台湾始新统—中新统沉积物源与沉积环境

台湾地区出露的始新统-中新统地层属南海北侧的范畴,其物质组成及沉积环境为揭示南海新生代早期构造沉积演化提供了关键性依据。对台湾西部麓山带中部南投粗坑地区、国姓地区以及东北海岸新港-基隆地区的始新统-中新统地层进行了岩石学、矿物学、稀土元素地球化学特征以及碎屑锆石U-Pb定年分析等研究。结果显示:台湾中部和北部从始新世到中新世经历了从陆相河流-湖泊相沉积环境到滨浅海相的环境转变,其砂岩成分成熟度随时间由老变新呈现规律性变化;沉积物源分析表明研究区沉积物在始新世-早渐新世,物源以近源中生代源区为主,碎屑锆石年龄谱系出现120 Ma和230 Ma两个主要峰值,与周边及华南沿海地区中生代火山岩时代一致;进入晚渐新世以后,锆石年龄谱系出现900 Ma及1 800 Ma等古老峰值,说明古老地块物质明显增加,这可能反映了昆莺琼古河流由南海西部到东部的物质输送对台湾地区的影响作用。     

剑川-兰坪盆地古近纪沉积-构造变革及其区域构造意义

滇西新生代兰坪盆地和剑川盆地分别位于哀牢山–红河断裂带两侧,青藏高原东构造结内,其沉积过程和构造变形对青藏高原东南缘的构造演化有重要的启示意义。通过对这两个盆地古近纪沉积和构造过程的研究,我们发现兰坪盆地和剑川盆地及邻区的构造变形分为三期:始新世早期的强烈挤压变形、始新世中晚期的伸展变形、渐新世的走滑变形。始新世早期的挤压变形主要表现为兰坪地区的褶皱–冲断系统、哀牢山-红河断裂的逆冲活动和剑川盆地的宽缓褶皱。沉积方面,古新统勐野井组(E_1m)较为稳定的细粒滨湖相沉积转变为始新统宝相寺组(E_2b)较粗的具有前陆盆地性质的河流相沉积,特别是宝相寺组底部发育的一套快速堆积的磨拉石建造,可能是对始新世强烈挤压环境下的沉积响应。始新世中晚期伸展变形体现在盆地的构造环境由早期的挤压环境变为伸展环境和该时期大量富钾岩体和岩脉的侵入,沉积学上,下始新统宝相寺组的河流相转变为中始新统金丝厂组(E_2j)具有快速堆积磨拉石特征的曲流河沉积,极可能是对构造体制变革的沉积响应。渐新世的走滑变形则体现在渐新统的缺失和哀牢山–红河断裂的早期左行走滑。因此,我们认为剑川–兰坪地区在始新世中期和渐新世均发生了显著的运动学转换,这一认识也得到了始新世中期兰坪和剑川盆地物源明显变化的支持。结合青藏高原东南部始新世中晚期岩浆的活动,渐新世大型剪切带(崇山剪切带、高黎贡剪切带)的强烈走滑和保山块体的旋转,我们推测青藏高原东南缘古近纪的构造演化为古新世-始新世早期的挤压、始新世中晚期的伸展、渐新世的转换压缩。     

黑龙江省老黑山盆地下白垩统穆棱组砂岩地球化学特征及其地质意义

为研究黑龙江老黑山盆地下白垩统穆棱组砂岩的源岩属性和源区大地构造背景,在穆棱组进行系统取样,开展地球化学特征和显微镜下分析。研究结果表明：穆棱组砂岩主量元素显示Fe2O3的含量小于FeO,CaO的含量大于MgO的含量,稀土元素具有轻稀土富集、重稀土平坦、多数样品的δEu值具有负异常等特征,样品间微量元素的富集和亏损差异明显。相关系列判别图解表明穆棱组源岩未经沉积再循环作用,属于短距离搬运堆积,且源岩主要为来自上地壳的长英质岩石,但存在多个物源。结合砂岩地球化学特征和Dickinson图解及区域构造背景认为,物源区主要形成于印支运动晚期活动大陆边缘构造背景下的再旋回造山源区和基底隆起区,源岩主要来自于晚三叠世—早中侏罗世的长英质火山岩和侵入岩,而少量可能来自于晚二叠世的变质岩。     

