北大别超高压榴辉岩的快速折返与缓慢冷却过程

岩石学研究表明,北大别超高压榴辉岩经过了超高压和高压榴辉岩相变质作用以及麻粒岩相叠加和角闪岩相退变质作用.其中,高压麻粒岩相和角闪岩相变质阶段形成的后成合晶以及石榴子石和单斜辉石等矿物中成分分带的存在,证明该区榴辉岩经历了一个快速折返过程;而不同变质阶段的温度、压力和形成时代,却反映该区榴辉岩在峰期超高压变质作用之后又经历了一个缓慢冷却过程.超高压岩石折返期间的缓慢冷却过程也许正是北大别长期难以发现柯石英和有关超高压证据的重要原因.因此,本文为大别山不同超高压岩片的差异折返模型的建立提供了新的证据.     

北大别的多阶段高温变质作用与部分熔融及其地球动力学过程和大地构造意义

北大别经历了三叠纪高温超高压变质作用和多阶段折返历史,因而榴辉岩中广泛发育多期减压结构,极少保留早期的超高压变质记录,这为它们不同变质阶段的温度条件估算带来了巨大困难。然而,目前流行的微量元素温度计为北大别榴辉岩的峰期及之后的退变质阶段温度的确定提供了可能性。根据锆石中Ti和金红石中Zr温度计,结合传统矿物对温度计的计算数据,获得了北大别榴辉岩中多阶段高温（>900 ℃）条件的数据,证明研究区经历了从超高压榴辉岩相→石英榴辉岩相→高压麻粒岩相阶段的高温变质过程。并且,北大别经历了折返初期（207±4 Ma）的减压熔融和碰撞后燕山期（约130 Ma）的加热熔融作用。长时间的高温变质作用与多期部分熔融也许正是北大别长期难以发现柯石英和有关超高压变质证据等的重要原因。因此,这些成果有助于甄别北大别的岩石成因和演化过程以及大别山多岩片差异折返模型的建立和完善。     

大别山北部榴辉岩的退变质特征及其地质意义

研究了大别山北部榴辉岩的变质岩岩石学。结果表明，该区榴辉岩相变质作用可分为早期(超高压)和晚期(高压)两个阶段，并在折返过程中形成了一系列特征性的退变质显微构造。其中，退变质结构主要包括：(1)由于压力降低而出溶形成的一些定向针状或叶片状矿物包裹体，如钠质单斜辉石中石英及石榴子石中的金红石、单斜辉石和磷灰石等；(2)冠状体或后成合晶，特别是石榴子石外围发育两期(“双层”)后成合晶；(3)反应边或退变边，如绿辉石的透辉石退变边、透辉石的角闪石退变边和金红石的钛铁矿退变边等。这些退变质结构为本区榴辉岩高级变质岩的快速折返过程和抬升历史提供了强有力的岩石学依据；石榴子石中针状矿物出溶体进一步证明研究区榴辉岩早期经历了超高压变质作用，峰期变质压力应大干4．0GPa，甚至可能达到5～7GPa或更高。     

北苏鲁荣成地区超高压变质带大理岩中石榴辉石岩的退变质过程

北苏鲁荣成地区超高压变质带大理岩中的退变质石榴辉石岩包裹体具有“核-幔-边”结构,核部主要由石榴子石与单斜辉石组成,幔部含有由细小角闪石与绿帘石组成的后成合晶以及颗粒较大的角闪石与单斜辉石,通过详细的岩相学分析以及矿物成分分析,认为这些后成合晶是由石榴子石、单斜辉石以及来自围岩的流体共同反应而产生,大颗粒的角闪石主要是由辉石转变而来的,在幔部这个转变并不彻底,仍有一些残余辉石颗粒。边部主要由角闪石和绿帘石组成。该石榴辉石岩曾经历榴辉岩相超高压变质阶段。没有柯石英超高压代表性矿物（采样处的其他类型岩石都含有柯石英）的原因是石榴辉石岩的原岩为超基性岩。     

北大别罗田榴辉岩的减压出溶结构与超高压变质作用

岩石学研究表明北大别罗田榴辉岩经过了榴辉岩相、麻粒岩相和角闪岩相变质作用,表现出多种减压出溶结构.特征性的减压出溶结构有单斜辉石和石榴石中分别发育石英+角闪石+斜长石等与金红石+单斜辉石+角闪石等针状矿物出溶体,以及锆石中含有柯石英残晶.这些进一步证明北大别南部（罗田一带）同北部（如黄尾河、百丈岩等地）榴辉岩一样经过了>5～7CPa的超高压变质作用.     

