Controls on accumulation of anomalously thick coals: Implications for sequence stratigraphic analysis

Coal seams preserve high-resolution records of ancient terrestrial water table (base level) fluctuations in ancient peat accumulations, but little is known about base level change in anomalously thick coal seams. Using the Early Cretaceous 91 m anomalously thick No. 6 coal (lignite) seam in the Erlian Basin (north-east China) as a case study, the origin and evolution of peat accumulation in a continental faulted basin is revealed by sedimentological, sequence stratigraphic and coal petrological analyses. The lignite is dominated by huminite, indicating oxygen-deficient and waterlogged conditions in the precursor mire. Four types of key sequence stratigraphic surfaces are recognized, including paludification, terrestrialization, accommodation-reversal and give-up transgressive surfaces. Vertically, the No. 6 coal seam consists of fourteen superimposed wetting-up and drying-up cycles separated by key sequence stratigraphic surfaces, with each of these cycles having a mean duration of about 156 to 173 kyr. In a high accommodation peat swamp system, the wetting-up cycles are generally characterized by an upward increase in mineral matter and inertodetrinite and an upward decrease in huminite with the paludification surface as their base and the give-up transgressive surface or accommodation-reversal surface as their top, representing a trend of upward-increasing accommodation. In contrast, the drying-up cycles are generally characterized by an upward decrease in mineral matter and inertodetrinite and an upward increase in huminite, with the terrestrialization surface as their base and the accommodation-reversal surface as their top, representing a trend of upward-decreasing accommodation. A multi-phase mire stacking model for accumulation of the coal seam is proposed based on high-frequency accommodation cycles and the stratigraphic relationships between coal and clastic sediments. High-frequency accommodation cycles in the coal are closely related to water table fluctuations in the precursor mires and are driven by high-frequency climate via changes in the intensity and seasonality of precipitation in a relatively stable subsidence regime. Recognition that the No. 6 coal seam is composed of multiple stacked mires has implications for studies addressing palaeoclimatic inferences and genesis of anomalously thick coals seams.     

含煤岩系层序地层学研究进展

层序地层学是分析聚煤规律的一种有效方法。层序地层学应用于含煤地层的分析始于20世纪90年代,Diessel最先在经典层序地层格架中建立了煤层的聚集模式;之后,Bochacs和Stuer通过讨论可容纳空间的变化速率和泥炭聚集速率之间比值的变化,具体分析了不同可容纳空间的煤层厚度、连续性及形态。通过对层序地层中煤层发育和分布的研究,多数煤田地质学家们认为,厚煤层主要发育于低位体系域晚期至海侵体系域早期及海侵体系域晚期至高位体系域早期。由于巨厚煤层往往是许多次级层序及界面的复合体,因此巨厚煤层不能简单地作为成因层序地层的界面,但可以通过煤岩学和地球化学方面的指标对其进行精细划分确定。我国煤田地质学家通过对国内海相煤层的研究,提出了海侵事件聚煤和海相层滞后时段聚煤等观点,从而大大促进了含煤岩系层序地层学的发展。      

On balanced and unbalanced accommodation/peat accumulation ratios in the Cretaceous coals from Gates Formation, Western Canada, and their sequence-stratigraphic significance

Coal composition was investigated by means of photometric and maceral analyses on closely spaced lithotype-based strip samples over the full thickness of several paralic coal seams from the Cretaceous Gates Formation of the Western Canadian Sedimentary Basin. The aim of this investigation was to test various methods of identifying accommodation trends in coal and use them to refine sequence-stratigraphic interpretation of continental sediments. Conventional sequence stratigraphy derives its subdivisions and significant surfaces from the records left by relative sea-level oscillations. These records either do not project into the continental realm, or are difficult to recognise in clastic non-marine sediments. Paralic coal seams have been selected to study this problem, because they are not entirely removed from marine influence and, compared with most inorganic deposits, coal has stored a greater wealth of information that can be analysed at a higher level of resolution. The study has led to the identification of five new surfaces with chronostratigraphic potential in the sequence-stratigraphic analysis of non-marine sediments. Two of these surfaces, called paludification surface (PaS) and terrestrialisation surface (TeS), occur at the bases of the investigated coal seams, while two other surfaces, referred to as non-marine flooding surface (NFS) and give-up transgressive surface (GUTS), form the tops of the coal. The fifth and probably most important new surface, called the accommodation-reversal surface (ARS), is independent of any particular facies and may either coincide with some of the other surfaces or occur separately. The proportion of detrital minerals has been used as the chief discriminator between different mire types and accommodation trends. Other useful indicators of mire type and peat dispersal have been the proportions of sporinite and inertodetrinite, as well as some derived maceral and/or mineral ratios, e.g., the groundwater influence index and the tissue preservation index. Isometamorphic variations of telovitrinite reflectance and fluorescence, as well as their coefficients of variation were also found to contribute to the identification of cyclic shifts between balanced and unbalanced accommodation/peat accumulation ratios. Some of these cycles, which are backed up by clastic stratigraphy, appear to correspond to the development of shallowing-upward and deepening-upward parasequences. Superimposed high-frequency, low-amplitude perturbations in the coal cycles relate to smaller-scale accommodation cycles of sub-parasequence level, not always recognised in non-marine strata. These sub-parasequence coal cycles do not always continue the shallowing-upward trend typical of conventional parasequences. Several coals were found to contain stacks of small-scale cycles with upward increasing accommodation signatures either in their lower or upper halves, or over the whole seam section.     