云南思茅盆地江城上白垩统勐野井组稀土微量元素特征及地质意义

沉积盆地中碎屑岩的地球化学成分主要受物源区控制,因此,通过分析碎屑岩的化学成分可以揭示盆地沉积岩的源区构造背景和物源属性。思茅盆地上白垩统勐野井组（K2me）细碎屑岩的稀土元素组成分析结果表明,研究区沉积物具有轻稀土元素富集,较平坦的重稀土元素分布模式,以及中等程度 Eu 负异常的总体特征。根据样品的（Hf-La/Th、La/Sc-Co/Th和REE-La/Yb）图解,特征性微量元素比值（La/Sc、Sc/Th、Cr/Th 和 Co/Th）,并结合岩矿薄片分析,认为勐野井组细碎屑岩具有典型的上陆壳特征,源区母岩以长英质岩石为主。微量元素 Cr/Co 结合岩相古地理的分析显示勐野井组细碎屑沉积物应属于近源沉积。通过与不同构造背景下杂砂岩的稀土元素特征对比及主元素（K2O/Na2O-SiO2/Al2O3和SiO2-K2O/Na2O）判别图解,勐野井组细碎屑岩源区构造背景应属被动大陆边缘环境,这与思茅盆地所处的三江造山带构造背景相符。     

南海陆缘盆地构造演化与烃源岩特征

受近南北向扩张机制控制,南海陆缘盆地或凹陷多呈NE向带状展布,总体上具有“南三北三”平行排列、外窄内宽的特点。新生代发生的4次重要区域构造运动具有穿时性,共发育3期盆地破裂不整合面,分别是早渐新世与晚渐新世之间、古近纪与新近纪之间、中中新世与晚中新世之间;由东往西,盆地破裂不整合面的时代逐渐变新。受构造运动与海平面升降影响,南海海域发育湖相、海陆过渡相和陆源海相3类烃源岩。由南北两侧向中央海盆,烃源岩类型由湖相逐渐过渡到海陆过渡相与陆源海相;从东向西,盆地主力烃源岩层位逐渐变新,由始新统-渐新统逐渐过渡到渐新统-中新统。南海海域烃源岩的分布规律与盆地破裂不整面存在密切关系:破裂不整合面形成早（早渐新世与晚渐新世之间）的盆地,主力烃源岩形成早（始新统湖相烃源岩）;反之,破裂不整合面形成晚（中中新世与晚中新世之间）的盆地,则烃源岩形成晚（渐新统-中新统海陆过渡相到陆源海相烃源岩）。     

北羌塘盆地沃若山剖面上三叠统土门格拉组沉积岩地球化学特征与构造背景分析

沉积岩中的微量元素和稀土元素特征对沉积环境、沉积物的物源和构造背景具有十分重要的指示作用(示踪)。对采自北羌塘盆地钙质泥岩样品中微量元素和稀土元素进行了测试与分析。结果表明,研究区土门格拉组微量元素中的深源元素(如N i、Cu、Ga等)普遍低于地壳粘土岩中的平均值,纵向上逐渐减小,而典型陆源元素Zr等的平均含量远高于地壳粘土岩中的平均含量,反映了大量的陆源物质的沉积且随着沉积作用的进行从底部到顶部陆源性质逐渐增强的特征;此外,Cr/Zr、Th/Sc、Th/U、Rb/Sr、Cr/Th等微量元素比值的特征还表明沉积物物源具有浅源、长英质、风化严重的特点。稀土元素分布模式和纵向变化规律表明土门格拉组从底部到顶部,稀土元素地球化学特征上具有一定的差异性,反映了沉积作用分异度低—高—低—高的特点及其沉积环境的还原—氧化—还原—氧化的变化过程。通过沉积岩La-Th-Sc、Co-Th-Zr/10和Sc-Th-Zr/10构造环境判别图、La/Th-H f和Th/Sc-Sc关系图解以及Th/U源岩判断分析,综合说明沃若山剖面土门格拉组沉积物源区主要以大陆岛弧构造背景为主,同时也有类似于被动大陆边缘构造背景的因素。     