大别山北部镁铁-超镁铁质岩带中榴辉岩的分布与变质温压条件

大别山北部镁铁-超镁铁质岩带中的榴辉岩主要有两种产状,一是产于变形较强(面理化)的橄榄岩中,另一种是产于片麻岩中。其中,绿辉石中硬玉端元组分大多为Jd=20mol％～52mol％。产于橄榄岩和片麻岩中榴辉岩的石榴子石成分分别相当于Coleman的B型和C型榴辉岩。石榴子石成分特征及钠质单斜辉石中石英针状出溶体的出现表明,本区榴辉岩早期可能经历过超高压变质作用,且至少经历了3个变质阶段,即:①榴辉岩相峰期变质阶段,主要矿物共生组合为石榴子石+绿辉石+金红石±蓝晶石+石英(或柯石英假象?),p≥2.5GPa、t=595～874℃;②高压麻粒岩相变质阶段,主要矿物共生组合为石榴子石+透辉石+紫苏辉石+钛铁矿+尖晶石+斜长石等,p=1.1～1.37GPa、t=817～909℃;③角闪岩相变质阶段,主要矿物共生组合为角闪石+斜长石+磁铁矿等,p=0.5～0.6GPa、t=500～600℃。该区榴辉岩独特的麻粒岩相退变质阶段,表明榴辉岩在折返初期并未能上升到中上地壳,而处于下地壳,它与南部超高压变质岩有不同的p-t演化史,即在榴辉岩相峰期变质之后经历了近等温减压(或稍升温减压)和降温减压变质过程。     

中国大陆科学钻探主孔0～4500米变质岩石锆石中保存的超高压矿物包体

中国大陆科学钻探主孔0-4500米的岩心主要由榴辉岩、斜长角闪岩、副片麻岩、正片麻岩以及少量的超基性岩所组成。岩相学研究结果表明,榴辉岩的围岩普遍经历了强烈角闪岩相退变质作用的改造,峰期超高压变质的矿物组合已完全被后期退变质过程中角闪岩相矿物组合所替代。采用激光拉曼技术,配备电子探针和阴极发光测试,发现主孔224件岩心中有121件(包括榴辉岩、斜长角闪岩、副片麻岩和正片麻岩)样品的锆石中普遍隐藏以柯石英为代表的超高压矿物包体,且不同岩石类型锆石中所保存的超高压矿物包体组合存在明显差异。(含多硅白云母)金红石石英榴辉岩锆石中保存的典型超高压包体矿物组合为柯石英 石榴石、柯石英 石榴石 绿辉石 金红石和柯石英 多硅白云母 磷灰石。黑云绿帘斜长角闪岩锆石中保存的超高压矿物组合为柯石英 石榴石 绿辉石、柯石英 石榴石 多硅白云母和柯石英 绿辉石 金红石,与榴辉岩所保存的超高压矿物组合十分相似,表明该类斜长角闪岩是由超高压榴辉岩在构造折返过程中退变质而成。在副片麻岩类岩石,如石榴绿帘黑云二长片麻岩锆石中,代表性的超高压包体矿物组合为柯石英 多硅白云母和柯石英 石榴石等;而在石榴黑云角闪钠长片麻岩锆石中,则保存柯石英 硬玉 石榴石 磷灰石、柯石英 硬玉 多硅白云母 磷灰石和柯石英 石榴石 磷灰石等超高压矿物包体。在正片麻岩锆石中,标志性的超高压矿物包体为柯石英、柯石英 多硅白云母、柯石英 蓝晶石 磷灰石和柯石英 蓝晶石 榍石等。此外,在南苏鲁东海至临沭一带的地表露头以及一系列卫星孔岩心的锆石中,也普遍发现以柯石英为代表的标志性超高压矿物包体,表明在南苏鲁地区由榴辉岩及其围岩的原岩所组成的巨量陆壳物质(方圆>5000km2,厚度超过4.5km)曾整体发生深俯冲,并经历了超高压变质作用。该项研究对于重塑苏鲁-大别超高压变质带俯冲-折返的动力学模式有着重要的科学意义。     

