北祁连东段红土堡基性火山岩和陈家河中酸性火山岩地球化学特征及构造环境

北祁连东段天水-宝鸡地区早古生代火山岩包括红土堡基性熔岩和陈家河中酸性火山岩。地球化学分析结果表明,红土堡基性熔岩和陈家河中酸性火山岩中所夹基性火山岩的特征相似,属于拉斑玄武岩,两者TiO2含量较高(1.50%～2.73%),∑REE分别为65.97×10-6～133.46×10-6和78.04×10-6～175.55×10-6,LREE轻度富集[(La/Yb)N分别为2.00～4.40和2.71～4.40],Eu异常不明显或略具Eu负异常(δEu分别为0.85～1.10和0.85～0.99);两者LILE明显富集,HFSE(尤其是Ta、Nb)强烈亏损,Nb/La较低(0.28～0.43),显示出与岛弧拉斑玄武岩(IAT)的亲源性;同时,基性熔岩的εNd(t)均为正值( 2.22～ 4.08),暗示其源区类似亏损地幔源区,Zr/Nb=17.21～36.33,Ce/Nb=5.73～8.17,又具有N-MORB的地球化学特征;两者的Sr、Nd、Pb同位素组成十分相似,显示出基性熔岩主要来自亏损地幔(DM)和富集地幔端员(EMⅠ或EMⅡ)混合源区,可能有少量地壳物质混染。陈家河中酸性火山岩属于钙碱性系列,∑REE=127.51×10-6～276.01×10-6,LREE显著富集[(La/Yb)N=4.79～13.51],多数具有弱负Eu异常(δEu=0.53～1.20);微量元素分配型式类似于岛弧花岗岩,具明显的Nb、Ta、Zr、Hf低谷。综合研究表明,北祁连最东段陈家河中酸性火山岩形成于岛弧环境,而其南部的红土堡玄武岩形成于弧间裂谷环境(或初始弧后盆地),是早古生代晚期北祁连东段岛弧带扩张向弧后盆地演化的早期产物。这些研究成果为秦祁结合部位沟弧盆体系的存在提供了佐证。     

东昆仑南缘布青山地区哈尔郭勒玄武岩地球化学特征及其地质意义

哈尔郭勒玄武岩位于东昆仑南缘布青山地区。详细的地球化学研究表明哈尔郭勒玄武岩可以分为碱性玄武岩和亚碱性玄武岩,其中碱性玄武岩的∑LREE=63.8×10-6~175.36×10-6,∑HREE=14.46×10-6~28.56×10-6,∑LREE/∑HREE=4.41~6.14,(La/Yb)N=4.14~6.71,(Ce/Yb)N=3.31~5.12,δEu=1.03~1.17,具有与洋岛玄武岩(OIB)相似的稀土配分模式;亚碱性玄武岩的∑LREE=11.07×10-6~29.95×10-6,∑HREE=12.56×10-6~25.41×10-6,∑LREE/∑HREE=0.88~1.54,(La/Yb)N=0.29~0.74,(Ce/Yb)N=0.37~0.77,δEu=1.02~1.22,具有正常洋中脊玄武岩(N-MORB)的稀土元素地球化学特征。这表明哈尔郭勒玄武岩是OIB与N-MORB的共生组合。布青山地区哈尔郭勒玄武岩中的OIB形成于洋脊附近的海山或洋岛环境,岩浆源区可能为EMⅡ型富集地幔;N-MORB形成于洋脊环境,起源于亏损地幔。哈尔郭勒玄武岩为布青山地区晚古生代存在洋盆提供了更充分的证据。     

