新疆布鲁斯台辉长岩岩石学特征及对南天山洋俯冲时限的制约

布鲁斯台辉长岩位于中天山南缘缝合带中段古洛沟蛇绿岩以北30km,是该带上出露的为数不多的较大的基性侵入岩体。辉长岩主要由斜长石(35%~45%)、单斜辉石(20%~25%)和角闪石(30%~35%)组成,角闪石主要为交代辉石后的产物。岩石化学成分显示,辉长岩具有高Al2O3(15.43%~23.20%)和CaO(12.96%~14.48%),低碱K2O(0.13%~0.19%)、Na2O(1.47%~3.00%)、P2O5(0.03%~0.07%)和TiO2(0.34%~0.61%)的特征。辉长岩稀土元素球粒陨石标准化配分模式与E-MORB相似,但ΣREE低(12.91×10-6~23.14×10-6),微量元素具有Ba、U、K、Sr等LILE富集和Nb、Ta、Zr、Hf、Th等HFSE亏损的特点。锆石原位εHf(t)值为+9.7~+15.0。上述特征反映辉长岩形成的构造背景为活动大陆边缘,源区为受俯冲流体影响的亏损地幔橄榄岩,且在上升的过程中未遭受地壳的明显混染。La、Sm、Yb判别图解显示岩石可能是亏损的尖晶石二辉橄榄岩发生5%~10%的部分熔融的产物。锆石LA-ICP-MS测年表明,辉长岩形成年龄为316.8±2.1Ma(MSWD=3.4,n=36)。结合区域地质、年代学和地球化学的资料,我们提出至少在晚石炭世,南天山洋还存在洋内和洋陆俯冲事件,南天山洋闭合的时间可能在更晚的早二叠世,而不是志留纪或者早泥盆世。     

早侏罗世新特提斯洋俯冲作用——来自松多高镁闪长岩锆石U-Pb定年及Hf同位素的制约

冈底斯岩浆岩带中东部松多地区新发现的高镁闪长岩对于探讨青藏高原新特提斯俯冲演化历史具有重要意义。通过松多高镁闪长岩的LA-ICP-MS锆石U-Pb年龄、锆石Hf同位素和全岩地球化学组成的研究,表明松多闪长岩的锆石U-Pb年龄加权平均值为186.8±1.3Ma。该类岩石具有高硅、高镁的特点,Si O2含量为54.17%~58.81%,Mg O含量较高,介于6.26%~7.29%之间,Mg~#值介于64~67之间,Cr和Ni含量高。该岩石富集轻稀土元素,具有平滑右倾的稀土元素配分曲线及弱负Eu异常。富集Rb、Ba、Pb、K等大离子亲石元素,亏损Nb、Ta、Ti等高场强元素。锆石负εHf(t)值(-5~-14.3)及远大于其侵入年龄的古老Hf模式年龄(1543~2129Ma),揭示松多早侏罗世闪长岩经历了古老地壳物质的部分熔融。Sr/Y-Y和(La/Yb)N-YbN判别图解显示,其形成可能与赞岐岩的岩浆作用过程相似,形成于消减带之上的地幔楔环境。综合研究表明,松多地区在早侏罗世处于雅鲁藏布新特提斯洋板片向欧亚大陆俯冲的活动陆缘构造背景。     

青藏高原南羌塘荣玛晚侏罗世闪长岩:班公湖——怒江特提斯洋向北俯冲产物

班公湖—怒江特提斯洋的演化一直以来备受关注,对于其俯冲极性存在不同认识。报道在青藏高原南羌塘荣玛地区新发现的晚侏罗世闪长岩年代学、地球化学和锆石Hf同位素特征。LA-MC-ICP-MS锆石U-Pb年龄结果表明,岩石形成于149.7±0.8Ma,时代为晚侏罗世。岩石呈富碱,低Mg O、TFe O、Ca O,富集轻稀土元素和Rb、Th、U、K等元素,亏损Ta、Nb、P、Ti等元素。锆石εHf(t)值为正值,并且具有较大的变化范围(+4.26~+9.29),指示岩浆来源于幔源和壳源岩浆的混合。结合区域地质背景认为,荣玛地区晚侏罗世闪长岩为班公湖—怒江特提斯洋向北俯冲所引起的幔源和壳源岩浆混合作用的产物。     