北祁连东段景泰地区下古生界两套砂岩微量元素和稀土元素特征及其构造意义

早奥陶世和早志留世是北祁连加里东造山带构造演化和盆地转变的关键时期。在造山带东段景泰地区,下奥陶统阴沟组和下志留统肮脏沟组两套砂岩的微量元素和稀土元素特征显示,阴沟组杂砂岩样品（Cj1和Cj3）具有最小的Eu/Eu*及最大的Th/Sc和REE,肮脏沟组杂砂岩具有较小的Eu/Eu*和较大的Th/Sc及REE;阴沟组岩屑砂岩样品（Cj13、Cj15和Cj18）具有最大的Eu/Eu*及最小的Th/Sc、REE和La/Yb。多个物源、构造背景判别图解和多元素蛛网图分析表明,阴沟组杂砂岩样品具大陆边缘的构造背景,主要物源为大陆上地壳再旋回沉积物和长英质岩石;岩屑砂岩样品为岛弧构造背景,以中基性安山质岩石为主要物源,可能受陆源物质的微弱影响。肮脏沟组杂砂岩构造背景复杂,表现出大陆岛弧、活动陆缘和被动陆缘三种环境共存的特点,受中基性火山弧物质、长英质岩石和再旋回沉积岩的混合物源的影响。两套砂岩的元素特征表明二者可能具有相似的源区。阴沟组杂砂岩源区可能为阿拉善地块南缘海原群变沉积岩或其他相似的陆源再旋回沉积物,砂岩碎屑以来自初始火山弧物质为主,以石灰沟岛弧型中基性火山岩作为其源岩最合适。阴沟组形成于初始弧后盆地环境,是岛弧活动的直接记录。肮脏沟组可能的源岩为阿拉善地块南缘海原群变沉积岩和中高等成熟度的石灰沟岛弧型火山岩及海原群岛弧型变火山岩,沉积于弧后前陆盆地,对构造环境的反映存在滞后性。     

库车坳陷第三系泥岩地球化学特征及其对构造背景和物源属性的指示

利用碎屑岩地球化学特征判断沉积盆地的构造背景和物源属性是盆地分析的重要手段，也是对利用粗碎屑沉积岩的组分统计判断盆地源区背景的有益补充和验证。对库车坳陷第三系36件泥岩样品的地球化学特征分析表明，主量元素中CaO的含量很高，对其他主量元素以及微量和稀土元素有稀释作用，一些可靠的物源分析指标主要指示了非碳酸盐沉积物的源区性质；REE分布模式与上地壳相似，轻稀土元素富集，Eu负异常，微量元素比值显示源岩以长英质岩石为主。通过K2O／Na20-SiO2以及La-Th-Sc和Th-Sc-Zr／10判别图分析，认为源区的构造背景具有类似于岛弧的特征。这一结果与前人所做的砂岩组分的研究结果存在差异，说明板内造山带与其前陆盆地之间在沉积与构造耦合上具有特殊性。     

从含油气检测来洞悉琼东南盆地东部发育始新统烃源岩的可能性

目前普遍认为琼东南盆地天然气来源于渐新统和中新统海相煤型烃源岩,对于始新统偏Ⅰ型干酪根烃源岩的存在尚不明确,因此确定始新统烃源岩生烃可能性及其分布将为下一步勘探提供重要依据.琼东南盆地东部45块样品的流体包裹体系统测试分析以及天然气和轻烃地球化学特征分析结果表明,盆地东部气藏以油型气及油型-煤型混合气为特征,至少有4期天然气充注,其中第1期天然气充注与始新统烃源岩生排烃有关.由此认为,琼东南盆地东部可能发育始新统偏Ⅰ型干酪根烃源岩,主要分布于松南-宝岛-长昌凹陷以及北礁凹陷.      