唐古拉山东段莫云地区二叠纪玄武岩地球化学特征及源区性质

在青藏高原腹地,二叠纪火山岩分布于唐古拉山东段,古地理上位于北羌塘盆地东缘。对唐古拉山东段莫云地区中二叠世栖霞期尕笛考组火山岩的主量元素、微量元素和Sr-Nd同位素进行了分析。岩相学和地球化学指标显示二叠纪火山岩为玄武岩,该套岩石低SiO2、MgO、K2O和Mg#值(0.39～0.48),富Na2O、TFeO、TiO2、P2O5含量,富集LREE和高场强元素(Nb、Ta、Zr、Hf、P、Ti),(La/Yb)N=14.89～23.23,(Gd/Yb)N=2.30～3.58,Eu异常不明显(δEu=0.76～0.99),具有明显的Th正异常和K、Sr负异常,显示与板内碱性玄武岩相似的地球化学特征;同位素组成以低(87Sr/86Sr)i(0.7033～0.7039)、高εNd(t)(+4.2,t=271Ma)为特点,反映岩浆源区既有亏损地幔源(DMM)又有富集地幔源(EMⅠ)的双重属性。岩浆起源可能与地幔柱诱导的软流圈上涌导致含石榴子石橄榄岩的岩石圈地幔部分熔融有关。莫云玄武岩形成于板内伸展环境(初始裂谷),具有主动裂谷作用性质。     

西天山阿吾拉勒阔尔库岩基解体的地球化学证据及意义

西天山阿吾拉勒阔尔库岩基被解体为早石炭世赛肯都鲁序列和早二叠世阔尔库序列.稀土微量元素研究表明,赛肯都鲁序列低Ba,高Sr,低稀土总量,贫LREE,类似埃达克岩.LREE/HREE=2.5,δEu=0.89,为幔源岛弧花岗岩,与研究区早石炭世大哈拉军山组钙碱性火山岩共同构成了岛弧火成岩组合.阔尔库序列高Ba,低Sr,高稀土总量,富集LREE,LREE/HREE=6.3,δEu=0.67,为壳源后造山花岗岩,与晚石炭-早二叠世大陆裂谷环境双峰式火山岩共同构成碰撞后火成岩组合.地球化学特征为该岩基解体提供了有力的证据.     

大兴安岭北部佳疙瘩组洋岛型玄武岩的发现及地质意义

大兴安岭北部奇乾一带的新元古界佳疙瘩组上部由灰黑色致密枕状玄武岩、含气孔-杏仁状构造的枕状玄武岩夹灰黑色粉砂质板岩、绿泥片岩和灰色薄层大理岩化灰岩组成。枕状玄武岩由斜长石、辉石、绿泥石等组成。地球化学特征表明,岩石为富钠碱性玄武岩,稀土元素总量较高∑REE为107.71×10~(-6)~127×10~(-6),轻稀土富集LREE/HREE为5.15~5.56,(La/Yb)_N为4.44~5.18,δEu=0.86~1.08,稀土元素配分曲线为右倾型。微量元素与MORB相比,富集Ti,Sr、K、Rb、Ba等不相容元素,Y、Yb含量略低于MORB,Y、Yb相对亏损。构造环境判别显示该枕状熔岩形成于大洋板内洋岛环境,佳疙瘩组洋岛玄武岩的发现标志着此时已经有成熟的大洋壳形成;综合玄武岩的地质地球化学特征,认为其源区来自软流圈地幔或与地幔柱组分有关。     

