富钙长石-橄榄石型包体与典型富Ca,Al包体的矿物岩石学特征对比研究

本文研究了2个富钙长石-橄榄石型包体和2个富黄长石-尖晶石型和富尖晶石-辉石型包体（分别来自宁强和南极格罗夫山碳质球粒陨石）的矿物岩石学特征,并对它们进行了对比。富钙长石-橄榄石型包体的矿物模式组成具有富橄榄石和缺失黄长石的特征,其可能是球粒和典型难熔包体之间的中间产物,是认识它们之间相互关系的钥匙。矿物岩石学特征表明富黄长石-尖晶石型和富尖晶石-辉石型包体可能是星云直接凝聚的产物,而富钙长石-橄榄石型包体经历过熔融结晶过程。富钙长石-橄榄石型包体的初始物质可能是富Al的球粒或含难熔组分的蠕虫状橄榄石集合体。矿物化学组成对比研究发现,GRV 022459-RI6中的尖晶石具有最富FeO的特征,表明包体的蚀变可能发生在高氧逸度的星云环境。     

富橄榄石的富Ca,Al组分集合体的矿物岩石学特征及对比研究

富Ca,Al包体、球粒和蠕虫状橄榄石集合体都是早期星云事件的产物。本文探讨了4个富橄榄石的富Ca,Al组分集合体的矿物岩石学特征,并对它们进行了对比。矿物岩石学特征表明含橄榄石边的富尖晶石-辉石型包体和富Ca,Al组分蠕虫状橄榄石集合体都属于星云直接凝聚的产物,而富钙长石-橄榄石型包体(POI)和富Ca,Al组分球粒经历过熔融结晶过程。矿物模式组成表明POI包体和富Ca,Al组分球粒可能是认识典型富Ca,Al包体与球粒之间相互关系的钥匙。蠕虫状橄榄石集合体GRV022459-2C1中尖晶石普遍具有高的FeO含量,表明其蚀变发生于高氧逸度的星云环境。球粒与粗粒富Ca,Al包体可能属于同一热事件的产物,粗粒富Ca,Al包体形成于富Ca,Al矿物富集的区域,Mg,Fe质硅酸盐球粒形成于富Ca,Al矿物缺失的区域,POI包体和富Ca,Al组分球粒可能形成于上述两个区域之间的过渡区域。     

肇东和亳县陨石中的黑包体及其成因意义

肇东、毫县陨石中的黑包体在总体成分、形状、大小上与陨石球粒相似,但两者的内部结构以及矿物组合不同。黑包体中矿物呈密堆状,主要由细粒橄榄石以及其它硅酸盐微晶组成,不含火成玻璃等特点表明黑包体未经历过熔融,它们可能是形成球粒的毛坯。因此认为球粒的形成有三个阶段:星云凝聚形成尘粒—尘粒吸积形成黑包体—黑包体熔融形成球粒。     

吉林陨石中橄榄石和辉石的化学成份特征兼谈平衡球粒陨石中的不平衡性

吉林陨石中的球粒分为正常快速冷却和过冷冷却球粒两种。前一类球粒中的橄榄石和辉石的化学成份相对稳定,代表了平衡球粒陨石的特征。后一类球粒中的橄榄石和辉石不仅在总的化学成份上有别于前者,而且矿物本身成份不稳定,反映了平衡球粒陨石中存在着不平衡性。     

石陨石中橄榄石和辉石的微量化学分析

在一般石陨石中，球粒陨石硅酸盐相约占其化学组成的三分之二，而橄榄石(Mg、Fe)，SiO4和斜方辉石(Mg、Fe)SiO3又是组成硅酸盐相的主要矿物。较详细地研究橄榄石和辉石的化学组成对石陨石各化学群的划分及球粒陨石岩石类型的划分都是十分重要的。     

