莱州海水入侵分析与防治研究

山东省莱州湾是中国最早发现海水入侵现象的沿海地区之一,由于地下水大量超采,造成较大范围的海水入侵,给工、农业生产和人民生活造成了极大危害.通过对多年资料的分析,较系统地分析了海水入侵的原因,并提出了诸多工程和非工程措施,对防止海水入侵取得了明显效果.     

基于GIS的海水入侵危险性评价方法——以深圳市宝安区为例

在总结前人关于海水入侵危险性评价研究的基础上,提出了基于GIS的层次分析法和模糊综合评判法,并以深圳市宝安区为例建立了海水入侵危险性评价体系.首先研究了宝安区海水入侵现状;然后选取了含水层结构、地下水氯离子质量浓度、地下水水位、地形地貌、与海岸线距离、地下水开采、土地利用类型7个评估因子;再利用层次分析法确定了各评估因子的权重,根据模糊综合评判法的原理,经过模糊运算得到危险性级别;最后运用GIS空间分析功能实现了海水入侵灾害危险性区划.结果表明:评价结果与该地区的海水入侵现状吻合较好.高危险区和较高危险区面积达107.77 km2,占研究区总面积的46.7%.     

用氢氧稳定同位素揭示闽江河口区河水、地下水和海水的相互作用

为了揭示闽江河口两岸的地下水形成演化规律以及河口区河水、地下水和海水的相互作用, 分别于2009年枯水期(10至11月)和2010年丰水期(7至8月), 在闽江河口区采集了河水、地下水和海水样品, 测定了水样的氢氧稳定同位素组成和盐度。研究结果表明: (1)闽江河口两岸的浅层地下水主要接受降水补给, 北岸地下水还接受山区基岩裂隙水补给, 南岸浅层地下水在枯水期还接受经过蒸发作用的灌溉水补给; (2)闽江河口区, 枯、丰水期河水与地下水的补排关系始终表现为地下水补给河水, 枯水期南岸地下水在河口混合中的贡献明显增大; (3)海岸带含水层基本上不存在海水入侵, 仅局部含水层有微弱的海水入侵迹象; (4)丰水期和枯水期的淡咸水混合带在河口中的位置和混合类型存在明显差异。     

海水入侵湛江市地下水的可能性及预防对策

预防海水入侵，是沿海城市开发利用地下水必须重视和研究的重要问题。根据湛江市区域水文地质条件、地下水运动的基本规律，结合开采现状及近年来地下水动态监测资料，运用地下水动力学的基本原理，对海水入侵湛江市地下水的可能性进行了探讨。认为，海水入侵地下水有湛江内港海水垂直入侵和中、深层承压水咸淡水过渡带外围咸水的水平入侵两种可能的方式。在分析两种入侵方式发生和发展条件的基础上，提出了合理开发水源、预防海水入     

广西北海市海城区西段含水层海水入侵地球化学过程研究

广西北海市海城区西段地下含水层出现过海水入侵.海水入侵过程中可能发生哪些地球化学作用是人们关注的问题.本文运用绘制Piper图、理论混合线(TML)、计算离子delta值和饱和指数SI以及水文地球化学模拟等方法研究了该区含水层在海水入侵后发生的地球化学作用.通常海水入侵后地下水含水层容易发生白云岩化作用,要通过模拟计算...     

变质岩山丘区裂隙水海水入侵监测技术研究——以荣成市俚岛镇为例

我国沿海地区海水入侵现象频繁出现,海水入侵的相关研究对沿海地区社会经济的可持续发展具有重要的理论意义和实际价值。受地质条件的影响海水入侵方式呈多样性,主要包括层状第四系松散沉积物分布区的孔隙式层状入侵和构造裂隙发育分布区的脉状入侵形式。海水入侵监测在预测地下水水质条件及评价管理沿海地区含水层过程中是必不可少的,因此构建科学的海水入侵动态监测系统是防治海水入侵的重要技术途径。本文通过对荣成市俚岛镇变质岩山丘区裂隙水海水入侵现状和监测中存在问题的进行分析,根据"点-面结合"、"直接-间接结合"的监测原则提出了地下水海水入侵监测系统的布局,为俚岛镇地下水的持续利用与保护提供基础信息和依据。     