Importance of vegetation type for mercury sequestration in the northern Swedish mire, Rödmossamyran

Even if mires have proven to be relatively reliable archives over the temporal trends in atmospheric mercury deposition, there are large discrepancies between sites regarding the magnitude of the anthropogenic contribution to the global mercury cycle. A number of studies have also revealed significant differences in mercury accumulation within the same mire area. This raises the question of which factors, other than mercury deposition, affect the sequestration of this element in peat. One such factor could be vegetation type, which has the potential to affect both interception and retention of mercury. In order to assess how small-scale differences in vegetation type can affect mercury sequestration we sampled peat and living plants along three transects on a northern Swedish mire. The mire has two distinctly different vegetation types, the central part consists of an open area dominated by Sphagnum whereas the surrounding fen, in addition to Sphagnum mosses, has an understory of ericaceous shrubs and a sparse pine cover. A few main patterns can be observed in our data; (1) Both peat and Sphagnum-mosses have higher mercury content (both concentration and inventory) in the pine-covered fen compared to the open Sphagnum area (100% and 71% higher for peat and plants, respectively). These differences clearly exceed the 33% difference observed for lead-210, which is considered as a good analogue for atmospheric mercury deposition. (2) The differences in mercury concentration between peat profiles within a single vegetation type can largely be attributed to differences in peat decomposition. (3) When growing side by side in the open Sphagnum area, the moss species Sphagnum subsecundum has significantly higher mercury concentrations compared to S. centrale (24 ± 3 and 18 ± 2 ng Hg g⁻¹, respectively). Based on these observations we suggest that species composition, vegetation type and decomposition can affect the mercury sequestration in a peat record, and that any changes in these properties over time, or space, have the potential to modify the mercury deposition signal recorded in the peat.     

The origin and distribution of HAPs elements in relation to maceral composition of the A1 lignite bed (Paleocene, Calvert Bluff Formation, Wilcox Group), Calvert mine area, east-central Texas

The origin and distribution of twelve potentially Hazardous Air Pollutants (HAPs; As, Be, Cd, Cr, Co, Hg, Mn, Ni, Pb, Sb, Se, and U) identified in the 1990 Clean Air Act Amendments were examined in relation to the maceral composition of the A1 bed (Paleocene, Calvert Bluff Formation, Wilcox Group) of the Calvert mine in east-central Texas. The 3.2 m-thick A1 bed was divided into nine incremental channel samples (7 lignite samples and 2 shaley coal samples) on the basis of megascopic characteristics. Results indicate that As, Cd, Cr, Ni, Pb, Sb, and U are strongly correlated with ash yield and are enriched in the shaley coal samples. We infer that these elements are associated with inorganic constituents in the coal bed and may be derived from a penecontemporaneous stream channel located several kilometers southeast of the mining block. Of the HAPs elements studied, Mn and Hg are the most poorly correlated to ash yield. We infer an organic association for Mn; Hg may be associated with pyrite. The rest of the trace elements (Be, Co, and Se) are weakly correlated with ash yield. Further analytical work is necessary to determine the mode of occurrence for these elements. Overall, concentrations of the HAPs elements are generally similar to or less than those reported in previous studies of lignites of the Wilcox Group, east-central region, Texas. Petrographic analysis indicates the following ranges in composition for the seven lignite samples: liptinites (5–8%), huminites (88–95%), and inertinites (trace amounts to 7%). Samples from the middle portion of the A1 bed contain abundant crypto-eugelinite compared to the rest of the samples; this relationship suggests that the degradation of plant material was an important process during the development of the peat mire. With the exception of Hg and Mn, relatively low levels of the HAPs elements studied are found in the samples containing abundant crypto-eugelinite. We infer that the peat-forming environment for this portion of the coal bed was very wet with minimal detrital input. Relatively high concentrations of crypto-humotelinite were found in samples from the top and base of the coal bed. The presence of abundant crypto-humotefinite in this part of the coal bed suggests the accumulation of wood-rich peat under conditions conducive to a high degree of tissue preservation in the peat mire. Although several of the trace elements (Be, Co, Ni, and Sb) exhibit enrichment in these samples, they are not necessarily chemically associated with humotelinite. We infer that these elements, with the exception of Be, are possibly associated with deposition of the roof and floor rock of the coal bed; however, further analytical work would be necessary to confirm this hypothesis. Beryllium may have an organic origin.     

