用以地幔岩包体中不相容元素的高度富集和（或（出现角闪石、金云母为标志。岩石学、地球化学、同位素资料等显示地幔交代作用与岩板俯冲及部分熔融作用之间存在密切联系，地幔组成、结构、演化与大陆构造演化之间存在紧密的关系。同位素模式年龄暗示地幔交代作用可能是大陆构造活动的深部原因。     

地幔柱理论研究概述

本文介绍了地幔柱理论研究的一系列进展，诸如地幔柱特征，动力学主模式及其一系列地质铲应；阐明了地幔柱构造与板块构造的关系，地幔柱理论涉及的是地幔深部物质垂直运动的机制，其研究对于进一步了解地球深部动力学机制有重大意义。     

地幔柱的识别和演化研究述评

地幔柱的研究已逐渐成为人类认识地球深部动力学机制的重要手段，其诞生-演化与LIPs形成、超大陆裂解以及生物大灭绝事件密切相关。近几十年来，对地幔柱的研究和探索取得了重要进展，尤其是动态地幔柱模式（t ime-dependent）的提出将这一研究热点推向了新的台阶。综合了近些年在地幔柱识别和演化方面的研究资料对前人工作进行总结，归结为以下几个主要方面：地幔柱的时空尺度及其与热点、溢流玄武岩、地壳抬升间的联系；地幔柱的热和物质起源；地幔柱上升和演化的动力学基础。目前仍存在的问题包括：地幔柱是主动还是被动上涌？地幔柱起源于上-下地幔还是核-幔边界？OIB是否代表原始地幔柱的熔融岩浆？无疑这些问题的深入探索将拓宽人类对核幔耦合、地幔对流及浅部物质-能量响应等动力学机制的认识。     

大陆地幔交代作用:地台活化的先驱事件?

地幔交代作用已得到幔源岩石地球化学研究的证实,并已广泛地用于解释上地幔的不均一性、地幔地球化学演化和幔源碱性岩浆的成因问题。本文通过分析国内外某些典型地洼区(中国滇西、华北;西德莱茵地堑;东非裂谷;澳大利亚东部;法国中央地块)幔源岩石的微量元素和Sr、Nd、Pb同位素资料,发现这些地洼区在地台阶段向地洼阶段转化过程中,上地幔化学结构由亏损状态向富集状态转化。上地幔的化学结构的这种转化主要由地幔交代作用所造成。同位素体系计时结果表明地幔交代作用是导致地台活化的先驱事件。地幔交代作用不仅改变了上地幔的化学结构,而且导致交代地幔热流升高、密度减小、体积膨大、固相线下降。所有这些效应加剧了地幔的蠕动和向地壳的热量释放,并产生地台的活化。     

华北克拉通-扬子克拉通与秦岭造山带古地幔组成及状态的对比

经研究，华北克拉通古地幔以含石榴石的二辉橄榄岩、方辉橄榄岩及纯橄榄岩为主．地幔交代作用强烈，岩石富集不相容元素，明显高于南非及西澳克拉通者．扬子克拉通古地幔主元素亏损程度差，交代作用较弱，岩石为石榴石／尖晶石二辉橄榄岩．秦岭造山带壳、幔交界带的岩石类型复杂，包括蛇纹石化尖晶石二辉橄榄岩（蛇纹岩）、石榴石辉石岩、榴闪岩、变辉长岩及变玄武岩等．蛇纹岩遭受强的塑性流变，剪切变形结构发育．与克拉通相比，地幔交代作用很弱．３个地幔域的古地温状态有差异，秦岭造山带最高，扬子克拉通居中，华北克拉通最低．上述结果表明，两克拉通的古地幔特征相差显著，暗示经历了不同的演化过程．交代作用可能发生在１７００Ｍａ以前和１１００～５００Ｍａ，后者强于前者．造山带地幔的剪切变形明显强于克拉通地幔     

地幔地球化学研究综述

系统地介绍了近二十年来地幔地球化学在全球及区域地幔平均化学组成，地幔的化学不均一性及区域太产分布，地幔交代作用，化学地球动力学，地幔物理化学环境等五个方面的研究现状与进展。     

