藏北羌塘中北部红脊山地区蓝闪石＋硬柱石变质矿物组合的特征及其意义

蓝闪石 硬柱石是羌塘中北部红脊山地区首次发现的呈北西-南东走向展布的硬柱蓝闪片岩带中典型的低温高压变质矿物组合.蓝闪石呈浅蓝灰色,纤柱状;硬柱石无色,多呈团块状,较均匀地与蓝闪石混杂分布.电子探针分析表明,蓝闪石主要为铁蓝闪石和青铝闪石,硬柱石为较典型的硬柱石.硬柱蓝闪片岩呈(透镜状)构造岩块分布,与围岩呈断层接触,原岩主要为变质玄武岩及少量辉(长)绿岩、基性火山碎屑岩,围岩为变质砂岩、板岩和少量碳酸盐岩.红脊山硬柱蓝闪片岩带伴有构造混杂岩发育,二者共存构成红脊山地区北羌塘甜水河陆块与南羌塘查多岗日陆块之间的分界线.     

藏北羌塘中北部红脊山地区蓝闪石 硬柱石变质矿物组合的特征及其意义

蓝闪石 硬柱石是羌塘中北部红脊山地区首次发现的呈北西-南东走向展布的硬柱蓝闪片岩带中典型的低温高压变质矿物组合.蓝闪石呈浅蓝灰色,纤柱状;硬柱石无色,多呈团块状,较均匀地与蓝闪石混杂分布.电子探针分析表明,蓝闪石主要为铁蓝闪石和青铝闪石,硬柱石为较典型的硬柱石.硬柱蓝闪片岩呈(透镜状)构造岩块分布,与围岩呈断层接触,原岩主要为变质玄武岩及少量辉(长)绿岩、基性火山碎屑岩,围岩为变质砂岩、板岩和少量碳酸盐岩.红脊山硬柱蓝闪片岩带伴有构造混杂岩发育,二者共存构成红脊山地区北羌塘甜水河陆块与南羌塘查多岗日陆块之间的分界线.     

中国蓝闪片岩相的变质作用

本文论述了中国蓝闪片岩的分布、变质条件及其构造位置。中国的蓝闪片岩从中晚元古代开始,各变质期均有出现。根据矿物组合,可分为两类:第一类蓝闪片岩常含有高压矿物,如硬柱石、硬玉和文石以及蓝闪石、绿纤石、黑硬绿泥石、多硅白云母、红帘石等,属高压亚绿片岩相,称蓝闪—硬柱石片岩相,形成温度约250—350℃,压力大于500—800MPa,甚至可达1200MPa。此类蓝闪—硬柱石片岩相多代表海洋板块古消减带。第二类蓝闪片岩的常见矿物为蓝闪石、青铝闪石或镁钠闪石、黑硬绿泥石、红帘石和绿片岩相中的绿帘石、阳起石、绿泥石、白云母、有时还有黑云母、铁铝榴石和钠质辉石。形成温度约350—450℃,压力500—800MPa。此类蓝闪绿片岩相虽处于活动带,但与板块构造没有直接关系。我国西藏南部和内蒙温都尔庙属第一类,但大部分蓝闪片岩带属第二类。     

西藏羌塘中部才多茶卡蓝闪石40Ar/39Ar年代学及地质意义

本文报道了藏北羌塘中部才多茶卡地区晚三叠世蓝闪石片岩及蓝闪石矿物的新发现及地质意义。通过对才多茶卡构造混杂岩地质剖面的实测,在剖面第6层灰绿色变基性火山岩(绿片岩)中新发现以产蓝闪石类矿物为特征的中—高压变质岩系——蓝闪石片岩。对蓝闪石片岩的岩石学和矿物学特征进行了详细室内研究。从蓝闪石片岩中挑选出蓝闪石单矿物进行了40Ar/39Ar同位素年龄测定,结果表明,蓝闪石单矿物的坪年龄值为209±4Ma,等时线年龄值为216±4Ma,坪年龄与等时线年龄基本一致,属于晚三叠世诺利期,这与区域上羌塘中部发育的红脊山—双湖蓝闪石片岩的中—高压变质事件相吻合。由于蓝闪石类矿物的产出具有特殊的构造机制和地质意义,因此双湖以东的才多茶卡地区蓝闪石片岩的新发现及蓝闪石矿物的40Ar/39Ar同位素年代学研究进一步补充和丰富了青藏高原腹地羌塘中部龙木错-双湖构造混杂岩带的物质组成和同位素年代学信息,同时也为解决羌塘地区"龙木错-双湖构造混杂岩带是否向东延伸"等重大基础性地质问题,提供了新的重要资料。研究资料表明,羌塘中部自西向东从冈玛错、红脊山、绒马,经嘎尔错到才多茶卡地区,沿构造线方向断续分布的长达600km的含蓝闪石片岩的中—高压变质岩系,都是龙木错-双湖构造混杂岩带印支期构造活动事件的产物。     

