Fenton氧化膜-生物反应器出水中丙烯腈的实验研究

采用膜-生物反应器和Fenton氧化组合工艺对丙烯腈废水进行处理。从GC/MS测量结果来看,膜-生物反应器出水中主要物质为2,6双（二甲基-乙基）-4-酚、苯二甲酸和硝基苯二甲酸,均为生物难降解有机物,使出水不能达标。后续Fenton氧化工艺处理膜生物反应器出水,可以使COD含量等指标达到所要求的排放标准。经过膜-生物处理与Fenton法结合的优化工艺,COD去除率达到80%~88%,去除率达到98%,出水水质可达排放标准。Fenton氧化工艺的最佳工艺条件为：pH值为3.4,硫酸亚铁的投加量为700mg/L,双氧水的投加量为600mg/L。     

水力旋转填料生物接触氧化处理城市污水的研究

通过对中试规模的新型水力旋转填料生物接触氧化法处理城市污水的试验研究,利用新型填料的独特构型,增强反应器的传质性能,探讨了接触氧化池对COD、NH+4-N的去除,及水力停留时间、气水比、温度对处理效果的影响。试验结果表明在水力停留时间为2~2.5h,气水比为(7~8)∶1,进水COD、NH4+-N浓度分别为130.1~366.5mg/L、11.3~19.2mg/L的条件下,两者的平均去除率为75.9%、65.4%,出水COD、NH4+-N浓度均已达到国家二级排放标准;气水比和水力停留时间对接触氧化池处理效果的影响较为明显;低温下接触氧化池对有机物、氨氮的去除仍具有较好的效果。     

Effectiveness of Wastewater Treatment Using an Anaerobic/Anoxic/Aerobic-membrane Bioreactor

采用厌氧/缺氧/好氧膜生物反应器对北京某城市污水处理厂的初沉池出水进行中试试验,约200 d的研究表明,在水力停留时间保持12.5 h后,化学需氧量、生物需氧量及总有机碳的去除率分别稳定在92%、98%、85%左右,其中生化降解部分与膜过滤部分对COD去除的贡献率分别为89%和11%;NH4＋-N、总氮（total nitrogen,TN）的去除率分别为98%、79%左右,出水ρ（TN）平均在10 mg/L左右;系统在污泥龄为40 d左右时,总磷（totalphosphorus,TP）平均去除率为85%,出水ρ（TP）在0.93 mg/L左右;反硝化除磷、好氧吸磷、膜截留对总磷的去除所占的比例分别为44.6%、51.8%、3.6%;出水浊度极低且几乎无悬浮物,可直接回用于城市杂用水.间歇抽吸、曝气冲刷、在线水力反冲及定期药洗保证了该系统的可持续运行.     

ABR-生物接触氧化工艺处理低碳氮比生活污水试验

近年来,城市生活污水呈现出低碳氮比的趋势,造成污水处理脱氮困难.采用ABR-生物接触氧化工艺对低碳氮比生活污水进行试验研究,确定了试验运行参数,即在进水COD/N为2～7范围内,当HRT=10 h,R=2.5、T=30℃时,系统对TN的去除效果良好;TN的平均去除率随着碳氮比的减小而迅速降低,此时,碳源不足成为制约脱氮效果的主要原因;在最佳运行条件下,当进水COD/N为6～7时,TN平均去除率达到80%以上,出水TN质量浓度小于15 mg/L,满足<城镇污水处理厂污染物排放标准>一级A标准.     