岚皋碱性镁铁-超镁铁质潜火山杂岩中金云角闪辉石岩类地幔捕虏体矿物学特征

金云角闪辉石岩类捕虏体产于扬子板块北缘岚皋县境的早古生代碱性镁铁质-超镁铁质潜火山杂岩中,它们的典型矿物组成为单斜辉石、角闪石、金云母、磷灰石和钛铁矿。捕虏体岩石具粗-细粒等粒结构、板状等粒结构、三联点结构、碎裂结构和肯克带结构,交代结构十分发育。岩石产状、结构和矿物成分特征研究表明,金云角闪辉石岩类捕虏体是地幔交代作用产物,可能代表了该区碱性镁铁质-超镁铁质潜火山杂岩的源区岩石。     

On the iron isotope heterogeneity of lithospheric mantle xenoliths: implications for mantle metasomatism, the origin of basalts and the iron isotope composition of the Earth

With the aim to better understand the cause of the iron isotope heterogeneity of mantle-derived bulk peridotites, we compared the petrological, geochemical and iron isotope composition of four xenolith suites from different geodynamic settings; sub-arc mantle (Patagonia); subcontinental lithospheric mantle (Cameroon), oceanic mantle (Kerguelen) and cratonic mantle (South Africa). Although correlations were not easy to obtain and remain scattered because these rocks record successive geological events, those found between δ⁵⁷Fe, Mg#, some major and trace element contents of rocks and minerals highlight the processes responsible for the Fe isotope heterogeneity. While partial melting processes only account for moderate Fe isotope variations in the mantle (<0.2 ‰, with bulk rock values yielding a range of δ⁵⁷Fe ± 0.1 ‰ relative to IRMM-14), the main cause of Fe isotope heterogeneity is metasomatism (>0.9 ‰). The kinetic nature of rapid metasomatic exchanges between low viscosity melts/fluids and their wall-rocks peridotite in the mantle is the likely explanation for this large range. There are a variety of responses of Fe isotope signatures depending on the nature of the metasomatic processes, allowing for a more detailed study of metasomatism in the mantle with Fe isotopes. The current database on the iron isotope composition of peridotite xenoliths and mafic eruptive rocks highlights that most basalts have their main source deeper than the lithospheric mantle. Finally, it is concluded that due to a complex geological history, Fe isotope compositions of mantle xenoliths are too scattered to define a mean isotopic composition with enough accuracy to assess whether the bulk silicate Earth has a mean δ⁵⁷Fe that is chondritic, or if it is ~0.1 ‰ above chondrites as initially proposed.     

Genesis and evolution of the lithospheric mantle beneath the Buffalo Head Terrane, Alberta (Canada)

Mantle xenoliths and xenocrysts were retrieved from three of the 88–86 Ma Buffalo Hills kimberlites (K6, K11, K14) for a reconnaissance study of the subcontinental lithospheric mantle (SCLM) beneath the Buffalo Head Terrane (Alberta, Canada). The xenoliths include spinel lherzolites, one garnet spinel lherzolite, garnet harzburgites, one sheared garnet lherzolite and pyroxenites. Pyroxenitic and wehrlitic garnet xenocrysts are derived primarily from the shallow mantle and lherzolitic garnet xenocrysts from the deep mantle. Harzburgite with Ca-saturated garnets is concentrated in a layer between 135–165 km depth. Garnet xenocrysts define a model conductive paleogeotherm corresponding to a heat flow of 38–39 mW/m². The sheared garnet lherzolite lies on an inflection of this geotherm and may constrain the depth of the lithosphere–asthenosphere boundary (LAB) beneath this region to ca 180 km depth.

A loss of >20% partial melt is recorded by spinel lherzolites and up to 60% by the garnet harzburgites, which may be related to lithosphere formation. The mantle was subsequently modified during at least two metasomatic events. An older metasomatic event is evident in incompatible-element enrichments in homogeneous equilibrated garnet and clinopyroxene. Silicate melt metasomatism predominated in the deep lithosphere and led to enrichments in the HFSE with minor enrichments in LREE. Metasomatism by small-volume volatile-rich melts, such as carbonatite, appears to have been more important in the shallow lithosphere and led to enrichments in LREE with minor enrichments in HFSE. An intermediate metasomatic style, possibly a signature of volatile-rich silicate melts, is also recognised. These metasomatic styles may be related through modification of a single melt during progressive interaction with the mantle. This metasomatism is suggested to have occurred during Paleoproterozoic rifting of the Buffalo Head Terrane from the neighbouring Rae Province and may be responsible for the evolution of some samples toward unradiogenic Nd and Hf isotopic compositions.