1∶25万查多岗日幅、布若错幅地质调查成果与进展

侏罗系和上三叠统肖茶卡组中采获较丰富的双壳类、腕足类、珊瑚、菊石、海绵等化石;首次在展金组、曲地组中发现瓣鳃、腕足类、介形虫、放射虫等古生物化石;首次在新近系唢呐湖组中发现瓣鳃类和植物化石;首次在图北湖一带曲地组中发现科化石,初步鉴定为Misellina等,属于典型的暖水相动物,常见于华南地区,说明早二叠世测区已进入古特提斯构造发展阶段;首次在原划若拉岗日岩群中发现放射虫化石。首次在一级河流阶地分别获取1 4 C年龄值1 5 6 0 0±5 4 0a和1 3390±6 70a ,暗示了羌塘高原在更新世以来发生了一次明显隆升过程。新发现多处侏罗系小型生物礁(点礁)。查明若拉岗日岩群的物质组成及变形变质特征,建立了弯岛弧湖蛇绿构造混杂岩带。查明测区中部一带出露新生代花岗斑岩,岩石化学特征反映为橄榄粗玄岩序列,属于同碰撞花岗岩,代表燕山晚期造山作用的产物。对大横山构造带内出露岩浆岩调查取得新的认识,蛇绿岩残片的存在,对认识大横山构造带的构造属性起到重要的作用,肯定了金沙江结合带西延至测区。基本查明测区变质岩的岩石类型其分布特征,查明蓝闪片岩带岩石类型、变形变质特征、空间分布,硬柱石与蓝闪石共生说明了红脊山蓝闪片岩可能属于碰撞造成的产物。查明戈木日岩组(?)中级变质岩系的分布     

1∶25万查多岗日幅、布若错幅地质调查成果与进展

侏罗系和上三叠统肖茶卡组中采获较丰富的双壳类、腕足类、珊瑚、菊石、海绵等化石;首次在展金组、曲地组中发现瓣鳃、腕足类、介形虫、放射虫等古生物化石;首次在新近系唢呐湖组中发现瓣鳃类和植物化石;首次在图北湖一带曲地组中发现(竹蜓)科化石,初步鉴定为Misellina等,属于典型的暖水相动物,常见于华南地区,说明早二叠世测区已进入古特提斯构造发展阶段;首次在原划若拉岗日岩群中发现放射虫化石.首次在一级河流阶地分别获取14C年龄值15600±540a和13390±670a,暗示了羌塘高原在更新世以来发生了一次明显隆升过程.新发现多处侏罗系小型生物礁(点礁).查明若拉岗日岩群的物质组成及变形变质特征,建立了弯岛弧湖蛇绿构造混杂岩带.查明测区中部一带出露新生代花岗斑岩,岩石化学特征反映为橄榄粗玄岩序列,属于同碰撞花岗岩,代表燕山晚期造山作用的产物.对大横山构造带内出露岩浆岩调查取得新的认识,蛇绿岩残片的存在,对认识大横山构造带的构造属性起到重要的作用,肯定了金沙江结合带西延至测区.基本查明测区变质岩的岩石类型其分布特征,查明蓝闪片岩带岩石类型、变形变质特征、空间分布,硬柱石与蓝闪石共生说明了红脊山蓝闪片岩可能属于碰撞造成的产物.查明戈木日岩组(?)中级变质岩系的分布及岩石类型、变形变质特征.查明红脊山构造带的空间分布的变形、变质特征.基本查明了测区内断裂构造形迹的基本特征,甜水河-弯岛湖北西断裂带的是一条控相的左行走滑断层.     