东昆仑马尼特地区片麻状花岗闪长岩锆石U-Pb年代学、地球化学及其构造背景

为确定东昆仑马尼特地区片麻状花岗闪长岩的形成时代、源区性质和构造背景,对其进行了锆石U-Pb年代学、地球化学和锆石Hf同位素研究.本次测试的片麻状花岗闪长岩锆石LA-ICP-MS(laser ablation inductively coupled plasma mass spectrometry) U-Pb加权平均年龄为495.6±1.1 Ma(MSWD=0.13),属于晚寒武世.马尼特片麻状花岗闪长岩SiO₂含量为61.47%~63.99%,Na₂O、K₂O和CaO含量分别为2.91%~3.64%、0.93%~2.31%和4.29%~6.52%,全碱ALK=3.92%~5.69%,铝饱和指数A/CNK=0.83~0.97,属准铝质钙碱性系列岩石.岩石具有富集大离子亲石元素(Rb、K)和不相容元素(Th、U),相对亏损Nb、Ta、Zr、Ti高场强元素的特征,Nb/Ta、La/Nb、Th/Nb、Th/La等比值显示出岩石具有壳源特征.岩石具有高的ε_Hf(t)值(12.2~15.0),Hf两阶段模式年龄在506~662 Ma范围内,其岩浆源区初始物质主要来源于新生地壳.岩石在微量元素Rb-(Y+Nb)构造判别图落入火山弧花岗岩区域,在R1-R2构造判别图落入板块碰撞前消减区花岗岩区域.结合岩石成岩年龄、地球化学特征以及区域构造演化,推测其应形成于原特提斯洋俯冲的构造环境,属于大洋洋壳向南俯冲的产物,即柴达木地块和万宝沟大洋玄武岩高原之间的洋壳同时向南、北发生双向俯冲消减.      

北阿尔金地区早古生代洋壳俯冲时限:来自斜长花岗岩和花岗闪长岩的证据

蛇绿岩在不同演化阶段自身形成的花岗质岩石和侵入到蛇绿岩中的花岗质岩石对于蛇绿岩的精确定年具有重要意义,是揭示洋壳俯冲时限的有力证据。对北阿尔金红柳沟—拉配泉蛇绿岩中斜长花岗岩和花岗闪长岩的锆石U-Pb及Lu-Hf同位素分析表明,红柳沟斜长花岗岩和花岗闪长岩的锆石LA-ICP-MS U-Pb定年结果分别为(501±3)Ma和(496±2)Ma,表明北阿尔金洋的俯冲时限可能开始于中寒武世或更早。斜长花岗岩和花岗闪长岩的锆石εHf(t)值均为正值,结果分别为1.6~5.6和3.3~6.9,反映其源区均为亏损型地幔。全岩地球化学分析结果表明,斜长花岗岩具有高Si O2、高Sr、低Y和相应的高Sr/Y等类似于埃达克质岩石的特征,可能来自热的洋壳俯冲到石榴角闪岩相条件下变基性岩发生小比例部分熔融形成,且其形成深度应该在40~50 km;花岗闪长岩属于高钾钙碱性系列岩石,可能代表了岛弧环境下下地壳基性岩石部分熔融的产物。年代学分析表明,北阿尔金洋可能存在南北双向俯冲,并且北阿尔金洋向北俯冲可能略早于向南俯冲。北阿尔金和北祁连的俯冲时限对比研究表明,北阿尔金早古生代缝合带是北祁连早古生代缝合带的西延部分。     

