青藏高原东南缘哀牢山构造带泥质高压麻粒岩的发现及其构造意义

哀牢山构造带泥质高压麻粒岩主要由石榴石、夕线石、钾长石和斜长石变斑晶及尖晶石、铁假蓝宝石、蓝晶石、石英、金红石和钛铁矿包裹体组成,为确定印支地块和华南地块的边界提供了关键性标志。石榴石-黑云母-斜长石-石英地质温压计(GBPQ)计算结果及标志性高温矿物组合(Spl+Qz)表明泥质高压麻粒岩的形成和演化经历了高压/高温进变质到中温/低压退变质的顺时针P-T演化过程。其中:1)高压/高温进变质阶段的矿物组合为Ky+Sil+Grt1+Kf1+Pl1+Spr+Ter(Kf+Pl)+Bt1+Spl+Qtz+Ilm1+Rut1,形成于850～919℃,≥10.4kbar;2)中温/低压退变质阶段的矿物组合为Grt2+Bt2+Pl2+Ms+Qtz+Ilm2+Rut2,早期和晚期的温压条件分别为664～754℃,4.9～6.5kbar和572～576℃,3.5～3.9kbar。反映陆壳物质在碰撞过程中俯冲到地下深处(≥30km)经高压高温变质后快速折返到中上地壳的动力学演变轨迹。     

西昆仑塔什库尔干布伦阔勒群的岩石地球化学特征及变质P-T轨迹

西昆仑布伦阔勒群变质岩是西昆仑造山带的重要组成部分,但其成因一直存在争议.在塔什库尔干县的马尔洋地区,布伦阔勒群主要由石榴斜长角闪片麻岩和孔兹岩组成.根据地球化学特征,石榴斜长角闪片麻岩稀土元素配分曲线可以分为两种类型:一种稀土总量较高(∑REE=190.2×10-6 ～ 359.1×10-6),从轻稀土到重稀土逐渐亏损((La/Yb)N =4.28～5.79),与E-MORB类似;另一种稀土总量较低(∑REE=89.28×10-6～113.0×10-6),轻稀土亏损((La/Yb)N=0.59 ～0.84),重稀土曲线平坦((Gd/Yb)N =0.99 ～ 1.07),与N-MORB类似.微量元素蛛网图中石榴斜长角闪片麻岩具有Ba正异常,Sm、Cr、Zr、Hf和Ti的负异常,轻微的Nb、Ta的负异常,显示为岛弧拉斑玄武岩的特征.孔兹岩的原岩判别图解显示其原岩可能为岛弧环境沉积的页岩和硬砂岩.因此,推测塔什库尔干布伦阔勒群的石榴斜长角闪片麻岩和孔兹岩的原岩形成于岛弧环境.根据岩相学观察、矿物化学分析和温压计算,石榴斜长角闪片麻岩经历了三个变质阶段:M1为高压变质阶段,矿物组合为Grt+ Hbl(1)+ Pl1+ Qtz,变质温压条件为850～ 870℃/12.9 ～13.3kb;M2和M3为两期角闪岩相退变质阶段,矿物组合分别为Hbl2+ Pl2+Qtz和Hbl3+ Pl3+ Kfs+ Bt+ Qtz,变质温压条件分别为730 ～ 770℃/7.3～7.8kb和680 ～ 740℃/4.7 ～5.7kb.孔兹岩也经历了三个变质阶段,推测其早期M1阶段变质温压条件可能与石榴斜长角闪片麻岩的峰期变质阶段相同(850～870℃/12.9 ～ 13.3kb);峰期M2和峰期后M3阶段变质矿物组合分别为Grt2+ Pl2+ Bt2+ Sil+ Qtz和Grt3+ Pl3+ Bt3+Sil+ Mus+ Qtz,温压计算结果分别为800～830℃/7.9～9.2kb和670～700℃/5.1～5.6kb.孔兹岩的M1、M2和M3变质阶段对应于石榴斜长角闪片麻岩的M1、M2和M3变质阶段.上述温压计算结果形成顺时针的P-T轨迹,表现为峰期高压变质作用后叠加了由高角闪岩相-中压麻粒岩相到低角闪岩相的退变质作用,反映了西昆仑与碰撞相关的大地构造背景,这可能与海西期古特提斯洋的闭合有关,之后叠加了印支期构造抬升过程中的剪切作用.     

