The “Problem of the quaternary” and the taxonomic rank of the late cenozoic in the international stratigraphic scale

An international scientific conflict has arisen around the International Stratigraphic Scale, the main document that regulates the rules of reading of geological records and, hence, concerns all Earth sciences. The matter of debate is the geological time scale of 2004, developed by the International Commission on Stratigraphy, where the Quaternary system was abandoned. This ICS decision triggered a protest among Quaternary geologists, members of INQUA, and became the subject of much controversy. This article provides a comprehensive analysis of the Quaternary problem and proposes a reasonable scientific solution that may be appropriate for both parties.     

Evolution of radiolarians in the late Albian–Campanian

The dynamics of radiolarian evolution in the late Albian–Campanian is analyzed, and several stages are recognized. The first stage (late Albian–middle Cenomanian), related to the MCE regional anoxic event, showed low evolutionary tempos and hence lacked structural change in radiolarian communities. The second stage (late Cenomanian–early Turonian), corresponding to ОАЕ 2, which was a global anoxic event, is characterized by a decrease in the number of genera, while many genera showed increased diversification of species composition. At this stage, a considerable number of genera became extinct and appeared, suggesting an increased rate of the radiolarian evolution. The third stage (middle Turonian–early Coniacian), including the beginning of ОАЕ 3, is characterized by a stabilized number of genera. The fourth stage (late Coniacian–Santonian) completely encompasses ОАЕ 3 except for its very beginning. At this stage, the radiolarian communities underwent a significant structural change, while their rate of evolution increased considerably. Nevertheless, during the ОАЕ 3 stage, a distinct trend toward a decrease in generic diversity continued from the late Cenomanian to the middle Turonian. The fifth stage (Campanian) is characterized by quite significant changes in the assemblage composition, while the trend toward a gradual decrease in the number of genera steadily continued. At this stage, which coincided with a considerable cooling, twice as many genera became extinct as during ОАЕ 2. The analysis of the dynamics of radiolarian evolution showed that the anoxic MCE, ОАЕ 2, and ОАЕ 3 events did not result in degradation of radiolarian assemblages. This suggests that this group has significant stratigraphic potential. In general, the evolution of radiolarians in the Late Cretaceous was gradual. By the end of the Campanian, nearly half of the generic diversity was composed of genera which appeared at the beginning of the Cretaceous and earlier.     

The Thakkhola–Mustang graben in Nepal and the late Cenozoic extension in the Higher Himalayas

The Thakkhola–Mustang graben is located at the northern side of the Dhaulagiri and Annapurna ranges in North Central Nepal. The structural pattern is mainly characterised by the N020–040° Thakkhola Fault system responsible for the development of the half-graben. A detailed study of the substrate and the sedimentary fill in several outcrops indicates polyphased faulting:-pre-sedimentation faulting (Miocene), with a mainly NNW–SSE to N–S compressional stress expressed in the substratum by N020–040° and N180–N010° sinistral and N130–140° dextral conjugate strike-slip faults;-syn-sedimentation faulting (Pliocene–Pleistocene), characterised by a W–E to WNW–ESE extensional stress and tectonic subsidence of the half-graben during the Tetang period (Pliocene probably), followed by a doming of the Tetang deposits and a short period of erosion (cf. Pliocene planation surface and unconformity between the Tetang and Thakkhola Formations); the Thakkhola period (Pleistocene) is characterized by a W–E to WNW–ESE extensional stress and a major subsidence of the half graben;-post-sedimentation recurrent extensional faulting and N–S and NE–SW normal faults in the late Quaternary terrace formations.Geodynamic interpretation of the faulting is discussed in relation to the following:

• 1.the geographic situation of the Thakkhola–Mustang half-graben in the southern part of Tibet and its setting in the Tethyan series above the South Tibetan Detachment System (STDS);
• 2.the geodynamic conditions of the convergence between India and Eurasia and the dextral east–west shearing between the High Himalayas and south Tibet;
• 3.the possible relations between the sinistral Thakkhola and the dextral Karakorum strike-slip faults in a N–S compressional stress regime during the Miocene.

