西藏南部冈底斯岩基曲林岩体渐新世-中新世高Sr/Y比岩浆作用及其对深部过程的启示

曲林岩体位于冈底斯带中段的南缘,为渐新世-中新世复合岩体,主体为粗粒花岗斑岩,被后期煌斑质、花岗闪长质和花岗质岩脉切割,是多期岩浆作用的产物,出露面积约8km²。花岗斑岩两组样品（T0849-PG和T0849-G）的锆石U-Pb定年结果分别为29.7±0.1Ma和30.0±0.2Ma。花岗斑岩为高钾,准铝质,低MgO,高度富集轻稀土元素（LREE）和大离子亲石元素（LILE）,亏损重稀土元素（HREE）和高场强元素（HFSE）。此外具有高Sr、Sr/Y、（La/Yb）_N;低Y和Yb,弱Eu负异常等特征。岩体内发育一系列近南北向展布的花岗闪长玢岩脉,其中两组样品的锆石U-Pb定年结果分别为15.5±0.1Ma（T0848-PY）和14.4±0.1Ma（T0850）。两条花岗闪长玢岩脉具有与岩体主体相似的稀土和微量元素分布模式,同样富集轻稀土及大离子亲石元素,亏损重稀土及高场强元素。花岗斑岩的⁸⁷Sr/⁸⁶Sr_（i）=0.706102~0.706202,ε_Nd（t）=-0.6~+0.6,锆石ε_Hf（t）=+4.9~+7.9;花岗闪长玢岩脉的⁸⁷Sr/⁸⁶Sr_（i）=0.705429~0.705474,ε_Nd（t）=-1.4~-0.2,锆石ε_Hf（t）=+2.6~+7.6。本文数据和文献数据结果表明：曲林花岗斑岩与花岗闪长玢岩脉均来源于加厚南拉萨下地壳的部分熔融,很可能与增厚的深部岩石圈的拆沉或俯冲印度岩石圈的撕裂诱发软流圈上涌有关。     

藏南冈底斯岩基东段朗县杂岩早白垩世岩浆作用:新特提斯洋二次俯冲

新特提斯洋长期俯冲消减作用在早白垩世可能经历二次俯冲启动或板片俯冲几何形态的重大转换。确定西藏南部冈底斯岩基早白垩世岩浆作用的岩石地球化学特征和作用方式是甄别上述过程的关键,对理解新特提斯洋的俯冲演化过程至关重要。本文就冈底斯岩基东段朗县杂岩中保存的各类早白垩世岩浆岩,开展了锆石U-Pb地质年代学和Hf同位素、全岩元素和同位素（Sr-Nd）组成分析。数据结果表明：1）基性岩侵位时代为早白垩世晚期（103.6~100.8Ma）,为高钾钙碱性偏铝质岩石,锆石ε_Hf（t）=+0.3~+5.7,全岩ε_Nd（t）=-0.8和-0.3,暗示其岩浆源区具有大量俯冲沉积物或流体的混入,为沉积物熔体和流体交代的地幔楔物质部分熔融的产物,经历了一定程度的角闪石分离结晶作用;2）中性岩形成于99.8~97.6Ma,略晚于基性岩,其主量元素与基性岩具有较好的线性关系,全岩ε_Nd（t）=+1.1,具有较多的地幔物质参与,为基性岩浆进一步演化形成;3）酸性岩（脉体）记录了多阶段岩浆作用（124.1~95.3Ma）,根据同位素组成不同进一步划分为两类,第一类具有较低的全岩ε_Nd（t）值（-8.3~-6.0）,其岩浆源区显示富集特征,t_DM2=1385~1586Ma,由古老地壳物质的再熔融形成;第二类的锆石ε_Hf（t）值（-2.8~+3.2）变化较大,岩脉的锆石ε_Hf（t）=+0.4~+8.1,t_DM=428~906Ma,全岩ε_Nd（t）=+0.1和+0.8,表明岩浆源区具有不均一性,为古老地壳物质被富流体地幔岩浆改造形成;和4）镁铁质包体的主量元素与寄主花岗岩具有较好的线性关系,锆石的Hf同位素组成变化较大（ε_Hf（t）=-9.3~+4.1）,变化范围可达13个ε单位,为岩浆混合成因。寄主花岗岩和角闪辉长岩分别作为酸性和基性端元,是基性岩浆与其诱发古老地壳熔融形成的花岗质岩浆经混合形成。结合冈底斯岩基早白垩世岩浆岩的研究结果,朗县杂岩在早白垩世（124~97Ma）的岩浆作用具有明显的岩浆混合现象,锆石Hf和全岩Sr-Nd同位素组成变化较大,可达13个ε单位,其岩浆源区复杂且富含流体,代表了新特提斯洋在早期（240~144Ma）经历漫长的俯冲之后,在早白垩世时期（~120Ma）俯冲带发生跃迁或俯冲角度达到临界点,导致大量俯冲沉积物和流体沿俯冲带俯冲下去,与发生部分熔融的地幔楔物质混合,底侵导致上覆古老地壳物质的再熔融,形成早白垩世复杂的岩浆岩组合,很可能是新特提斯洋二次俯冲开始的标志。     