南祁连盆地上三叠统阿塔寺组碎屑岩地球化学特征及其源岩

南祁连盆地在晚三叠世时期处于陆相沉积,上三叠统阿塔寺组碎屑岩十分发育。盆地三叠系砂岩的岩性及岩相特征与二叠系非常相似,但是源岩构造背景、物质组成及物质来源与二叠系有所差异。根据地球化学主量元素、微量元素分析结果,上三叠统阿塔寺组源岩构造背景活动性较强,以活动性较强的大陆岛弧及活动大陆边缘为主,源岩物质组成以长英质火成岩为主。结合区域地质构造背景判断,南祁连盆地上三叠统阿塔寺组沉积物源区以北物源为主,以南物源为辅,中祁连的前震旦系及下古生界变质结晶岩系及花岗岩为其主要物源。     

THE EVOLUTIONARY SERIES OF EARLY PRECAMBRIAN STRUCTURES AND THEIR METALLOGENY

The central Anatolian basins can be grouped into two basic types—arc-related (forearc and intra-arc) basins and collision-related (peripheral foreland) basins. The former began developing in the Late Cretaceous, whereas the latter started to form at the beginning of the Eocene. Both types of basins were filled until the Oligocene with turbidites overlain by shelf and nonmarine strata. During the Oligocene, all these basins were unified into a large epi-Anatolide molasse basin, in which widespread gypsiferous series were deposited together with abundant clastic deposits and volcanics. After the Oligocene, these basins evolved into an areally more extensive “intra-cratonic” basin that bears no relation to the earlier orogenic structures. This superposition of different types of basins makes the geology of central Anatolia extremely complicated. To date, no reliable evolutionary tectonic model for this region has been formulated. Considering that the hydrocarbon potential of these basins is largely unknown, this complication appears to have also frustrated exploration efforts.     

内蒙古中部元古宙火山沉积铁、铜、多金属矿床的成矿区划

一、矿床成因分类形成独立的矿床成因类型的火山沉积矿床,一般分为火山碎屑冲积层、含矿熔岩和含矿水流、热液沉积矿层、热液淋滤和热液交代矿层四类.内蒙古中部元古宙火山沉积矿床是以火山喷气沉积和火山热液沉积为基础,伴随热液淋滤和热液交代的产物.苏联矿床学者B·E、波波夫,据沉积成矿的方式、矿石矿物成分和围岩(反映自己层序岩相特点的成分)特点,把火山沉积铜、铅、锌矿床分为三大组:1)含金属矿的熔岩;2)在火山活动带堆积起来的火山岩和火山沉积岩层中的热液沉积和上升热液交代的块状矿层(黄铁矿的、含铜黄铁矿的和黄铁多金属矿床);3)在离火山活动带很大距离内     

青藏高原北部新生代陆相盆地石油地质条件及勘探前景

青藏高原北部陆相盆地中烃源岩发育层位包括始新统风火山组、渐新统雅西措组和中新统五道梁组。古近系雅西措组烃源岩,特别是灰岩属于中好烃源岩范畴,有机质类型较好,且烃源岩主体处于成熟阶段,是藏北高原新生代陆相盆地主力烃源岩的发育层位。陆相盆地储集岩较发育,储层较丰富,发育层位包括风火山组和雅西措组,其中雅西措组是储层主力分布层位。对测区分析数据表明：通天河盆地具备一定规模的生油岩厚度,而且有机质丰度为沱沱河地区最高,表明其勘探前景较好。     

西藏吉瓦地区渐新统日贡拉组物源分析及找矿意义

通过详实的野外调查和室内研究,在西藏吉瓦地区新发现了砂岩型铜矿床,赋矿层位为渐新统日贡拉组,矿床类型为层控矿床。为探讨日贡拉组砂岩的物源特征及其构造背景、查明其含矿物质来源,通过碎屑矿物定量分析、元素地球化学方法及重矿物组合分析等一系列物源分析方法对日贡拉组的物质来源进行了研究。结果显示,研究区主要岩性为岩屑砂岩,岩屑主要成分为酸性火山岩,砂岩结构成熟度低,分选磨圆差。碎屑组分分析表明物源集中在火山弧物源区,地球化学特征为硅质含量高、LREE富集、HREE相对亏损、显示Eu负异常,均表明物源与酸性火山岩密切相关;日贡拉组砂岩的大地构造背景主要为大陆岛弧,砂岩碎屑来自上地壳长英质源区。重矿物组合以反映物源为中酸性岩浆岩成分的赤褐铁矿+磁铁矿、锆石、电气石、石榴子石为主,沉积环境为气候干旱、水体较浅的富氧环境。锆石形态特征指示物源距母岩区较近,重矿物的相关性分析也指示了物源与火山岩密切相关。研究区的日贡拉组砂岩与早白垩酸性火山岩微量元素及重矿物的对比表明,碎屑物质源区特点从岩石学特征、地球化学特征及重矿物组合特征上均表现出了亲缘关系,物源成分与火山作用紧密相关,很可能主要来自班公湖-怒江洋壳南向俯冲与雅鲁藏布江洋壳北向俯冲双重制约条件下产生于火山弧环境中的早白垩世火山岩。日贡拉组发现了砂岩型铜矿,火山岩提供了成矿物质来源,为寻找同类型的矿床开启思路。     