Microfacies and depositional environment of Tertiary Tanjung Enim low rank coal, South Sumatra Basin, Indonesia

The South Sumatra basin is among the most important coal producing basins in Indonesia. Results of an organic petrography study on coals from Tanjung Enim, South Sumatra Basin are reported. The studied low rank coals have a mean random huminite reflectance between 0.35% and 0.46% and are dominated by huminite (34.6–94.6 vol.%). Less abundant are liptinite (4.0–61.4 vol.%) and inertinite (0.2–43.9 vol.%). Minerals are found only in small amounts (0–2 vol.%); mostly as iron sulfide.Based on maceral assemblages, the coals can be grouped into five classes: (1) humotelinite-rich group, (2) humodetrinite-rich group, (3) humocollinite-rich group, (4) inertinite-rich group and (5) humodetrinite–liptinite-rich group. Comparing the distribution of maceral assemblages to the maceral or pre-maceral assemblages in modern tropical domed peat in Indonesia reveals many similarities. The basal section of the studied coal seams is represented typically by the humodetrinite–liptinite-rich group. This section might be derived from sapric or fine hemic peat often occurring at the base of modern peats. The middle section of the seams is characterized by humotelinite-rich and humocollinite-rich groups. The precursors of these groups were hemic and fine hemic peats. The top section of the coal seams is typically represented by the humodetrinite-rich or inertinite-rich group. These groups are the counterparts of fibric peat at the top of the modern peats. The sequence of maceral assemblages thus represents the change of topogenous to ombrogenous peat and the development of a raised peat bog.A comparison between the result of detailed maceral assemblage analysis and the paleodepositional environment as established from coal maceral ratio calculation indicates that the use of coal maceral ratio diagrams developed for other coal deposits fails to deduce paleo-peat development for these young tropical coals. In particular, mineral distribution and composition should not be neglected in coal facies interpretations.     

Climate change during the past 1000 years: a high‐temporal‐resolution multiproxy record from a mire in northern Finland

We present a record of peatland development in relation to climate changes and human activities from the Palomaa mire, a remote site in northern Finland. We used fine‐resolution and continuous sampling to analyse several proxies including pollen (for vegetation on and around the mire), testate amoebae (TA; for mire‐wetness changes), oxygen and carbon isotopes from Sphagnum cellulose (δ¹⁸O and δ¹³C; for humidity and temperature changes), peat‐accumulation rates and peat‐colour changes. In spite of an excellent accumulation model (30 ¹⁴C dates and estimated standard deviation of sample ages <1 year in the most recent part), the potential to determine cause–effect (or lead–lag) relationships between environmental changes and biotic responses is limited by proxy‐specific incorporation processes below the actively growing Sphagnum surface. Nevertheless, what emerges is that mire development was closely related to water‐table changes rather than to summer temperature and that water‐table decreases were associated with increasing peat‐accumulation rates and more abundant mire vegetation. A rapid fen‐to‐bog transition occurred within a few years around AD 1960 when the water table decreased beyond the historical minimum, supporting the notion that mires can rapidly shift into bogs in response to allogenic factors. Copyright © 2012 John Wiley & Sons, Ltd.     

Sea-level and reef accretion history of Marine Oxygen Isotope Stage 7 and late Stage 5 based on age and facies of submerged late Pleistocene reefs,Oahu, Hawaii

In situ Pleistocene reefs form a gently sloping nearshore terrace around the island of Oahu. TIMS Th–U ages of in situ corals indicate that most of the terrace is composed of reefal limestones correlating to Marine Oxygen Isotope Stage 7 (MIS 7, ~ 190–245 ka). The position of the in situ MIS 7 reef complex indicates that it formed during periods when local sea level was ~ 9 to 20 m below present sea level. Its extensiveness and geomorphic prominence as well as a paucity of emergent in situ MIS 7 reef-framework deposits on Oahu suggest that much of MIS 7 was characterized by regional sea levels below present. Later accretion along the seaward front of the terrace occurred during the latter part of MIS 5 (i.e., MIS 5a–5d, ~ 76–113 ka). The position of the late MIS 5 reefal limestones is consistent with formation during a period when local sea level was below present. The extensiveness of the submerged Pleistocene reefs around Oahu compared to the relative dearth of Holocene accretion is due to the fact that Pleistocene reefs had both more time and more accommodation space available for accretion than their Holocene counterparts.     