     

Timing of glacier fluctuations and trigger mechanisms in eastern Qinghai–Tibetan Plateau during the late Quaternary

It is highly debated whether glacial advances on the Qinghai–Tibetan Plateau (QTP) occurred as a response to temperature cooling, or whether they were forced by an increase in moisture brought by the intensive Indian summer monsoon. We here report a case study investigating this issue. Multiple moraine series in the Yingpu Valley, Queer Shan ranges of the Hengduan Mountains, and eastern QTP, provide an excellent archive for examining the timing and trigger mechanism of glacier fluctuations. Twenty-seven optically stimulated luminescence (OSL) samples of glacial sediments were collected from this valley. The quartz OSL ages show that the moraine series of Y-1, I, M and O were formed during the Late Holocene, Late Glacial, the global Last Glacial Maximum (LGM) and Marine Oxygen Isotope Stage (MIS) 3 (likely mid-MIS-3). The youngest Y-2 moraines probably formed during the Little Ice Age (LIA). The oldest H moraines formed before MIS-3. We found that glacial advances during the late Quaternary at the Yingpu Valley responded to cold stages or cold events rather than episodes of enhanced summer monsoon and moisture. As a result, glaciers in the monsoonal Hengduan Mountains were mainly triggered by changes in temperature. Millennial time scale temperature oscillations might have caused the multiple glacial advances.     

Origin and evolution of volatiles in the Central Europe late Variscan granitoids,using the example of the Strzegom-Sobótka Massif,SW Poland

Mineralogy and Petrology - The results of the new Electron Microprobe Analysis of apatite, hornblende and biotite crystals of the hornblende-biotite variety of the Strzegom-Sobótka granite...     

Radiolarian paleobiogeography in the late Albian–Santonian

Radiolarian paleobiogeography for the late Albian–Santonian is proposed for the first time. The paleobiogeographic differentiation is found to be different for the Albian, Cenomanian, Turonian, and Coniacian–Santonian. The Tethyan and Boreal superrealms can be recognized for the Albian–Santonian. For the Albian–Santonian, the Tethyan Superrealm can be subdivided into realms: Atlantic-Mediterranean, Carpathian-Caucasian, and Tropical-Pacific. The boundaries of these realms changed throughout geological time. The Boreal Superrealm recognized for the Albian so far cannot be subdivided into realms, whereas in the Cenomanian it included the East European and Western Siberian realms without a clear definition of the boundaries and the Boreal-Pacific (in the North Pacific). The Boreal Superrealm is subdivided in the Turonian into two realms (European-Western Siberian and Boreal-Pacific), and in the Coniacian–Santonian, it is subdivided into three realms (European, Western Siberian, and Boreal-Pacific). The Austral Superrealm can be recognized only for the Albian and Cenomanian, and because of the lack of data, it cannot be delineated for the Turonian and Coniacian–Santonian.     

Petrogenesis of the late Cretaceous Turnagoel intrusion in the eastern Pontides： Implications for magma genesis in the arc setting

A series of Cretaceous plutons is present in the eastern Pontides of northeastern Turkey.The Turnagl intrusion is the least studied and,thus,the least understood plutons in the orogen.This intrusion consists of hornblende-biotite granodiorites emplaced at 78 Ma based on LA-ICP-MS U-Pb zircon dating.It is of sub- alkaline affinity,belongs to the medium- to high-K calc-alkaline series,and displays features typical of Itype granites.The rocks of the intrusion are enriched in large-ion lithophile elements and light rare earthelements with negative Eu anomalies（Eu/Eu^*= 0.69-0.82）,but are deficient in high-field-strength elements.They have a small range of (⁸⁷Sr/⁸⁶Sr)_i（0.7060-0.7063）,ε_Ndi（-2.6 to -3.1）,and δ¹⁸O（+8.1 to +9.1） values.Their Pb isotopic ratios are ²⁰⁶Pb/²⁰⁴Pb = 18.63-18.65,²⁰⁷Pb/²⁰⁴Pb = 15.62-15.63,and ²⁰⁸Pb/²⁰⁴Pb = 38.53-38.55.The fractionation of plagioclase,hornblende,and Fe-Ti oxides had key functions in the evolution of the Tumagl intrusion.The crystallization temperatures of the melts ranged from 758 to 885℃ as determined by zircon and apatite saturation thermometry.All these characteristics,combined with the low values of K₂O/Na₂O and（Na₂O + K₂O）/（FeO^t+MgO + TiO₂）,as well as the high values of （CaO + FeO^t + MgO + TiO₂）.suggest an origin by dehydration melting from a metabasaltic lowercrustal source.     