新疆四顶黑山花岗岩体锆石LA-ICP-MS U-Pb年龄及地质意义

新疆东天山位于中亚造山带南缘,天山—兴安造山系北天山造山带东段,发育大量泥盆纪—石炭纪花岗岩,其形成过程多与觉罗塔格洋的俯冲作用有关。四顶黑山花岗岩体位于东天山觉罗塔格构造岩浆带的东端,岩体在地表呈不规则状产出,侵位于元古界片岩-变火山岩、奥陶系变玄武岩和泥盆系雀儿山群火山岩;主要岩石类型为花岗岩和花岗闪长岩。花岗岩的LA-ICP-MS锆石U-Pb年龄为380.4 Ma±3.7 Ma,表明岩体形成于晚泥盆世。岩石表现出高硅(w(SiO_2)=64.87%~74.71%)、高碱(w(K_2O)=3.35%~4.68%,w(Na_2O)=2.26%~3.85%)、富铝(w(Al_2O_3)=11.82%~14.13%)和低MgO(w(MgO)=0.56%~2.12%)、CaO(w(CaO)=1.68%~3.74%)、TiO_2(w(TiO_2)=0.26%~0.57%)、P_2O_5(w(P_2O5)=0.01%~0.19%)特征,A/CNK=0.83~1.00;富集Ba、K、La、Ce、Nd,亏损Th、Nb、Ta、Sr、Ti,铕负异常较明显(δEu=0.70~0.73);具有岛弧型花岗岩特征。四顶黑山花岗岩体形成于岛弧环境,属于觉罗塔格洋向南俯冲过程中的产物。四顶黑山花岗岩体两侧的镁铁-超镁铁质岩体的形成时代应晚于晚泥盆世。     

内蒙古北山造山带百合山地区350 Ma石英闪长岩的成因及对红石山-百合山洋俯冲时限的制约

对内蒙古白山岩浆弧内百合山石英闪长岩进行了LA-ICP-MS锆石U-Pb测年、Hf同位素及岩石地球化学分析。结果显示,该岩体的形成年龄为350.8±1.5 Ma,岩浆锆石的ε_(Hf)(t)值在5.28～9.88之间,模式年龄为724～1018 Ma。地球化学数据显示,百合山石英闪长岩为一套I型钙碱性系列岩石,富碱(Na_2O+K_2O=6.03%～6.96%),富钠(Na_2O/K_2O2),较低的Mg~#(35.48～39.78)、Ni(2.06×10~(-6)～5.54×10~(-6))和Cr(2.11×10~(-6)～7.93×10~(-6))含量。相对富集轻稀土元素,重稀土分馏不明显,较低的(La/Yb)_N值(4.28～5.60),无明显Eu异常,相对富集Rb、K、U等大离子亲石元素,亏损Nb、Ta、P、Ti等高场强元素等,地球化学成分表明,石英闪长岩具有俯冲带成因的特征。石英闪长岩的锆石U-Pb年龄和岩石成因证明了350 Ma石英闪长岩是晚古生代白山岩浆弧内首次发现的可以明确与红石山-百合山洋俯冲消减作用有关的最早的弧岩浆记录。表明红石山-百合山洋于约350 Ma之前就已经开始发生俯冲消减,比前人一般认为的俯冲开始的时间提前了22 Ma。     

中天山巴仑台地区变形花岗岩类LA-ICP-MS-U-Pb年代学及其构造意义

本文对巴仑台地区中天山南北边缘的变形花岗岩体进行了详细的锆石LA-ICP-MS-U-Pb年代学研究。中天山北缘花岗质片麻岩中岩浆锆石结晶年龄为630.0±5.0 Ma,代表了中天山微陆基底的新元古代岩浆事件年龄;其变质增生锆石边的年龄为440.9±3.3 Ma,精确限定了中天山北缘洋盆闭合与碰撞造山作用的时代为早志留世。中天山南缘糜棱岩化花岗闪长岩中岩浆锆石结晶年龄为389.5±3.2 Ma,指示出中天山南缘洋壳在中泥盆世向北俯冲形成陆缘岩浆弧;其变质增生锆石边的年龄为362.1±4.3 Ma,精确限定了中天山南缘洋盆闭合与碰撞造山作用的时代为晚泥盆世末期。研究结果还表明中天山微陆块具有年龄为2.5Ga和1.8Ga的古老结晶基底。     

Zircons LA-ICP-MS U-Pb Dating on the Baluntai Deformed Granitoids,Central Tianshan Block, Northwest China,and Its Tectonic Implications