Depositional history of the Fire Clay coal bed (Late Duckmantian), Eastern Kentucky, USA

More than 3800 coal thickness measurements, proximate analyses from 97 localities, and stratigraphic and sedimentological analyses from more than 300 outcrops and cores were used in conjunction with previously reported palynological and petrographic studies to map individual benches of the coal and document bench-scale variability in the Fire Clay (Hazard No. 4) coal bed across a 1860 km² area of the Eastern Kentucky Coal Field. The bench architecture of the Fire Clay coal bed consists of uncommon leader benches, a persistent but variable lower bench, a widespread, and generally thick upper bench, and local, variable rider benches. Rheotrophic conditions are inferred for the leader benches and lower bench based on sedimentological associations, mixed palynomorph assemblages, locally common cannel coal layers, and generally high ash yields. The lower bench consistently exhibits vertical variability in petrography and palynology that reflects changing trophic conditions as topographic depressions infilled. Infilling also led to unconfined flooding and ultimately the drowning of the lower bench mire. The drowned mire was covered by an air-fall volcanic-ash deposit, which produced the characteristic flint clay parting. The extent and uniform thickness of the parting suggests that the ash layer was deposited in water on a relatively flat surface without a thick canopy or extensive standing vegetation across most of the study area. Ash deposits led to regional ponding and establishment of a second planar mire. Because the topography had become a broadly uniform, nutrient-rich surface, upper-bench peats became widespread with large areas of the mire distant to clastic sources. Vertical sections of thick (>70 cm), low-ash yield, upper coal bench show a common palynomorph change from arborescent lycopod dominance upward to fern and densospore-producing, small lycopod dominance, inferred as a shift from planar to ombrotrophic mire phases. Domed mires appear to have been surrounded by wide areas of planar mires, where the coal was thinner (<70 cm), higher in ash yield, and dominated by arborescent lycopods. Rectangular thickness trends suggest that syndepositional faulting influenced peat accumulation, and possibly the position of the domed mire phase. Faulting also influenced post-depositional clastic environments of deposition, resulting in sandstone channels with angular changes in orientation. Channnels and lateral facies were locally draped by high-ash-yield rider coal benches, which sometimes merged with the upper coal bench. These arborescent-lycopod dominant rider coal benches were profoundly controlled by paleotopography, much like the leader coal benches. Each of the benches of coal documented here represent distinctly different mires that came together to form the Fire Clay coal bed, rather than a single mire periodically split by clastic influx. This is significant as each bench of the coal has its own characteristics, which contribute to the total coal characteristics. The large data set allows interpretation of both vertical and lateral limits to postulated domed phases in the upper coal bench, and to the delineation of subtle tectonic structures that allow for meaningful thickness projections beyond the limits of present mining.     

Origin and fluxes of atmospheric REE entering an ombrotrophic peat bog in Black Forest (SW Germany): Evidence from snow, lichens and mosses

The fate of the Rare Earth Elements (REE) were investigated in different types of archives of atmospheric deposition in the Black Forest, Southern Germany: (1) a 70 cm snow pack collected on the domed part of a raised bog and representing 2 months of snow accumulation, (2) a snow sample collected close to the road about 500 m from the peat bog, (3) two species of lichens and (4) a peat profile representing 400 years of peat accumulation as well as a “preanthropogenic” sample and the living moss layer from the top of the core. REE concentrations in peat are significantly correlated to Ti which is a lithogenic conservative element suggesting that REE are immobile in peat bog environments. Snow, lichens and peat samples show similar PAAS (Post Archean Australian Shale) normalized REE distributions suggesting that the complete atmospheric REE signal is preserved in the peat profile. However, the annual flux of REE accumulated by the peat is ca. 10 times greater than that of the bulk winter flux of REE. This difference probably indicates that the REE concentrations in the snowpack are not representative of the average REE flux over the whole year. Despite the pronounced geological differences between this site (granite host-rock) and a previously studied peat bog in Switzerland (limestone host-rock) similar REE distribution patterns and accumulation rates were found at both sites. Given that both sites confirm an Upper Continental Crust signature, the data suggests both sites are influenced by regional and not local, soil-derived lithogenic aerosols.     