北大别超高压榴辉岩中麻粒岩相变质的多期记录

<正>大别山是三叠纪华南板块向华北板块之下俯冲形成的碰撞型造山带,包含南大别低温榴辉岩带、中大别超高压变质带和北大别杂岩带等3个含榴辉岩的岩石单位,简称南大别、中大别和北大别。北大别超高压榴辉岩普遍经历过多阶段变质演化过程,特别是峰期之后的麻粒岩相变质叠加,表现为早期的绿辉石退变为细粒的单斜辉石+斜长石+斜方辉石后成合晶(Xu S-T et al.,2000;Liu Y-C et al.,2005,2007,2011,     

青藏高原拉萨地块松多榴辉岩的岩相学特征和变质演化过程

松多榴辉岩出露于拉萨地块的石英片岩中,主要由较为基性的金红石榴辉岩和较为酸性的石英榴辉岩组成。榴辉岩相矿物组合为石榴子石 绿辉石 绿帘石±多硅白云母±石英±金红石。岩石发生了较强烈的退变质作用,退变质矿物有角闪石、绿帘石、石英、钠长石及绿泥石。石榴子石变斑晶具有生长环带结构,变斑晶和基质石榴子石主要落入C类榴辉岩区,少数石榴子石变斑晶边部和基质石榴子石落入B类榴辉岩区;单斜辉石主要为绿辉石,少数Ⅰ世代和Ⅲ世代为普通辉石;角闪石均为钙质角闪石。根据石榴子石-绿辉石-多硅白云母矿物温压计计算,获得的温压范围为630～777℃和2.58～2.70GPa,峰期变质条件接近于石英-柯石英转变线。榴辉岩的原岩经历了从高绿片岩相、角闪岩相、榴辉岩相、角闪岩相到高绿片岩相的变质过程,这反映了与古特提斯洋闭合有关的俯冲进变质作用和随后的折返退变质作用。     

苏鲁地体超高压矿物的三维空间分布

采用激光拉曼技术,配备电子探针和阴极发光测试,确认苏鲁地体大多数花岗质片麻岩,所有类型片麻岩、斜长角闪岩、蓝晶石英岩和大理岩的锆石中均隐藏以柯石英为代表的超高压包体矿物组合。其中花岗质片麻岩典型超高压包体矿物为柯石英±多硅白云母;副片麻岩为柯石英+石榴子石+绿辉石、柯石英±石榴子石+硬玉+多硅白云母+磷灰石、柯石英+多硅白云母±磷灰石;斜长角闪岩为柯石英+石榴子石+绿辉石±金红石;蓝晶石英岩为柯石英+蓝晶石+金红石+磷灰石、柯石英+蓝晶石+多硅白云母+金红石;大理岩为柯石英+透辉石、柯石英+橄榄石。表明苏鲁地体由榴辉岩及其围岩所组成的巨量陆壳物质曾普遍发生深俯冲,并经历了超高压变质作用。锆石的矿物包体分布特征及相应的阴极发光图像研究表明,在同一样品中,锆石的成因特征存在明显差异。有的锆石显示继承性(碎屑)锆石的核(core)、超高压变质的幔(mantle)和退变质的边(rim);有的锆石则具有超高压的核、幔和退变质的边;而有的锆石却记录了深俯冲的核、超高压的幔和退变质的边。标志着苏鲁超高压变质带各类岩石副矿物锆石均具有十分复杂的结晶生长演化历史。因此,在充分研究锆石中矿物包体性质、分布特征以及相应阴极发光图像的基础上,采用SHRIMP离子探针技术,在锆石晶体的不同     