甘肃玉门昌马地区的蓝闪片岩

蓝闪片岩产于一套含放射虫硅质岩、硅质大理岩、板岩、变质基性火山岩中,与此相伴的超基性岩块,以一系列向南逆冲的断片产出。蓝闪片岩中的蓝闪石往往和黑硬绿泥石、钠长石、绿泥石以及钠钙闪石(蓝透闪石、冻蓝闪石等)、钙闪石(阳起石等)共存。据钠角闪石、绿泥石计算的生成压力是0.65GPa至0.8GPa,略大于美国佛兰西斯科的瓦尔德溪蓝片岩中该矿物对生成的压力。稀土元素分析证明蓝片岩的原岩是典型洋底(中脊)玄武岩和岛弧玄武岩,这是蓝片岩沟-弧俯冲-碰撞的证据之一。     

甘肃玉门昌马地区的蓝闪片岩

蓝闪片岩产于一套含放射虫硅质岩、硅质大理岩、板岩、变质基性火山岩中,与此相伴的超基性岩块,以一系列向南逆冲的断片产出。蓝闪片岩中的蓝闪石往往和黑硬绿泥石、钠长石、绿泥石以及钠钙闪石(蓝透闪石、冻蓝闪石等)、钙闪石(阳起石等)共存。据钠角闪石、绿泥石计算的生成压力是0.65GPa至0.8GPa,略大于美国佛兰西斯科的瓦尔德溪蓝片岩中该矿物对生成的压力。稀土元素分析证明蓝片岩的原岩是典型洋底(中脊)玄武岩和岛弧玄武岩,这是蓝片岩沟-弧俯冲-碰撞的证据之一。     

青藏高原羌塘中部不同时代榴辉岩的识别及其意义——来自榴辉岩及其围岩~（40）Ar-~（39）Ar年代学的证据

羌塘中部高压变质带由榴辉岩、石榴子石白云母片岩、蓝片岩等组成,与蛇绿混杂岩、晚古生代浅变质地层岩片等共同构成了龙木错-双湖板块缝合带这一构造混杂岩带。目前已先后在片石山地区、果干加年山地区和冈玛错地区发现典型的榴辉岩,以片石山和果干加年山地区的榴辉岩为研究对象。片石山地区的榴辉岩为低温型榴辉岩,围岩为石榴子石白云母片岩,变质作用峰期温压条件为T=500℃,p=2.3GPa。已获得230～244Ma锆石SHRIMP U-Pb年龄和石榴子石Lu-Hf等时线年龄,代表榴辉岩相变质作用的时代。榴辉岩及其围岩在误差范围内具有相同的Ar-Ar年龄,为210～220Ma,代表了榴辉岩及其围岩冷却抬升至近地表的时代。果干加年山地区的榴辉岩具有和片山地区榴辉岩相似的野外产状、矿物组合、温压条件和围岩。Ar-Ar年代学研究显示,果干加年山地区的榴辉岩在240Ma左右即已折返并抬升至近地表,其变质作用峰期时代明显要早于片石山地区。     

青藏高原羌塘中部不同时代榴辉岩的识别及其意义——来自榴辉岩及其围岩40Ar-39Ar年代学的证据

羌塘中部高压变质带由榴辉岩、石榴子石白云母片岩、蓝片岩等组成,与蛇绿混杂岩、晚古生代浅变质地层岩片等共同构成了龙木错-双湖板块缝合带这一构造混杂岩带。目前已先后在片石山地区、果干加年山地区和冈玛错地区发现典型的榴辉岩,以片石山和果干加年山地区的榴辉岩为研究对象。片石山地区的榴辉岩为低温型榴辉岩,围岩为石榴子石白云母片岩,变质作用峰期温压条件为T=500℃,p=2.3GPa。已获得230~244Ma锆石SHRIMP U-Pb年龄和石榴子石Lu-Hf等时线年龄,代表榴辉岩相变质作用的时代。榴辉岩及其围岩在误差范围内具有相同的Ar-Ar年龄,为210～220Ma,代表了榴辉岩及其围岩冷却抬升至近地表的时代。果干加年山地区的榴辉岩具有和片山地区榴辉岩相似的野外产状、矿物组合、温压条件和围岩。Ar-Ar年代学研究显示,果干加年山地区的榴辉岩在240Ma左右即已折返并抬升至近地表,其变质作用峰期时代明显要早于片石山地区。     

Police, politics, and the right to the city

Space and spatiality have recently been at the core of debates concerning the political possibilities of the city. The arguments advanced in this paper might be seen as an attempt to contribute to these debates through a reflection on the spatiality of (in) justice, politics, and the right to the city. The case of French urban policy, with its focus on distressed urban areas, and the `suburban problem' in France are used as examples to make arguments more concrete.     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.     