海水入侵模拟方法VFT3D及应用

海水入侵是困扰沿海地区经济社会发展的重大资源、环境问题,严重影响沿海地区地下水资源。定量模拟、预测和可视化管理是对海水入侵进行有效监测和机理分析的重要手段。基于前期海水入侵模拟的理论研究及方法,提出了海水入侵模拟及预测模型VFT3D,该模型综合考虑地表水-地下水对海水入侵的协同控制作用,能够模拟变密度地下水流及复杂反应性迁移,实现模拟海水入侵的完整水文循环过程。文章介绍了VFT3D模型,利用VFT3D模型模拟了一个海水入侵案例,并与SEAWAT模型模拟结果进行了对比分析。结果表明VFT3D 模型模拟水头与SEAWAT模型模拟结果相差不大,但SEAWAT模型无法模拟海水入侵中复杂的化学反应过程。VFT3D 模型模拟发现,水文地球化学过程（阳离子吸附交换作用）对阳离子（Na+、K+、Mg2+和Ca2+）运移产生明显影响,同时引起过渡带中离子组分浓度发生变化,对海水入侵过程产生较大影响。因此,考虑变密度和复杂反应过程,才能更加准确地描述海水入侵,从而有利于地下咸水治理工程的科学实施。     

基岩海岛地下水与海水相互作用研究

中国北方基岩海岛水文地质条件独特,气候变化和人类活动不同程度地影响着海岛地下水与海水相互作用过程,然而对包括海水入侵(SWI)和海底地下水排泄(SGD)的水文过程的定量认识比较缺乏。本研究基于2012—2016年我国北方某基岩群岛降水、地下水水位、水质动态监测数据,运用数理统计、空间插值和水力学方法,分析了基岩海岛地下水与海水相互作用的特征和影响因素。结果表明,降水和开采是影响地下水、海水相互作用的主要因素,地下水水位变化滞后于降水事件约10 d;南岛东北岸、南岸的大部分地区没有发生海水入侵,地下水向海排泄过程较稳定,2012—2016年SGD速率均值为0.2 m/d,向海NO₃^-N通量均值为81.8 mmol/(m²·d);北岛东南地区是海水入侵的严重区域,地下水水位长期低于海平面且逐年下降,2012—2016年SWI速率均值为0.3 m/d,向陆NO₃^-N通量均值为69.6 mmol/(m2·d)。分别计算南、北两岛枯水季(2014年4月)、丰水季(2013年9月)SGD水...     

构建以预防海水入侵为重点的湛江市区地下水动态监测系统

通过对湛江市区地下水开采和监测现状的分析,指出了湛江市地下水现有监测系统存在的主要问题;根据地下水(主要为中、深层承压水)区域降落漏斗的形态特征,提出了将地下水监测由控制区域降落漏斗发展调整到以预防海水入侵为重点的布局方案,以确保湛江市区地下水资源合理开发利用和有效保护.     

河北省秦皇岛市海水入侵地质灾害及其防治措施

随着秦皇岛地区人口增加、经济发展,地下水的开采日益加大,沿海地区由此产生的海水入侵现象较为普遍。海水入侵也是一种地质灾害,如何防止海水入侵是广大地质工作者和相关科技人员所要解决的问题。本文在分析了本地区海水入侵分布规律、发生原因及产生机理的基础上,提出科学管理地下水开采、引调客水补充地下水以及修建拦潮坝等多种举措防治海水入侵。借鉴国内外成熟的经验和方法,修建拦水坝拦潮蓄洪是治理海水入侵行之有效的方法。同时指出,修建梯级多道拦水坝逐级提高河水位强化对地下水的补给是治理海水入侵的一种新的尝试。     

福建盐田海水补给型地热系统地球化学特征及其成因

海水补给型地热系统具有补给资源量大,但温度低、水质咸化等特点,查明沿海地热水循环补给条件和成因机制,对东南沿海地热资源的合理开发利用和保护具有重要意义。在泉州官桥盐田地热区分别采集了地热水、地下水和海水样品14个,利用水化学同位素特征分析和地球化学温标法,揭示了官桥盐田地热水循环补给和地热资源成因机制。结果表明：地热水水化学类型为Cl—Na型水,与海水水化学类型一致;H01和H02的溶解性固体总量（TDS）分别为2 610 mg/L和3 090 mg/L,地下水以TDS小于400 mg/L的HCO3—Na型水为主;地热水富集Br-,地下水中Br-未检测,表明盐田地热水存在现代海水或者海相沉积层古海水补给。根据盐田地热田H01和H02地热水Cl-混合模型计算,地热水H01海水混入比为9.13%,H02海水混入比为10.76%,显示H01在出露于第四系地层后混入了更多的地下水。综合分析认为,海水是盐田地热水的重要补给资源,地热水化学组分受海水混合作用影响明显,深层热水上升过程中存在两次或者多次地下水或者海水混入从而形成浅层热储,采用SiO2地热温标和多矿物平衡法估算的浅层热储温度在89～1...     