藏南冈底斯岩基东段米林地区晚侏罗世-白垩纪侵入岩的岩石成因和地球动力学意义

冈底斯岩基东部的米林地区发育辉长质片麻岩和花岗质片麻岩近垂向相间排布的侵入杂岩体及东侧未变形闪长岩体。野外穿切关系和锆石SHRIMP U-Pb年龄结果表明：早期辉长质片麻岩（146.3±1.6Ma）被晚期花岗质片麻岩（141.7±2.0Ma）侵入,并一起经历了后期变质作用（~90Ma）和晚白垩世闪长质岩浆作用（87.8±1.1Ma）。辉长质片麻岩具有E-MORB特征,经历了富Ti矿物相的堆晶作用,母岩浆主要来源于板片流体交代上覆亏损地幔楔物质（ε_Hf（t）=+9.9~+14.5;ε_Nd（t）=+3.0~+4.1）。花岗质片麻岩具有岛弧型岩浆岩的地球化学特征,同时伴有Fe-Ti氧化物的分离结晶,源区物质主要为部分熔融的初生下地壳（ε_Hf（t）=+10.9~+15.1;ε_Nd（t）=+4.1~+4.3）。闪长岩具有弱的Eu正异常,暗示源区存在斜长石的堆晶作用,其母岩浆来源于板片流体交代上覆亏损地幔楔物质（ε_Hf（t）=+12.2~+15.6）,并在岩浆演化的过程中混入地壳物质。冈底斯岩基南缘发育晚侏罗世的辉长岩和早白垩世花岗可能是第一次新特提斯洋北向俯冲即将终止的产物。晚白垩世岩浆岩是与新特提斯洋再次俯冲引起的峰期岩浆活动的标志,可能是板块回撤引发软流圈上涌的产物。     

西秦岭温泉钼矿区含钼花岗斑岩锆石U-Pb年龄、Hf同位素组成及岩浆物质来源讨论

温泉钼矿床位于西秦岭造山带北缘,是西秦岭地区唯一斑岩型钼矿床。矿体产于花岗斑岩体及其与围岩接触带内。对温泉钼矿含矿花岗斑岩开展锆石U-Pb年代学与原位Hf同位素研究,有助于精确约束含钼花岗斑岩时代,揭示岩浆演化信息,深化温泉钼矿床成因的认识。本文利用LA-ICPMS锆石U-Pb定年方法,对温泉钼矿区含钼岩体进行精确同位素定年。结果表明：花岗斑岩的锆石环带结构明显,Th/U比值较大（0.41~0.88）,为典型的岩浆锆石,含钼花岗斑岩侵位年龄为212.43~213.4 Ma,其侵入的似斑状二长花岗岩年龄（围岩）则为219.9 Ma,均属晚三叠世岩浆活动的产物。温泉矿区花岗斑岩锆石Hf同位素组成较为一致,ε_Hf（t）值均为负值,介于-1.89~-0.63,平均-1.59,在ε_Hf（t）-t图解中,样点集中分布于球粒陨石以及亏损地幔线之下,暗示其岩浆源区较单一,应为经改造过的地壳物质部分熔融的产物。二阶段模式年龄（T_DM2）主要集中在1291~1408 Ma,表明中元古代地壳物质可能为岩体主要来源。     