Disturbed Re–Os isotope systematics, evident in implausible model ages, were obtained in situ for sulfides in several spinel lherzolites and suggest that many sulfides are secondary (metasomatic) or mixtures of primary and secondary sulfides. Sulfide in one peridotite has unradiogenic ¹⁸⁷Os/¹⁸⁸Os and gives a model age of 1.89±0.38 Ga. This age coincides with the inferred emplacement of mafic sheets in the crust and suggests that the melts parental to the intrusions interacted with the lithospheric mantle.

A younger metasomatic event is indicated by the occurrence of sulfide-rich melt patches, unequilibrated mineral compositions and overgrowths on spinel that are Ti-, Cr- and Fe-rich but Zn-poor. Subsequent cooling is recorded by fine exsolution lamellae in the pyroxenes and by arrested mineral reactions.

If the lithosphere beneath the Buffalo Head Terrane was formed in the Archaean, any unambiguous signatures of this ancient origin may have been obliterated during these multiple events.     

地幔矿物与水流体之间元素分配系数的研究及意义

流体是地球内部物质和能量迁移最为活跃的介质，它在造成地幔化学的富集和亏损，产生具有不同地球化学特征的幔源岩浆岩石，以及促进壳幔物质的再循环过程等诸多方面都起了重大作用，高温高压下实验模拟流体与地幔岩石和矿物之间痕量元素分配作用是揭示地幔流体的组成与性质，地幔中不同元素类型之间或内部的分异作用，地幔交代介质的类型与特征，岛孤玄武岩高场强元素亏损原因的一个重要的手段，并对近年来有关高温高压下流体与地幔矿物之间痕量元素分配作用的实验模拟研究进行了评述，分析了制约流体与地幔矿物之间痕量元素分配系数的因素，总结了这些研究的应用。     

造山带橄榄岩记录的大陆俯冲带多期壳幔相互作用

俯冲带是地壳与地幔之间物质交换的主要场所.前人对大洋俯冲带壳幔相互作用进行了大量研究,但是对俯冲带壳幔相互作用的物理化学过程和机理仍缺乏明确认识.在大陆俯冲带出露有造山带橄榄岩,它们来自俯冲板片之上的地幔楔,是解决这个问题的理想样品.通过对大别-苏鲁和柴北缘造山带橄榄岩进行系统的岩石学和地球化学研究,发现地幔楔橄榄岩由于俯冲地壳的交代作用而含有新生锆石和残留锆石,它们能为地壳交代作用时间、交代介质来源、性质和组成提供制约.地幔楔橄榄岩在大陆碰撞过程的不同阶段受到了俯冲大陆地壳衍生的多期不同性质流体的交代作用.地幔楔橄榄岩还受到了陆壳俯冲之前古俯冲洋壳衍生流体的交代作用.深俯冲陆壳衍生熔体与橄榄岩反应形成的石榴辉石岩具有高的水含量,能提供高水含量的地幔源区.      

Oxidation of the Kaapvaal lithospheric mantle driven by metasomatism

The oxidation state, reflected in the oxygen fugacity (fO₂), of the subcratonic lithospheric mantle is laterally and vertically heterogeneous. In the garnet stability field, the Kaapvaal lithospheric mantle becomes progressively more reducing with increasing depth from Δlog fO₂ FMQ-2 at 110 km to FMQ-4 at 210 km. Oxidation accompanying metasomatism has obscured this crystal-chemical controlled depth-fO₂ trend in the mantle beneath Kimberley, South Africa. Chondrite normalized REE patterns for garnets, preserve evidence of a range in metasomatic enrichment from mild metasomatism in harzburgites to extensive metasomatism by LREE-enriched fluids and melts with fairly unfractionated LREE/HREE ratios in phlogopite-bearing lherzolites. The metasomatized xenoliths record redox conditions extending up to Δlog fO₂ = FMQ, sufficiently oxidized that magnesite would be the stable host of carbon in the most metasomatized samples. The most oxidized lherzolites, those in or near the carbonate stability field, have the greatest modal abundance of phlogopite and clinopyroxene. Clinopyroxene is modally less abundant or absent in the most reduced peridotite samples. The infiltration of metasomatic fluids/melts into diamondiferous lithospheric mantle beneath the Kaapvaal craton converted reduced, anhydrous harzburgite into variably oxidized phlogopite-bearing lherzolite. Locally, portions of the lithospheric mantle were metasomatized and oxidized to an extent that conversion of diamond into carbonate should have occurred. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