新疆东准噶尔卡拉麦里钾质玄武岩的地球化学特征、成因及其构造意义

卡拉麦里钾质火山岩位于准噶尔盆地的东北缘下石炭统巴塔玛依内山组内。这些火山岩以粗面玄武岩和玄武质粗面安山岩为主,SiO2含量稳定(46.29%～51.56%),具有较高的碱含量(K2O+Na2O=5.39%～6.96%)以及高K2O/Na2O比值(K2O/Na2O=0.5～1.4),TiO2含量相对稳定(0.94%～1.21%),显示钾玄质岩石特征。岩石地球化学表明,钾玄岩强烈富集LILE(如K、Rb和Sr)和LREE((La/Yb)N=4.39～6.25),Eu正异常明显(δEu=1.3～1.7),相对亏损HFSE(如Zr、Hf),Ta、Nb和Ti呈明显的"TNT"负异常,及较高Ba/Nb和Ba/Ta比值(分别为38～93,574～1470),显示典型岛弧岩浆特征,而Nd-Sr同位素显示亏损地幔源区特征。不相容元素(Nb/La)N和Ba/La比值(分别为0.33～0.41,11.07～18.82)以及高Nb含量(4.45×10-6～7.76×10-6),表明这些岩石来自一个交代作用富集的地幔源区。通过钾质火山岩环境的梯次判别图研究,发现巴塔玛依内山组钾玄岩形成于后碰撞环境,显示岛弧的岩石地球化学特征。在后碰撞期,由于陆内调整和均衡作用,东准噶尔东北缘的岩石圈伸展减薄,随着岩石圈地幔的减薄,前期交代富集的下部地幔楔(金云母和/或钾质角闪石-尖晶石相二辉橄榄岩)发生低度部分熔融形成钾玄质母岩浆,诱发了后碰撞型钾玄质岩浆活动(具有弧火山岩岩石地球化学特征),形成了卡拉麦里巴塔玛依内山组钾质玄武岩。     

华北克拉通大红峪组高钾火山岩的地球化学特征及其岩石成因

华北克拉通中元古代大红峪组火山岩是一套高钾(K2O Na2O)、富铝、贫硅的碱玄岩-响质碱玄岩-响岩组合。地球化学特征显示其富集轻稀土(LREE)和大离子亲石元素(LILE)(Rb,Ba,K等)、贫高场强元素(HFSE)(Th,Zr,Hf,HREE等)和弱亏损Nb,Ta的微量元素特征。稀土元素配分模式为右倾,有轻微的Eu正异常,类似于OIB的特征。较稳定的La/Nb比值和εNd(t)值,说明岩浆在上升过程中并未遭受到明显的地壳混染作用;结合岩石Nb,Ta弱亏损以及εNd(t)值为-0.66~0.63的特征,表明其地球化学特征更多的是其地幔源区的反映。因此,岩浆来源于富集地幔,可能为被俯冲交代作用改造过的深部岩石圈地幔,并有OIB特征的软流圈组分加入。构造环境分析表明,大红峪组火山岩形成于板内裂谷,其深部地球动力学过程可能与地幔柱有关。     

北祁连冷龙岭蛇绿岩地质地球化学特征及构造意义

在北祁连造山带冷龙岭地区新发现一条蛇绿岩带,该蛇绿岩从下向上由地幔橄榄岩、辉长辉绿岩、玄武岩、硅质岩组成。岩石地球化学特征表明,玄武岩可分类高Ti和低Ti两类,其中高Ti玄武岩具有LREE富集的稀土配分型式,富集K、Rb、Ba、Th、Nb、Ta等不相容元素,呈现隆起型(驼峰式)分布型式,显示了典型的洋岛火山岩地球化学特征,为板内岩浆作用的产物。低Ti玄武岩具有LREE亏损,类似N-MORB的稀土配分模式,同时又具有相对于N-MORB富集的大离子亲石元素,亏损Nb、Ta等高场强元素的岛弧火山岩的地球化学特征,代表了弧后盆地环境岩石组合。蛇绿岩岩石组合和岩石地球化学特征显示该蛇绿岩套形成于弧后盆地环境,是早奥陶世北祁连洋的残留。     