粤北白沙地区晚侏罗世高分异I型细粒花岗岩年代学、地球化学特征及其地质意义

受东西向佛冈-丰良断裂控制的佛冈复式岩体形成于多期次和不同来源的岩浆侵入作用。白沙地区细粒黑云母二长花岗岩体位于佛冈岩体北缘,是佛冈岩体的一部分,成因目前还不明确。文章以该岩体细粒黑云母二长花岗岩为研究对象,进行了岩石学、锆石U-Pb年代学、地球化学和Hf同位素组成研究。研究结果显示,白沙地区细粒黑云母二长花岗岩LA-ICP-MS锆石U-Pb加权平均年龄为155.6~157.1 Ma,表明其侵位于晚侏罗世。岩体具高硅（w（SiO₂）=70.74%~77.47%）、富碱（w（Na₂O+K₂O）=5.78%~8.62%）、低磷（w（P₂O₅）=0~0.10）等特征,富集Rb、Th、U、K、Pb、Nd、Zr和Hf等元素,亏损Ba、Nb、La、Ce、Sr、P、Eu和Ti等元素。岩石总体上明显富集轻稀土元素（（La/Yb）_N=0.94~54.69,1个为0.94）,具明显的负Eu异常（δEu=0.07~0.57,n=6）,个别正Eu异常（1.00~1.16,n=3）。岩体地球化学特征指示,细粒黑云母二长花岗岩为高分异I型花岗岩。岩体形成于古太平洋板块（库拉板块）与欧亚板块俯冲作用和菲律宾地块与南中国-印支地块的岩石圈消减作用下,岩石圈伸展-减薄,导致地幔物质上涌,在高温条件热流作用下幔源物质诱导下地壳中-元古代物质部分熔融形成。     

大别造山带研子岗碱性岩体成因及其构造意义：锆石U-Pb年龄和地球化学制约

出露于大别造山带西南部的研子岗碱性杂岩体侵位于元古代和新太古代随县群中,本文采用锆石LA-ICPMS U-Pb定年方法,获得岩体的主体岩性角闪正长岩的岩浆锆石年龄为133± 1Ma,代表岩体的结晶年龄,这一年龄也是大别造山带中已知形成时代最早的早白垩世碱性岩体的结晶年龄（单颗粒锆石U-Pb法）。研子岗碱性杂岩体具有碱性岩典型的富碱（K₂O＋Na₂O＝8.38%~11.26%）、低硅（SiO₂＝63.41%~66.51%）的特点。主要矿物为微斜条纹长石,暗色矿物主要为镁角闪石。地球化学特征表明,全部岩石均具有高Ba-Sr花岗岩类高Ba（1230× 10^-6~4865× 10^-6）、高Sr（583× 10^-6~2088× 10^-6）和无负Eu异常（Eu/Eu^*＝0.97~1.12）等特征,并具有A型花岗岩的部分地球化学特征。岩石的Y/Nb比（0.46~1.09）较低,具洋岛玄武岩的部分地球化学特征,(⁸⁷Sr/⁸⁶Sr) _i初始比值（0.70513~0.70543）较低,表明岩体的物源主要来源于幔源。Nd二阶段模式年龄(t_2DM=1859~1942Ma)和锆石Hf二阶段模式年龄(t_DM2=2130~2330Ma）较老,ε_Nd(133)值(-12.5~-11.4）和ε_Hf(133)值(-18.2~-15.4）较低。综合分析表明,岩体主要为古老的富集岩石圈地幔物质低程度部分熔融和随后地壳物质轻度AFC（混染和分离结晶作用）过程的产物,源岩熔融的热量主要来源于软流圈物质的上涌底侵作用提供。研子岗岩体形成于碰撞后构造环境,岩体的形成预示着大别造山带早白垩世造山过程的即将结束,板内时期的即将来临。     