山东省鄄城陨石中的金属矿物及组构特征

1997年降落在山东省鄄城县的陨石雨,是橄榄石-古铜辉石球粒陨石。该陨石中的金属矿物主要为铁纹石和陨硫铁,其次为镍纹石,金属矿物呈填隙状分布于以橄榄石和古铜辉石为主的硅酸盐矿物粒间及球粒周围。陨石中可见由铁纹石和镍纹石组成的显微蠕虫状连晶,是陨石中金属矿物在降温冷却过程中发生固溶体分离作用而成。陨石中金属矿物的分布特征表明,金属Fe-Ni和硫化物（FeS）应该是星云凝聚不同阶段的产物。陨石中金属矿物的成分和组构特征及陨石中出现的球粒结构、橄榄石的炉条结构等特征表明,该球粒陨石是星云物质快速冷却的产物。     

林东陨石的分类与成因探讨

林东陨石发现于我国内蒙古地区,被划分为LL5-6型普通球粒陨石角砾岩。本项工作对林东陨石开展了深入的岩石矿物学分析,提出将其重新划分为表土角砾岩的新观点。林东陨石主要由大至厘米级的角砾、以及微米大小的细粒基质两部分构成。不同角砾之间,表现出明显差异的岩石结构,反映了不同程度的热变质,岩石类型变化范围为4～6型。角砾以岩屑为主,还含有残余球粒和粗粒的矿物碎屑。不同岩石类型角砾的橄榄石Fa值（29.7 mol%～30.5 mol%）、低钙辉石Fs值（24.9 mol%～26.1 mol%）、以及铁纹石的Co含量（2.38%～2.51%）等,表明这些角砾均为低铁低金属的LL化学群,判断其来自同一小行星母体。林东陨石的细粒基质主要由微米大小的矿物碎屑固结而成,颗粒之间有较多的孔隙,整体较为松散。细粒基质的化学组成与岩石角砾中的矿物颗粒相同,应当是后者的机械粉碎产物。据此推测林东陨石的母体是一颗LL群小行星,表面经历了长期的小天体碰撞,形成各种岩屑和微细矿物晶屑,然后固结成林东陨石表土角砾岩。林东陨石的发现为研究小行星表面的演化历史,以及太阳风辐射等太空风化提供了珍贵样品,并为我国小行星探测提供可供对照的对象。     

对南极类C1陨石成因和星云水化作用范围的几点看法

南极陨石的研究发现，有几个碳质球粒陨石富含与ＣＩ陨石类似的含水层状硅酸盐集合体及其角砾，其氧同位素比值也与ＣＩ接近，因而称之为类Ｃ１陨石。类Ｃ１陨石与Ｃ１陨石的区别是：类Ｃ１陨石中的含水层状硅酸盐既以基质的形式产出，也出现在球粒中；类Ｃ１陨石中含有球粒及有关组分，如球粒碎块、矿物集合体等。每个陨石中所含这些组分的数量不同，其矿物的成分也差别很大，从而说明它们形成的星云环境不同。因此笔者认为类Ｃ１陨     