西藏冈底斯带叶巴组火山岩地球化学及成因

叶巴组早侏罗世双峰式火山岩分布在拉萨、达孜至墨竹工卡之间, 岩性为浅变质玄武岩、玄武质熔结凝灰岩、英安岩、酸性凝灰岩及火山角砾岩等.火山岩SiO₂含量集中在41%~50.4%和64%~69%两个区间, 为钙碱性系列的玄武岩和英安岩2类.玄武岩的显著特征是TiO₂含量极低, 仅为0.66%~1.01%, 远低于大陆拉斑玄武岩.玄武岩的稀土总量∑REE=60.3~135μg/g, 英安岩的稀土总量∑REE=126.4~167.9μg/g.玄武岩和英安岩具有相似的稀土和微量元素特征, 两者均为轻稀土富集型, 分布特征相似, 轻、重稀土的分馏较明显, Eu异常均不显著; 均表现为LILE、LREE富集, HFS、HREE亏损的特点.玄武岩亏损Ti、Ta、Nb、Zr, Nb和Ta仅略负亏损, Nb*=0.54~1.17, 平均为0.84;英安岩亏损HFS中P、Ti, Ta、Nb略负异常, Nb*=0.74~1.06, 平均为0.86.玄武岩类的ε_Nd(t) =0.96~10.03、(87Sr/86Sr)_i=0.7043~0.7064, 英安岩的ε_Nd(t) =-1.42~1.08、(87Sr/86Sr)_i=0.7038~0.7049.从微量元素和同位素成分看, 玄武岩和英安岩浆起源于俯冲带之上的地幔楔不同程度的部分熔融, 源岩可能是亏损的尖晶石二辉橄榄岩.源区曾受到具地壳成分特征的流体不均匀交代.后期变质作用对岩石大离子亲石元素含量有影响.叶巴组双峰式火山岩形成于成熟岛弧后期的短暂拉张环境, 是印支期冈底斯岩浆弧演化的结果.      

中祁连东段兴隆山群基性火山岩锆石U-Pb定年及岩石成因研究

兴隆山群主体为一套浅变质、变形较强的碎屑岩与基性火山岩建造组合,可分为下、中、上三个组.岩石学、主量元素和微量元素地球化学研究揭示:下组基性熔岩为玄武岩或玄武安山岩,SiO2含量高(50.97%～54.70%),TiO2含量小于1%(0.74%～0.75%),MgO含量较低(3.76%～4.20%);稀土总量高,轻稀土富集,重稀土亏损;微量元素原始地幔标准化分配型式显示出岛弧火山岩或受地壳混染的大陆玄武岩特有的Nb-Ta和Ti负异常.中、上组基性火山熔岩为细碧玢岩或细碧岩,SiO2含量较低(45.71%～49.58%),TiO2含量多大于1%,MgO含量较高(5.75%～9.88%);轻稀土亏损,重稀土富集;微量元素原始地幔标准化分配型式为平坦型.兴隆山群基性火山岩均为亚碱性拉斑系列火山岩,源岩浆在演化过程中经历了plag cpx[±ol]的分离结晶作用.下组基性熔岩形成于大陆板内拉伸环境,岩浆上升过程中经历了较强的地壳混染作用;中、上组基性熔岩形成于拉张较为强烈的构造环境,具N-MORB型地球化学特征,代表洋壳的出现.上组基性熔岩LA-ICPMS锆石U-Pb测年结果显示最新的岩浆锆石年龄为713±53Ma,结合区域地质特征,推断兴隆山群形成年龄极有可能为新元古代.具明显岩浆结晶特征的锆石年龄构成1.0～1.2Ga的最大峰值,可能是与Rodinia超大陆形成有关的岩浆事件在该地区的响应.兴隆山群提供了Rodinia超大陆形成后一段不完整的由大陆伸展至洋壳发育阶段的地质历史记录.     

Geochemical Constrains on Petrogenesis and Tectonic Setting of Volcanic Rocks from the Baimianxia and Sanwan Formations in the Northern Margin of the Yangtze Plate