粤东铁坑坳铁锡多金属矿床锆石及锡石U-Pb年代学、Nd-Hf同位素特征及其意义

铁坑坳铁锡多金属矿床位于粤东莲花山断裂带西部,矿区出露的花岗岩类主要有粗粒二长花岗岩和花岗闪长斑岩,花岗质岩石与碳酸盐岩的接触带中发育铁锡多金属矿化。该矿区的成岩成矿时代尚不明确,成矿与哪一种岩体具有成因上的联系也不清楚。文章选择与铁锡多金属矿体相关的花岗岩类的锆石和块状矿石中的锡石,首次开展LA-ICP-MS U-Pb定年和Nd-Hf同位素研究。结果表明：粗粒二长花岗岩和花岗闪长斑岩的锆石U-Pb年龄分别为（132±1） Ma （n=24,MSWD=0.78）和（94±1） Ma （n=25,MSWD=1.80）;块状矿石中锡石U-Pb年龄为（130±3） Ma （n=36,MSWD=0.62）,成矿时代与粗粒二长花岗岩形成时代基本一致,均形成于早白垩世;粗粒二长花岗岩的锆石ε_Hf （t）变化于-4.9~-0.1,平均值为-2.8,地壳Hf模式年龄T_DMC=1192~1497 Ma,平均值为1366 Ma,全岩ε_Nd （t）值介于-8.8~-8.7,Nd同位素二阶段模式年龄T_DM2变化于1630~1642 Ma;花岗闪长斑岩的锆石ε_Hf （t）变化于-5.7~-2.9,平均值为-4.4,地壳Hf模式年龄T_DMC=1342~1523 Ma,平均值为1440 Ma,全岩ε_Nd （t）值介于-5.4~-4.9,Nd同位素二阶段模式年龄T_DM2变化于1291~1332 Ma。Nd-Hf同位素综合研究表明,粗粒二长花岗岩的源区物质主要来自于中元古代地壳,有少量幔源组分或新生地壳的加入,花岗闪长斑岩的源区物质中幔源组分或新生地壳的混入比例高于粗粒二长花岗岩。     

安徽滁州和管店早白垩世高镁埃达克质侵入岩的成因:锆石U-Pb年代学和Sr-Nd-Hf同位素的制约

本文以华北陆块东部早白垩世滁州闪长玢岩和管店石英闪长岩为研究对象,报道了新的全岩地球化学（主量元素、微量元素以及Sr-Nd同位素）以及锆石U-Pb年代学和Hf同位素的综合研究结果,进而约束其岩石成因和构造意义。滁州闪长玢岩中锆石发育振荡环带,管店石英闪长岩中锆石具条痕状吸收的特点,它们均为岩浆成因。锆石LA-ICP-MS U-Pb定年结果显示,滁州和管店闪长质锆石年龄分别为128±1Ma和130±2Ma,表明二者均形成于早白垩世。地球化学特征显示,滁州和管店闪长质岩石具有类似的主量元素和微量元素组成,整体具中等的SiO₂含量（58.55%~60.12%）和富MgO（4.43%~5.10%,Mg^#=57~61）的特征,Na₂O/K₂O比值为1.20~1.47,属于高钾钙碱性系列岩石;富集轻稀土元素和大离子亲石元素（如Rb、Ba）,亏损重稀土元素和高场强元素（如Nb、Ta、Zr、Hf）,并具不同程度的Eu负异常（δEu=0.85~0.93）。它们具高的Sr（575×10^-6~1035×10^-6）和低的Y含量（10.2×10^-6~15.3×10^-6）以及高的Sr/Y比值（57~69）,属于埃达克质岩石。此外,滁州和管店闪长质岩石具有类似的Sr-Nd以及锆石Hf同位素的特征,滁州闪长玢岩的⁸⁷Sr/⁸⁶Sr初始比值介于0.7061~0.7066之间,ε_Nd（t）值为-17.7~-16.9,锆石ε_Hf（t）值变化于-23.1~-19.1之间,而管店石英闪长岩的⁸⁷Sr/⁸⁶Sr初始比值为0.7046~0.7059,ε_Nd（t）值为-18.7~-15.8,锆石ε_Hf（t）值为-25.6~-20.0。综合上述,滁州和管店闪长质岩石均属于高镁埃达克质岩石,起源于拆沉的加厚下地壳部分熔融的熔体与地幔橄榄岩反应的产物,形成于早白垩世华北东部陆块拆沉作用下的伸展背景。     