二连盆地吉尔嘎朗图凹陷下白垩统赛汉塔拉组层序地层及聚煤特征

二连盆地吉尔嘎朗图凹陷是一个陆相断陷聚煤盆地,下白垩统赛汉塔拉组是其主要含煤地层,作者利用岩心、钻孔资料对其岩相类型、沉积相、层序地层及聚煤作用特征进行研究。(1)赛汉塔拉组主要由砂砾岩、砂岩、粉砂岩、泥岩、碳质泥岩及厚层褐煤组成,发育扇三角洲平原相、扇三角洲前缘相、辫状河三角洲平原相、辫状河三角洲前缘相、滨浅湖相,分别属于扇三角洲沉积体系、辫状河三角洲沉积体系和湖泊沉积体系。(2)识别出2种层序界面:不整合面和下切谷冲刷面,将赛汉塔拉组划分为2个三级层序。从层序Ⅰ到层序Ⅱ,煤层厚度逐渐增大,聚煤作用逐渐增强。(3)在滨浅湖环境下厚煤层主要形成于湖侵体系域早期,在扇/辫状河三角洲环境下厚煤层主要形成于湖侵体系域晚期,煤层厚度在凹陷中部最大,向西北和东南方向均变小。聚煤作用明显受基底沉降作用影响,可容空间增加速率与泥炭堆积速率相平衡,从而形成了区内巨厚煤层。     

How a Sphagnum fuscum‐dominated bog changed into a calcareous fen: the unique Holocene history of a Slovak spring‐fed mire

In general, mires develop by autogenic succession from more groundwater‐fed to more rainwater‐fed. This study from a calcareous mire in the West Carpathians (Slovakia) describes a similar development in the Early Holocene, followed by a reverse development in the Middle and Late Holocene. Pollen, macrofossil and testate amoeba analyses show that the site started as a minerotrophic open fen woodland. After 10 700 cal a BP autogenic succession led to the accumulation of at least 1 m of Sphagnum fuscum peat. Around 9000 cal a BP, as climate could no longer sustain a stable water regime, the bog desiccated and a fire broke out. The fire removed part of the peat layer and as a consequence relative water levels rose, leading to the establishment of a wet minerotrophic swamp carr with Thelypteris palustris, Equisetum sp. and Alnus sp. with extremely slow peat accumulation. After 600 cal a BP, rapid peat accumulation with calcareous tufa formation resumed as a result of anthropogenic deforestation and hydrological changes in the catchment and resulting increased groundwater discharge. At present the mire still hosts a wealth of relict and endangered plant and animal species typical of calcareous fens and fen meadows. Copyright © 2011 John Wiley & Sons, Ltd.     

The use of principle component analyses in characterising trace and major elemental distribution in a 55 kyr peat deposit in tropical Australia: Implications to paleoclimate

The Lynch’s Crater peat deposit in NE-Australia is a sensitive environmental archive located in the tropical Southern Hemisphere. This unique deposit illustrates that local and regional changes had a profound effect on the local Australian ecosystem over the past 55 kyr. To obtain a proxy of past climate changes, trace and major element geochemistry analyses were applied to a 13 m peat core from the crater. Principle component analysis (PCA) was used to identify the main factors that control elemental distribution in the peat and to add interpretative strength to the geochemical behavior of selected major and trace elements. For example, Sc, Al, Cu, and Pb were found to be related to increased erosion of the basin soils, and from this, several periods of significant flux from atmospheric input and/or terrigenous run-off were identified. Geochemically mobile elements during rock weathering and pedogenesis, such as Mg, Ca, and Sr helped to identify the peat ombrotrophic-minerotrophic boundary at ∼1.5 m depth and offered important information about fluxes of these nutrients to the mire and their dynamics within the deposit. Arsenic and V comparisons between the peat record (high concentrations in some peat sections) and in local basin rocks (very low concentrations), suggested the presence of a long range, atmospheric dust source early in the formation of the mire. The Lynch’s Crater peat record presents a continuous record of environmental change in tropical Australia and contributes new understanding to geochemical processes in peatlands.     