本文对巴仑台地区中天山南北边缘的变形花岗岩体进行了详细的锆石LA-ICP-MS U-Pb年代学研究.中天山北缘花岗质麻岩中岩浆锆石结晶年龄为630.0±5.0Ma,代表了中天山微陆基底的新元古代岩浆事件年龄;其变质增生锆石边的年龄为440.9±3.3Ma,精确限定了中天山北缘洋盆闭合与碰撞造山作用的时代为早志留世.中天山南缘糜棱岩化花岗闪长岩中岩浆锆石结晶年龄为389.5±3.2Ma,指示出中天山南缘洋壳在中泥盆世向北俯冲形成陆缘岩浆弧;其变质增生锆石边的年龄为362.1±4.3Ma,精确限定了中天山南缘洋盆闭合与碰撞造山作用的时代为晚泥盆世末期.研究结果还表明中天山微陆块具有年龄为2.5Ga和1.8Ga的古老结晶基底.     

粤东新寮岽铜多金属矿区石英闪长岩锆石U-Pb年龄、地球化学及Hf同位素组成

新寮岽铜多金属矿是近年来在粤东地区新发现的一个铜矿床。对该矿床中与成矿关系密切的石英闪长岩进行了锆石U-Pb年龄、地球化学、Hf同位素研究,以约束其形成时代和岩石成因。测得石英闪长岩LA-ICP-MS锆石U-Pb年龄为161±1Ma(n=25,MSWD=0.57),被解释为岩体的成岩年龄。地球化学数据显示,石英闪长岩具有碱含量中等(Na2O+K2O=3.99%~5.05%),高镁(Mg O=4.53%~4.91%)的特征,属准铝质钙碱性系列。稀土和微量元素特征表明,其富集轻稀土元素和大离子亲石元素(K、Rb、Ba、Th、U),亏损重稀土元素和高场强元素(Nb、Ta、Ti、P),具弱负Eu异常(δEu=0.68~0.76)。电子探针分析结果表明,石英闪长岩中黑云母为镁质黑云母,具环带结构,斜长石为拉长石。锆石Hf同位素分析结果表明,石英闪长岩εHf(t)为-5.8~2.7,tDM2=1.03~1.58Ga。岩石地球化学和锆石Hf同位素组成特征表明,石英闪长岩源区较复杂,为壳幔混合源,可能为俯冲板片部分熔融并与楔形地幔橄榄岩相互作用形成,且岩浆上侵过程中有古老地壳物质的混染。综合岩石地球化学、矿物化学及Hf同位素特征,结合区域构造演化史和前人研究成果,推测岩体形成于俯冲背景下的活动大陆边缘环境。     

Wavelength-dispersive X-ray fluorescence spectrometric determination of Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites

Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.     

高压微波消解法测定醋酸纤维过滤器采集的微尘粒子中的砷镉钴铬铜铁锰镍铅钒锌

最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提     

硅酸盐类样品中硅、铁、铝、钛、锰、钙、镁、钾、钠和磷的x射线荧光光谱测定

本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.     

Viscous, cohesive, non-Newtonian, depositing, radial slurry flow

Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.     

硅酸盐中铁、锰、钛、钙、钾、磷、硅、铝、镁、钠、锶、铷、钡的X-射线荧光光谱定量测定

本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。     

岩石密度和超高压岩石折返速率

在常温常压条件下对中国大陆科学钻CCSD主孔100-3000米岩心样品进行了密度测量,建立了密度连续剖面,并界定了不同超高压岩石的密度值。通过对比高温高压物性实验资料,岩石密度随着退变程度增强而降低,榴辉岩密度变化序列为3.52g/cm3→3.49g/cm3→3.07g/cm3→2.93g/cm3。超高压长英质岩石密度变化序列为3.00g/cm→2.80g/cm3→2.65g/cm3。上述实验资料是讨论不同折返阶段岩石所受浮力的基础,为研究折返速率大小提供了基本参数。本文通过折返板块运动平衡时,上浮力与粘滞力平衡这一关系式,定量研究了大陆俯冲板块的折返速率,认为密度差产生上浮力从而引起折返,温度对板块折返速率的影响最为显著;密度差大小、折返角度、折返板块大小对折返速率也有直接的影响。定量模拟分析表明,在温度高于850℃时,板块的折返速率可以超过100mm/a;当温度降至700℃时,折返速率则低于1.5mm/a。作者认为在折返早期,温度较高,板块快速折返至60-70km榴辉岩相深度;随着传导散热,温度降低,板块以较慢的速率折返至中下地壳。折返速率的估算表明,浮力是板块折返第一阶段(从>100km深部折返至<40km的中下地壳)的主要驱动力。     

