The role of infiltration processes in steep slope stability of pyroclastic granular soils: laboratory and numerical investigation

Rainfall-induced landslides on steep slopes are a common feature in much of Italy’s mountain areas covered by shallow-pyroclastic deposits. Generally, these deposits are unsaturated and have a slope angle higher than 40°–50°; hence their stability is due to the positive effect of matric suction on soil shear strength. During rainfall, rainwater infiltration causes a decrease in suction, which in turn causes changes in soil mechanical and hydraulic properties, leading towards an instability process. However, the response of pyroclastic soil slopes to rainwater infiltration is not fully understood. The aim of this study is to link slope instability to the infiltration process on the basis of advanced geotechnical characterization, in situ monitoring and numerical analysis calibrated through a back-analysis of well-instrumented flume tests.     

Physicochemical parameters of the formation of hydrothermal deposits: A fluid inclusion study. I. Tin and tungsten deposits

The author’s database, which presently includes data from more than 18500 publications on fluid and melt inclusions in minerals and is continuing to be appended, was used to generalize results on physicochemical parameters of the formation of hydrothermal deposits and occurrences of tin and tungsten. The database includes data on 320 tin and tin-tungsten deposits and occurrences and 253 tungsten and tungstentin deposits around the world. For most typical minerals of these deposits (quartz, cassiterite, tungsten, scheelite, topaz, beryl, tourmaline, fluorite, and calcite), histograms of homogenization temperatures of fluid inclusions were plotted. Most of 463 determinations made for cassiterite are in the range of 300–500°C with maximum at 300–400°C, while those for wolframite and scheelite (453 determinations) fall in the range of 200–400°C with maximum at 200–300°C. Representative material on pressures of hydrothermal fluids included 330 determinations for tin and 430 determinations for tungsten objects. It was found that premineral, ore, and postmineral stages spanned a wide pressure range from 70–110 bar to 6000–6400 bar. High pressures of the premineral stages at these deposits are caused by their genetic relation with felsic magmatism. Around 50% of pressure determinations lie in the range of 500–1500 bar. The wide variations in total salinity and temperatures (from 0.1 to 80 wt % NaCl equiv and 20–800°C) were obtained for mineral-forming fluids at the tin (1800 determinations) and tungsten (2070 determinations) objects. Most of all determinations define a salinity less than 10 wt % NaCl equiv. (∼60%) and temperature range of 200–400°C (∼70%). The average composition of volatile components of fluids determined by different methods is reported. Data on gas composition of the fluids determined by Raman spectroscopy are examined. Based on 180 determinations, the fluids from tin objects have the following composition (in mol %): 41.2 CO₂, 39.5 CH₄, 19.15 N₂, and 0.15 H₂S. The volatile components of tungsten deposits (190 determinations) are represented by 56.1 CO₂, 30.7 CH₄, 13.2 N₂, and 0.01 H₂S. Thus, the inclusions of tungsten deposits are characterized by higher CO₂ content and lower (but sufficiently high) contents of CH₄ and N₂. The concentrations of tin and tungsten in magmatic melts and mineral-forming fluids were estimated from analysis of individual inclusions. The geometric mean Sn contents are 87 ppm (+ 610 ppm/−76 ppm) in the melts (569 determinations) and 132 ppm (+ 630 ppm/−109 ppm) in the fluids (253 determinations). The geometric mean W values are 6.8 ppm (+ 81/−6.2 ppm) in the magmatic melts (430 determinations) and 30 ppm (+ 144 ppm/−25 ppm) in the mineral-forming fluids (391 determinations).     