Depositional record of an avulsive fluvial system controlled by peat compaction (Neogene, Most Basin, Czech Republic)

This paper illustrates the response of a fluvial depositional system to the interplay between peat compaction and clastic sediment supply, at a range of spatial and temporal scales, as documented by extensive exposures in an open-cast mine in the Most Basin, part of the Oligo-Miocene Ohře Rift (Eger Graben) basin system in the Czech Republic. The Most Basin is characterized by the occurrence of a number of phenomena resulting from syn- and post-depositional interactions between clastic sedimentary systems and the underlying accumulation of organic material that was the precursor of the main lignite seam of up to 45 m thickness. The studied strata are interpreted as deposits of an avulsive, mixed-load fluvial system. The large-scale depositional architecture documents an existence of at least five stratal packages up to 1500 m wide and up to several tens of metres thick, representing a record of long-term evolution of a clastic floodplain bordered by accumulating peat. Within each of the packages, several small-scale channel-belts were documented. Individual packages are separated by carbonaceous mudstones indicating a period of reduced clastic input and interpreted as due to avulsion of the fluvial channels out of the floodplain limit. Two main, mutually linked, processes controlled the evolution of the studied fluvial system: (i) syndepositional compaction of the underlying peat and (ii) avulsions of the channels away from the original floodplain, resulting in formation of a new floodplain. The processes which caused the channels of the Hrabák fluvial system to reach the avulsion threshold were: (i) decrease of rate of creation of accommodation leading to increased sinuosity and thus to a decreased channel slope, and (ii) cross-floodplain tilting of the channel belt caused by differential compaction of underlying organic-rich substratum.     

Organic petrology of Paleocene Marcelina Formation coals, Paso Diablo mine, western Venezuela: Tectonic controls on coal type

About 7 Mt of high volatile bituminous coal are produced annually from the four coal zones of the Upper Paleocene Marcelina Formation at the Paso Diablo open-pit mine of western Venezuela. As part of an ongoing coal quality study, we have characterized twenty-two coal channel samples from the mine using organic petrology techniques. Samples also were analyzed for proximate–ultimate parameters, forms of sulfur, free swelling index, ash fusion temperatures, and calorific value.Six of the samples represent incremental benches across the 12–13 m thick No. 4 bed, the stratigraphically lowest mined coal, which is also mined at the 10 km distant Mina Norte open-pit. Organic content of the No. 4 bed indicates an upward increase of woody vegetation and/or greater preservation of organic material throughout the life of the original mire(s). An upward increase in telovitrinite and corresponding decrease in detrovitrinite and inertinite illustrate this trend. In contrast, stratigraphically higher coal groups generally exhibit a ‘dulling upward’ trend.The generally high inertinite content, and low ash yield and sulfur content, suggest that the Paso Diablo coals were deposited in rain-fed raised mires, protected from clastic input and subjected to frequent oxidation and/or moisture stress. However, the two thinnest coal beds (both 0.7 m thick) are each characterized by lower inertinite and higher telovitrinite content relative to the rest of Paso Diablo coal beds, indicative of less well-established raised mire environments prior to drowning.Foreland basin Paleocene coals of western Venezuela, including the Paso Diablo deposit and time-correlative coal deposits of the Táchira and Mérida Andes, are characterized by high inertinite and consistently lower ash and sulfur relative to Eocene and younger coals of the area. We interpret these age-delimited coal quality characteristics to be due to water availability as a function of the tectonic control of subsidence rate. It is postulated that slower subsidence rates dominated during the Paleocene while greater foreland basin subsidence rates during the Eocene–Miocene resulted from the loading of nappe thrust sheets as part of the main construction phases of the Andean orogen. South-southeastward advance and emplacement of the Lara nappes during the oblique transpressive collision of the Caribbean and South American tectonic plates in the Paleocene was further removed from the sites of peat deposition, resulting in slower subsidence rates. Slower subsidence in the Paleocene may have favored the growth of raised mires, generating higher inertinite concentrations through more frequent moisture stress. Consistently low ash yield and sulfur content would be due to the protection from clastic input in raised mires, in addition to the leaching of mineral matter by rainfall and the development of acidic conditions preventing fixation of sulfur. In contrast, peat mires of Eocene–Miocene age encountered rapid subsidence due to the proximity of nappe emplacement, resulting in lower inertinite content, higher and more variable sulfur content, and higher ash yield.     