河道污染治理技术-- 生物接触氧化填料研究

选择不同填料对生物接触氧化法处理生活污水进行了进一步的研究与应用,探讨了温度、接触氧化停留时间等因素对其处理效果的影响。实验研究结果表明,在水温为18℃~20℃,水力负荷为70m l/m in时,采用鹅卵石和沸石的复合填料挂膜,进行生物接触氧化法处理生活污水,在降解NH3-N和氨氮等方面取得良好效果,COD、NH3-N去除率都高达80%以上。     

EPP填料曝气生物滤池处理城市污水厂二级出水的中试研究

对韩国产EPP填料应用于曝气生物滤池（BAF）处理二级出水的效果及影响因素进行了研究,结果表明：利用该填料的BAF系统处理二级出水,CODCr,平均去除率为49．1％,BOD5平均去除率为51．4％,NH4^＋-N平均去除率为76％,SS平均去除率为52．6％。系统稳定运行后,出水水质达到了城市杂用水水质控制指标。改变水力负荷和气水比对CODCr、BOD5、NH3^-N的去除效率都有影响,但对SS去除率影响不大。     

固定化生物技术在合成染料废水处理中的应用

在多级折流板反应器生物处理装置中,采用活性炭为载体人工固定化生物处理合成染料废水,出水水质稳定, 出水中的烷烃肽链变短;其对COD_Cr和BOD₅的去除率可达96.46%、99.77% ;对SO^2-₄和钙镁总量的去除效率超过80.37%、78.66%;折流板反应器的容积负荷率N_v可达2.8 kg COD/(d•m³)。活性炭经生物固定化后,不仅不会影响它的处理效果,还会延长活性炭的使用寿命;当冲击性有机负荷发生时,固定化生物活性炭能够承受并能很快恢复。     

微压流化式复合生物反应器的同步脱氮

通过对曝气系统的调节,微压流化式复合生物反应器（MP-FHBR）内可以实现好氧区和缺氧区共存,利用这一特点和MP-FHBR中同时存在的活性污泥﹑悬浮生物膜复合生物体系,进行了同步脱氮的试验研究。结果表明,MP-FHBR在好氧-缺氧条件下,实现了同步脱氮过程,TN和COD的平均去除率分别达到77.5%和98.3%。降低DO质量浓度使反应器内形成完全缺氧环境,对MP-FHBR同步脱氮效果没有显著影响,但会降低系统去除COD的效果;而提高DO质量浓度使反应器内形成完全好氧环境,MP-FHBR同步脱氮效果显著下降。在一定范围内提高进水COD/TN有利于提高MP-FHBR同步脱氮效果,COD/TN 由2升高到10,TN平均去除率由58.4%提高到78.8%,而继续提高COD/TN对系统同步脱氮效果的影响并不明显。在反应器允许的条件下,提高污泥质量浓度(MLSS)有利于提高系统反硝化脱氮效果,TN去除率随MLSS的增加而提高。     

膜生物反应器在中水工程的应用

通过对生活污水处理方法的介绍,说明MBR膜生物反应器法的优点,并对各种类型膜生物反应器的优缺点进行分析,通过实例说明MBR膜生物反应器在生活污水回用应用于中水方面的价值.     

固体停留时间对HLB-MR反应器直接回收城市污水中有机物的影响

为优化高负荷生物絮凝-膜反应器（HLB-MR）的工艺参数,提高其资源化城市污水的效能,采用平行对比实验,考察了不同固体停留时间（t_SR）条件下反应器的有机物去除效率、生物絮凝效果、有机物回收效果和膜污染情况。结果表明：在t_SR分别为0.2、0.6、1.0 d时,HLB-MR反应器有机物去除效率均在85%以上,其出水化学需氧量（COD）质量浓度均保持在30 mg/L左右;反应器内的生物絮凝效果随着t_SR的延长而增强,其胶体COD絮凝效率从t_SR为0.2 d时的66%增加到t_SR为1.0 d时的95%,与此同时,有机物的矿化损失率也逐渐增加,从t_SR为0.2 d时的6.9%增加到t_SR为1.0 d时的10.5%,总COD的回收率逐渐降低;反应器内浓缩液的膜污染潜势随着t_SR的延长逐渐缓解,这与较长t_SR条件下反应器内胞外聚合物（EPS）产量较高、生物絮凝效果较好、微细颗粒（0~1 μm）的颗粒浓度较低有关。经过综合对比分析,0.6 d为反应器较优的t_SR参数,在该条件下,胶体COD的絮凝效率高达90%,膜污染程度较轻;总COD的矿化损失率低至7.4%,总COD的回收率（忽略膜清洗时有机物损失）可高达80%以上。     