Bellechester,Minnesota, USA,lagoon collapses

Bellechester, Minnesota, is a small community of approximately 155 residents located on the county line between Goodhue and Wabasha counties in southeast Minnesota's karst region. Bellechester is served by a 21-year-old wastewater treatment facility (WWTF) consisting of three waste-stabilization ponds. On 28 April 1992 six sinkholes were discovered to have drained cell 2 of the WWTF resulting in the loss of approximately 8.7×10⁶ 1 of partially treated effluent and about 600 m³ of soil into previously undetected subsurface voids of unknown dimensions. In the week following the collapse, approximately 200 water wells located within a 5-km radius of the WWTF were sampled in an after-the-fact, emergency sampling program. Twelve samples with elevated fecal coliform levels, 18 samples with nitrate-nitrogen greater than the 10 mg/1 standard, and no samples with elevated chlorides were found. However, the elevated levels could not be unambiguously attributed to the WWTF collapse. This is the third WWTF to fail by sinkhole collapse in southeast Minnesota since 1974. All three collapsed lagoons have been located in similar geomorphic and stratigraphic settings. However, at least two lagoons have collapsed in the adjacent area in northeast Iowa, and these lagoons are located at different stratigraphic positions. Twenty-two WWTFs constructed in southeast Minnesota's karst region in the last 25 years have been identified as subject to potential sinkhole collapse. An unknown but significant number of manure storage lagoons, flood control structures, etc., have also been constructed in the karst region and are at risk. Public agencies are beginning to develop plans to deal with the risk associated with existing and future waste lagoons in this environment. The critical hydrogeologic parameters that can be used to prioritize the risk of collapse at existing facilities include: (1) the lithology of the first bedrock beneath each lagoon, (2) the thickness of surficial materials between the lagoon and the bedrock surface, (3) the presence and construction of liners (seepage rate), and (4) the proximity to existing sinkholes.     

Mercury,arsenic, antimony,and selenium contents of sediment from the Kuskokwim River,Bethel, Alaska,USA

The Kuskokwim River at Bethel, Alaska, drains a major mercury-antimony metallogenic province in its upper reaches and tributaries. Bethel (population 4000) is situated on the Kuskokwim floodplain and also draws its water supply from wells located in river-deposited sediment. A boring through overbank and floodplain sediment has provided material to establish a baseline datum for sediment-hosted heavy metals. Mercury (total), arsenic, antimony, and selenium contents were determined; aluminum was also determined and used as normalizing factor. The contents of the heavy metals were relatively constant with depth and do not reflect any potential enrichment from upstream contaminant sources.     

滇东南花岗岩与锡、银、铜、铅、锌多金属矿床的成因关系

滇东南锡、银、铅、锌多金属矿床主要分布在个旧、白牛厂、都龙3个矿区,而滇东南较大的3个花岗岩体又分别出露在3个矿区或附近.花岗岩体均形成于燕山晚期,岩石化学、矿物成分相似,富含锡、银、铅、锌、钨、铜等成矿元素.矿床主金属元素组合与岩体之间的距离由远而近出现由锡、钨、(铍、铌、钽)→锡、钨、(铁)、铜、铟→锡、铅、锌、银、铟、(锑)有规律的变化.花岗岩浆是成矿物质来源和成矿热源.岩浆侵入初期使上覆地层隆起产生背斜(凹陷部位成向斜);同时使地层产生一系列裂隙、压性断层或层间断裂;岩浆侵入晚期,这些断层再次活动,表现为张性,岩浆产生的含矿热液沿由其活动所造成的断裂迁移、充填、交代、沉淀而形成矿床.