Types of Karst-fractured and Porous Reservoirs in China''''s Carbonates and the Nature of the Tahe Oilfield in the Tarim Basin

Almost all the oil and gas reservoirs developed in marine sedimentary strata of China have undergone processes of multi-phase reservoir formation and later modification. The irregular reservoirs are classified into three types as the Naxi, Tahe and Renqiu ones, increasing successively in the development degree of karstificated pores and fissures and the connection degree of independent reservoirs. In these reservoirs, the unity in the fluid feature, pressure and oil-gas-water interface also increases successively from the Naxi to the Renqiu type. The main body of Ordovician reservoirs of the Tahe Oilfield in the Tarim Basin is a network pool rather than a stratified, massive, stratigraphically-unconformed or weathering-crust one. The fluid nature of oil, gas and water, the interface positions and the pressures, as well as the dynamic conditions of fluids within the reservoirs during the production are all different from those in stratified or massive oil and gas reservoirs. Carbonates in the Akekule upli     

Early subduction–exhumation and late channel flow of the Greater Himalayan Sequence: implications from the Yadong section in the eastern Himalaya

Based on metamorphic studies of the Yadong high-pressure (HP) granulite and multiple thermochronological investigations of granitoids from both upper and lower parts, the Yadong section in the eastern Himalaya constrains the Cenozoic tectonic evolution of the Greater Himalayan Sequence (GHS). The Yadong HP granulite, located at the top of the GHS, underwent a peak-stage HP granulite facies metamorphism and two stages of retrograde metamorphism. Granulite and hornblende facies retrograde metamorphism took place at 48.5 and 31.8 Ma, respectively, marking the time of exhumation of the subducted Indian slab to lower and middle crustal levels. Subsequently, an average young zircon U–Pb age obtained from the Yadong HP granulite indicated that this unit was captured by its surroundings in a partially molten condition at 16.9 Ma. In addition, three granitoids from both the lower and the upper parts of the GHS yielded biotite ⁴⁰Ar/³⁹Ar ages of 11.0, 11.3, and 11.5 million years. These consistent ages suggest that the GHS along the Yadong section was laterally extruded and synchronously cooled to ～300°C at ～11.3 Ma. Furthermore, the granitic gneisses yield apatite fission track ages of ～7 million years, documenting the cooling of the GHS to ～110°C. A two-stage model describes the Cenozoic tectonic evolution of the GHS: (1) the Indian slab had subducted under Tibet before ～55 Ma, and was exhumed to the lower crust (50-40 km) at 48.5 Ma, and to the middle crust (22-15 km) at 31.8 Ma; and (2) the partial melting occurred at middle crustal levels during the period 31.8 to 16.9 Ma, causing channel flow. In the late stage, the GHS was laterally extruded by ductile mid-crustal flow during the period 16.9 to ～7 Ma, characterized by a fast cooling rate of ～2 mm per year.     