预处理／复合水解酸化／复合好氧氧化工艺处理综合制药废水

针对传统水解酸化和好氧氧化处理工艺存在的问题,对水解酸化工艺及好氧氧化处理工艺进行了改进;并针对东北制药集团制药废水水质特征,设计开发了预处理 复合水解酸化 复合好氧氧化的生物处理技术。工程设计规模为30000 m3/d,两年的运行结果表明,此工艺运行稳定,耐冲击负荷能力强。当平均进水浓度COD为3600 mg/L、BOD5为1000 mg/L、SS为450 mg/L时,平均出水浓度COD≤300mg/L、BOD5≤100 mg/L、SS≤50 mg/L,达到了国家城市排水三级标准医药企业污水排放标准(COD300mg/L)。     

Mechanism of efficient nutrient removal and microbial analysis of a combined anaerobic baffled reactor–membrane bioreactor process

A combined ABR–MBR process consisting of an anaerobic baffled reactor (ABR) combined with an aerobic membrane bioreactor (MBR) treating municipal wastewater was investigated at controlled pH range 6.5–8.5 and at constant temperature 25 ± 1 °C. Total nitrogen (TN), ammonia (NH₄ ⁺–N), total phosphorus (TP), and chemical oxygen demand (COD) removal performances were evaluated by analyzing the mechanism for efficient nutrient removal. The results showed that the average removal rates of COD, NH₄ ⁺–N, TN, and TP reached 93, 99, 79, and 92 %, respectively, corresponding with the COD, NH₄ ⁺–N, TN, and TP effluent of 24 (18–31), 0.4 (0–0.8), 10.6 (8.8–12.9), and 0.31 (0.1–0.5) mg/L under the operational condition of hydraulic retention time (HRT) 7.5 h, recycle ratio 200 %, and dissolved oxygen 3 mg/L. The MBR enhanced NH₄ ⁺–N, TN, and TP removal rates of 13, 10, and 18 %, respectively, and the membrane retention reduced TP 0.17 mg/L. The process was able to maintain a stable performance with high-quality effluent. Analysis of the results by fluorescence in situ hybridization showed that the abundance of ammonia-oxidizing bacteria, nitrite-oxidizing bacteria, and phosphorus accumulating organisms as percentages of all bacteria in each compartment was stable. The enriched microorganisms in the system appear to be the main drivers of the process efficient for nutrient removal.     

The geochemical role of phyto- and zooplankton in the extraction of chemical elements from water

This paper provides for the first time comparative assessment of the contents of 70 chemical elements occurring in the aquatic environment in water, phytoplankton, and zooplankton. The assessment was made using modern highly sensitive methods. The studies were performed at Beloyarskoe Reservoir, a manmade freshwater lake situated in the Middle Urals that has been studied in detail. The chemical elements were ranked in groups differing in the accumulation coefficient (AC) values for the phyto- and zooplankton. The comparison revealed that for the vast majority of chemical elements, the AC values were higher in zooplankton (53, or 76%) than in phytoplankton (17, or 24%). The average AC values for zooplankton (∼740 000) exceeded that for phytoplankton (∼68 000) by more than 10 times. It was found that some elements had very high AC values in zooplankton compared to phytoplankton. For instance for Nb, the ratio AC_zoo/AC_phyto was 1 200 000; for B, Ta, Sn, Lu, U, 300 000–500 000; for Sb and Y, 100 000–130 000; for La and Nd, 80 000–85 000; for Mo, Cd, Pr, Gd, Dy, Sc, Se, Bi, 20 000–30 000; and for Pd, Hf, Sm, Sb, Er, As, 10 000–20 000. It is concluded that zooplankton is sometimes more suitable for the biogeochemical indication of the pollution of natural water bodies, because the AC values for most elements are much higher in zooplankton than in phytoplankton and the total plankton. Considering the high assimilability of microelements and radionuclides, the plankton may serve not only as an indication but also as the mean of regulated purification of waterbodies from these elements.     