Single-grain apatite geochemistry of Permian–Triassic granitoids and Mesozoic and Eocene sandstones from Chiapas,southeast Mexico: implications for sediment provenance

ABSTRACT

This article reports single-grain multi-elemental results (Sr, Y, Th, U, and rare earth elements) obtained in 966 apatites from 18 rocks (sandstones and granitoids) that were sampled from the Mesozoic (Todos Santos and San Ricardo Formations) and Eocene (the El Bosque Formation) successions as well as from the Permian–Triassic Chiapas Massif Complex (CMC), all of which are exposed within the Sierra de Chiapas (SCH), SE Mexico. The objectives of the present study are (1) to establish changes in provenance between the Mesozoic and Eocene sedimentary sequences using single-grain apatite geochemistry, and (2) to identify source areas for siliciclastic materials from the Todos Santos, San Ricardo, and the El Bosque Formations. The results of the present work strongly suggest that apatites from the Todos Santos and San Ricardo Formations were mainly derived from intermediate to felsic I-type granitoids as well as from arc-related volcanic rocks, indicating that the CMC basement was the most important source area for the Mesozoic sandstones in the SCH. An abrupt change in provenance from Mesozoic to Eocene units was identified based on single-grain apatite geochemistry. Detrital apatites of the Ypresian–Lutetian El Bosque Formation were derived from diverse source rocks such as mafic–ultramafic rocks, intermediate to felsic I-type plutons, strongly fractionated S-type granites and pegmatites, as well as from different metamorphic source lithologies (including high-pressure rocks) such as gneisses, migmatites, metapelites, and/or eclogites. It was proposed, therefore, that most Eocene sediments of the SCH were derived from the Guatemala Suture Complex, which involves all the rock types mentioned above. A minor portion of the El Bosque Formation sediments was derived from the CMC area and/or from recycled sandstones from the Mesozoic Todos Santos and San Ricardo Formations. Some advantages and disadvantages of provenance studies based on detrital apatite chemistry were also observed and briefly discussed.     

南海北部第三系的沉积特征与生油、储油层系

南海北部指北纬16°00'至23°00'与东经108°00'至120°00'之间的海域。包括广东大陆以南、海南、台湾两岛之间的广阔大陆架和陆坡区以及北部湾。东西长约1300公里,南北宽约200至400公里。面积约40万平方公里。经过地球物理勘探普查工作及几十口钻井资料,证实该区第三纪沉积广泛分布,厚逾万米。按沉积岩厚度大于1000米所圈定的范围约在30万平方公里以上,形成了北部湾、莺歌海、琼东南、珠江口及台湾西南五个沉积盆地(图1、2)。在北部湾、琼东南、珠江口及台湾西南盆地中,分别在下第三系流沙港组、陵水组、珠江组，上第三系角尾组、韩江组发现了储油气层(表1)。     

Geochemistry of the submarine Vityaz Ridge at the pacific slope of the Kurile island arc