Topical issues of the theory of gold deposit formation

The issues of the theory of gold deposit formation are considered. These issues were crucial in the works by N.V. Petrovskaya. The systematics of gold deposits based on stable mineral assemblages and mineral and geochemical types of ores and their families characteristic of certain groups of gold deposits is consonant with contemporary analogue classifications of ore deposits, which, however, require improvement by means of developing their genetic version. Petrovskaya’s proposed subdivision of gold deposits into families distinguished by depth of their formation is such a version, because in Petrovskaya’s understanding, the factor of depth integrates genetic features of deposits formed at shallow, medium, and great depths. According to recent data, the depth interval of localization of ore deposits is estimated at 15–20 km instead of 6–10 km suggested earlier; thus, the intervals of medium and great depths increase. Attention is called to the Petrovskaya’s ideas of stadial progressive development of ore formation with change in pyrite-arsenopyrite mineralization by base-metal and telluride mineralization along with advanced and concomitant deposition of quartz. The stadial formation of shallow-seated deposits and colloidal mineral formation therein, as well as the concept of gel metasomatism and mechanisms of accompanying destruction of preceding mineral assemblages developed by Petrovskaya, are considered and their implications are illustrated by specific deposits. Petrovskaya’s views on sources of ore matter and the polygenetic character of gold and Au-bearing deposits are discussed.     

Organic Geochemistry of Lead—Zinc Polymetallic Dposits,Northern Guangdong

The characters of organic matter in rocks and ores in the Fankou and Dabaoshan deposits are systematically studied with regard to their implications for mineralization.The results show that kerogens in this area faaa mainly into the plutonism field in Van Krevelen‘s diagram.Reflectivity of the organic substance was measured to be 3.06%(Fankou)and 1.67%(Dabaoshan),corresponding to the paleo-geotemperatures of 232℃ and 184℃ respectively.The same types of porphyrins and hydrocarbons were recognized in the rocks and ores and hydrocarbon-bearing inclusions are widespread in quartz and calcite,particularly in Dabaoshan,It is thought that the orgain matter must have played a critical role in diagenesis and metallization in these deposits and that the hydrothermal solution was most likely to be the type of water-oil hot brine.     

Influence of crude oil cracking on distribution of hydrocarbons in the Earth’s interior (experimental data)

The compositions and phase conditions of water-hydrocarbon fluids in synthetic quartz inclusions were studied by the methods of microthermometry, local IR spectroscopy, and gas-liquid chromatography. Synthetic quartz was grown in near-neutral fluoride, low-alkali bicarbonate, and alkali carbonate solutions with crude oil and its major fractions. The crystals with fluid inclusions were grown under thermal gradient conditions at relatively low temperatures (240–280°C) and pressures (6–45 MPa). After the study, the inclusions of grown crystals were subject to thermal processing in autoclaves at 350–380°C and 80–125 MPa. As a result, the initial water-hydrocarbon inclusions underwent significant changes. Hydrocarbon gases, largely methane and residual solid bitumens, appeared in their composition; the gasoline-kerosene fraction content increased substantially in liquid hydrocarbons (HCs). These changes are caused, first of all, by crude oil cracking, which is manifested already at 330°C and attains its maximum activity at 350–500°C (pressure of saturated vapor and higher). In natural conditions with increase in depths and, thus, the thermobaric parameters, this process is inevitable. According to the obtained experimental data, this very phenomenon and the existence of real thermal and baric gradients in the Earth’s interior provide for the formation of vertical zoning in the distribution of hydrocarbon deposits of different types.     

Evolution of a Carboniferous carbonate-hosted sphalerite breccia deposit,Isle of Man

A newly discovered, extensive sphalerite-bearing breccia (~7.5 wt.% Zn) is hosted in dolomitised Carboniferous limestones overlying Ordovician–Silurian metasedimentary rocks on the Isle of Man. Although base metal sulphide deposits have been mined historically on the island, they are nearly all quartz vein deposits in the metamorphic basement. This study investigates the origin of the unusual sphalerite breccia and its relationship to basement-hosted deposits, through a combination of petrographic, cathodoluminescence, fluid inclusion, stable isotope and hydrogeologic modelling techniques. Breccia mineralisation comprises four stages, marked by episodes of structural deformation and abrupt changes in fluid temperature and chemistry. In stage I, high-temperature (T _h > 300°C), high-salinity (20–45 wt.% equiv. NaCl) fluid of likely basement origin deposited a discontinuous quartz vein. This vein was subsequently dismembered during a major brecciation event. Stages II–IV are dominated by open-space filling sphalerite, quartz and dolomite, respectively. Fluid inclusions in these minerals record temperatures of ~105–180°C and salinities of ~15–20 wt.% equiv. NaCl. The δ³⁴S values of sphalerite (6.5–6.9‰ Vienna-Canyon Diablo troilite) are nearly identical to those of ore sulphides from mines in the Lower Palaeozoic metamorphic rocks. The δ¹⁸O values for quartz and dolomite indicate two main fluid sources in the breccia’s hydrothermal system, local Carboniferous-hosted brines (~0.5–6.0‰ Vienna standard mean ocean water) and basement-involved fluids (~5.5–11.5‰). Ore sulphide deposition in the breccia is compatible with the introduction and cooling of a hot, basement-derived fluid that interacted with local sedimentary brines.     