Organic petrology, mineralogy and depositional environment of the Kipra lignite seam, Maritza-West basin, Bulgaria

The aim of the present study is to provide additional information about the properties and depositional environment of the Kipra lignite seam, which was deposited during the regressive stage of development of the Maritza-West basin. Petrographical and mineralogical data, along with ash yields and sulphur contents of 24 samples from a seam profile, have been used to study the vertical variation of the depositional settings during peat accumulation and subsequent coalification.The Kipra lignite is characterized by high ash yields and sulphur contents. It formed in a rheotrophic, low-lying mire with alkaline pH value. Vegetation with low preservation potential dominated within the palaeomire. During peat formation, frequent changes of the water level controlled the depositional environment. During the deposition of units 1 and 2, high water energy caused the transportation of high amounts of inorganic material into the mire, resulting in the formation of weakly gelified mineral-rich lignite. The organic matter from units 3 and 4 is characterized by enhanced gelification, which probably reflects the decreasing energy of the system. Good positive correlation between sulphur contents and the GI values was established in units 4, indicating that the gelification of the tissues was probably mainly controlled by the bacterial activity. In contrast, the gelification of the samples from unit 3 of the Kipra seam was probably governed by the redox conditions. The organic matter deposited under relatively wet conditions, in which the thermal and oxidative destruction of the tissues, was limited.A variety of major, minor and accessory minerals are present in Maritza-West lignite. The mineral composition is dominated mainly by pyrite, gypsum and calcite, and to a lesser extent limonite, quartz, kaolinite, montmorillonite, illite, chlorite and plagioclase. Jarosite, hematite, halloysite, mica, K-feldspar, aragonite, siderite, and dolomite were also determined in very low concentrations. These minerals formed syngenetically and epigenetically. The syngenetic stage is characterized mainly by the formation of pyrite, carbonates, silicates and sulphates, whereas the Fe-oxyhydroxides, partially the carbonates and almost all silicates are of detrital origin. During the epigenetic stage, carbonates, sulphates, clay minerals, pyrite, and Fe-oxyhydroxides were formed. Alteration products like gypsum, jarosite, limonite, chlorite, kaolinite, illite, mica, and calcite were generated due to the transformation of detrital and authigenic minerals.     

Properties and depositional environment of the Neogene Elhovo Lignite, Bulgaria

Several Mio-Pliocene aged lignite seams occur as part of a non-marine transgressive sequence in the Elhovo graben in south-eastern Bulgaria. The present study is focused on 45 samples collected from three boreholes in the eastern part of the basin. Petrographic data along with ash and sulphur contents were used in order to determine the lateral and vertical variations of the coal facies and depositional environment of the Elhovo lignite.The lignite seams accumulated in a rheotrophic, low-lying mire with high pH value and are characterized by high ash yields and sulphur contents. Despite of the neutral to weakly alkaline environment the bacterial activity was limited and the tissue preservation and gelification were mainly controlled by the redox conditions.Vegetation rich in decay resistant conifers dominated in the Elhovo basin together with mesophytic angiosperm species. The absence of algal remains and sapropelic coal indicated that open water areas were not present during peat accumulation. The latter processed in an environment, characterized by low subsidence rate, in which prior to the burial the woods were subjected to severe mechanical destruction. According to our interpretation, the enhanced impregnation of the tissues bacteria and fungi played only a secondary role in the process of humification. The lignite from borehole 122 and partly from BH 145 deposited in an environment characterized by relatively low (ground)water table, whereas to the south an area dominated by a flooded forest swamp (BH 104) formed. This is suggested by the better tissue preservation and gelification of the organic matter in BH 104. The vertical variation of the maceral composition in the studied lignite is interpreted as a consequence of vegetational changes, rather than to changes in the depositional environment. The low contents of inertinite macerals indicate that despite of the low water level the environment was relatively wet and the thermal and oxidative destruction of the tissues was limited.Peat accumulation was terminated by a major flooding event and a short term establishment of a lake. In contrast to the West Maritsa basin, no seam formed in the Elhovo basin during the filling stage of the lake.     

Overbank flooding and human occupation of the Shalongka site in the Upper Yellow River Valley,northeast Tibet Plateau in relation to climate change since the last deglaciation

Increased flooding caused by global warming threatens the safety of coastal and river basin dwellers, but the relationship of flooding frequency, human settlement and climate change at long time scales remains unclear. Paleolithic, Neolithic and Bronze Age cultural deposits interbedded with flood sediments were found at the Shalongka site near the north bank of the upper Yellow River, northeastern Tibetan Plateau. We reconstruct the history of overbank flooding and human occupation at the Shalongka site by application of optically stimulated luminescence and radiocarbon dating, grain size, magnetic susceptibility and color reflectance analysis of overbank sediment and paleosols. The reliability of OSL dating has been confirmed by internal checks and comparing with independent ¹⁴C ages; alluvial OSL ages have shown a systematic overestimation due to poor bleaching. Our results indicate that the Yellow River episodically overflowed and reached the Shalongka site from at least ~ 16 ka and lasting until ~ 3 ka. Soil development and reduced flooding occurred at ~ 15, ~ 8.3–5.4, and after ~ 3 ka, and prehistoric populations spread to the Shalongka site area at ~ 8.3, ~ 5.4, and ~ 3 ka. We suggest that climate change influenced the overbank flooding frequency and then affected prehistoric human occupation of the Shalongka site.     