Types of Karst-fractured and Porous Reservoirs in China''s Carbonates and the Nature of the Tahe Oilfield in the Tarim Basin

Almost all the oil and gas reservoirs developed in marine sedimentary strata of China have undergone processes of multi-phase reservoir formation and later modification. The irregular reservoirs are classified into three types as the Naxi, Tahe and Renqiu ones, increasing successively in the development degree of karstificated pores and fissures and the connection degree of independent reservoirs. In these reservoirs, the unity in the fluid feature, pressure and oil-gas-water interface also increases successively from the Naxi to the Renqiu type. The main body of Ordovician reservoirs of the Tahe Oilfield in the Tarim Basin is a network pool rather than a stratified, massive, stratigraphically-unconformed or weathering-crust one. The fluid nature of oil, gas and water, the interface positions and the pressures, as well as the dynamic conditions of fluids within the reservoirs during the production are all different from those in stratified or massive oil and gas reservoirs. Carbonates in the Akekule upli     

Capybaras (Rodentia,Hydrochoeridae, Hydrochoerinae) and their bearing in the calibration of the late Miocene–Pliocene sequences of South America

Fossil capybaras were long regarded as composed of numerous taxa, each one endemic to a particular area, a scenario completely different from the one shown by the living species. The interpretation of the record according to new criteria of ontogenetic change has demonstrated that they are useful for biocorrelation because their members have short biochrons with wide geographic distribution. The levels with capybaras of each locality would represent a short lapse within the bearing lithostratigraphic units. In turn, they would also represent short intervals within the temporal extension proposed for each Stage/Age or SALMA. All the late Miocene–Pliocene records of capybaras were analyzed and a chronological scheme was built mainly for Argentina, where records are most abundant. Numerical ages and magnetostratigraphic studies contribute to correlate this scheme with the global time scale. The Chasicoan SALMA would be correlated with part of the Tortonian Stage/Age; the Huayquerian SALMA with the late Tortonian-Messinian, and it could even extend to the earliest Zanclean. The Montehermosan SALMA would be restricted to the Zanclean. The Chapadmalalan SALMA would be correlated with the late Zanclean-early Piacenzian.     

Fluctuations in late Neoproterozoic atmospheric oxidation — Cr isotope chemostratigraphy and iron speciation of the late Ediacaran lower Arroyo del Soldado Group (Uruguay)

Oxygenation of the Earth's atmosphere occurred in two major steps, near the beginning and near the end of the Proterozoic Eon (2500 to 542 Ma ago), but the details of this history are unclear. Chromium isotopes in iron-rich chemical sediments offer a potential to highlight fine-scale fluctuations in the oxygenation of the oceans and atmosphere and to add a further dimension in the use of redox-sensitive tracers to solve the question regarding fluctuations of atmospheric oxygen levels and their consequences for Earth's climate. We observe strong positive fractionations in Cr isotopes (δ⁵³Cr up to + 5.0‰) in iron-rich cherts and banded iron formation horizons within the Arroyo del Soldado Group (Ediacaran; Uruguay) that can be explained by rapid, effective oxidation of Fe(II)-rich surface waters. These fluctuations are correlated with variations in ratios of highly reactive iron (Fe_HR) to total iron (Fe_tot) which indicate a predominance of anoxic water columns (Fe_HR/Fe_tot > 0.38) during the onset of oxidation pulses. We favor the scenario by which isotopically heavy Cr(VI) entered the basin after pulses of oxidative weathering on land and in which Fe(II) accumulated in the water column. Neodymium isotopes reveal that these oxygenation pulses were followed by increased influxes to the basin of continental crust-derived detrital components of Paleoproterozoic (Nd T_DM model ages = 2.1–2.2 Ga) provenance typical of the Rio de la Plata Craton. The association of positive δ⁵³Cr–ferruginous (Fe_HR/Fe_tot > 0.38) stratigraphic intervals with low-diversity acritarch assemblages dominated by Bavlinella faveolata strongly support models postulating a stratified, eutrophic Neoproterozoic ocean. Thus, even within a few million years of the Precambrian–Cambrian boundary, paleoceanographic conditions resembled more those of Paleoproterozoic oceans than Phanerozoic and present oceans. This highlights the sheer magnitude of ecological changes at the Precambrian–Cambrian transition, changes which ultimately led to the demise of the Precambrian world and the birth of the metazoan-dominated Phanerozoic.     