An analytical source function for a coupled hybrid wave model

An analytical form for the source function is formulated by comparing the fetch-limited approximation of the Ocean Wave Transport equation and the empirical equation for the fetch-dependent wave forecast nomograms. The source function thus generated has been utilised in the numerical model based on Toba’s formulation of wave transport equation and tested for the seas around the Indian subcontinent (5°S to 25°N latitude; 45°E to 100°E longitude). The grid averaged hindcast wave heights are found to be moderately matching with the GEOSAT altimeter measured significant wave heights of the 1987–1989 period, particularly for waves higher than 1 meter.     

Sédimentologie, paléontologie et paléoenvironnements c?tiers de la région de Porrentruy (Sud-Rhénan, Paléogène, Jura, Suisse): implications géodynamiques

Resume. Situés dans la partie la plus distale du bassin molassique suisse et dans le prolongement sud du fossé rhénan, les dép?ts conglomératiques appartenant au groupe stratigraphique des Gompholithes & Conglomérats ont fait l’objet d’une étude sédimentologique et paléontologique détaillée. La multitude des affleurements réalisés lors des travaux de construction de l’autoroute Transjurane dans la région de Porrentruy (Jura), permet d’appréhender ces paléoenvironnements rupéliens (Oligocène inférieur). Les études sédimentologiques et paléontologiques révèlent l’existence d’environnements c?tiers avec des falaises de calcaires mésozo?ques entaillées par des canyons où se trouvent des rivières au régime torrentiel. Ces rivières qui érodent les couches du Mésozo?que créent des galets qui sont déposés sous la forme de deltas marins progradant vers le nord. A l’abri des exutoires des canyons se développent quelques environnements lacustres. Ces dép?ts conglomératiques sont fortement liés à l’activité tectonique rupélienne. La distension rhénane et l’activité de la faille transformante située entre le fossé rhénan et le bassin de la Bresse subdivisent les différents blocs mésozo?ques en horsts et grabens, permettant ainsi l’érosion des sédiments dans les parties hautes (horst) et leur transport dans les zones basses (graben). La découverte de rares galets de roches endogènes et effusives dans les dép?ts conglomératiques montre un transport du socle des Vosges vers le sud dans la région de Porrentruy par l’intermédiaire sans doute d’une dérive littorale. Bien que la surrection des Vosges et de la Forêt-Noire et leur mise à l’érosion soient connues dès la base du Miocène, la présence de ces galets atteste l’existence de failles dès le début du Rupélien qui mettent à l’érosion le socle du massif des Vosges.

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Located in the distal part of the Swiss Molasse Basin and in the southern extension of the Rhine Graben, the conglomeratic deposits belonging to the Gompholithes & Conglomérats stratigraphic group have been the object of detailed sedimentological and paleontological studies. The great number of outcrops that came into sight during the building works of the Transjurane highway in the vicinity of Porrentruy (Swiss Jura) lead to a better understanding of Rupelian paleoenvironments (Early Oligocene). The sedimentological and paleontological studies reveal the existence of coastal environments with Mesozoic limestone cliffs notched by canyons with torrential rivers. Those rivers eroding the Mesozoic series create pebbles deposits forming marine deltas prograding towards North. In protected areas, some lacustrine environments can develop. These conglomeratic deposits are strongly bound to the Rupelian tectonic activity. The rhenish distension and the activity of the transform faults located between the Rhine Graben and the Bresse basin divide the Mesozoic blocks in horst and graben structures, thus allowing the erosion of sediments in higher regions (horst) and their transport in lower zones (graben). The discovery of rare pebbles made of endogene and effusive rocks in those conglomeratic deposits shows a transport coming from the Vosges massifs towards south to the Porrentruy region, probably with the support of a littoral drift. Although the surrection of the Vosges and Schwarzwald massifs (and the beginning of their erosion) is normally attributed to the base of the Miocene, the presence of those pebbles attests the existence of faults putting the basement of the Vosges massif to erosion since the base of Rupelian.