Rb-Sr, K-Ar, H-and O-Isotope systematics of the Middle Riphean shales from the Debengda Formation, the Olenek Uplift, North Sibera

Clay subfractions (SFs) of <0.1, 0.1–0.2, 0.2–0.3, 0.3–0.6, 0.6–2 and 2–5 μm separated from Middle Riphean shales of the Debengda Formation are studied using the TEM, XRD, K-Ar and Rb-Sr isotopic methods. The oxygen and hydrogen isotope compositions in the SFs are studied as well. The low-temperature illite-smectite is dominant mineral in all the SFs except for the coarsest ones. The XRD, chemical and isotopic data imply that two generations of authigenic illite-smectite different in age are mixed in the SFs. The illite crystallinity index decreases in parallel with size diminishing of clay particles. As compared to coarser SFs, illite of fine-grained subfractions is enriched in Al relative to Fe and Mg, contains more K, and reveals higher K/Rb and Rb/Sr ratios. The Rb-Sr age calculated by means of the leachochron (“inner isochron”) method declines gradually from 1254-1272 Ma in the coarsest SFs to 1038-1044 Ma in finest ones, while the K-Ar age decreases simultaneously from 1225–1240 to 1080 Ma. The established positive correlation of δ¹⁸O and δD values with dimensions of clay particles in the SFs seems to be also consistent with the mixing systematics. The isotopic systematics along with data on mineral composition and morphology lead to the conclusion that mixedlayer illite-smectite was formed in the Debengda shales during two periods 1211–1272 and 1038–1080 Ma ago. The first period is likely close to the deposition time of sediments and corresponds to events of burial catagenesis, whereas the second one is correlative with the regional uplift and changes in hydrological regime during the pre-Khaipakh break in sedimentation.     

Influences of the unsaturated,saturated, and riparian zones on the transport of nitrate near the Merced River,California, USA

Transport and transformation of nitrate was evaluated along a 1-km groundwater transect from an almond orchard to the Merced River, California, USA, within an irrigated agricultural setting. As indicated by measurements of pore-water nitrate and modeling using the root zone water quality model, about 63% of the applied nitrogen was transported through a 6.5-m unsaturated zone. Transport times from recharge locations to the edge of a riparian zone ranged from approximately 6 months to greater than 100 years. This allowed for partial denitrification in horizons having mildly reducing conditions, and essentially no denitrification in horizons with oxidizing conditions. Transport times across a 50–100-m-wide riparian zone of less than a year to over 6 years and more strongly reducing conditions resulted in greater rates of denitrification. Isotopic measurements and concentrations of excess N₂ in water were indicative of denitrification with the highest rates below the Merced River. Discharge of water and nitrate into the river was dependent on gradients driven by irrigation or river stage. The results suggest that the assimilative capacity for nitrate of the groundwater system, and particularly the riverbed, is limiting the nitrate load to the Merced River in the study area.     

扬子北缘马元铅锌矿床闪锌矿微量元素及S-Pb-He-Ar-C同位素地球化学研究

马元铅锌矿床是近年扬子陆块北缘铅锌找矿的新突破。矿体呈层状、似层状产于碑坝隆起翼部震旦系灯影组角砾状白云岩层间构造带中,围岩蚀变很弱。矿石中硫化物以闪锌矿、方铅矿为主,中粗粒晶质结构,充填于白云岩角砾间。闪锌矿富集Cd、Ge、Ag,贫In、Tl、Se,Ga/In为6~132,Ge/In多1000,成矿温度以中-低温为主。金属硫化物ε~(34)S值相对集中,为12.9‰~19.4‰,平均为17.4‰,来自于海相硫酸盐的还原。铅同位素组成稳定,~(206)Pb/~(204)Pb为17.858~17.918:~(207)Pb/~(204)Pb为15.603~15.694;~(208)Pb/~(204)Pb为37.756~38.046,具有造山带和上地壳铅的特征,震旦系可能提供了金属成矿物质。闪锌矿中流体包裹体的~3He/~4He为0.03Ra~1.05Ra,~(40)Ar/~(36)Ar为326.1~765.1,~(38)Ar/~(36)Ar为0.183~0.204,表明成矿流体主要为地壳流体和饱和大气水(大气降水或海水)的混合。闪锌矿内流体包裹体挥发分δ~(13)C_(CH_4)值为-36.01‰~-28.80‰,δ~(13)C_(C_2H_6)值为-27.72‰~-22.44‰,δ~(13)C_(CO_2)值为-23.24‰~-9.68‰,表明有机流体参与了成矿作用。石英、方解石的H-O同位素结果表明具有海水和有机水混合的特征。可见,成矿流体具有两种流体混合的特征,一为蒸发海水与围岩反应所形成的盆地卤水,二为有机流体。推测矿区可能存在一个古油气藏,由于TSR生成一高硫气藏,为区内还原性有机流体的主要来源。当富含Pb、Zn等成矿物质的成矿流体运移至富含CH_4和H_2S的还原性流体的矿区角砾岩带时,两种流体混合,Pb、Zn等遇到H_2S发生反应而沉淀成矿,并伴生热液白云石等,形成了马元铅锌矿床。综上所述,我们认为马元矿床属MVT型铅锌矿床。     

