西藏普兰地区拉昂错蛇绿岩中辉绿岩的锆石SHRIMP U—Pb年龄及其地质意义

蛇绿岩中的辉绿岩岩墙是洋脊扩张的产物．其形成年龄代表了扩张事件的时间,也代表了蛇绿岩的形成时代？对雅鲁藏布江缝合带西段拉昂错蛇绿岩中的辉绿岩岩墙进行锆石SHRIMPU—Pb定年,得出加权平均年龄为120．2Ma±2．3Ma,代表辉绿岩的结晶年龄。结合已有的关于雅鲁藏布江蛇绿岩的形成年龄（西段休古嘎布122．3Ma±2．4Ma,中段大竹卡126．0Ma±1．5Ma、吉定123．0Ma＋_1．8Ma,东段罗布莎162．9Ma±2．8Ma）的报道,表明拉昂错地区特提斯洋海底扩张的时代与体古嘎布地区一致．雅鲁藏布江西段与中段地区洋盆的形成时代一致,但晚于东段的发育时代。这意味着整个东提斯洋盆的发育时代存在东早西晚的特点。     

西藏桑桑蛇绿岩辉绿岩SHRIMP锆石U-Pb年龄：对特提斯洋盆发育的年代学制约

蛇绿岩中的辉绿岩岩墙是洋脊扩张的产物,其形成年龄代表了扩张事件的时间,也代表了蛇绿岩的形成时代.对雅鲁藏布江缝合带中段桑桑蛇绿岩中的辉绿岩岩墙进行了SHRIMP锆石U-Pb定年,得出加权平均年龄为(125.2±3.4)Ma(2σ,MSWD=1.15),即辉绿岩结晶年龄.结合已有的关于雅鲁藏布江蛇绿岩形成年龄(中段大竹卡(126.0±1.5)Ma,吉定(123.0±1.8)Ma;西段休古嘎布(122.3±2.4)Ma和东段罗布莎(162.9±2.8)Ma)的报道,该结果表明桑桑地区特提斯洋海底扩张的时代,与中段大竹卡、吉定地区以及西段休古嘎布地区洋盆形成时代一致,但晚于东段发育时代,表明雅鲁藏布江缝合带中段地区洋盆时代相当,而整个东特提斯洋盆发育时代存在东早西晚的特点.     

西藏休古嘎布蛇绿岩中辉绿岩锆石SHRIMP定年及其地质意义

应用SHRIMPⅡ锆石U-Pb法,对西藏休古嘎布蛇绿岩中的辉绿岩墙进行了测年,获得辉绿岩形成年龄为122.3±2.4Ma。该年龄代表了休古嘎布-达巴特提斯洋盆的形成时代,与雅鲁藏布江缝合带中段洋盆形成时代(126±1.5Ma)相当,此结果对于确定研究区特提斯洋盆的古构造格局及其发育演化过程等提供了重要的年代学制约。     

西藏群让蛇绿岩辉长岩SHRIMP锆石U-Pb年龄及地质意义

对雅鲁藏布江缝合带中段群让蛇绿岩中的辉长岩进行SHRIMP锆石U-Pb定年,得出加权平均年龄为125.6±0.88Ma(2σ,MSWD=1.9),即辉长岩结晶年龄。结合已有的关于雅鲁藏布江蛇绿岩形成年龄的报道,该结果表明群让地区特提斯洋海底扩张的时代与中段大竹卡、吉定地区一致;雅鲁藏布江西段与中段地区洋盆形成时代一致,但晚于东段发育时代;整个东特提斯洋盆发育时代存在东早西晚的特点。     

西藏班公湖-怒江缝合带中段江错蛇绿岩岩石学、地球化学、年代学及地质意义

江错蛇绿岩位于班公湖-怒江缝合带中段, 位于切里湖蛇绿岩亚带的最东端, 南邻蓬湖西蛇绿岩.江错蛇绿岩岩石组合相对较全, 主要由变质橄榄岩、辉长岩和辉绿岩等组成.江错蛇绿岩辉长岩-辉绿岩与N-MORB相比具有较高的Mg#、低Ti、K、Na和P的特征, 富集大离子亲石元素Sr、Rb、Ba和亏损高场强元素Th、Hf、Ta、Nb, REE配分图总体显示为平坦型分布模式.通过地球化学元素分析认为江错蛇绿岩是形成于SSZ之上的弧后盆地扩张脊环境.对其进行辉长岩锆石SHRIMP U-Pb定年, 得出加权平均年龄为189.8±3.3 Ma(MSWD=0.97), 该结果代表了班公湖怒江缝合带中段江错地区特提斯洋的扩张时代, 与中段东巧地区蛇绿岩年龄一致, 但晚于东段洋盆发育时代且早于西段洋盆发育时代, 表明整个班公湖-怒江洋盆发育时代存在东早西晚的特点.      

