流化床混凝装置中多级速度梯度的建立及其对混凝反应的影响

利用不同性质颗粒在流化状态下可实现自然水力分级的特征,在流化床反应器中沿水流方向实现了多级速度梯度的建立。在研究流化床混凝反应器的混凝动力学特征基础上,探讨了以800 μm和1 200 μm树脂颗粒为固相的多级速度梯度流化床（MGF）的速度梯度分布特征、混凝效率和絮体形态特征,并与以1 200 μm树脂颗粒为固相的单级速度梯度流化床（SGF）进行了对比研究。结果表明：与单级速度梯度相比,多级速度梯度可为胶体或微颗粒的高效碰撞和絮体再增长创造更适宜的环境,有助于形成尺寸更大、密度更大的絮体,提高了絮体的可沉降性;MGF在处理人工配置的高岭土悬浊液和分散红染料废水时,混凝效率比SGF分别提高了2%～4%和7%～20%。     

弹丸侵彻高强度混凝土的高速摄影试验研究

采用高速摄影仪,拍摄轻气炮中弹丸对侵彻面不同侵角的高强度混凝土靶体的侵彻过程,分析靶体侵角、弹丸着靶速度对弹丸侵彻靶体的运动特征。研究结果表明,弹丸以200 m/s左右的低速侵彻靶体时,弹丸在侵彻角度为0°的靶体中作水平运动,靶体侵角大于0°时,弹丸均在着靶后150～200 μs发生偏转;弹丸在靶体中的水平侵彻速度、偏转角度与其侵彻时间有很好的相关性,靶体侵角一定时,弹丸着靶速度越小,弹丸水平侵彻时所需时间越短,靶体飞溅物的速度越小;靶体侵彻面角度对靶体飞溅物速度和弹丸水平侵彻时间的影响作用相对比弹丸着靶速度的大,说明靶体侵角的大小是安全防护工事中不可忽视的重要问题。     

连续流气提式流化床启动过程中好氧颗粒污泥的形成机制

探讨连续流气提式好氧颗粒污泥流化床(CAFB)反应器的运行特征,对该工艺颗粒污泥形成过程、形成机理和颗粒性质进行分析。以市政污泥为接种污泥,以醋酸钠为碳源,在连续运行方式下培养好氧颗粒污泥。研究结果表明：CAFB反应器启动的第4－5天即有大量颗粒污泥形成,颗粒直径800~1 000 μm,比重1.006,生物相丰富,能够分泌大量胞外聚合物。当COD有机负荷高达8 和13 kg/(m³·d)时,对COD处理效率均维持在93%~97%,COD出水质量浓度仅为30~80 mg/L,引起启动后期丝状菌的大量繁殖,污泥流失。进一步提高污泥负荷有望控制污泥膨胀。     

水力紊动条件对泥沙絮体分形结构的影响

在含沙量为85 kg/m3的悬浊液中投加阳型高分子聚合物,改变水力紊动条件:剪切速率(r)或速度梯度(G)与剪切时间(t),借助沉降技术、图像分析技术及分形特性定量表征参数“分维”探讨了架桥絮体结构的演变规律,得出分形结构达最佳状态时的水力紊动强度(Gt)值存在两个临界值:快速絮凝阶段和慢速絮凝阶段。实验发现,不同含沙量架桥絮体分形结构致密度最高时所需的最佳Gt值相近。含沙量越低,r或G值应降低,t值增加,分维值降低。另外,相同含沙量无机混凝剂絮体与高分子架桥絮体分形结构达最佳时,前者所需Gt值高,对应的G值低,t需延长,絮体平均质量分维(D₃)值高,但絮体结构脆弱。     

黄河沉积物中稀土元素(REE)组成的粒度效应*

依据Stokes颗粒沉降原理将黄河利津水文站和汊河清八站的表层沉积物分别提取为<2μm,2~4μm,4~8μm,8~16μm,16~32μm和32~63μm的6个粒级,采用ICP-MS法对各个粒级沉积物的15个稀土元素进行测试。结果表明:黄河沉积物两个样品REE含量随粒度增大的变化趋势有细微差别,但总体随粒度大小呈"高—低—高"的不对称马鞍型分布,其中最高REE含量和最低REE含量分别位于<4μm的粘土粒级和4~16μm细粉砂粒级中; 各粒级沉积物经北美页岩标准化后,REE的配分模式一致,呈平缓的右倾型,相对富集轻稀土,明显的Eu正异常和Ce负异常。对各个粒级样品进行X射线衍射分析及体视镜下观测,石英含量随粒级增大而增加, 长石在8~16μm中含量最高,在16~32μm中,碳酸岩含量最高,随着粒级增大,重矿物含量逐渐增加,黄河沉积物REE随粒度的变化特征与粘土矿物对其吸附及流域碎屑沉积物不同粒级的矿物成分密切相关。     