Variable Phanerozoic thermal history in the Southern Canadian Shield: Evidence from an apatite fission track profile at the Underground Research Laboratory (URL), Manitoba

Analysis of a 1.15 km deep apatite fission track (AFT) thermochronology profile at the Underground Research Laboratory (URL), in the southwestern Canadian Shield suggests two Phanerozoic heating and cooling episodes indicating significant, previously unsuspected, Phanerozoic heat flow variations. Phanerozoic temperature and heat flow variations are temporally associated with burial and erosion of the Precambrian crystalline shield and its overlying Phanerozoic successions, which are now eroded completely. Maximum Phanerozoic temperatures occurred in the late Paleozoic when the geothermal gradient is estimated to have been ~ 40-50 °C/km (compared to a present day gradient of ~ 14 ± 2 °C/km) and the sedimentary cover was ~ 800-1100 m thick. Our thermal history models, confirm regional stratigraphic relationships that suggest that the Paleozoic succession was completely eroded prior to beginning of Mesozoic sedimentation. A second heating phase occurred during Late Cretaceous-Paleogene burial when the geothermal gradient is estimated to have been ~ 20-25 °C/km and the Mesozoic and Cenozoic succession was ~ 1200 to 1400 m thick. The Phanerozoic thermal history at the URL site shows a pattern similar to that inferred previously for the epicratonic Williston Basin, the centre of which lies several 100 km to the west. This implies a common regional thermal history for cratonic rocks underlying both the basin and the currently exposed shield. It is suggested that the morphotectonic differences between the Williston Basin and the exposed shield at the URL are due to a dissimilar thermomechanical response to a common, but more complicated than previously inferred, Phanerozoic geodynamic history. The two Phanerozoic periods of variations in geothermal gradient (heat flow) were coeval with epeirogenic movements related to the deposition and erosion of sediments. These paleogeodynamic variations are tentatively attributed to far-field effects of orogenic processes occurring at the plate margin (i.e. the Antler and the Cordilleran orogenies) and the associated accumulation of cratonic seaway sedimentary sequences (Kaskaskia and Zuni sequences).     

Conceptual models for short‐eccentricity‐scale climate control on peat formation in a lower Palaeocene fluvial system,north‐eastern Montana (USA)

Fluvial systems in which peat formation occurs are typified by autogenic processes such as river meandering, crevasse splaying and channel avulsion. Nevertheless, autogenic processes cannot satisfactorily explain the repetitive nature and lateral continuity of many coal seams (compacted peats). The fluvial lower Palaeocene Tullock Member of the Fort Union Formation (Western Interior Williston Basin; Montana, USA ) contains lignite rank coal seams that are traceable over distances of several kilometres. This sequence is used to test the hypothesis that peat formation in the fluvial system was controlled by orbitally forced climate change interacting with autogenic processes. Major successions are documented with an average thickness of 6·8 m consisting of ca 6 m thick intervals of channel and overbank deposits overlain by ca 1 m thick coal seam units. These major coal seams locally split and merge. Time‐stratigraphic correlation, using a Cretaceous–Palaeogene boundary event horizon, several distinctive volcanic ash‐fall layers, and the C29r/C29n magnetic polarity reversal, shows consistent lateral recurrence of seven successive major successions along a 10 km wide fence panel perpendicular to east/south‐east palaeo‐flow. The stratigraphic pattern, complemented by stratigraphic age control and cyclostratigraphic tests, suggests that the major peat‐forming phases, resulting in major coal seams, were driven by 100 kyr eccentricity‐related climate cycles. Two distinct conceptual models were developed, both based on the hypothesis that the major peat‐forming phases ended when enhanced seasonal contrast, at times of minimum precession during increasing eccentricity, intensified mire degradation and flooding. In model 1, orbitally forced climate change controls the timing of peat compaction, leading to enhancement of autogenic channel avulsions. In model 2, orbitally forced climate change controls upstream sediment supply and clastic influx determining the persistence of peat‐forming conditions. At the scale of the major successions, model 2 is supported because interfingering channel sandstones do not interrupt lateral continuity of major coal seams.