On the basis of petrogeochemical data, the volcanic lavas of the Baimianxia Formation can be classified into two units: high TiO2 and low TiO2. The TiO2 concentration of the former is generally higher than 1%, which occurs in the lower part with high-grade metamorphism, but the latter is less than 1% and crops out in the upper part with low-grade metamorphism. The high-TiO2 unit is dominated by tholeiitic lavas showing high rare earth element (REE) contents (ΣREE?=?83.4–180.8?μg/g), high light/heavy REE (LREE/HREE) ratios (LREE/HREE=2.17–5.85) and weak negative Eu anomaly (Eu=0.79–1.01). Its trace element patterns display weak Nb-Ta anomalies with respect to Th, K, La, Ce, showing within-plate basalt affinities. In contrast, the low-TiO2 unit is characterized by low REE contents, low LREE/HREE ratios, and pronounced Nb-Ta anomalies, indicating typical arc or continental arc signature. Chondrite-normalized REE patterns of basalts and andesites from the Sanwan Formation are flat or LREE depletion, which is very similar to normal mid-oceanic basalt. Therefore, we suggest that these lavas should be formed in a back-arc basin setting. Sr-Nd isotopic data of the basalt in the lower part suggest that the rocks would have been formed in ~1144?Ma. Based on the geochemical and isotopic features of the basalts, we suggest that these rocks in the low part of the Baimianxia Formation should originate from an asthenospheric oceanic-island basalt-like mantle source, which may be produced by partial melting of garnet lherzolite, and significantly underwent fractional crystallization and crustal or lithospheric mantle contamination en route to the surface. However, laser ablation inductively coupled plasma mass spectrometry zircon U-Pb dating of the basalt sample from the upper part of the Baimianxia Formation gives a 437 Ma, indicating a Early Paleozoic age. The geochemical analysis in this paper suggests that they may originate from an arc or continental arc in response to aqueous fluids or melt expelled from a subducting slab, and the partial melting occurred in the garnet stability field. The samples of basalts and andesites in the Sanwan Formation show they are derived from depleted mantle source similar to normal mid-oceanic basalt. Finally, we can conclude that the lavas in the lower part of the Baimianxia Formation represent the geological records of rift-related volcanism in the middle Proterozoic, which is commonly considered to be the precursor of continental breakup and followed by oceanic basin forming from Neoproterozoic to early Paleozoic. Whereas, the lavas in upper part of the Baimianxia Formation and Sanwan Formations may have been generated by the oceanic and continental conversion that occurred in the early Paleozoic.     

粤东晚三叠世小水组——早侏罗世金鸡组古气候及构造背景的矿物和地球化学记录

对揭西灰寨剖面上三叠统小水组和惠州黄洞剖面下侏罗统金鸡组采集的泥岩和砂岩样品进行了全岩分析和ICP-MS微量、稀土元素测试和矿物成分分析,根据元素含量及其比值的变化,提出了粤东揭西地区晚三叠世小水组和惠州地区早侏罗世金鸡组水体整体为还原、厌氧环境,以干燥炎热气候为主。小水组w(∑REE)较大,轻稀土富集(LREE/HREE为10.86和15.63),重稀土较稳定(w(∑HREE) 为6.09×10^-6和7.99×10^-6),Eu负异常(δEu为0.67和0.87);金鸡组轻稀土富集(LREE/HREE=7.29~10.03),重稀土较稳定(w(∑HREE)为(15.39~19.72)×10^-6),Eu负异常(δEu=0.59~0.65)。泥岩稀土元素分布模式图和源岩判别图解显示,小水组和金鸡组源岩来自上地壳的沉积岩、花岗岩和玄武岩,小水组下部样品沉积物源岩较上部要深,金鸡组上部沉积物源岩较中下部要深。Dickinson图解、K₂O/Na₂O-w(SiO₂)、Zr-Th、La-Th-Sc、Th-Co-Zr/10判别图解和稀土元素特征值显示,晚三叠世揭西地区的构造背景为弧后伸展盆地,有被动大陆边缘特性,但也有大陆岛弧(由安第斯大陆边缘弧转变而来)的特性,其物源来自火山弧造山带。早侏罗世黄洞地区为弧后挤压盆地,具有被动陆缘特性,沉积物物源来自于切割的岩浆弧。     