Field tests on a grease trap effluent filter

This study investigates the field performance tests of a commercial grease trap effluent filter for removal of total suspended solids, and oil and grease discharged from the clear zone of full service restaurant grease traps. The grease trap effluent filters were installed on 1,000-gallon, 2,000-gallon and 5,400-gallon full service restaurant grease traps over a period of 8 weeks, and samples were taken at the inlets and outlets. On average, the effluent filters demonstrated to be capable of removing 41% to 57% of TSS, and 43% to 52% of O and G. Field test data also showed that the total amount of TSS removed by the grease trap effluent filter installed on 1,000 gallon, 2,000 gallon and 5,400 gallon grease traps were approximately 2,542 kg, 709 kg, and 2,319 kg, respectively; and the total amount of O and G removed over the same period were approximately 1,104 kg, 271 kg, and 897 kg, respectively.     

High-performing antifouling bacterial consortium for submerged membrane bioreactor treating synthetic wastewater

Biofouling, associated with membranes, is considered as a major operational challenge in membrane bioreactor (MBR) technology. Interrupting the process for the formation of biofilm by the action of interspecies quorum quenching (QQ) has received a significant attention since recent years. An antifouling bacterial consortium was identified to improve biofouling inhibition performance during MBR operation. For this purpose, various QQ bacteria were isolated from laboratory-scale MBR using enrichment culture method and identified via 16S rRNA. Potential quenching strains including Enterobacter cloaca, Delftia sp., and Pseudomonas sp. were utilized to control biofouling in the MBR operated in the continuous mode for 38 days. Three laboratory-scale MBRs, including two MBRs with different anti fouling consortium and a control, were operated in parallel under similar operating conditions. Biofouling control by QQ bacteria was compared based on the membrane permeability and EPS secretion from biofilm on the membrane. Both MBRs with antifouling consortium (AC-MBRs) experienced around three times less biofouling as compared to conventional MBR leading to significant decrease in acyl homoserine lactones (AHLs) concentration in the biocake. More than 90, 45, and 49% of COD, NH₄–N, and PO₄ ^3?–P removal efficiencies elucidate that QQ bacterial consortium could effectively reduce membrane biofouling without compromising the MBR efficiency. Comparatively lower concentration of bound EPS in AC-MBRs restricted the bacterial adhesion to membrane resulting in enhanced membrane permeability depicting that a broader range of signal molecules could be hydrolyzed using antifouling consortium than single or no QQ strain in the submerged MBR.     

过去2000年中国东部冬半年温度变化

根据近年收集、整理的历史文献冷暖记载及过去有关研究结果,对中国东部地区过去2000年冬半年的温度状况进行了定量推断,重建了中国东部地区过去2000年分辨率为10～30年的冬半年温度距平变化序列,并分析了中国东部过去2000年的冷暖变化阶段与变化幅度。结果发现:在过去2000年中,中国东部冬半年温度高于1951～1980年平均值且持续时间超过百年的暖期有4个,其中最暖的30年出现在1230’s～1250’s(较1951～1980年高0.9℃);低于1951～1980年平均值且持续时间超过百年的冷期有3个,其中最冷的30年出现在1650’s～1670’s(较1951～1980年低1.1℃)。在冷暖期之间相互转换的过程中,冬半年温度一般都出现1℃左右的升、降温;在冷暖期内,一些幅度较大的升、降温也与之相仿;在相邻的两个30年中,温度变化幅度达0.5℃以上的有19次之多。对比过去2000年中的冷暖交替变化还可以看出:20世纪回暖时的升温幅度与过去2000年中的其他回暖过程所出现的幅度相似,特别是与5世纪末至6世纪的回暖极为相似;而在当前温暖阶段中,1981～1999年较1951～1980年升高了0.5℃,不但使其接近过去2000年中的最暖30年,而     

The Diavik Waste Rock Project: Particle size distribution and sulfur characteristics of low-sulfide waste rock