西藏西南部休古嘎布蛇绿岩的Sm-Nd年龄及Nd-Sr-Pb同位素特征

休古嘎布蛇绿岩位于雅鲁藏布江蛇绿岩带西段,属于SSZ型蛇绿岩。用Sm-Nd法测定了该蛇绿岩中辉长辉绿岩的结晶年龄,辉石、斜长石和两个全岩样品的等时线年龄为(126.2±9.1)Ma,代表新特提斯洋在该区俯冲消减的时限。同时,对辉长辉绿岩的Nd-Sr-Pb同位素的测定结果表明,辉长辉绿岩的初始εNd(t)值高(6.7～9.1),反映原始岩浆起源于强烈亏损的地幔源区,未受大陆地壳物质的混染;初始206Pb/204Pb比值较低(17.412～17.523),但初始208Pb/204Pb比值较高(37.352～37.706),并具有较高的ISr值(0.70278～0.70383),指示休古嘎布蛇绿岩源于印度洋MORB型地幔域。     

西藏西南部达巴—休古嘎布绿岩带铬铁矿的找矿前景

雅鲁藏布江蛇绿岩带长1500km以上,分为东段(曲水—墨脱)、中段(昂仁—仁布)和西段(萨嘎以西至中印边境)3部分。西段又进一步分为北亚带(达机翁—萨嘎蛇绿岩带)和南亚带(达巴—休古嘎布蛇绿岩带),以往的研究程度很低。达巴—休古嘎布蛇绿岩带的蛇绿岩体(块)由地幔橄榄岩组成,主要岩石类型是方辉橄榄岩和纯橄榄岩,极少量二辉橄榄岩,缺少典型蛇绿岩剖面中的洋壳单元。带内岩体规模大,岩相分带明显,出现较大面积的纯橄榄岩相。拉昂错、东坡、当穷岩体和休古嘎布岩体群发现有较多的铬铁矿化点,矿体呈透镜状(豆荚状)、短脉状、不规则状,矿石以致密块状为主,少部分为浸染状,Cr2O3含量一般达40%以上。矿化类型属于豆荚状铬铁矿。对比研究显示,该岩带的岩体在构造环境,蛇绿岩的类型,岩体规模,岩石组成,保存部位,部分熔融程度,岩石、矿物地球化学特征,铬铁矿化特征等许多方面与国内外大型豆荚状铬铁矿床的含矿岩体相似,成矿条件好,找矿前景较大。提出区内找矿前景最好的地段是拉昂错岩体西北部的纯橄榄岩相,其次是东坡岩体的纯橄榄岩相、纯橄榄岩-方辉橄榄岩相,以及当穷岩体的方辉橄榄岩-纯橄榄岩相。     

西藏泽当蛇绿岩玄武岩SHRIMP锆石U-Pb年龄 及其地质意义

雅鲁藏布江缝合带中各蛇绿岩体的准确定年对待提斯洋演化和青藏高原隆升的研究具有重要意义.泽当蛇绿岩是雅鲁藏布江缝合带东段最大的蛇绿岩块体,关于其形成年龄目前仍存在不同的认识.通过SHRIMP锆石U-Pb测年得到蛇绿岩中玄武岩的形成年龄为154.9Ma±2.0Ma(95％置信度,MSWD=0.98).蛇绿岩中的玄武岩是洋脊扩张的产物,其形成年龄代表了扩张事件的时间,也代表了蛇绿岩的形成时代.结合已有的雅鲁藏布江缝合带蛇绿岩的形成年龄,该年龄进一步反映出雅鲁藏布江缝合带蛇绿岩形成时间具有东早西晚的特点.泽当蛇绿岩与含有埃达克质英云闪长岩的泽当岛弧火成岩基本为同期形成的.地球化学特征显示定年的玄武岩形成于俯冲带之上,且具有指示洋内俯冲环境的地球化学特征.因此,泽当SSZ型蛇绿岩可能形成于洋内俯冲机制.     

雅鲁藏布江缝合带西段北亚带的基性岩成因和构造意义

雅鲁藏布江蛇绿岩带自萨嘎以西分为达巴—休古嘎布(南亚带)和达机翁—萨嘎(北亚带)两个亚带,但两者的成因和构造背景还不清楚。本文在研究北亚带加纳崩—错不扎基性岩脉的年代学和地球化学及对比南亚带的基础上,探讨了两个带的成因和关系问题。加纳崩辉长岩和错不扎辉绿岩呈脉状或长透镜状产在方辉橄榄岩中,宽1~3 m不等,走向北西。两者的锆石U-Pb年龄分别为(125.8±2.6)Ma和(127.0±0.5)Ma。岩石地球化学均具有高Si、Al、Na、Mg和低Ti、K、P的特征,属钙碱性玄武质成分。球粒陨石标准化曲线与N-MORB一致;N-MORB标准化蛛网图中显示Nb、Ta、Ti负异常,判断两者形成于大洋俯冲的弧前或弧后环境。对比前人研究,南亚带普兰、东波和休古嘎布蛇绿岩中的基性岩具有相同产状和时代(120~130 Ma),地球化学特征也同样显示形成于洋内俯冲带环境。结合两带基性岩的围岩地幔橄榄岩均具有弧前环境特征,初步认为南北蛇绿岩亚带可能是相同构造背景的大洋岩石圈残余。     