大西洋洋中脊TAG热液区中块状硫化物的Os同位素研究

新测得TAG热液区中5件海底块状硫化物样品的锇含量及其同位素组成,187Os/186Os比值在2.305～7.879之间,均值为5.986,介于现代海水和上部洋壳岩石的锇同位素组成之间,表明该区海底块状硫化物中锇是海水和上部洋壳来源锇混合的产物.在海底热液循环过程中,海水的混入对该区热液流体的Os浓度及其同位素组成产生了明显的影响。     

海岛环境下地下水封油库海水入侵数值模拟研究

海水入侵是影响海岛地下水封油库施工及运营安全的重要因素。海岛环境下建设地下水封油库,大规模的地下开挖将显著改变海岛天然地下水渗流场,海水入侵地下洞室一方面引发突水风险,另一方面海水中的氯离子将会对地下洞库结构设施造成侵蚀,影响地下油库的使用寿命。因此在海岛环境下建造地下水封油库,除了需要考虑水封可靠性与岩体稳定性外,还需要关注海水入侵等现象。科学设置水幕系统可以有效地减弱海水入侵风险,论文基于污染质运移相关理论,采用有限元数值模拟方法,以拟建浙江省舟山市某海岛大型地下水封油库为例,模拟了地下油库建造及运营期的海水入侵现象,研究表明:若不设置淡水水幕系统,开挖地下洞室会直接导致海水入侵;设置水平水幕后在确保水封可靠性的前提下,能在一定程度上减弱海水入侵;而设置垂直水幕系统则能较为明显地抑制海水入侵的发生。该成果为海岛环境下建造地下水封油库可能遇到的海水入侵问题研究提供了理论依据。     

海水层对海洋大地电磁勘探的影响研究

为了研究海水层对大地电磁测深的影响,建立了一维层状模型并进行计算。结果表明,海水层对电磁场的影响特征主要表现为高频段的影响大于低频段,磁场的影响大于电场,相位的影响大于振幅。针对海洋大地电磁测深中使用远参考道问题,设计了三种二维地电模型(取参考点位于陆地或海底,测点位于海底),并对三种模型的大地电磁响应进行了有限单元法数值模拟,通过异常对比研究表明,在海洋大地电磁测深中可以使用远参考道,获得海底深部介质的地电信息。     

Hydrogeochemical modelling of fluid–rock interactions triggered by seawater injection into oil reservoirs: Case study Miller field (UK North Sea)

A hydrogeochemical model is presented and applied to quantitatively elucidate interdependent reactions among minerals and formation water–seawater mixtures at elevated levels of CO₂ partial pressure. These hydrogeochemical reactions (including scale formation) occur within reservoir aquifers and wells and are driven by seawater injection. The model relies on chemical equilibrium thermodynamics and reproduces the compositional development of the produced water (formation water–seawater mixtures) of the Miller field, UK North Sea. This composition of the produced water deviates from its calculated composition, which could result solely from mixing of both the end members (formation water and seawater). This indicates the effect of hydrogeochemical reactions leading to the formation and/or the dissolution of mineral phases.     

The chemistry of lava-seawater interactions II: the elemental signature

The flow of lava into the ocean at the shoreline of Kilauea Volcano during the ongoing Pu’u O’o eruption has allowed a detailed study of the geochemical interaction between lava and seawater. This paper focuses on the chemistry of the major and minor elements in the fluids that resulted from this interaction. The elemental enrichments in these fluids are dominated by three processes: (1) evaporation of water from seawater, which creates solutions enriched in the major elements found in seawater, (2) congruent dissolution of the basalt glass matrix, which is limited by the solubility of some of the elements in seawater, and (3) removal of volatile phases from the lava on contact with seawater.Using a simple model of volatile emanation (using published emanation coefficients) and congruent dissolution, we are able to explain the concentrations observed for the majority of elements in precipitation from the steam plume at the shoreline lava entry and in water allowed to interact with molten lava in controlled experiments. Fe, Al, Ti, and some of the rare earth elements (REEs) in precipitation samples from the steam plume at the lava entry were > 10,000-times enriched over their ambient seawater concentrations, suggesting that these elements may be useful for identifying submarine eruptions. The flux of elements from the Kilauea ocean lava entry is greater than that from a typical midocean ridge hydrothermal vent field for Al, Cd, Co, and the REEs, whereas the opposite is true for the remainder of the elements studied.     