Fluid evolution of the late Archaean Rämepuro gold deposit in the Ilomantsi greenstone belt in eastern Finland

The late Archaean (ca. 2.7 Ga) Ilomantsi greenstone belt hosts a large number of small mesozonal gold occurrences. The Rämepuro deposit is spatially related to a feldspar porphyry dyke which has intruded the contact between metagreywackes and intermediate metavolcanic rocks. It consists of gold-bearing quartz-tourmaline-sulphide veins located mainly within an intensively altered and sheared zone about 20-30 m in width. Two types of fluid inclusions were distinguished in the quartz veins: (1) H₂O-CH₄ (Й equiv. wt% NaCl), and (2) H₂O-CO₂ (⢬ equiv. wt% NaCl). The two compositionally different fluid-inclusion types occur in separate veins. The compositions of decrepitate residues indicate that the type 1 fluid inclusions consist predominantly of Na, S, Ca, Cl, and in lesser proportions of K and Fe. The residues of the type 2 fluid inclusions are dominated by Na, Ca, Cl and minor K. For the type 1 and type 2 fluid inclusions, microthermometric experiments indicate average homogenisation temperatures of 310-350 and 220-250 °C respectively. Both types of fluid inclusions contain 1-3 anisotropic solids (Ca/Mg carbonate?, nahcolite?, tourmaline?). Sulphide daughter minerals occur only in the type 1 fluid inclusions. This fluid type is also often associated with short trails of sulphide inclusions which suggest mobilisation and redistribution of ore constituents. Some type 1 fluid inclusions display distinct morphological features ("implosion textures") related to post-trapping re-equilibration. The presence of the fluid-inclusion re-equilibration textures in some auriferous quartz veins and their absence in other gold-bearing quartz veins suggest an age difference between them. This conclusion is also supported by the compositionally different fluid regimes associated with the different quartz veins, indicating a change from reducing (CH₄) to a more oxidising (CO₂) fluid environment. The fluid-inclusion evidence suggests two separate gold mineralisation events, one related to late Archaean regional metamorphism, the other to Palaeoproterozoic thrusting and metamorphism.     

The distribution of calcareous nannofossils in the late Santonian–Late Maastrichtian deposits in the southwest of Iran (Khuzestan Province)

The first data on the distribution of calcareous nannofossils in the Behbehan section, the Kuh-e-Rish, are considered. According to the distribution of nannofossils, the Upper Cretaceous deposits of the section are subdivided into nine biostratigraphic zones. CC17 (Calculites obscurus zone) indicate the Late Santonian. Biozones CC18 (Aspidolithus parcus zone), CC19 (Calculites ovalis zone), CC20 (Ceratolithoides aculeus zone), CC21 (Quadrum sissinghii zone), and CC22 (Quadrum trifidum zone) represent the Campanian. Biozone CC23 (Tranolithus phacelosus zone) indicate the Late Campanian–Early Maastrichtian. Biozones CC24 (Reinhardtites levis zone) and CC25 (Arkhangelskiella cymbiformis zone) suggest the Middle and Late Maastrichtian, respectively. In the late Late Maastrichtian, due to decreasing in water depth at the study area, Nephrolithus frequens zone (CC26) defined in Tethysian domain was not recognized. The boundary between Gurpi–Pabdeh Formations represented a non-depositional period from the late Late Maastrichtian to the end of Early Paleocene. Also, it seems that predominant conditions of the sedimentary environment of Neotethys basin with the presence of index species calcareous nannofossils specified, which itself indicates that the warm climate and high depth of the basin in Late Santonian to Late Maastrichtian, in low latitudes has been prevalent.     