德钦县贡卡—书松地区蛇绿岩年代学、地球化学特征及其地质意义

通过对德钦县贡卡—书松地区蛇绿岩的岩石学特征、地球化学特征及形成时代进行分析,结果表明该区蛇绿岩套岩石组份有超镁铁质岩、基性岩墙、中基性熔岩、紫红色硅质岩及灰岩。其中超基性岩为镁质、贫铝系列,微量元素表现为仅少量大离子亲石元素富集型;放射性生热元素U为富集型。基性岩岩石的微量元素表现为大离子亲石元素富集型;放射性生热元素Th富集,稀土元素丰度反映LREE富集,显富轻稀土型,表明该蛇绿岩套属扩张洋脊型。书松地区粗玄岩内锆石年龄为300.06Ma,洛玉村一带辉绿岩及辉长岩中锆石年龄为(252.4±1.7)Ma和(258.7±2.7)Ma,表明研究区内蛇绿岩套形成时代大约在晚石炭世—晚二叠世,与峨眉地裂运动相对应,是拉张活动的中心区域。     

Wavelength-dispersive X-ray fluorescence spectrometric determination of Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites

Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.     

高压微波消解法测定醋酸纤维过滤器采集的微尘粒子中的砷镉钴铬铜铁锰镍铅钒锌

最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.     

硅酸盐中铁、锰、钛、钙、钾、磷、硅、铝、镁、钠、锶、铷、钡的X-射线荧光光谱定量测定

本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。     

硅酸盐类样品中硅、铁、铝、钛、锰、钙、镁、钾、钠和磷的x射线荧光光谱测定

本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。     

Viscous, cohesive, non-Newtonian, depositing, radial slurry flow

Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.     

Regional distribution of Al,B, Ba,Ca, K,La, Mg,Mn, Na,P, Rb,Si, Sr,Th, U and Y in terrestrial moss within a 188,000 km2 area of the central Barents region: influence of geology,seaspray and human activity

Five hundred and ninety-eight samples of terrestrial moss (Hylocomium splendens and Pleurozium schreberi) collected from a 188,000 km² area of the central Barents region (NE Norway, N Finland, NW Russia) were analysed by ICP-AES and ICP-MS. Analytical results for Al, B, Ba, Ca, K, La, Mg, Mn, Na, P, Rb, Si, Sr, Th, U and Y concentrations are reported here. Graphical methods of data analysis, such as geochemical maps, cumulative frequency diagrams, boxplots and scatterplots, are used to interpret the origin of the patterns for these elements. None of the elements reported here are emitted in significant amounts from the smelting industry on the Kola Peninsula. Despite the conventional view that moss chemistry reflects atmospheric element input, the nature of the underlying mineral substrate (regolith or bedrock) is found to have a considerable influence on moss composition for several elements. This influence of the chemistry of the mineral substrate can take place in a variety of ways. (1) It can be completely natural, reflecting the ability of higher plants to take up elements from deep soil horizons and shed them with litterfall onto the surface. (2) It can result from naturally increased soil dust input where vegetation is scarce due to harsh climatic conditions for instance. Alternatively, substrate influence can be enhanced by human activity, such as open-cast mining, creation of ‘technogenic deserts’, or handling, transport and storage of ore and ore products, all of which magnify the natural elemental flux from bedrock to ground vegetation. Seaspray is another natural process affecting moss composition in the area (Mg, Na), and this is most visible in the Norwegian part of the study area. Presence or absence of some plant species, e.g., lichens, seems to influence moss chemistry. This is shown by the low concentrations of B or K in moss on the Finnish and Norwegian side of the (fenced) border with Russia, contrasting with high concentrations on the other side (intensive reindeer husbandry west of the border has selectively depleted the lichen population).     

NEW SET OF LOW CONCENTRATION STANDARDS FOR LA, CE, SM, YB, LU, Y, SC, V, NB AND TA IN SILICATES

We have developed a set of four synthetic standards for the rare earth and high field strength elements designed for use in the determination of those elements in silicates. The base material is a glass nominally at the eutectic of the MgO-Al₂O₃-SiO₂ ternary system. The nominal doping level was 2 wt% of the elements as oxides. To avoid problems associated with peak interference, the elements were doped in four separate glasses.     

Mountains,nations, parks,and conservation

Between 1985 and 1991, two new mountain protected areas (MTNPA) covering more than 35,000 km² and based on participatory management models — the Makalu-Barun National Park and Conservation Area, Nepal, and Qomolangma Nature Preserve, Tibet Autonomous Region — were successfully established through the collaborative efforts of Woodlands Mountain Institute and conservationists in China and Nepal. Characteristics common to both projects include the importance of establishing (1) effective rationales, (2) local support constituencies, (3) a senior advisory group, (4) a task force, (5) linkages between conservation and development, and (6) fund raising mechanisms. The lessons derived from the experiences of Woodlands Mountain Institute are of significant value to others in preserving MTNPA. Increased collaboration and communication between all interested in conservation, however, will remain a critical component for expanding mountain protected area coverage to throughout the world.