Delivery of Trace Metals (Al,Fe, Mn,V, Co,Ni, Cu,Cd, Ag,Pb) from the Trinity River Watershed Towards the Ocean

The Trinity River (Texas, USA) contains in its watershed 23 different reservoir lakes, the largest one being Lake Livingston situated in the lower Trinity River watershed and two potentially polluting metroplexes, Dallas and Houston. In order to determine fluxes of nutrients and trace metals to Galveston Bay, a survey that included 24 discreet samples collected over a year and at various stages of discharge was carried out during 2000–2001. Geochemical (i.e., sorption by Fe oxyhydroxides), biological (i.e., seasonal uptake by sinking algae in Lake Livingston), and hydrological (i.e., dilution effects by increasing flow rates) controls were found to be mainly responsible for variations in dissolved trace metal concentrations rather than pollution sources. The Trinity River loads of suspended sediments and pollutant trace metals entering Galveston Bay at Anahuac were <20% of those reaching Lake Livingston, and only a few percent of the total upstream trace metal load is entering the Gulf of Mexico. Thus, during the transit through the 23 man-made lakes and an estuary, >96% of the pollutant trace metal load is lost to sediments.     

山西五台山区滹沱群变质玄武岩岩石学、地球化学特征及其成因意义

在野外地质调查的基础上,选取滹沱群豆村亚群底部四集庄组玄武岩、顶部青石村组玄武岩和东冶亚群中下部河边村组玄武岩,进行岩石学和地球化学研究。分析结果表明：玄武岩主量元素高TiO2、TFeO,低MgO,具有演化的基性岩浆的特征。稀土元素含量相对较高,具有弱—中等程度的轻稀土元素富集,中等程度的轻重稀土元素分异,轻微的Eu异常;玄武岩中Cr、Ni含量变化较大,但与Mg#具有很好的正相关性。微量元素配分图解中具有明显的Sr负异常,部分样品具有Nb、Ta和Ti负异常,无Zr、Hf负异常,与岛弧火山岩不同;同时Nb、Ta无分异,Zr/Hf值较高,具有板内玄武岩浆的特征。综合分析认为,滹沱群玄武岩可能形成于板内裂谷环境。在岩浆上升过程中发生橄榄石与尖晶石的分离结晶作用,同时不同程度地受到地壳的混染。     

海南长塘岭矿区大坡岩体岩石学、地球化学特征及其含矿性初探

海南大坡岩体位于五指山褶皱带内,主要受昌江—琼海构造带、琼西构造带与潭爷断陷构造带控制.岩石地球化学及岩石学研究表明,大坡岩体形成于海西-印支晚期,岩性单一,主要为中细粒似斑状黑云母二长花岗岩.岩体显示为Ⅰ型花岗岩与S型花岗岩的混合,主体以地壳物质部分熔融为主,形成过程有少量地幔物质加入.元素对的比值及稀土元素配分特征说明岩体钨锡等多金属含矿性可能较差.     

贵州岑巩羊桥罗家塘杷榔动物群的发现及其后生动物早期演化的意义

岑巩县羊桥乡罗家塘杷榔组仅出露中-上部地层,岩性单一,均为青灰、灰绿色粉砂质泥、页岩.在其上部层位发现了俞氏贵州始海百合(Guizhoueocrinus yui Zhao,Parsley et Peng,2007),计有棘皮动物始海百合、腕足动物、软体动物-软舌螺、节肢动物-三叶虫等8属9种,包括了2个未定名的新种和1...