海入水侵的动态监测指标研究

本文经多次试验，在大量实测数据基础上，首次提出监测海水入侵发展的两项明确指标，即以特征离子比值为主体的水化学监测指标和电阻率，充电率为主体的物探监测指标，同时，对指标间的相互对应关系及应用事项进行了具体阐述。     

Modeling of seawater intrusion in a coastal aquifer of Karaburun Peninsula,western Turkey

Seawater intrusion is a major problem to freshwater resources especially in coastal areas where fresh groundwater is surrounded and could be easily influenced by seawater. This study presents the development of a conceptual and numerical model for the coastal aquifer of Karareis region (Karaburun Peninsula) in the western part of Turkey. The study also presents the interpretation and the analysis of the time series data of groundwater levels recorded by data loggers. The SEAWAT model is used in this study to solve the density-dependent flow field and seawater intrusion in the coastal aquifer that is under excessive pumping particularly during summer months. The model was calibrated using the average values of a 1-year dataset and further verified by the average values of another year. Five potential scenarios were analyzed to understand the effects of pumping and climate change on groundwater levels and the extent of seawater intrusion in the next 10 years. The result of the analysis demonstrated high levels of electrical conductivity and chloride along the coastal part of the study area. As a result of the numerical model, seawater intrusion is simulated to move about 420 m toward the land in the next 10 years under “increased pumping” scenario, while a slight change in water level and TDS concentrations was observed in “climate change” scenario. Results also revealed that a reduction in the pumping rate from Karareis wells will be necessary to protect fresh groundwater from contamination by seawater.     

Seawater intrusion in Syrian coastal aquifers, past, present and future, case study

Overexploitation of shallow aquifers on the Syrian coast, north of Latakia (Damsarkho) for irrigation and tourism has caused an intrusion of seawater. The seawater intrusion into this aquifer has been presented by a three-dimensional finite element model using the FEFLOW numerical code. This conceptual model is based on field and laboratory data collected during the period 1966–2003. Meteoric infiltration and flows from the adjoining carbonate aquifer recharge the aquifer; natural outflow occurs through a diffuse flow into the sea; and artificial outflow occurs through intensive extraction of groundwater from wells. Water exchanges in the aquifer occur naturally (leakage) and artificially (multi-screened wells). The model was calibrated for transient conditions. The model helped establish that seawater intrusion is essentially due to withdrawals near the coast during the irrigation season and that it mainly occurs in the Damsarkho plain. The effects of hypothetical aquifer exploitation were assessed in terms of salt budget.     

An Review of the Strontium Isotopic Vomposition of Phanerozoic Seawater

Strontium isotopic evolution of the Phanerozoic seawater is an emerging research field of the material cycle in the Earth’s outer-spheres. It is greatly significant for the research of the environmental change on the Earth’s surface during the geological history. The researches of the strontium isotopic evolution of the Phanerozoic seawater have gone through three stages: The early stage, the accumulated stage, and the integrated stage. In the early stage, the primitive evaluation of the diagenetic alteration and the low precision of the analytical instruments resulted in most strontium isotope data without stratigraphic significance. Most researches were only at the initially exploratory stage. In the accumulated stage, the gradually mature evaluation of the diagenetic alteration and higher precision of the analytical instruments made ongoing progress in the researches, especially the establishment and development of the high-resolution strontium isotopic evolution curves of the Cenozoic seawater had spawned a new interdisciplinary branch: Strontium isotope stratigraphy. In the integrated stage, the accumulated high-quality strontium isotope data had been integrated into some strontium isotope database of Phanerozoic seawater. These databases are becoming one of the effective tools to solve the problems in the stratigraphy, petrology, ore deposit, hydrology, and other related applications. Currently, many problems still have not been satisfactorily resolved in the researches of the strontium isotopic evolution of the Phanerozoic seawater, such as the preservation differences of the original seawater information in a sample, the age of uncertainty of samples, lower dating accuracy of more ancient samples, the materials and stratigraphic questions of the Cambrian samples, trace rubidium contamination of samples, the isotope fractionation between ⁸⁶Sr and ⁸⁸Sr, the interlaboratory bias, the uncertainty of the data fitting, etc. These problems are the difficulties to possess more practicability and applicability of strontium isotope stratigraphy. Based on the summary of the research progress, we attempted to systematically summarize the stages and differences of the researches of strontium isotopic composition of Phanerozoic seawater at different periods. We wish this paper offer some perspective to the researches of strontium isotopic composition of Phanerozoic seawater in future.