皖南歙县邓家坞钼矿床年代学及Hf同位素地球化学研究

歙县邓家坞片麻状花岗闪长岩体位于扬子陆块南缘,区内钼矿体主要产于岩体与变质流纹凝灰岩的外接触带上,受区内北东向的断裂控制。歙县邓家坞花岗闪长岩具有强过铝质的特征,为S-型花岗岩,属于高钾钙碱性系列岩石。岩石富集大离子亲石元素(Rb、Th、K),相对亏损高场强元素(Nb、Ta、Ti),稀土元素含量较低(ΣREE=114.3×10^-6~259.1×10^-6),轻重稀土分异明显(ΣLREE/ΣHREE=6.48~10.98),中等的Eu负异常(Eu_N/Eu_N^*=0.46~0.60),具有典型岛弧岩浆岩的特征。锆石U-Pb同位素定年结果显示²⁰⁶Pb/²³⁸U表面年龄为739~816Ma,加权平均年龄为772±11Ma (MSWD=5.0),表明邓家坞片麻状花岗闪长岩体形成于新元古代,与皖南新元古代花岗闪长岩的主成岩年龄(740~825Ma)基本一致。根据岩石Zr含量计算出歙县邓家坞花岗闪长岩的"锆石饱和温度"为792~827℃。锆石Hf同位素ε_Hf(t)为0.55~4.69,平均值为2.48,二阶段模式年龄(t_DM2)为1364~1565Ma,表明邓家坞片麻状花岗闪长岩源区主要为新生地壳组分。邓家坞钼矿5个辉钼矿样品Re-Os同位素定年的模式年龄为141.1~141.6Ma,等时线年龄为141.8±2.2Ma,表明该钼矿的成矿时代为早白垩世。邓家坞片麻状花岗闪长岩体不是成矿岩体,因此推测可能其深部有隐伏的早白垩世岩体。辉钼矿的Re含量为12.6×10^-6~43.8×10^-6,表明成矿物质以壳源为主。     

新疆准噶尔北东缘乌图布拉克岩体形成时代、地球化学特征及地质意义

乌图布拉克岩体位于准噶尔北东缘,额尔齐斯-玛因鄂博构造带南侧。岩体主要由花岗闪长岩和二长花岗岩组成,有少量石英闪长岩和钾长花岗岩。岩体的锆石SHRIMP U-Pb年龄为360.1±3.6Ma。岩石的K₂O+Na₂O=7.05%~9.48%,A/NKC=0.91~1.04,属准铝-过铝质“I”型花岗岩。岩石稀土总量低,∑REE为72×10^-6~184×10^-6,轻稀土富集,(La/Yb)_N=5~13。石英闪长岩、花岗闪长岩、二长花岗岩具弱的铕负异常或无明显异常（δEu=0.72~0.98）;钾长花岗岩铕负异常明显（δEu=0.15~0.21）。在微量元素配分模式中,具有Sr、Ba、P、Ti的亏损,而Nb、Ta亏损不明显。岩石有低的Sr初始值（0.70165~0.70462）和高的ε_Nd(t)u（+4.7~+6.9）。2个样品的Nd模式年龄分别为758Ma和551Ma。上述特征表明,岩浆可能具有较复杂的来源,推测该岩体岩浆可能来源于年轻的玄武质地壳,并有幔源物质的加入。综合本文资料及区域地质特征分析,阿尔泰造山带后碰撞时限可能为360~290Ma,即泥盆纪末-石炭纪末。     

Wavelength-dispersive X-ray fluorescence spectrometric determination of Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites

Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.     

高压微波消解法测定醋酸纤维过滤器采集的微尘粒子中的砷镉钴铬铜铁锰镍铅钒锌

最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提     

硅酸盐类样品中硅、铁、铝、钛、锰、钙、镁、钾、钠和磷的x射线荧光光谱测定

本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.     

Viscous, cohesive, non-Newtonian, depositing, radial slurry flow

Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.     