Manuscrit re?u le 4 février 2003 Révision acceptée le 30 mars 2005     

Gold mineralisation at the Lady Bountiful Mine,Western Australia: An example of a granitoid-hosted Archaean lode gold deposit

The Lady Bountiful granitoid-hosted lode gold deposit, located in the mid-greenschist facies metamorphosed Ora Banda greenstone sequence, is hosted predominantly by the late-tectonic Liberty Granodiorite. Gold mineralisation is localised along quartz-veined, sinistral, brittle fault-zone(s) that transect the boundary between the Liberty Granodiorite and Mt Pleasant sill. Quartz vein textures indicate two stages of a single gold-related vein-development event, with high-grade gold mineralisation restricted to the second stage. Ore minerals include pyrite, chalcopyrite, pyrrhotite, galena, sphalerite, Au−Ag−Bi−Pb-tellurides, and native gold. Fluid infitration has resulted in narrow (<1 m) bleached wallrock alteration envelopes to the fault zones comprising albite-K-mica ±chlorite±calcite±rutile assemblages. Temperature-pressure conditions varied from Stage I (300°±50°C, ≈2 kbar) to Stage II (250°±50°C, ≈0.5 to 2 kbar), with the hydrothermal fluid in both stages characterised by X(CO₂)≤0.15 and moderate salinity (≈1.28 m NaCl). Intermittent phase separation of Stage II mineralising fluids, initiated by pressure fluctuations in dilational sites, and/or fluid-dominated fluid: wallrock interaction, are invoked as the dominant depositional mechanisms. The granitoid-hosted Lady Bountiful lode gold deposit shares many features with other granitoid-hosted lode gold deposits in the Yilgarn Craton and the Superior Province. Granitoid-hosted lode gold deposits, such as the Lady Bountiful deposit, provide additional evidence that the dominant control on the localisation of gold mineralisation within a granitoid host is structure, with competency contrasts playing a significant role. Furthermore, the hydrothermal wallrock alteraction and orefluid chemistry characteristics of the granitoid-hosted lode gold deposits are comparable to those established for greenstone-hosted lode gold mineralisation.     

Evolution of the angle between the magnetic moment and the rotation axis of radio pulsars

It is shown that, when angular-momentum losses of a radio pulsar are represented as a sum of magnetic-dipole and current losses, the angle between the magnetic moment and rotation axis of the radio pulsar tends to some equilibrium value (near 45°). This process takes place on a timescale of the order of the pulsar’s characteristic age. Taking into account the non-dipolarity of the pulsar’s magnetic field changes this equilibrium angle.     

Mobility of palladium chloride complexes in mafic rocks: insights from a flow-through experiment at 25 °C using air-saturated, acidic, and Cl-rich solutions

Summary A flow-through chromatographic experiment was carried out to determine the ability of an oxidized, acidic, chloride-bearing solution to transport Pd through a column of crushed Columbia River basalt at 25 °C. An initial plug of solution containing 13.8 mg Pd/kg H₂O was loaded onto the column of crushed basalt and eluted with an air-saturated, 1 m NaCl solution of pH 3. Even after 3606 h of elution, corresponding to a fluid-rock mass ratio of 1338, less than 10% of the Pd originally loaded on the column was recovered. On the other hand, in a similar experiment involving relatively unreactive quartz sand, the Pd was almost completely recovered after the passage of only 4 pore masses of eluent (or a fluid-rock mass ratio of approximately one), a behavior similar to that of Rb. The results suggest that unrealistically large amounts of oxidizing and acidic fluids are required to react with a given mass of basalt in order to overcome the acid- and redox-buffering capacity of the rock and to mobilize palladium as a chloride complex. On the other hand, Pd-chloride complexes can be easily transported through a rock with minimal acid- and redox-buffering capacity, such as clean quartz sandstone. The implications of this study for PGE enrichments in sediment-hosted stratiform copper (Kupferschiefer type) deposits are explored briefly. Authors’ addresses: Scott A. Wood, Department of Geological Sciences, University of Idaho, Box 443022, Moscow, Idaho 83844-3022, USA; Charles Normand, Département des Sciences de la Terre et de l’Atmosphère, Université du Québec à Montréal, Case postale 8888, Succursale Centre-ville, Montréal (Québec), H3C 3P8 Canada     