Nature and significance of the late Mesozoic granitoids in the southern Great Xing’an range,eastern Central Asian Orogenic Belt

ABSTRACT

Abundant late Mesozoic granitic rocks are widespread in the southern Great Xing’an Range (GXAR), which have attracted much attention due to its significance for the Mesozoic tectonic evolution in the eastern Central Asian Orogenic Belt. However, controversy has still surrounded the late Mesozoic geodynamic switching in the continental margin of east China, especially the spatial and temporal extent of the influence of the Mongol-Okhotsk and Palaeo-Pacific tectonic regimes. In order to better understand the Late Mesozoic evolutionary history of the southern GXAR, a number of geochemical, geochronological, and isotopic data of the granitoids in this region are collected. Magmatism in the southern GXAR can be divided into six phases: Late Carboniferous (325–303 Ma), Early-Middle Permian (287–260 Ma), Triassic (252–220 Ma), Early Jurassic (182–176 Ma), Late Jurassic (154–146 Ma), and Early Cretaceous (145–111 Ma). Mesozoic magmatic activities in the southern GXAR peaked during the Late Jurassic to Early Cretaceous, accompanied by large-scale mineralization. Sr–Nd–Hf isotopic evidence of these granitic rocks suggested they were likely originated from a mixed source composed of lower crust and newly underplated basaltic crust. Assimilation-fractional crystallization (AFC) or crustal contamination possibly occurred in the magma evolution, and a much more addition of juvenile component to the source of the Early Cretaceous granitoids than that of Late Jurassic. The closure of Mongol-Okhotsk ocean and the break-off of the Mongol-Okhotsk oceanic slab at depth in the Jurassic triggered extensive magmatism and related mineralization in this region. The Jurassic intrusive activities was affected by both the subduction of the Palaeo-Pacific plate and the closure of Mongol-Okhotsk ocean. Less influence of the Mongol-Okhotsk tectonic regime on the Early Cretaceous magmatism, whereas, in contrast the Palaeo-Pacific tectonic regime possibly continued into the Cenozoic.     

On the Age of the Dongtang Formation in the Hengyang Basin of Hunan and the Cretaceous and Tertiary Boundary

Since the coexistence of the Cretaceous and Palaeocene was ascertained in the Hengyang Basin of Hunan in the middle of the 1960's, the Cretaceous and Tertiary boundary has been discussed in several papers, but it still remains controversal. The points at issue are the connotation, stratigraphical position and lateral correlation of the Dongtang (or Chejiang) Formation.     

Types of Karst-fractured and Porous Reservoirs in China＇s Carbonates and the Nature of the Tahe Oilfield in the Tarim Basin

Almost all the oil and gas reservoirs developed in marine sedimentary strata of China have undergone processes of multi-phase reservoir formation and later modification. The irregular reservoirs are classified into three types as the Naxi, Tahe and Renqiu ones, increasing successively in the development degree of karstificated pores and fissures and the connection degree of independent reservoirs. In these reservoirs, the unity in the fluid feature, pressure and oil-gaswater interface also increases successively from the Naxi to the Renqiu type. The main body of Ordovician reservoirs of the Tahe Oilfield in the Tarim Basin is a network pool rather than a stratified, massive, stratigraphically-unconformed or weathering-crust one. The fluid nature of oil, gas and water, the interface positions and the pressures, as well as the dynamic conditions of fluids within the reservoirs during the production are all different from those in stratified or massive oil and gas reservoirs. Carbonates in the Akekule uplift and the Tahe Oilfield are assemblages of various types of reservoirs, which have an overall oH-bearing potential and obvious uneven distribution. Testing and producing tests are the major means to evaluate this type of reservoirs and acid fracturing improvement is a key link in petroleum exploration and development.     

Speciation studies of arsenic in the environment and in human

Arsenic is the 20th most abundant element in the Earth crust. Humans are exposed to naturally occurring and anthropogenic sources of arsenic compounds in the environment. A wide variety of adverse health effects have been attributed to chronic exposure to high levels of arsenic. More than two-dozen arsenic compounds （species） are present in the environment and in biological systems. The various arsenic species have dramatically different behavior and toxicity. This presentation briefly describes arsenic speciation analysis, human exposure to and metabolism of arsenic species. Environmental issues on arsenic in Canada are briefly discussed. These include （1） the arsenic waste left from previous gold mining and smelting activities; （2） the domestic use of wood treated with chromated copper arsenate; and （3） use of well water as the source of drinking water by approximately one third of the Canadian population.