Three large-scale instrumented waste rock piles were constructed at the Diavik Diamond Mine in the Northwest Territories, Canada. These experimental waste rock piles (test piles) are 15 m high and are part of an integrated field and laboratory research program to characterize and compare low-sulfide waste rock and drainage at various scales. During test pile construction, samples of the <50 mm fraction of waste rock were collected from two types of waste rock that are segregated during mining operations based on S content. The samples were analyzed for S content and particle size distribution. One test pile contained waste rock with an average of 0.035 wt.% S in the <50 mm fraction, within the operational S target of <0.04 wt.% S for the lower S waste rock type. The second test pile contained waste rock with an average of 0.053 wt.% S in the <50 mm fraction, lower than the operational S target of >0.08 wt.% S for the higher S waste rock type. The third test pile has a low permeability till layer and a low sulfide waste rock thermal layer covering a core of waste rock with average 0.082 wt.% S in the <50 mm fraction, which is within the operational S target of >0.08 wt.% S for the higher S waste rock. Particle size distributions for the lower and higher S waste rock are similar, but the higher S waste rock has a higher proportion of fine-grained particles. Sulfur determinations for discrete particle sizes of the <50 mm fraction illustrate higher S concentrations in smaller particles for both the lower S waste rock and the higher S waste rock. Similarly, S concentrations calculated for the >10 m scale, from composite blast hole cuttings, are lower than those calculated for the <50 mm scale. Acid–base accounting using standard methods and site-specific mineralogical information was used to calculate the ratio of neutralization potential to acid generating potential. A comparison of calculation approaches to pH and alkalinity data from humidity cell and test pile effluent suggest that ratios are very sensitive to the calculation method. The preferred calculation method was selected by comparing calculation results to pH and alkalinity data from humidity cell effluent collected over 95 weeks and test pile effluent collected over five field seasons. The preferred acid–base accounting values were obtained by calculating the average neutralization potential divided by the average acid potential of a sample set. This approach indicates that waste rock with >0.05 wt.% S is of uncertain acid-generating potential and effluent data indicate this waste rock generates acidic effluent; whereas lower S waste rock does not produce acidic effluent, consistent with the acid–base accounting predictions.     

连续流气提式流化床启动过程中好氧颗粒污泥的形成机制

探讨连续流气提式好氧颗粒污泥流化床(CAFB)反应器的运行特征,对该工艺颗粒污泥形成过程、形成机理和颗粒性质进行分析。以市政污泥为接种污泥,以醋酸钠为碳源,在连续运行方式下培养好氧颗粒污泥。研究结果表明：CAFB反应器启动的第4－5天即有大量颗粒污泥形成,颗粒直径800~1 000 μm,比重1.006,生物相丰富,能够分泌大量胞外聚合物。当COD有机负荷高达8 和13 kg/(m³·d)时,对COD处理效率均维持在93%~97%,COD出水质量浓度仅为30~80 mg/L,引起启动后期丝状菌的大量繁殖,污泥流失。进一步提高污泥负荷有望控制污泥膨胀。     

Nitrate removal from groundwater using solid-phase denitrification process without inoculating with external microorganisms

Denitrification of groundwater was studied using a laboratory-scale reactor packed with biodegradable snack ware served as both carbon source and biofilm support for microorganisms. The complete removal of 50 mg/L of nitrate-nitrogen was achieved in a 23-day-old reactor with 2.1 h of hydraulic retention time without inoculating with any external microorganisms, which indicates that indigenous microorganisms in groundwater proliferate readily and result in stable biofilm formation onto biodegradable snack ware. Accumulation of nitrite and nitrate residue was detected when hydraulic retention time was lower than 2.1 h. The breakthrough of nitrate-nitrogen up to over 10 mg/L in the effluent water was observed with nitrate removal efficiency reducing to about 75 % when hydraulic retention time was lowered to 1.4 h. The highest rate of denitrification was observed with 1.5 h of hydraulic retention time. Dissolved organic carbon concentration in the effluent water ranged between 10 and 20 mg/L during the stable operation of the reactor, and nitrite-nitrogen concentration was never higher than 0.09 mg/L. Considering its relatively low price and high denitrification rate, biodegradable snack ware can become a good alternative for denitrification process.