河南洛宁太华变质杂岩区早元古代变质作用P-T-t轨迹及其大地构造意义

太华变质杂岩广泛出露于华北克拉通南缘,总体呈SW-NE向展布.在河南洛宁地区,太华变质杂岩以TTG片麻岩、斜长角闪片麻岩和变泥质片麻岩为主.斜长角闪片麻岩中可识别出三个阶段的变质矿物组合:进变质阶段矿物组合(M1)为石榴子石变斑晶内部的包裹体矿物组合( Amp1+ Pl1+Qtz),变质高峰期矿物组合(M2)为石榴子石变斑晶边部和基质矿物组合( Grt2+ Amp2+ Pl2+ Qtz),退变质阶段矿物组合(M3)为“白眼圈”状后成合晶组合(Amp3+ Pl3+ Qtz).运用矿物温度计与压力计估算三个阶段的P-T条件分别为:进变质阶段约600 ～ 680℃/7.0～ 7.6kbar,变质高峰期为680 ～ 790℃/9.5 ～10.7kbar,退变质阶段为580～720℃/6.5 ～7.6kbar.变泥质片麻岩中保留了进变质阶段(M1)包裹体矿物组合(Bt1+Pl1+Qtz)和峰期变质阶段(M2)矿物组合(Grt2 +Bt2+Pl2 +Qtz)两个阶段.其中未发现后期退变质反应结构,石榴子石中也未发现成分环带.P-T条件估算结果分别为:M1阶段620 ～ 710℃/4.9 ～5.6kbar,M2阶段710～760℃/7.3～8.3kbar.洛宁地区太华变质杂岩记录了顺时针的近等温降压型的P-T轨迹,可能经历了与华北中部造山带其它杂岩类似的变质演化过程,推测其形成于华北克拉通东部陆块和西部陆块沿中部造山带的拼合过程中.SIMS与ICP-MS锆石U-Pb定年表明,斜长角闪片麻岩记录了1938～1967Ma的变质事件,比华北中部造山带其它变质杂岩区所广泛记录的～1850Ma变质事件早了约100Ma,暗示中部造山带的拼合可能是一个长期的、复杂的过程.     

冈底斯岩浆弧东段夕线石榴黑云片岩的变质作用P-T轨迹与构造意义

冈底斯岩浆弧东段的中-新生代变质岩是揭示岩浆弧深部组成与形成演化的窗口。本文对该地区的变质沉积岩——夕线石榴黑云片岩进行了岩石学和锆石年代学研究。岩相学和矿物化学研究表明,夕线石榴黑云片岩具有三期矿物组合:(1)进变质矿物组合为Grt+Pl+Bt+Ms+Qz+Ep+Rt+Ilm,其保存于石榴石和斜长石变斑晶核部;(2)峰期矿物组合为Grt+Pl+Bt+Ms+Qz+Rt+Ilm,为包裹在石榴石变斑晶幔部和基质中的矿物;(3)退变质矿物组合是Grt+Pl+Bt+Sil+Qz+Ilm,为石榴石的冠状体或产在基质中。相平衡模拟表明,岩石的进变质、峰期和退变质条件分别为600～650℃和9～13kbar、～820℃和～16kbar、～680℃和～7kbar,表明岩石具有一个顺时针型的变质作用P-T轨迹,其峰期发生在高压和高温麻粒岩相条件下,并经历了明显的部分熔融。锆石U-Pb定年表明,岩石的变质作用发生在～89Ma。本文和现有研究结果表明,夕线石榴黑云片岩作为晚白垩世岩基中的包体记录了大体积幔源岩浆岩底垫和增生导致的岩浆弧地壳显著加厚过程,以及加厚弧根的高温和高压变质与深熔作用。     