Ultrahigh Pressure Metamorphism and Tectonic Evolution of Southwestern Tianshan Orogenic Belt,China: A Comprehensive Review

Recently, a huge ultrahigh‐pressure (UHP) metamorphic belt of oceanic‐type has been recognized in southwestern (SW) Tianshan, China. Petrological studies show that the UHP metamorphic rocks of SW Tianshan orogenic belt include mafic eclogites and blueschists, felsic garnet phengite schists, marbles and serpentinites. The well‐preserved coesite inclusions were commonly found in eclogites, garnet phengite schists and marbles. Ti‐clinohumite and Ti‐chondrodite have been identified in UHP metamorphic serpentinites. Based on the PT pseudosection calculation and combined U‐Pb zircon dating, the P‐T‐t path has been outlined as four stages: cold subduction to UHP conditions before ～320 Ma whose peak ultrahigh pressure is about 30 kbar at 500oC, heating decompression from the Pmax to the Tmax stage before 305 Ma whose peak temperature is about 600oC at 22kbar, then the early cold exhumation from amphibolite eclogite facies to epidote‐amphibolite facies metamorphism characterized by ITD PT path before 220 Ma and the last tectonic exhumation from epidote amphibolite facies to greenschist facies metamorphism. Combining with the syn‐subduction arc‐like 333‐326 Ma granitic rocks and 280‐260 Ma S‐type granites in the coeval low‐pressure and high‐temperature (LP‐HT) metamorphic belt, the tectonic evolution of Tianshan UHP metamorphic belt during late Cambrian to early Triassic has been proposed.     

Retrogressive Microstructures:A Key to Post Collisional Uplift and Extension Tectonics of Ultrahigh-Pressure Metamorphic Rocks from Dabie Orogenic Belt,China

ThereisanunanimousunderstandingthattheUHPmetamorphisminDabie-SuluareaswasformedduringtheTri-assiccollisioneventbetweentheYangtzeandNorthChinacratons(Congetal.,l994$Zhouetal-,l996;Liouetal.,l994)-Eclogiteisthemostimportantrocktypeamongtheul-trahigh-pressure(UHP)metamorphicrocks.Accordingtotheiroccurrencethereare3typesofeclogites:typeIisen-clavesinultramaficintrusionsandasmembersinthelayeredmafic-ultramaficcomplex(Jahnl998);typeIispodsorlay-ersinthehighlymetamorphicsupracrustals(mainlying…     

Partial melting of metapelites at ultrahigh-pressure conditions, Greenland Caledonides

Eclogite, orthogneiss and, by association, metapelite from an island at 78°N in North‐East Greenland experienced ultrahigh‐pressure (UHP) metamorphism at approximately 970 °C and 3.6 GPa, at the end of the Caledonian collision, 360–350 Ma. Hydrous metapelites contain abundant leucocratic layers and lenses composed of medium‐grained, anhedral, equigranular quartz, antiperthitic plagioclase and K‐feldspar with minor small garnet and kyanite crystals. Leucosomes are generally parallel to the matrix foliation, are interlayered with residual quartz bands, anastomose around residual garnet and commonly cross‐cut micaceous segregations. Textures suggest that the leucosomes crystallized from a syntectonic melt, but crystallized at the end of local high‐grade deformation. The metapelite outcrop is < 1.5 km from kyanite eclogites with confirmed coesite, but the metapelites lack coesite and palisade textures diagnostic of coesite pseudomorphs. They do contain highly fractured garnet megacrysts with polycrystalline quartz inclusions (some surrounded by radial fractures) and Ti‐rich phengite inclusions that suggest the former presence of coesite. Polyphase inclusions in garnet contain reactants and products of the inferred dehydration melting reaction: Phe + Qtz = Ky + Kfs + Rt + melt. The reactants are thought to have been early inclusions of hydrous phases within garnet that melted and then crystallized new phases. Garnet surrounding these inclusions has patchy zoning with elevated Ca, consistent with experiments that produced similar patchy microstructures in garnet around inclusions with an unequivocal melt origin. The peak UHP metamorphic assemblage in these rocks is inferred to have been phengite, coesite, garnet, kyanite, rutile, fluid ± omphacite ± epidote. Phase diagrams indicate that dehydration melting of phengite in this assemblage would have occurred after decompression from peak pressure, but still above the coesite to quartz transition. Unusual crown‐ and moat‐like textures in garnet around some polycrystalline quartz inclusions are also consistent with the inference that melting took place at UHP conditions.     