南极三块（L3）陨石球粒结构类型及其矿物学物征

我国第16次南极考察队回收到6块稀少种类陨石-L3型,GRV99001,GRV99019,GRV99020,GRV99021, GRV99022,GRV99026。本文对其中3块陨石进行研究,研究它们的球粒结构和矿物化学成分．它们虽然都属于非平衡普通球粒陨石(L3),但它们的亚类不同,GRV 99001为L3．4,GRV99026为L3．5,GRV99019为L3．6．它们的球粒结构和球粒内的矿物晶体完整性和矿物组合变化比较大,橄榄石和辉石以高镁为特征．这三块陨石的球粒结构种类比较多,有班状的、炉条状的、扇形的和隐晶质的等．在GRV99001陨石中班状结构的球粒内能见到一个或两个以上完整的单晶橄榄石构成的球粒,也能见到多个细小的或是破碎橄榄石,被包裹在辉石晶体内．而在GRV99019和GRV99026陨石中只能见到多个细小单晶体或是破碎的橄榄石晶体．GRV99001陨石的炉条状结构,好象是由一条带状长石矿物,穿插在单个橄榄石晶体中构成．扇形和伞形结构的球粒,以一个点为中心,向外放射呈扇形．如GRV99019陨石中扇形结构球粒,它们是以辉石为主,陨硫铁充填在低钙辉石缝隙中,形成扇形．另一种是以多个点为中心,如GRV99001陨石,它们是由橄榄石、低钙辉石和长石质的玻璃,构成多个小伞形,形状类似三维立体的球,裂缝中也充填有金属矿物．隐晶质的球粒在GRV99026陨石中有两种,一种是在一厘米等于 100un时呈现隐晶质矿物,而放大到一厘米等于5un时,就可以清楚看到两种低钙辉石矿物,在低钙辉石中还有金属矿物．另一种隐晶质结构球粒由极细小破碎的橄榄石和辉石矿物构成．这三块陨石中的橄榄石和辉石都以高镁为特征．班状结构球粒,在GRV99001陨石中橄榄石的MgO-33．37-51．21,辉石为35．9-36．61;GRV99019陨石中橄榄石23．33-56．58,辉石 21．38-33．07;GRV99026陨石中橄榄石45．91-52．63,辉石34．48-37．35．扇形结构球粒,在GRV99001陨石中橄榄石29．94 -46．22,辉石28．17-30．36;GRV99019陨石中橄榄石29．17-34．38,辉石23．11-27．79．炉条状结构的球粒,在GRV99001 陨石中橄榄石51．84-56．03．隐晶质结构球粒,在GRV99026陨石中辉石20．17-21．54,橄榄石30．84-32．66．由此看出矿物晶体完整性越好镁的含量越高．     

山东省鄄城县董口乡损石雨的初步研究

１９９７年２月１５日２３时，一场损石雨降落在中国山东省鄄城县董口乡。陨石的主要组成矿物的橄榄石、古铜辉石和金属矿物。金属矿物为损硫铁和铁纹石。副矿物有磷灰石和铬铁矿。球粒结构，定名为橄榄石－古铜辉石球粒损石。     

Petrology, Mineralogy and Geochemisty of Antarctic Mesosiderite GRV 020175: Implications for Its Complex Formation History

<正>GRV 020175 is an Antarctic mesosiderite,containing about 43 vol%silicates and 57 vol% metal.Metal occurs in a variety of textures from irregular large masses,to veins penetrating silicates, and to matrix fine grains.The metallic portion contains kamacite,troilite and minor taenite.Terrestrial weathering is evident as partial replacement of the metal and troilite veins by Fe oxides.Silicate phases exhibit a porphyritic texture with pyroxene,plagioclase,minor silica and rare olivine phenocrysts embedded in a fine-grained groundmass.The matrix is ophitic and consists mainly of pyroxene and plagioclase grains.Some orthopyroxene phenocrysts occur as euhedral crystals with chemical zoning from a magnesian core to a ferroan overgrowth;others are characterized by many fine inclusions of plagioclase composition.Pigeonite has almost inverted to its orthopyroxene host with augite lamellae, enclosed by more magnesian rims.Olivine occurs as subhedral crystals,surrounded by a necklace of tiny chromite grains(about 2-3μm).Plagioclase has a heterogeneous composition without zoning. Pyroxene geothermometry of GRV 020175 gives a peak metamorphic temperature(～1000℃) and a closure temperature(～875℃).Molar Fe/Mn ratios(19-32) of pyroxenes are consistent with mesosiderite pyroxenes(16-35) and most plagioclase compositions(An_(87.5_96.6)) are within the range of mesosiderite plagioclase grains(An_(88-95)).Olivine composition(Fo_(53.8)) is only slightly lower than the range of olivine compositions in mesosiderites(Fo_(55-90)).All petrographic characteristics and chemical compositions of GRV 020175 are consistent with those of mesosiderite and based on its matrix texture and relatively abundant plagioclase,it can be further classified as a type 3A mesosiderite.Mineralogical, penological,and geochemical studies of GRV 020175 imply a complex formation history starting as rapid crystallization from a magma in a lava flow on the surface or as a shallow intrusion.Following primary igneous crystallization,the silicate underwent varying degrees of reheating.It was reheated to 1000℃,followed by rapid cooling to 875℃.Subsequently,metal mixed with silicate,during or after which,reduction of silicates occurred;the reducing agent is likely to have been sulfur.After redox reaction,the sample underwent thermal metamorphism,which produced the corona on the olivine, rims on the inverted pigeonite phenocrysts and overgrowths on the orthopyroxene phenocrysts,and homogenized matrix pyroxenes.Nevertheless,metamorphism was not extensive enough to completely reequilibrate the GRV 020175 materials.     