青海省同仁地区上二叠统石关组上部火山岩的新发现及其地球化学特征和构造环境意义

青海省同仁地区位于秦、祁结合部,构造演化历史悠久.在该区隆务河两侧广泛发育着二叠、三叠纪地层,通过两套地层岩石组合分析,我们认为晚二叠世晚期至早三叠世早期该区属于半深海浊积扇相沉积环境.在该区晚二叠世晚期地层中新发现一套火山岩,火山岩的岩石组合主要为玄武岩、安山岩、玄武安山岩等.根据岩石的常量元素特征,可以将本区火山岩分为两部分:下部岩石的SiO2含量为49.04%~52.43%,平均为51.28%,TiO2含量为0.67%~1.11%,平均为0.9%,ALK值为2.64%~3.6%.通过常量元素投点图分析,本组火山岩岩性偏基性,属于拉斑玄武岩系列,显示高钛玄武岩特征.上部岩石的SiO2含量为56.25%~60.36%,平均为58.76%,TiO2含量为0.52%~0.63%,平均为0.58%,ALK值在5.26%~5.54%之间.岩性偏中性,属于钙碱性系列,显示低钛玄武岩特征.火山岩的稀土元素也有明显差异,下部稀土总量较低,∑REE=(61.7~97.17)×10-6,(La/Lu)N比值平均为3.07,轻重稀土分馏不明显,显示与过渡型洋中脊玄武岩相似的特征;而上部稀土总量较高,∑REE=(107.51~143.32)×10-6,(La/Lu)N比值平均为7.78,轻重稀土分馏明显,稀土分配曲线显示与岛弧安山岩相似的特征.该区火山岩的微量元素比值蛛网图显示与岛弧钙碱性玄武岩-过渡类型玄武岩具有较强的相似性.构造环境判别显示出本区火山岩具有从拉张的过渡型洋中脊环境到闭合的岛弧环境的演化特征.     

山西吕梁地区吕梁群变基性火山岩原岩形成年龄、地球化学特征及形成环境

华北克拉通古元古代中期构造环境及演化至今尚存有争议,该时期相关岩浆作用的成因研究可为这些问题的解决提供重要证据。本文对华北克拉通中部山西吕梁地区古元古代中期形成的吕梁群近周营组基性火山岩开展综合研究,获得2 180±19 Ma 的形成年龄,岩石地球化学低TiO₂、高Al₂O₃ 和K₂O,属钙碱性系列。微量元素富集Rb、Ba、Th、U、Sr 等大离子亲石元素,亏损Nb、Ta、Ti 和P等高场强元素,富集Pb,具轻稀土略富集、铕弱异常的右倾稀土模式,与典型消减带弧岩浆产物特征一致。同位素组成显示正ε_Nd（t）= 1.0～2.6 和ε_Hf（t）= 1.8～9.2, 指示它们来源于亏损地幔,低的Ti/Y（246～385）和Ce/Y 值（0.99～1.77）进一步揭示,地幔源区受到俯冲流体的交代和沉积物的参与,是楔尖晶石二辉橄榄岩与石榴石二辉橄榄岩过渡带略亏损地幔区发生部分熔融,并经历了橄榄石、单斜辉石等矿物分离结晶作用而形成。结合同期埃达克岩-高镁安山岩-富Nb玄武岩-安山岩组合以及弧花岗岩类的出现提出,2 200 Ma 华北中部带已演化至活动大陆边缘弧的构造环境。     

An Ordovician intra-oceanic subduction system influenced by ridge subduction in the West Junggar,Northwest China

We report elemental and Nd–Sr isotopic data for three types of Ordovician volcanic and gabbroic rocks from the Sharburti Mountains in the West Junggar (Xinjiang), Northwest China. Gabbros and Type I lavas occur in the Early Ordovician Hongguleleng ophiolite whereas Type II and III lavas are parts of the Middle Ordovician Bulukeqi Group. Gabbros and Type I lavas are tholeiites with a depleted light rare earth element (LREE) and mid-oceanic ridge basalt (MORB)-like signature with a crystallization sequence of plagioclase–clinopyroxene, suggesting formation at a mid-oceanic ridge. Type II lavas are Nb-enriched basalts (NEBs, Nb = 14–15 ppm), which have E-MORB-like REE patterns and Nb/Yb and Th/Yb ratios. They come from mantle metasomatized by slab melts. Type III lavas are further divided into two sub-types: (1) Type IIIa is tholeiitic to calc-alkaline basalts and andesites, with REE patterns that are flat or slightly LREE enriched, and with a negative Nb anomaly and Th/Yb enrichment, indicating that they were generated above a subduction zone; (2) Type IIIb is calc-alkaline basalts and andesites, which are strongly enriched in LREE with a marked negative Nb anomaly and Th/Yb enrichment, suggesting generation in a normal island-arc setting. The initial ⁸⁷Sr/⁸⁶Sr ratios of Type III lavas range from 0.70443 to 0.70532 and ?Ndt ranges from +1.5 to +4.5, suggesting that these melts were derived from mantle wedge significantly modified by subducted material (enriched mantle I (EMI)) above a subduction zone. Contemporary tholeiitic to calc-alkaline basalt–andesite and NEB association suggest that the NEBs erupted during development of the tholeiitic to calc-alkaline arc. We propose a model of intra-oceanic subduction influenced by ridge subduction for the Ordovician tectono-magmatic evolution of the northern West Junggar.     