This paper reports the results of geological studies at the submarine Vityaz Ridge carried out during cruises 37 and 41 on the R/V “Akademik Lavrent’ev” in 2005 and 2006. The studied area is located at the near-island trench of the slope in the central part of the Kurile island arc. Morphologically, it consists of two parts: inner volcanic arc represented by the Great Kurile Range and outer arc corresponding to the submarine Vityaz Ridge. Diverse rocks that compose the basement and sedimentary cover of the ridge were recovered by dredging. Based on K-Ar dating and geochemistry, the volcanics were divided into Paleocene, Eocene, late Oligocene, and Pliocene-Pleistocene complexes. Each of the distinguished complexes reflects the tectonomagmatic stage in the ridge evolution. The geochemical and isotope data on the volcanics indicate the contribution of ancient crustal material in magma source and, correspondingly, the formation of this structure on the continental basement. Two-stage model ages, T_DM2, vary in a wide range from zero values in the mafic rocks to 0.77 Ga in felsic varieties, pointing to the presence of Precambrian protolith in the source of the felsic rocks of the Vityaz Ridge. The Pliocene-Pleistocene volcanics are classed with the tholeiitic, calc-alkaline, and subalkaline series, which differ in alkali contents and REE fractionation. The values of (La/Sm)_N and (La/Yb)_N ratios vary from 0.74 and 0,84 in the tholeiitic varieties to 1.19 and 1.44 in the calcalkaline and 2.32 and 3.73 in the subalkaline rocks. All three varieties occur within the same volcanic edifices and were formed during differentiation of magmatic melt that were channeled along fault zones from the mantle source slightly enriched in crustal component     

珠江口盆地渐‒中新世古气候及物源特征:以阳江东凹为例

珠江口盆地阳江东凹处于太平洋构造域与新特提斯构造域交汇处,地球动力学背景、构造演化历史复杂,对于盆地物源特征和物源区古气候演化方面研究比较薄弱。选取珠江口盆地阳江东凹A钻井岩心中的珠海组-韩江组砂泥岩样品,对其进行地球化学分析,结果显示,样品呈轻稀土元素富集、重稀土元素平坦的配分模式,有明显的负Eu异常特征,与花岗岩相似;Al_2O_3/TiO_2、F1-F2、La/Th-Hf和Co/Th-La/Sc判别图解表明源岩以长英质为主,并有镁铁质岩石的混入;Al_2O_3/TiO_2、Cr/Zr和Th/Sc值也体现出长英质成分为主的物源特征;(Fe_2O_3+MgO)-TiO_2、Th-Co-Zr/10和Th-Sc-Zr/10构造环境判别图解显示,大部分样品落在大陆岛弧和主动大陆边缘区域,综合研究表明源区岩石特征与中国东南沿海大面积发育的岩浆岩极为相似。化学蚀变指数(CIA)、化学风化指数(CIW)、斜长石蚀变指数(PIA)等指标以及Mg/Ca值,指示珠江口盆地阳江东凹晚渐新世至中中新世物源区经历了中等程度的化学风化,对应温暖湿润的古气候环境,且从早到晚气温降低、降水量减少。     

Petrology and geochemistry of sandstones in the southern Benue Trough of Nigeria： Implications for provenance and tectonic setting

Petrographic and geochemical analyses of three Cretaceous lithostratigraphic sandstone units were undertaken to constrain their provenance and tectonic setting. Petrographic analysis showed that there are differences in composition between the three sandstone bodies, which can be attributed to differences in provenance relief, transport distance and geology of the terrain. Composition of the three lithostratigraphic sandstone bodies fall within the craton interior field.
Framework mode and chemical features indicated their derivation from basaltic volcanics, source rocks during the early rifting stage, and felsic, intermediate and mafic igneous source rocks located at the southeast basement complex terrain, with minor sedimentary components from the uplifted and folded older Cretaceous strata.
The chemical composition of the sandstones is mainly related to source rocks, chemical weathering conditions and transport agents. The source rocks were derived mainly from the southeastern Precambrian basement of Nigeria. Through examination of the sandstones, the tectonic setting was modeled. The Benue Trough belongs to a continental sedimentary basin of the passive margin type.
The tectonic evolution from Albian to Maastrichtain of the trough is contributed to the difference in framework mode and chemical composition of the sandstones. The evolution of the basin was reconstructed in terms of sandstone petrology and geochemistry. The tectonic evolution can be subdivided into three stages from the petrology and geochemistry data. The first stage covers Albian; the second stage the Turonian-Coniacian, and the third stage the Campanian-Maastrichtain. These are the three mega discontinuities in the sandstone composition among these three stages. These three discontinuities signify the influence of tectonism.