Geomorphic and structural evidences of neotectonic activity in the Sub-Himalayan belt of Nahan Salient,NW India

Neotectonism in the Sub-Himalayan belt is not new. Moreover, the word ‘Sub-Himalaya’ is almost synonymous with ‘neotectonic activity’. In the present paper, we report some of the most convincing geomorphic and structural evidences of neotectonic activity from the Sub-Himalayan belt in the Nahan Salient. The geomorphic evidences mainly include the four geomorphic surfaces identified from the transverse topographic profiles drawn parallel to the Himalayan front. These surfaces are commonly covered with terrace deposits that are tilted as well as faulted at a number of places. A number of faults, directly observable in the field, are normal in nature and they are oriented at high angles to the Himalayan Frontal Thrust (HFT). These faults are similar to the E-W extension in southern Tibet in response to the oblique convergence of India at ∼N20°E in the NW Himalaya. They are attributable to the kinematics of neotectonic compression along the HFT, the frontal ramp-oblique ramp-frontal ramp geometry of the thrust fault and related adjustments.     

Atlanta’s urban heat island under extreme heat conditions and potential mitigation strategies

The urban heat island (UHI), together with summertime heat waves, foster’s biophysical hazards such as heat stress, air pollution, and associated public health problems. Mitigation strategies such as increased vegetative cover and higher albedo surface materials have been proposed. Atlanta, Georgia, is often affected by extreme heat, and has recently been investigated to better understand its heat island and related weather modifications. The objectives of this research were to (1) characterize temporal variations in the magnitude of UHI around Metro Atlanta area, (2) identify climatological attributes of the UHI under extremely high temperature conditions during Atlanta’s summer (June, July, and August) period, and (3) conduct theoretical numerical simulations to quantify the first-order effects of proposed mitigation strategies. Over the period 1984–2007, the climatological mean UHI magnitude for Atlanta-Athens and Athens-Monticello was 1.31 and 1.71°C, respectively. There were statistically significant minimum temperature trends of 0.70°C per decade at Athens and −1.79°C per decade at Monticello while Atlanta’s minimum temperature remained unchanged. The largest (smallest) UHI magnitudes were in spring (summer) and may be coupled to cloud-radiative cycles. Heat waves in Atlanta occurred during 50% of the years spanning 1984–2007 and were exclusively summertime phenomena. The mean number of heat wave events in Atlanta during a given heat wave year was 1.83. On average, Atlanta heat waves lasted 14.18 days, although there was quite a bit of variability (standard deviation of 9.89). The mean maximum temperature during Atlanta’s heat waves was 35.85°C. The Atlanta-Athens UHI was not statistically larger during a heat wave although the Atlanta-Monticello UHI was. Model simulations captured daytime and nocturnal UHIs under heat wave conditions. Sensitivity results suggested that a 100% increase in Atlanta’s surface vegetation or a tripling of its albedo effectively reduced UHI surface temperature. However, from a mitigation and technological standpoint, there is low feasibility of tripling albedo in the foreseeable future. Increased vegetation seems to be a more likely choice for mitigating surface temperature.     

The nature and dimensions of regional and local gold-related hydrothermal alteration in tholeiitic metabasalts in the Norseman goldfields: the missing link in a crustal continuum of gold deposits?