山东蒙阴科马提岩地球化学特征及其意义

山东蒙阴科马提岩具有典型的鬣刺结构，高镁低钛，铝不亏损，具有正的Rb、Ba、Sr、U异常，轻稀土元素亏损，重稀土元素平坦，稀土元素总量很低，高场强元素与稀土元素发生分异，Nb/Nb^＊〉1，与加拿大蒙罗镇科马提岩地球化学特征和同位素特征相似。研究表明，蒙阴科马提岩可能起源于长期亏损的地幔源区，岩浆不可能来源于以橄榄石、辉石和石榴石（或者majorite）为主要矿物相的地幔源区。最新Sm-Nd同位素研究显示，蒙阴科马提岩样品的εNd值为-0．4～＋3．6，新鲜样品一般为＋3．3，也证实了科马提岩来自长期亏损的地幔源区，并且地幔柱在上升过程中受到地壳混染程度很小，推测研究区科马提岩的喷出可能是新太古代大陆增生事件的重要组成部分。     

南秦岭中段西乡群火山岩岩石成因

南秦岭中段新元古代中期（730-845Ma）西乡群（自下而上包括孙家河组、大石沟组和白勉峡组）火山岩喷发于大陆板内裂谷环境。它们极有可能与导致Rodinia超大陆裂谷化裂解的地幔柱活动有关。根据岩石地球化学数据．南秦岭中段新元古代中期西乡群裂谷基性熔岩总体上属于低Ti／Y（LT,Ti／Y〈500）岩浆类型。LT熔岩又可进一步划分为LT1和LT2等2个亚类。LT1熔岩以高Nb／La（0．87～0．98）、低Thw／NbN（≈1）、缺乏Nb—Ta和Ti的亏损、具有“大隆起”式微量元素原始地幔标准化分配型式、（^87SrSr^86Sr）（t）=0．703869、εNd（t）=4．83为特征,属于拉斑玄武质岩浆系列;LT2熔岩以低Nb／La（〈0．75）、高ThN／NbN（〉1．4）、Nb—Ta和Ti亏损明显和Sr—Nd同位索比值变化较大为特征。元素和同位素数据表明,西乡群裂谷火山岩的化学变化不是由一个共同的母岩浆结晶分异作用所产生。孙家河组、大石沟组和自勉峡组中TiO2含量大于1．09％的火山岩的母岩浆经受了辉长岩质结晶分离作用。而白勉峡组中TiO2含量小于0．69％的基性熔岩的化学演化则是受控于单斜辉石（cpx）±橄榄石（ol）结晶分离作用。西乡群火山岩系中,基性、中性和酸性熔岩间为分异结晶关系。南秦岭中段新元古代中期西乡群裂谷火山岩系极有可能是源于共同的地幔柱,该地幔柱组分的成分为;εNd（t）≈＋5,^87Sr／^86Sr（t）≈0．704,La／Nb≈0．7。南秦岭中段新元古代中期西乡群裂谷基性熔岩存在空间上的地球化学变化：LT1熔岩的母岩浆,没有受到明显的大陆岩石圈混染,保存了鲜明的地幔柱信号;而大陆地壳或大陆岩石圈混染作用对于LT2熔岩的形成则有着重要贡献。研究揭示,南秦岭中段新元古代中期西乡群裂谷基性熔岩的母岩浆总体上产生于上涌地幔柱上部层位（地幔柱头）3GPa?     