左权变质杂岩区早前寒武纪变质演化及其构造指示

左权变质杂岩构造上位于华北中部带中南段,向东紧邻赞皇变质杂岩。研究区广泛发育长英质黑云斜长片麻岩和斜长角闪岩,无典型变泥质岩石出露,斜长角闪岩多以似层状或透镜状方式产于似层状的片麻岩中,二者在局部地区侵入接触关系明显。该地区可识别出三期变形作用和三期变质作用,区域片麻理所代表的第二期变形作用(D2)与峰期变质作用(M2)事件相对应。杂岩区含榴黑云斜长片麻岩和含榴斜长角闪岩中较好地保留了多个阶段的变质作用信息,本文重点研究其变质演化过程。含榴黑云斜长片麻岩中仅保留峰期阶段矿物组合,变质条件为730℃/8.5kbar。含榴斜长角闪岩记录了3个阶段的变质矿物组合,第一阶段矿物组合(M1)为进变质矿物组合,以石榴石变斑晶内部的早期包裹体及其临近的石榴石核部为代表,即Grt1+Pl1+Amp1+Qtz±Bt1±Chl1±Ilm±Ap,该阶段的温度和压力范围分别为:608~643℃/5.2~5.5kbar;第二阶段矿物组合(M2)为变质峰期矿物组合,主要由石榴石XMn最低的"边部"和基质矿物(Grt2+Amp2+Pl2+Qtz±Cpx2±Bt2±Ep2±Ilm±Ap)组成。最高变质温度大于670℃,最高变质压力大于9.4kbar。第三阶段矿物组合(M3)为退变质减压矿物组合,其典型代表是石榴石边部发育的Pl3+Hbl3+Cum3+Qtz±Bt3后成合晶矿物组合,呈细粒交生状结构特征,该阶段温压估算范围为:611~627℃/5.1~5.9kbar。左权变质杂岩区岩石变质程度虽明显低于赞皇变质杂岩区(Tmax812℃,Pmax12.5kbar),但两杂岩区岩石拥有类似的变质演化特征,均记录了包含近等温降压型(ITD)退变质片段的顺时针P-T轨迹,指示碰撞造山环境。结合中部带其它杂岩区的变质演化特征,推测左权变质杂岩卷入了晚太古代-早元古代末期华北克拉通东、西部陆块之间的碰撞造山过程。     

内蒙古集宁三岔口夕线堇青石榴二长片麻岩变质作用及年代学研究

三岔口夕线堇青石榴二长片麻岩出露于华北克拉通孔兹岩带东部的集宁变质杂岩中,该岩石保留了典型的减压反应结构。系统的岩相学观察和矿物化学研究结果表明,三岔口地区夕线堇青石榴二长片麻岩保存了两个阶段变质作用的矿物组合及相应的变质反应结构,其中峰期变质阶段M1的矿物组合为石榴石+夕线石+黑云母+石英+斜长石+钾长石+钛铁矿±磁铁矿;峰后减压的M2-1变质阶段矿物组合为石榴石+堇青石+夕线石+石英+斜长石+钾长石+钛铁矿±尖晶石,M2-2阶段的矿物组合为石榴石+堇青石+黑云母+石英+斜长石+钾长石+钛铁矿+磁铁矿±尖晶石。自峰期变质阶段到峰后减压阶段,典型的转变(减压)反应包括:Grt+Sil+Melt→Crd+Bt+Fe-oxide和Grt+Sil→Crd+Spl。相平衡模拟结合传统地质温压计限定峰期变质阶段的温压条件为T=852~862℃,P=9.3~10.2kbar;峰期后近等温减压的M2-1和M2-2阶段的温压条件分别为854~880℃和7.0~7.4kbar,820~848℃和5.3~6.4kbar。三岔口夕线堇青石榴二长片麻岩记录了典型的近等温减压型的顺时针P-T轨迹。阴极发光图像特征显示夕线堇青石榴二长片麻岩存在大量变质锆石,LA-ICP-MS U-Pb定年结果表明,所有变质锆石记录了十分一致的207Pb/206Pb年龄,其变质时代为1912±11Ma。变质作用历史说明内蒙古孔兹岩带东段的集宁地体卷入了华北克拉通西部的阴山陆块和鄂尔多斯陆块之间的俯冲-碰撞,并经历了古元古代(~1912Ma)的麻粒岩相变质作用后快速折返至地表的过程。     