泥石流浆体与大颗粒冲击力特征的试验研究

开展了密度为1 400～2 200 kg/m3的泥石流浆体、浆体与大颗粒混合流体的冲击力试验,获取了流速为2.8～4.9 m/s条件下31组冲击力试验数据。采用小波分析方法有效地去除了冲击力数据中的噪声信号,依据离散傅里叶变换（FFT）为基础的频谱分析结果,将低频泥石流浆体冲击和高频大颗粒冲击的临界频率值界定为2 Hz,实现了浆体和大颗粒冲击信号的分离。目前水动力学公式中待定系数α缺乏统一的确定方法,以不同地区157组泥石流观测和试验数据为基础,建立了待定系数?与流体Fr数的幂函数关系,形成可表征不同流态,且弱化尺度效应的浆体动压力计算公式。与泥石流浆体平滑信号相比,大颗粒冲击压力具有一定随机性。泥石流大颗粒冲击次数与频率随大颗粒的质量比增加而增大,其质量比从0.05增至0.21时,冲击总次数从1 305次增至2 838次,冲击频率从82次/s增至195次/s,且龙头段大颗粒的冲击频率高于后续泥石流体。测得大颗粒的压力约为60 kPa,是相同密度和流速下浆体动压力的3倍。随着大颗粒比例的增加,上部1#和2#传感器测得大颗粒冲击频率增加量明显高于下部3#～6#。说明随着流体中大颗粒比例上升,颗粒物质多集中于泥石流上部或表层运动,也佐证了泥石流运动中大颗粒多集中在龙头顶部的认识。对大颗粒和浆体冲击规律的分析可为固液两相流运动机制研究和防治工程设计以及承灾体易损性定量评估提供合理参数。     

激发极化法在吉林安图刘生店钼矿的应用

为了在吉林东部覆盖较厚地区寻找深部隐伏矿体, 在安图刘生店钼矿勘查中利用中间梯度装置激发极化法扫面, 发现了极化率为1.88% ～4.61%、电阻率为300～500Ω ·m的高极化率低阻异常。异常体上对称四极装置激电测深结果表明: 3勘查线极化体顶面埋深20 ～30 m, 底面埋深150～170 m; 11勘查线极化体顶面埋深为25～65 m, 底面埋深> 200 m。经钻探工程验证, 钼矿体的形态、产状、顶、底板的埋深与异常解译成果基本吻合。     

不同粒度颗粒在非恒定管流中跟随性试验

管道中固液两相流水击对管道和输送系统可能产生严重的破坏,而固液两相在这种非恒定流中的运动特性是计算最大水击压力变化的重要依据。采用粒子图像测速技术（Particle Image Velocimetry,PIV）,通过试验研究水击发生时,水平圆管中不同平均流速、颗粒粒径条件下,流体介质和粗颗粒在管道断面的速度分布以及粗颗粒跟随性的变化规律。研究结果表明:①在水击发生的不同时刻,圆管流中粗颗粒的流速在管道断面分布呈不规则的抛物线型分布,主要表现为靠近管道壁面底部的颗粒流速略小于靠近管道顶部流速,当颗粒粒径大于1.5 mm,平均流速小于2.5 m/s时,粗颗粒表现出明显的沉降特性;②粗颗粒的跟随性与颗粒受力有密切关系,其中颗粒速度与流体速度的变化量是影响颗粒受力的重要参数;③基于试验数据拟合得到了水击条件下粗颗粒跟随性系数k的经验公式,并分析了颗粒粒径、管道直径、两相流平均流速以及水击发生时间等不同参数对粗颗粒跟随性系数的影响,公式计算值与实测值之间的误差在5%以内。     

高速远程滑坡超前冲击气浪三维动力学分析

为研究沟谷多级折射高速远程滑坡超前冲击气浪的特征,以牛圈沟滑坡三维地形形态为原型,采用CFD软件,引入Voellmy准则定义运动阻力,在反演碎屑流运动全过程的同时,对其冲击气浪的流场特征进行了数值模拟,分析其形成的动力学机制。结果表明：(1) 牛圈沟滑坡从启动到停止历时为119 s,最大速度出现在滑体内部靠近前缘处,峰值分别为14 s的52 m/s、27 s的55 m/s和50 s的49 m/s。(2) 气浪速度的最大值50 s时为38 m/s,其压强的最大值达657 Pa,相当于11级暴风。(3) 当碎屑流前方出现高大的障壁时,来不及扩散的高压气流产生极为明显的压强梯度;当其前方遇跌坎或翻越山脊冲向山坡下方在其速度瞬间增大的同时,强烈压缩前方空气并导致其压强值局部出现陡增。     