苏鲁-大别山超高压变质带迟家店和碧溪岭石榴二辉橄榄岩橄榄石组构

大别山碧溪岭和山东荣成分别发育壳源和幔源的石榴二辉橄榄岩。它们在扬子板块向华北板块的俯冲过程中与俯冲板片一起经历了超高压变质作用。这两种原岩来源不同的石榴橄榄岩中的橄榄石具有相似的结晶学优选方位(LPO):[100]轴主板密垂直于面理面,[010]轴主极密平行于线理,这种橄榄石结晶学优选方位明显不同于高温地幔橄榄岩包体中的橄榄石组构,也不同于最近在超高压变质地体中发现的水导致的橄榄石组构。我们认为碧溪岭和荣成石榴二辉橄榄岩中的这种橄榄石组构可能是在相对较干的超高压变质条件下形成的。本研究为大陆深俯冲超高压变质石榴橄榄岩橄榄石组构特征提供了第一手资料。     

Deformation microstructures of olivine and pyroxene in mantle xenoliths in Shanwang,eastern China,near the convergent plate margin,and implications for seismic anisotropy

Deformation microstructures, including lattice-preferred orientations (LPOs) of olivine, enstatite, and diopside, in mantle xenoliths at Shanwang, eastern China, were studied to understand the deformation mechanism and seismic anisotropy of the upper mantle. The Shanwang is located across the Tan-Lu fault zone, which was formed due to the collision between the Sino-Korean and South China cratons. All samples are spinel lherzolites and wehrlites, and LPOs of minerals were determined using scanning electron microscope/electron backscattered diffraction. We found two types of olivine LPO: type-B in spinel lherzolites and type-E in wehrlites. Enstatite showed two types of LPO (types BC and AC), and diopside showed four different types of LPO. Observations of strong LPOs and numerous dislocations in olivine suggest that samples showing both type-B and -E LPOs were deformed in dislocation creep. The seismic anisotropy of the P-wave was in the range of 2.2–11.6% for olivine, 1.2–2.3% for enstatite, and 2.1–6.4% for diopside. The maximum seismic anisotropy of the shear wave was in the range 1.93–7.53% for olivine, 1.53–2.46% for enstatite, and 1.81–6.57% for diopside. Furthermore, the thickness of the anisotropic layer was calculated for four geodynamic models to understand the origin of seismic anisotropy under the study area by using delay time from shear wave splitting, and S-wave velocity and anisotropy from mineral LPOs. We suggest that the seismic anisotropy under the study area can be most likely explained by two deformation modes that might have occurred at different times: one of deformed lherzolites with a type-B olivine LPO by lateral shear during/after the period of the Mesozoic continental collision between the Sino-Korean and South China cratons; and the other deformed the wehrlites with a type-E olivine LPO by horizontal extension during the period of change in absolute plate motion in relation to the westward-subducting Pacific plate.     

Deformation microstructures of olivine in peridotite from Spitsbergen, Svalbard and implications for seismic anisotropy

To understand the deformation mechanism and seismic anisotropy in the uppermost mantle beneath Spitsbergen, Svalbard, in the Arctic, the deformation microstructures of olivine in the peridotite of Spitsbergen were studied. Seismic anisotropy in the upper mantle can be explained mainly by the lattice-preferred orientation (LPO) of olivine. The LPOs of the olivine in the peridotites were determined using electron backscattered diffraction patterns. Eight specimens out of 10 showed that the [100] axis of the olivine was aligned subparallel to the lineation and that the (010) plane was subparallel to the foliation, showing a type A LPO. In the other two specimens the [100] axis of olivine was aligned subparallel to the lineation and both the [010] and [001] axes were distributed in a girdle nearly perpendicular to the lineation, showing a type D LPO. The dislocation density of the olivine in the samples showing a type D LPO was higher than that in the samples showing a type A LPO. The result of an Fourier transformation infrared study showed that both the types A and D samples were dry. These observations were in good agreement with a previous experimental study ( Tectonophysics , 421 , 2006, 1 ): samples showing a type D LPO for olivine were observed at a high stress condition and samples showing both types A and D LPO were deformed under dry condition. Observations of both strong LPOs and dislocations of olivine indicate that the peridotites studied were deformed by dislocation creep. The seismic anisotropy calculated from the LPOs of the olivine could be used to explain the seismic anisotropy of P - and S -waves in the lithospheric mantle beneath Spitsbergen, Svalbard.     