阿尔金淡水泉花岗质高压麻粒岩P-T演化及年代学研究

岩相学研究表明阿尔金南缘淡水泉一带出露的花岗质片麻岩的峰期矿物组合为Grt+Kfs+Ky+Rt+Qz,为典型的高压麻粒岩相矿物组合。利用Thermocalc3.33程序计算的P-T视剖面图和矿物温压计,确定其峰期变质温压条件为T=875~925℃,P=14.5~15.9kbar,该岩石后期还经历了以矿物组合Grt+Kfs+Bt+Pl+Sill+Ilm+Qz为代表的麻粒岩相和以Sill+Bt+Pl+Mu+Qz±Ilm为代表的角闪岩相的退变质作用,具有一个早期快速等温降压,后期近等压降温的顺时针型的退变质P-T演化轨迹。锆石的U-Pb同位素定年结果显示其原岩的时代为866±5Ma,峰期变质时代为505±5Ma。其中该岩石原岩的形成时代与阿尔金及其周缘地区广泛发育的由Rodinia超大陆裂解事件导致的岩浆活动时代一致,而峰期变质时代则与南阿尔金高压/超高压变质岩的峰期变质时代(486~509Ma)一致,说明花岗片麻岩原岩的形成与罗迪尼亚超大陆裂解有关,并在早古生代卷入了陆壳深俯冲事件,构成了南阿尔金高压/超高压变质带的一部分。     

柴北缘早古生代中低压麻粒岩相变质作用——以乌兰地区泥质麻粒岩为例

柴北缘乌兰地区出露有大量早古生代中低压泥质麻粒岩。据岩石学和矿物化学研究,将乌兰地区早古生代泥质麻粒岩变质作用划分为两期。其中峰期变质阶段矿物组合为Grt_1+Bt_1+Sil+Kfs+Pl+Qtz+melt,退变质阶段矿物组合为Bt_2+Ms+Grt_2+H_2O±Pl±Qtz。通过对泥质麻粒岩样品进行锆石LA-ICP-MS U-Pb定年,获得泥质麻粒岩峰期变质时代为(482±3)Ma。为厘清乌兰地区早古生代泥质麻粒岩变质演化历史,揭示麻粒岩变质机制,通过相平衡模拟技术和黑云母Ti温度计,获得乌兰地区早古生代泥质麻粒岩峰期和退变质温压条件分别为:710℃～730℃/5～6.2 kbar和560℃～650℃/5～6.2 kbar。由于岩浆的冷却使其退变质阶段经历等压降温变质作用。     

点苍山变质杂岩新生代变质-变形演化及其区域构造内涵

点苍山变质杂岩体是哀牢山-红河韧性剪切带四个变质杂岩体之一,遭受了多期多阶段变质-变形作用改造。本文重点针对点苍山杂岩的新生代变质-变形作用,尤其是以富铝质高级变质岩即夕线石榴黑云片麻岩和侵位于其中的糜棱岩化细晶花岗质岩石开展了深入研究。对夕线石榴黑云片麻岩的显微构造分析与矿物共生组合研究,确定了高角闪岩相和低角闪岩相变质矿物共生组合,分别为:石榴石(Grt)+夕线石(Sil)+钾长石(Kfs)+黑云母(Bi)+斜长石(Pl)±石英(Q)和夕线石(Sil)+白云母(Ms)+黑云母(Bi)+石英(Q)。对其中的变质锆石进行SHRIMP U-Pb测试,获得了新生代三个阶段的变质作用年龄,即54.2±1.7Ma、31.5±1.5Ma和27.5±1.2Ma.本文还深入研究了侵位于高级变质岩中的一个花岗岩质糜棱岩的宏观与显微构造特点,其LA-ICP-MS年龄为24.4±0.89Ma,代表着同剪切就位花岗质岩浆侵位和结晶年龄。夕线石榴黑云片麻岩中变质锆石从2150～27Ma多期多阶段表观年龄的发育,表明点苍山变质杂岩体具有复杂的构造演化史。点苍山杂岩的多阶段新生代构造-热演化归咎于印度-欧亚板块会聚与碰撞作用(约54Ma)、造山后伸展作用(大约40～30Ma)和沿着哀牢山-红河剪切带大规模左行走滑变形作用(约27～21Ma)。     