北京市昌平区钻孔岩芯的磁化率与粒度组份变化的相关性研究

以昌平区钻孔岩芯为例,分析沉积物粒级组分与磁化率大小变化的相关性。从厚约150 m的剖面选取590多个样品,分别测试从0.5~500 μm各个粒度区间颗粒的百分含量和磁化率。通过计算它们之间的相关关系,认为湖相沉积物磁化率的变化与0.5~30 μm间细粒物质的含量,特别是与0.5~10 μm区间悬浮物质的含量反相关,而与65~500 μm间较粗粒物质的含量正相关。这种相关性与黄土沉积刚好相反,反映了二者之间磁化率不同的变化机制, 蕴涵着一定的古气候信息。     

紊流对粘性细颗粒泥沙絮凝影响

以分形聚集生长模型为基础,通过三维模拟泥沙颗粒在布朗运动、重力沉降和紊流作用下的碰撞、粘结和破碎过程,探讨了紊流对粘性细颗粒泥沙絮凝速度、絮团平均粒径及分形维数的时空影响。试验结果表明:紊流作用下,泥沙絮凝及絮团平均粒径的变化可分为加速段、等速段和减速段,絮凝等速段的作用时间及粒径等速增长段的速度均随紊动强度呈先增后减的规律,且中部区域的絮凝速度和絮团平均粒径较小;泥沙絮团分形维数随水流紊动强度的增加逐渐增大,最终趋于稳定,随时间呈先减后增的规律。模拟空间下部区域分形维数最大,上部次之,中部最小。     

三峡库区泥沙絮凝临界条件现场测量

三峡库区絮凝现象是细颗粒泥沙淤积的重要原因,泥沙絮凝临界条件对三峡库区泥沙淤积规律和模拟具有重要意义。在三峡库区忠县和奉节河段开展泥沙絮凝的现场测量,基于声学多普勒流速仪（Acoustic Doppler Velocimeter,ADV）和泥沙采样测得同步的瞬时流速和含沙量,通过泥沙扩散理论反算现场泥沙沉速及絮团粒径,得到了三峡库区泥沙絮凝度及其与粒径、流速和含沙量的关系。结果表明:库区细颗粒泥沙发生絮凝,且多为中轻度絮凝,重度絮凝较少;库区泥沙絮凝的临界粒径约为0.018 mm,临界流速约为0.7 m/s,临界含沙量约为0.8 kg/m3。研究结果可为三峡库区泥沙的运动规律以及泥沙淤积模拟等提供一定的理论支撑。     

The prodelta environment of a fjord: suspended particle dynamics

The dynamics of suspended particles within a fjord's estuarine circulation are investigated and the results compared with larger non-enclosed prodelta environments. In the upper prodelta, the seaward-flowing river plume flows over the ambient marine water depositing much of the initial riverine suspended load. Sedimentation is dominated by coarse silt and fine-grained sand particles with coarseness determined by the tidal and fluvial stage. Particles less than 10 μn have similar settling velocities regardless of size because they settle in flocs: the settling velocity at a water depth of 5 m is 30 m day^-1 and increases with depth so that at 30 m the particles settle at 100 m day^-1. For larger particles, the downward settling velocity enhancement due to flocculation decreases with increasing grain size. Hydraulic sorting allows the preferential settling of feldspar and quartz over mica. Particle dynamics in the lower prodelta are dependent on the character of the freshwater wedge that thins seaward of the upper prodelta. The vertical flux of particles is controlled by biogeochemical interactions such as pelletization of fine particles and flocculation (which occurs within rather than below the surface layer in contrast to the upper prodelta). The pellets are produced by indiscriminate filter feeding zooplankton. Across the lower prodelta the suspensate character, recognized in the composition of both flocs and pellets, changes from a dominance of mineral grains to that of autochthonous organic matter. The interaction of bacteria with the suspended particles increases with depth and seaward distance. At depth, the mucoid filaments form stable interconnecting webs. Particle concentration in the surface layer decreases at a rate proportional to the negative one-half and three-halves power of the distance seaward over the upper and lower prodelta, respectively. This relationship is hypothesized as being universal for large marine deltas dominated by buoyancy flow dynamics, regardless of the levels of initial riverine particle concentration or their composition.     

Drying by fluidized bed that contains inert particles

The method of drying by a fluidized bed that contains inert particles was used to dry slurries of sodium chloride, limestone, clay, and a 50 - 50 wt.% mixture of clay and limestone. The slurries were prepared by mixing specified weights of the material with a specified weight of distilled water. The slurry was fed into the air-fluidized bed either by the use of compressed air or the use of a sectorized feeder. The bed contains fluidized inert particles on which the slurry was dried. The inert particles used here were sand particles. The drying rate of the slurries depends on a number of factors. These factors are air mass velocity, air inlet temperature, latent heat of vaporization and the logarithmic-mean temperature difference. Combining these factors a general drying rate equation was obtained. The results were compared with method of drying by through-circulation; drying by fluidized bed was far better.     