PTtD Path and Fluid Evolution of HighPressure Eclogites from the Dabie Mountains,Central East China

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High-and Ultrahigh-pressure Metamorphism and Retrogressive Textures of Gneiss in the Donghai Area--Evidence from gneisses in drillhole ZK2304

In the gneisses from the drillhole ZK2304 of the Donghai area, there have been preserved high- and ultrahigh-pressure metamorphic mineral assemblages, a series of complicated retrogressive textures and relevant metamorphic reactions. In addition to garnet, jadeititic-clinopyroxene and rutile, other peak stage (M2) minerals in some gneisses include phengite, aragonite and coesite or quartz pseudomorphs after coesite. The typical peak-stage mineral assemblages in gneisses are characterized by garnet + jadeitic-clinopyroxene + rutile + coesite, garnet + jadeitic-clinopyroxene + phengite + rutile ± coesite and garnet + jadeitic-clinopyroxene + aragonite + rutile ± coesite. The grossular content (Gro) in garnet is high and may reach 50.1 mol%. The SiO2 content of phengite ranges from 54.37% to 54.84% with 3.54- 3.57 p.f.u. Quartz pseudomorphs after coesite occur as inclusions in garnet.The gneisses of the Donghai area have been subjected to multistage recrystallization and exhibit a closewise P-T evolutional path characterized by the near-isothermal decompression. The inclusion assemblage (Hb+Ep+Bi+Pl+Qz) within garnet and other minerals has recorded a pre-peak stage (M1) epidote amphibole facies metamorphic event. High- and ultrahigh-pressure peak metamorphism (M2) took place at T=750- 860° C and P>2.7 GPa. The symplectitic assemblages after garnet, jadeitic-clinopyroxene and rutile imply a near-isothermal decompression metamorphism (M3, M4) during the rapid exhumation. Several lines of evidence of petrography and metamorphic reactions indicate that both gneisses and eclogites have experienced ultrahigh-pressure metamorphism in the Donghai area. This research may be of great significance for an in-depth study of the metamorphism and tectonic evolution in the Su-Lu ultrahigh-pressure metamorphic belt.     

Retrogressive Microstructures of the Eclogites from the Northern Dabie Mountains, Central China： Evidence for Rapid Exhumation

The ultrahigh-pressure eclogites from the northern Dabie Mountains in central China occurred as tectonic lens or blocks within granitic gneisses or meta-peridotites. Petrologic studies suggest that the studied eclogites experienced strongly retrogressive metamorphism and produced a series of characteristic retrogressive microstructures. The retrograde structures mainly include: (1) oriented needle mineral exsolution, e. g. , quartz needles in Na-clinopyroxene and rotile, clinopyroxene and apatite exsolution in garnet formed under decreasing pressure conditions during exhumation; (2) symplectite, especially, two generations of symplectites developed outside the garnet grains, which are called ““double symplectite““ here; (3) compositional zoning of minerals such as garnet and clinopyroxene; (4) minerals with a reaction rim or retrograde rim, e.g. , omphacite with a diopside rim, diopside with an amphibole rim and rutile with a rim of ilmenite. These retrograde textures, especially mineral zoning and symplectite, provide important petrologic evidence for the exhumation process and uplift of high-grade metamorphic rocks such as eclogite in the northern Dabie Mountains, indicating a rapid exhumation process.