甘肃敦煌观音沟地区变质作用初步研究

敦煌东南三危山观音沟地区,出露有石榴斜长角闪片麻岩,岩石中保存了三个阶段的变质矿物组合。进变质阶段的矿物组合(M1)以石榴子石变斑晶中的包裹体矿物组合(Hbl1+Pl1+Qtz1)为代表,形成条件约为550~575℃/5.2~5.7kbar(绿帘角闪岩相)。变质高峰期矿物组合(M2)主要由石榴子石变斑晶和基质矿物(Hbl2+Pl2+Qtz2±Cpx2)组成,形成温度670℃,压力11.9kbar(角闪岩相)。退变质阶段矿物组合(M3)为后成合晶矿物组合(Hbl3+Pl3+Qtz3),形成条件约为590~640℃/4.3~5.9kbar(角闪岩相)。观音沟石榴斜长角闪片麻岩记录了包含进变质、变质高峰、退变质过程的造山过程"西阿尔卑斯"型P-T轨迹,其中退变质阶段具有明显的近等温降压特征。变质作用P-T轨迹指示本地区可能经历了俯冲-碰撞-快速抬升的造山过程。结合年代学资料,该期造山事件可能发生于泥盆纪。     

The nature of fluids during pegmatite development in metamorphic terrains: Evidence from Hamadan complex,Sanandaj-Sirjan metamorphic zone,Iran

In the Sanandaj-Sirjan zone of metamorphic belt of Iran, the area south of Hamadan city comprises of metamorphic rocks, granitic batholith with pegmatites and quartz veins. Alvand batholith is emplaced into metasediments of early Mesozoic age. Fluid inclusions have been studied using microthermometry to evaluate the source of fluids from which quartz veins and pegmatites formed to investigate the possible relation between host rocks of pegmatites and the fluid inclusion types. Host minerals of fluid inclusions in pegmatites are quartz, andalusite and tourmaline. Fluid inclusions can be classified into four types. Type 1 inclusions are high salinity aqueous fluids (NaCl_eq >12 wt%). Type 2 inclusions are low to moderate salinity (NaCl_eq <12 wt%) aqueous fluids. Type 3 and 4 inclusions are carbonic and mixed CO₂-H₂O fluid inclusions. The distribution of fluid inclusions indicate that type 1 and type 2 inclusions are present in the pegmatites and quartz veins respectively in the Alvand batholith. This would imply that aqueous magmatic fluids with no detectable CO₂ were present during the crystallization of these pegmatites and quartz veins. Types 3 and 4 inclusions are common in quartz veins and pegmatites in metamorphic rocks and are more abundant in the hornfelses. The distribution of the different types of fluid inclusions suggests that CO₂ fluids generated during metamorphism and metamorphic fluids might also contribute to the formation of quartz veins and pegmatites in metamorphic terrains.     