陕西旬邑新近系红土剖面粒度组成的古气候意义

陕西旬邑下墙新近系红土的粒度组成中,粗颗粒含量在剖面中的变化不大,<2 μm粘土粒含量有较大幅度的波动。结合其他因素分析推断,可能与当时青藏高原已升至有意义高度,冬、夏季风已初步形成,但都较弱,其中夏季风相对强一些,气候以暖湿为主,在暖湿的背景上,还存在凉干与暖湿的交替。在新近系距今 5.2Ma前后,可能有一次较明显的降温与变干。粒度曲线变化最显著的是由新近纪进入第四纪后,曲线上粗颗粒含量明显增加,<2 μ粘土粒含量明显减少,曲线由高频低幅突然变为低频高幅。这很可能主要与青藏高原在第四纪初发生剧烈隆升有关。     

Flocculation Potential of Estuarine Particles: The Importance of Environmental Factors and of the Spatial and Seasonal Variability of Suspended Particulate Matter

Estuarine systems are complex environments where seasonal and spatial variations occur in concentrations of suspended particulate matter, in primary constituents, and in organic matter content. This study investigated in the laboratory the flocculation potential of estuarine-suspended particulate matter throughout the year in order to better identify the controlling factors and their hierarchy. Kinetic experiments were performed in the lab with a “video in lab” device, based on a jar test technique, using suspended sediments sampled every 2 months over a 14-month period at three stations in the Seine estuary (France). These sampling stations are representative of (1) the upper estuary, dominated by freshwater, and (2) the middle estuary, characterized by a strong salinity gradient and the presence of an estuarine turbidity maximum. Experiments were performed at a constant low turbulent shear stress characteristic of slack water periods (i.e., a Kolmogorov microscale >1,000 μm). Flocculation processes were estimated using three parameters: flocculation efficiency, flocculation speed, and flocculation time. Results showed that the flocculation that occurred at the three stations was mainly influenced by the concentration of the suspended particulate matter: maximum floc size was observed for concentrations above 0.1 g l⁻¹ while no flocculation was observed for concentrations below 0.004 g l⁻¹. Diatom blooms strongly enhanced flocculation speed and, to a lesser extent, flocculation efficiency. During this period, the maximum flocculation speed of 6 μm min⁻¹ corresponded to a flocculation time of less than 20 min. Salinity did not appear to automatically enhance flocculation, which depended on the constituents of suspended sediments and on the content and concentration of organic matter. Examination of the variability of 2D fractal dimension during flocculation experiments revealed restructuring of flocs during aggregation. This was observed as a rapid decrease in the floc fractal dimension from 2 to 1.4 during the first minutes of the flocculation stage, followed by a slight increase up to 1.8. Deflocculation experiments enabled determination of the influence of turbulent structures on flocculation processes and confirmed that turbulent intensity is one of the main determining factors of maximum floc size.     

Exploiting the dual functions of polymer depressants in fine particle flotation

Fine hydrophilic particles are known to be entrained with water in flotation of many ores. Flocculation of the hydrophilic particles by polymer depressants could potentially reduce the mechanical entrainment of these particles. This paper reports testwork completed on fine particles of several solids, iron oxide, hydroxyapatite and sphalerite, as well as on a relatively coarse quartz sample (− 75 + 38 μm). Dodecylamine was used as a collector for quartz, and several dispersants and polymer depressants, including sodium silicate, sodium metaphosphate, zinc sulfate, cornstarch, corn dextrin and carboxymethyl celluloses (with molecular weights of both 700,000 and 80,000) were used as flotation modifiers. The major part of the testwork involved flotation tests in a 200 mL flotation column. It was observed that flocculation of the fine hydrophilic particles significantly reduced their mechanical entrainment, while dispersion severely aggravated it. Thus, in the flotation separation of synthetic mixtures of the − 75 + 38 μm quartz and fine (reagent grade) iron oxide or hydroxyapatite, polymer depressants that caused flocculation performed better than those that did not cause flocculation.     

A lumped discrete population balance model for shear flocculation-model development

In the shear flocculation process, flocculation of ultrafine (size < 10 μm) hydrophobic particle occurs in the presence of a high shear field. Hence, it is necessary to consider both processes of coalescence and breakage, while modelling shear flocculation.In this paper, a lumped discrete population balance model is presented considering both processes of coalescence and breakage of flocs. A method is also proposed to convert discrete kernels to lumped discrete kernels by satisfying the constraints on them. The numerical solution of the model is compared with some special analytical solutions of the continuous population balance model, with which it is observed to be in agreement. The model equations are derived in such a way that it predicts correctly both the rate of change of number and the total volume of the flocs. The size distribution of a flocculating suspension can be predicted by this model.