硅酸盐中铁、锰、钛、钙、钾、磷、硅、铝、镁、钠、锶、铷、钡的X-射线荧光光谱定量测定

本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。     

岩石密度和超高压岩石折返速率

在常温常压条件下对中国大陆科学钻CCSD主孔100-3000米岩心样品进行了密度测量,建立了密度连续剖面,并界定了不同超高压岩石的密度值。通过对比高温高压物性实验资料,岩石密度随着退变程度增强而降低,榴辉岩密度变化序列为3.52g/cm3→3.49g/cm3→3.07g/cm3→2.93g/cm3。超高压长英质岩石密度变化序列为3.00g/cm→2.80g/cm3→2.65g/cm3。上述实验资料是讨论不同折返阶段岩石所受浮力的基础,为研究折返速率大小提供了基本参数。本文通过折返板块运动平衡时,上浮力与粘滞力平衡这一关系式,定量研究了大陆俯冲板块的折返速率,认为密度差产生上浮力从而引起折返,温度对板块折返速率的影响最为显著;密度差大小、折返角度、折返板块大小对折返速率也有直接的影响。定量模拟分析表明,在温度高于850℃时,板块的折返速率可以超过100mm/a;当温度降至700℃时,折返速率则低于1.5mm/a。作者认为在折返早期,温度较高,板块快速折返至60-70km榴辉岩相深度;随着传导散热,温度降低,板块以较慢的速率折返至中下地壳。折返速率的估算表明,浮力是板块折返第一阶段(从>100km深部折返至<40km的中下地壳)的主要驱动力。     

Bellechester,Minnesota, USA,lagoon collapses

Bellechester, Minnesota, is a small community of approximately 155 residents located on the county line between Goodhue and Wabasha counties in southeast Minnesota's karst region. Bellechester is served by a 21-year-old wastewater treatment facility (WWTF) consisting of three waste-stabilization ponds. On 28 April 1992 six sinkholes were discovered to have drained cell 2 of the WWTF resulting in the loss of approximately 8.7×10⁶ 1 of partially treated effluent and about 600 m³ of soil into previously undetected subsurface voids of unknown dimensions. In the week following the collapse, approximately 200 water wells located within a 5-km radius of the WWTF were sampled in an after-the-fact, emergency sampling program. Twelve samples with elevated fecal coliform levels, 18 samples with nitrate-nitrogen greater than the 10 mg/1 standard, and no samples with elevated chlorides were found. However, the elevated levels could not be unambiguously attributed to the WWTF collapse. This is the third WWTF to fail by sinkhole collapse in southeast Minnesota since 1974. All three collapsed lagoons have been located in similar geomorphic and stratigraphic settings. However, at least two lagoons have collapsed in the adjacent area in northeast Iowa, and these lagoons are located at different stratigraphic positions. Twenty-two WWTFs constructed in southeast Minnesota's karst region in the last 25 years have been identified as subject to potential sinkhole collapse. An unknown but significant number of manure storage lagoons, flood control structures, etc., have also been constructed in the karst region and are at risk. Public agencies are beginning to develop plans to deal with the risk associated with existing and future waste lagoons in this environment. The critical hydrogeologic parameters that can be used to prioritize the risk of collapse at existing facilities include: (1) the lithology of the first bedrock beneath each lagoon, (2) the thickness of surficial materials between the lagoon and the bedrock surface, (3) the presence and construction of liners (seepage rate), and (4) the proximity to existing sinkholes.     

Mercury,arsenic, antimony,and selenium contents of sediment from the Kuskokwim River,Bethel, Alaska,USA

The Kuskokwim River at Bethel, Alaska, drains a major mercury-antimony metallogenic province in its upper reaches and tributaries. Bethel (population 4000) is situated on the Kuskokwim floodplain and also draws its water supply from wells located in river-deposited sediment. A boring through overbank and floodplain sediment has provided material to establish a baseline datum for sediment-hosted heavy metals. Mercury (total), arsenic, antimony, and selenium contents were determined; aluminum was also determined and used as normalizing factor. The contents of the heavy metals were relatively constant with depth and do not reflect any potential enrichment from upstream contaminant sources.     

滇东南花岗岩与锡、银、铜、铅、锌多金属矿床的成因关系

滇东南锡、银、铅、锌多金属矿床主要分布在个旧、白牛厂、都龙3个矿区,而滇东南较大的3个花岗岩体又分别出露在3个矿区或附近.花岗岩体均形成于燕山晚期,岩石化学、矿物成分相似,富含锡、银、铅、锌、钨、铜等成矿元素.矿床主金属元素组合与岩体之间的距离由远而近出现由锡、钨、(铍、铌、钽)→锡、钨、(铁)、铜、铟→锡、铅、锌、银、铟、(锑)有规律的变化.花岗岩浆是成矿物质来源和成矿热源.岩浆侵入初期使上覆地层隆起产生背斜(凹陷部位成向斜);同时使地层产生一系列裂隙、压性断层或层间断裂;岩浆侵入晚期,这些断层再次活动,表现为张性,岩浆产生的含矿热液沿由其活动所造成的断裂迁移、充填、交代、沉淀而形成矿床.