变质地质学研究中的一些困难问题

变质地质学研究中,首先需要准确判明变质过程是属于多期或单期、多峰或单峰变质作用。研究中应该对同一研究区不同类型的变质岩石开展综合研究,查明各种变质反应结构,以期对变质反应结构的解释尽可能准确,并对变质反应进行定量论证。同一变质岩内前、后两个世代变质矿物组合之间,并不存在所谓的热力学局部平衡。在应用方面,矿物温度计与压力计属于反演方法,热力学视剖面图模拟属于正演方法。本文指出了它们之间的相同之处和各种区别。众所周知,目前反演出的变质作用压力并无方向性,差异应力对总应力的贡献尚不明朗。最好根据同一视域或同一块变质岩石,来反演变质作用P-T-t轨迹。实际上,P-T-t轨迹一般不应该是圆滑的曲线,其构造意义的解释也还存在不确定性。同一地区变质作用PT条件的突变、P-T-t轨迹的明显差异,表明地质体之间存在断层接触关系。变形作用与变质作用的耦合研究需要加强,变质作用的定年也不能仅仅局限于变质副矿物。特别值得注意的是,同一造山带内范围有限的地域,也未必属于同一变质相系。     

Ordovician igneous and metamorphic units in southeastern Puna: New U–Pb and Sm–Nd data and implications for the evolution of northwestern Argentina

New field, petrological, geochemical, and geochronological data (U–Pb and Sm–Nd) for Ordovician rock units in the southeastern Puna, NW Argentina, indicate two lithostratigraphic units at the eastern–northeastern border of salar Centenario: (1) a bimodal volcanosedimentary sequence affected by low- to medium-grade metamorphism, comprising metasediments associated with basic and felsic metavolcanic rocks, dated 485 ± 5 Ma, and (2) a plutonic unit composed of syenogranites to quartz-rich leucogranites with U–Pb zircon ages between 462 ± 7 and 475 ± 5 Ma. Felsic metavolcanic and plutonic rocks are peraluminous and show similar geochemical differentiation trends. They also have similar Sm–Nd isotopic compositions (T_DM model ages of 1.54–1.78 Ga; ε_Nd(T) values ranging from −3.2 to −7.5) that suggest a common origin and derivation of the original magmas from older (Meso-Paleoproterozoic?) continental crust. Mafic rocks show ε_Nd(T) ranging from +2.3 to +2.5, indicating a depleted mantle source. The data presented here, combined with those in the literature, suggest Ordovician magmatism mainly recycles preexisting crust with minor additions of juvenile mantle-derived material.     

Crustal thickness and VP/VS variations in the Grenville orogen (Ontario, Canada) from analysis of teleseismic receiver functions

We have developed a simple semblance-weighted stacking technique to estimate crustal thickness and average V_P/V_S ratio using teleseismic receiver functions. We have applied our method to data from 32 broadband seismograph stations that cover a 700 × 400 km² region of the Grenville orogen, a 1.2–0.98 Ga Himalayan-scale collisional belt in eastern North America. Our seismograph network partly overlaps with Lithoprobe and other crustal refraction surveys. In 8 out of 9 cases where a crustal-refraction profile passes within 30 km of a seismograph station, the two independent crustal thickness estimates agree to within 7%. Our regional crustal-thickness model, constructed using both teleseismic and refraction observations, ranges between 34.0 and 52.4 km. Crustal-thickness trends show a strong correlation with geological belts, but do not correlate with surface topography and are far in excess of relief required to maintain local isostatic equilibrium. The thickest crust (52.4 ± 1.7 km) was found at a station located within the 1.1 Ga mid-continent (failed) rift. The Central Gneiss Belt, which contains rocks exhumed from deep levels of the crust, is characterized by V_P/V_S ranging from 1.78 to 1.85. In other parts of the Grenville orogen, V_P/V_S is found to be generally less than 1.80. The thinnest crust (34.5–37.0 km) occurs northeast of the 0.7 Ga Ottawa–Bonnechere graben and correlates with areas of high intraplate seismicity.     