Geochemical Features of a Subduction Initiation Ophiolite Type in Habana-Matanzas Region (Western Cuba)

We present new geochemical data for the upper mantle and crustal sections(whole-rock major and trace element compositions)as well as mineral chemical data,from the Northern Carbibbean ophiolites in the Habana-Matanzas region in Western Cuba.These ophiolites are part of the Northern Cuban Ophiolitic Belt(NCOB),extending for more than 1000 km along the island.The upper mantle peridotites are composed mainly of refractory harzburgite with tectonite textures,and show convex-downward patterns depleted in MREE normalized to chondrite values(Mc Donough and Sun,1995).These geochemical trends are characteristic for depleted mantle wedge peridotites metasomatized by slab-derived,LREE enriched melts.The NCOB also includes abyssal peridotites having lower LREE/HREEratiosanddisplayingrelativelyhomogeneous and flat patterns from MREE to HREE.These peridotites represent fragments accreted into the continental margin from a subducted oceanic lithosphere.Gabbro and dolerite units in the NCOB are systematically depleted in High Field Strength Elements(HFSE:Nb,Ta,Hf,Ti)and REE with respect to N-MORB(1 X N-MORB).Their melt evolution was affected by subduction input.Spatially associated granitic rocks have a volcanic arc geochemical affinity.Some mafic extrusive rocks within the NCOB exhibit boninitic signatures,and may represent the products of subduction initiation magmatism,whereas other extrusive rock occurrences display N-MORB to E-MORB geochemical fingerprints,slightly modified by subduction derived fluids.Using these geochemical data and constraints,we present a tectonomagmatic model for the evolution of the NCOB within the framework of the Caribbean geology.     

Archaean greenstone belt from the Central African Republic (Equatorial Africa)

The Bandas belt, one of two prominent Archaean greenstone belts in the Central African Republic (Equatorial Africa), is ca. 250 km long. At the southernmost part of the belt, a metasedimentary—metavolcanic rock suite is preserved only in brachysynclines. The suite can be divided into two lithostratigraphic units. The lower unit is composed predominantly of volcanic rocks, while the upper one contains mainly metasedimentary rocks. The volcanic rocks, which are part of a sequence ca. 3600 m thick, can be sub-divided according to stratigraphic position, lithology and geochemistry into three groups. The lowermost group includes low-K tholeiitic basalts depleted in light REE. The second group consists of tholeiitic basalts with light REE-enriched patterns and the third, uppermost, group includes andesites, which are similar in several respects to Recent calc-alkaline andesites.The tholeiitic basalts of the first two groups are probably related to different upper mantle sources. The andesites of the third group were produced either by fractional crystallization from a basaltic magma enriched in light REE or equilibrium melting of eclogite or garnet amphibolite.     

内蒙古锡林浩特岩群岩相学、地球化学特征及构造环境分析

锡林浩特岩群是内蒙古中东部锡林郭勒微地块内原锡林郭勒杂岩的重要组成部分,由一套片麻岩夹层状斜长角闪岩、磁铁石英岩和变粒岩等变质岩组成,形成于中元古代［1］。岩群中片麻岩样品显示轻稀土元素富集的中等分异特征((La/Yb)N=4.71~7.97),斜长角闪岩具有平坦型((La/Yb)N=0.74~0.95)和轻稀土元素微弱富集型((La/Yb)N=1.06~3.63)两种稀土元素配分模式。在微量元素N MORB标准化图解中,斜长角闪岩显示出洋中脊玄武岩和岛弧玄武岩的过渡类型特征。同时结合岩相学和岩石地球化学图解分析,推断片麻岩原岩为富含泥质的亚杂砂岩,而斜长角闪岩原岩为一套具有拉斑质到钙碱性过渡型特征的玄武岩;变质沉积岩形成于活动大陆边缘大陆岛弧环境;变质基性火山岩形成于岛弧弧后盆地。二者指示锡林浩特岩群形成于活动大陆边缘体系。