Phlogopite in mantle xenoliths and kimberlite from the Grib pipe,Arkhangelsk province,Russia:Evidence for multi-stage mantle metasomatism and origin of phlogopite in kimberlite

We present petrography and mineral chemistry for both phlogopite,from mantle-derived xenoliths(garnet peridotite,eclogite and clinopyroxene-phlogopite rocks)and for megacryst,macrocryst and groundmass flakes from the Grib kimberlite in the Arkhangelsk diamond province of Russia to provide new insights into multi-stage metasomatism in the subcratonic lithospheric mantle(SCLM)and the origin of phlogopite in kimberlite.Based on the analysed xenoliths,phlogopite is characterized by several generations.The first generation(Phil)occurs as coarse,discrete grains within garnet peridotite and eclogite xenoliths and as a rock-forming mineral within clinopyroxene-phlogopite xenoliths.The second phlogopite generation(Phl2)occurs as rims and outer zones that surround the Phil grains and as fine flakes within kimberlite-related veinlets filled with carbonate,serpentine,chlorite and spinel.In garnet peridotite xenoliths,phlogopite occurs as overgrowths surrounding garnet porphyroblasts,within which phlogopite is associated with Cr-spinel and minor carbonate.In eclogite xenoliths,phlogopite occasionally associates with carbonate bearing veinlet networks.Phlogopite,from the kimberlite,occurs as megacrysts,macrocrysts,microcrysts and fine flakes in the groundmass and matrix of kimberlitic pyroclasts.Most phlogopite grains within the kimberlite are characterised by signs of deformation and form partly fragmented grains,which indicates that they are the disintegrated fragments of previously larger grains.Phil,within the garnet peridotite and clinopyroxene-phlogopite xenoliths,is characterised by low Ti and Cr contents(TiO_21 wt.%,Cr_2 O_31 wt.% and Mg# = 100 × Mg/(Mg+ Fe)92)typical of primary peridotite phlogopite in mantle peridotite xenoliths from global kimberlite occurrences.They formed during SCLM metasomatism that led to a transformation from garnet peridotite to clinopyroxene-phlogopite rocks and the crystallisation of phlogopite and high-Cr clinopyroxene megacrysts before the generation of host-kimberlite magmas.One of the possible processes to generate low-Ti-Cr phlogopite is via the replacement of garnet during its interaction with a metasomatic agent enriched in K and H_2O.Rb-Sr isotopic data indicates that the metasomatic agent had a contribution of more radiogenic source than the host-kimberlite magma.Compared with peridotite xenoliths,eclogite xenoliths feature low-Ti phlogopites that are depleted in Cr_2O_3 despite a wider range of TiO_2 concentrations.The presence of phlogopite in eclogite xenoliths indicates that metasomatic processes affected peridotite as well as eclogite within the SCLM beneath the Grib kimberlite.Phl2 has high Ti and Cr concentrations(TiO_22 wt.%,Cr_2O_31 wt.% and Mg# = 100× Mg/(Mg + Fe)92)and compositionally overlaps with phlogopite from polymict brecc:ia xenoliths that occur in global kimberlite formations.These phlogopites are the product of kimberlitic magma and mantle rock interaction at mantle depths where Phl2 overgrew Phil grains or crystallized directly from stalled batches of kimberlitic magmas.Megacrysts,most macrocrysts and microcrysts are disintegrated phlogopite fragments from metasomatised peridotite and eclogite xenoliths.Fine phlogopite flakes within kimberlite groundmass represent mixing of high-Ti-Cr phlogopite antecrysts and high-Ti and low-Cr kimberlitic phlogopite with high Al and Ba contents that may have formed individual grains or overgrown antecrysts.Based on the results of this study,we propose a schematic model of SCLM metasomatism involving phlogopite crystallization,megacryst formation,and genesis of kimberlite magmas as recorded by the Grib pipe.