High-T phase transition of synthetic ANaB(LiMg)CMg5Si8O22(OH)2 amphibole: an X-ray synchrotron powder diffraction and FTIR spectroscopic study

The synthetic amphibole Na_0.95(Li_0.95Mg_1.05)Mg₅Si₈O₂₂(OH)₂ was studied in situ at high-T, using IR OH-stretching spectroscopy and synchrotron X-ray powder diffraction. At room-T the sample has P2₁ /m symmetry, as shown by the FTIR spectrum. It shows in the OH region two well-defined and intense absorptions at 3,748 and 3,712 cm⁻¹, respectively, and two minor bands at 3,667 and 3,687 cm⁻¹. The main bands are assigned to the two independent O–H groups in the primitive structure. The two minor bands evidencing the presence of small amount of vacant A-site (^A□_0.05). With increasing T, these bands shift continuously and merge into a unique absorption at high temperature. A change as a function of increasing T is revealed by the evolution of the refined unit-cell parameters, whose trend shows a transition to C2/m at about 320–330°C. The spontaneous scalar strain, fitted with a tricritical 2–6 Landau potential, gives a T _c of 325(10)°C (β parameter = 0.27). Comparison with the second-order P2₁ /m ⇔ C2/m phase transition at 255°C for synthetic amphibole ^ANa_0.8^B(Na_0.8Mg_1.2)^CMg₅Si₈O₂₂(OH)₂ indicates that the substitution of Na with Li at the B-sites strongly affects the thermodynamic character and the T _c of the phase transition. The comparison of LNMSH amphiboles with cummingtonitic ones shows that the high-T thermodynamic behaviour is affected by A-site occupancy.     

Equation of state,structural behaviour and phase diagram of synthetic MgFe<Subscript>2</Subscript>O<Subscript>4</Subscript>, as a function of pressure and temperature

The behaviour of synthetic Mg-ferrite (MgFe₂O₄) has been investigated at high pressure (in situ high-pressure synchrotron radiation powder diffraction at ESRF) and at high temperature (in situ high-temperature X-ray powder diffraction) conditions. The elastic properties determined by the third-order Birch–Murnaghan equation of state result in K₀=181.5(± 1.3) GPa, K=6.32(± 0.14) and K= –0.0638 GPa^–1. The symmetry-independent coordinate of oxygen does not show significant sensitivity to pressure, and the structure shrinking is mainly attributable to the shortening of the cell edge (homogeneous strain). The lattice parameter thermal expansion is described by _a0+_a1*(T–298)+_a2/(T–298)², where _a0=9.1(1) 10^–6 K^–1, _a1=4.9(2) 10^–9 K^–2 and _a2= 5.1(5) 10^–2 K. The high-temperature cation-ordering reaction which MgFe-spinel undergoes has been interpreted by the ONeill model, whose parameters are = 22.2(± 1.8) kJ mol^–1 and =–17.6(± 1.2) kJ mol^–1. The elastic and thermal properties measured have then been used to model the phase diagram of MgFe₂O₄, which shows that the high-pressure transition from spinel to orthorombic CaMn₂O₄-like structure at T < 1700 K is preceded by a decomposition into MgO and Fe₂O₃.     

山东半岛基性高压麻粒岩的成因矿物学及变质演化

在山东半岛的平度-莱西-莱阳-烟台一带,广泛出露基性高压麻粒岩,它们呈大小不等的透镜体或不规则脉状体产于TTG片麻岩中,且与超镁铁质岩石密切"伴生"。根据岩相学、矿物相转变、变质反应以及温压条件的系统研究结果,确定山东半岛基性高压麻粒岩经历了四个阶段的变质演化。早期进变质阶段(M1)的标志性矿物组合以石榴石及其内部的细粒单斜辉石+斜长石±石英为特征,记录的温压条件为T=740～770℃、P=0.9～1.0GPa;峰期高压麻粒岩相变质阶段(M2)的矿物组合以基质中石榴石(富Ca核部)+单斜辉石(富Al核部)+斜长石(富Na核部)±石英为特征,记录的温压条件为T=850～880℃、P=1.45～1.65GPa;峰后近等温减压(中压)麻粒岩相退变质阶段(M3),以发生一系列典型减压反应和斜方辉石的大量出现为标志,典型的矿物组合为斜方辉石+单斜辉石+斜长石+磁铁矿±角闪石,记录的温压条件为T=780～830℃、P=0.65～0.85GPa;晚期角闪岩相退变质阶段(M4)以石榴石发生降温反应、形成角闪石+斜长石+磁铁矿±石英等退变矿物组合为特征,记录的温压条件为T=590～650℃、P=0.62～0.82GPa。高压基性麻粒岩的变质演化的P-T轨迹具有顺时针型式,先后经历了近等温减压过程(ITD)和近等压降温过程(IBC)变质演化过程,指示研究区基性高压麻粒岩是古老陆块之间在俯冲-碰撞造山过程中加厚下地壳折返地表的产物。该项成果对于重新认识华北克拉通在早前寒武纪古老陆块的碰撞-拼贴及其演化的动力学过程具有重要科学意义。     