辽南斑状金伯利岩岩相学特征及其成因研究

辽南金伯利岩岩区是我国最大的原生金刚石矿产区，该区金刚石主要寄主岩石类型为斑状金伯利岩。橄榄石是金伯利岩中最重要的造岩矿物，根据其结构特征可以分为橄榄石粗晶、橄榄石斑晶以及基质中微细粒三个世代。本文将岩相学特征和前人研究成果相结合，构建辽南斑状金伯利岩岩浆起源、上升、喷发和成岩模型，探讨各世代矿物的形成过程。具体包括：深部交代地幔部分熔融，形成初始碳酸盐岩浆；初始岩浆上升过程中捕获的岩石圈地幔橄榄岩不断溶解(形成橄榄石粗晶)，岩浆成分发生改变，成为金伯利岩岩浆；金伯利岩岩浆迅速上升侵位，至地表处爆破喷发，最后冷却固结形成包含粗晶及其他两个世代橄榄石的斑状金伯利岩。     

新疆坡北镁铁-超镁铁杂岩体中橄榄石成分特征及其成因意义

橄榄石的矿物化学成分可以很好的反映母岩浆成分、岩浆分异结晶及硫化物熔离作用等信息.坡北镁铁-超镁铁杂岩体中橄榄石电子探针成分分析表明:橄榄石均为贵橄榄石,其化学成分与寄主岩石类型密切相关,其中橄榄辉长岩中橄榄石的Fo值在74～81之间,橄长岩或橄榄单斜辉石岩中橄榄石Fo=75～82.7,异剥橄榄岩或橄榄岩中橄榄石Fo值为83.6～86.3,暗示橄榄岩结晶早于橄榄辉长岩.橄榄石Ni含量变化范围为(174～2281)×10-6.利用最高Fo含量的橄榄石成分计算得到坡北岩体母岩浆MgO=14.38％,为高镁玄武岩浆.橄榄石分离结晶和硫化物熔离模拟显示:坡北岩体主要发生了～25％的橄榄石分离结晶,在橄榄石结晶程度为2％～4％的过程中,发生过硫化物熔离作用,但熔离程度较低(～0.2％).总体来看,该区成矿远景不佳.     

山东金伯利岩中榄橄石的研究

本文百次研究了山东金伯利岩中橄榄石的产状、含量、大小、世代、形态、颜色、环带、矿物包体、折光率、2V、化学成分、端员组分特征及红外光谱和穆斯堡尔谱特征,并分析研究了橄榄石的成因。指出了无色—浅绿色的、含MgO、Cr2O3、NiO高的橄榄石是找金刚石矿的指示性矿物。     

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报道了浙江衢县、福建明溪等地新生代玄武岩中尖晶石(石榴石)二辉馓榄岩包体和捕虏晶中发现的橄榄石成分分带现象。给出了电子探针分析结果,总结并讨论了这种分带的特点、成因以及不同地区之间的差别。     

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含镁硅酸盐矿物是重要自然资源,国内外大都采用传统的化学方法进行开发利用,而微生物法释放含镁硅酸盐矿物中镁和硅的研究还未见报道.试验采用摇瓶培养与对照结合的方法研究烟曲霉(Aspergillusfumigatus)对含镁硅酸盐矿物——蛇纹石和橄榄石的风化作用.试验采用ICP-OES测定第5、10、20、30 d培养液滤液...     

Mapping Lunar Olivine Using Clementine Spectral Indices and Chemical Composition Parameters

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