Crustal transect from the North Atlantic Knipovich Ridge to the Svalbard Margin west of Hornsund

The crustal structure along a 312 km transect, stretching from the axial mountains of the North Atlantic Knipovich Ridge to the continental shelf of Svalbard, has been obtained using seismic reflection data and wide angle OBS data. The resulting seismic V_p and V_s models are further constrained by a 2-D-gravity model. The principal objective of this study is to describe and resolve the physical and compositional properties of the crust in order to understand the processes and creation of oceanic crust in this extremely slow-spreading counterpart of the North Atlantic Ridge Systems. V_p is estimated to be 3.50–6.05 km/s for the upper oceanic crust (oceanic layer 2), with a marked increase away from the ridge. The measured V_p of 6.55–6.95 km/s for oceanic layer 3A and 7.10–7.25 km/s for layer 3B, both with a V_p/V_s ratio of 1.81, except for slightly higher values at the ridge axis, does not allow a clear distinction between gabbro and mantle-derived peridotite (10–40% serpentized). The thickness of the oceanic crust varies a lot along the transect from the minimum of 5.6 km to a maximum of 8.1 km. The mean thickness of 6.7 km for the oceanic crust is well above the average thickness for slow-spreading ridges (<10 mm/year half-spreading rate). The areas of increased thickness could be explained by large magma production-rates found in the zones of axial highs at the ridge axis, which also have generated the off-axial highs adjacent the ridge. We suggest that these axial and off-axial highs along the ridge control the lithological composition of the oceanic crust. This approach suggests normal gabbroic oceanic crust to be found in the areas bound by the active magma segments (the axial and off-axial highs) and mantle-derived peridotite outside these zone.     

扬子克拉通古元古代变质演化——来自黄陵穹窿石榴斜长角闪岩的证据

为探讨扬子克拉通古元古代变质作用特征及其形成的构造背景,对黄陵穹窿北部石榴斜长角闪岩开展了岩相学、地球化学和年代学研究。结果表明,石榴斜长角闪岩中主要矿物有石榴子石、斜长石、角闪石、单斜辉石、石英、钛铁矿等,其中保留有3个阶段的不同变质期次的矿物组合,进变质矿物组合为角闪石+斜长石+石英+钛铁矿,峰期矿物组合为石榴子石+角闪石+斜长石+单斜辉石+石英+钛铁矿,退变质矿物组合为石榴子石+角闪石+斜长石+石英+钛铁矿。石榴斜长角闪岩原岩为亚碱性玄武岩,属于拉斑系列,Mg^#较低,表明其原岩经历了一定程度的分异作用。使用传统地质温压计计算不同变质阶段的温压条件分别为：进变质阶段,t=596～625℃,p=0.70～0.82 GPa;峰期变质阶段,t≈760℃,p≈1.35 GPa;退变质阶段,t=692～738℃,p=0.68～0.74 GPa,并建立了一条顺时针的p-t轨迹,显示出先升温升压至峰期阶段,随后发生近等温减压的过程。这一p-t轨迹体现了汇聚板块边缘俯冲-碰撞的构造背景,对石榴斜长角闪岩中的锆石进行U-Pb定年,获得了2 008±11 Ma的谐和年龄,并结合该...