The Archaean lode-gold deposits at Norseman, Western Australia, consist of auriferous quartz veins in dextral-reverse ductile-brittle shear zones within tholeiitic metabasalts of upper-greenschist to amphibolite facies metamorphic grade. Three types of deposits (Northern, Central, Southern) are delineated on the basis of their spatial distribution, veining style, alteration mineraloty and metamorphic grade of host rocks. Northern deposits, hosted in upper-greenschist to lower-amphibolite facies rocks, comprise massive to laminated quartz veins with selvedges of quartz-chlorite-calcite-biotite-plagioclase assemblages. Central deposits, hosted in lower-amphibolite facies rocks, consist of laminated to massive quartz veins with selvedges of quartz-actinolite-biotite-plagioclasecalcite assemblages. Southern deposits, hosted in middleamphibolite facies metabasalts, consist of banded quartz-diopside-calcite-microcline-zoisite veins. All deposits exhibit variable ductile deformation of veins and contiguous alteration haloes, consistent with a syn-deformational genesis at high temperatures. From Northern to Southern deposits, the alteration assemblages are indicative of higher temperatures of formation, and there are progressively greater degrees of dynamically recovered textures in alteration and gangue minerals. These observations imply that a thermal variation of gold-related hydrothermal alteration exists within the Norseman Terrane over a distance of 40 km, with T_Northern<T_Central<T_Southern This thermal zonation is corroborated by T−X_{CO 2} phase relations between vein selvedge assemblages, which signify formation temperatures of approximately 420°–475°C, 470°–495°C and >500°C for Northern, Central and Southern deposits, respectively. The sum of structural, petrographic and mineral chemistry data indicates that the alteration assemblages formed in high-temperature, open hydrothermal systems and have not been subsequently metamorphosed. The thermal differences between the deposit groups may reflect (1) a temperature gradient, at relatively constant P, corresponding to the proximity of the deposits to regional granitoid complexes, or (2) formation of the deposits at progressively deeper crustal levels from north to south. In either case the deposits represent a continuum of gold deposition from upper-greenschist to amphibolite facies, now exposed in an oblique section through the Archaean crust at Norseman.     

Rank statistical analysis of nickel sulphide resources of the Norseman-Wiluna Greenstone Belt,Western Australia

Estimating the undiscovered mineral resources of a terrane is a challenging, yet essential, task in mineral exploration. We apply Zipf’s law rank statistical analysis to estimate the undiscovered nickel sulphide resources in the Norseman-Wiluna Greenstone Belt, Western Australia. The analysis suggests that about 3.0 to 10.0 Mt of nickel sulphide resources are yet to be discovered in this belt, compared to the currently known total nickel sulphide endowment of 10.8 Mt. This undiscovered nickel sulphide endowment is likely to be hosted by incompletely delineated deposits and undiscovered deposits in less explored komatiites in the belt. Using the more detailed data subset of the Kambalda domain, this study manipulates Zipf’s law to estimate the sizes of undiscovered deposits, in addition to the domain’s total nickel sulphide endowment estimate. Importantly, regression analysis shows that the gradient of the line of best fit through the logarithmic rank-size plot for the detailed Kambalda data subset is −1. This gradient, which is the key Zipf’s law constant k, has the value of −0.92 for the Norseman-Wiluna Greenstone Belt which is collectively less mature than the Kambalda domain. This result corroborates the use of k = −1 in Zipf’s law predictive analyses of mineral resources for deposit populations for which the value of k = −1 has not yet been attained due to exploration immaturity.     

Hydrocarbon- and ore-bearing basinal fluids: a possible link between gold mineralization and hydrocarbon accumulation in the Youjiang basin,South China

The Youjiang basin, which flanks the southwest edge of the Yangtze craton in South China, contains many Carlin-type gold deposits and abundant paleo-oil reservoirs. The gold deposits and paleo-oil reservoirs are restricted to the same tectonic units, commonly at the basinal margins and within the intrabasinal isolated platforms and/or bioherms. The gold deposits are hosted by Permian to Triassic carbonate and siliciclastic rocks that typically contain high contents of organic carbon. Paragenetic relationships indicate that most of the deposits exhibit an early stage of barren quartz ± pyrite (stage I), a main stage of auriferous quartz + arsenian pyrite + arsenopyrite + marcasite (stage II), and a late stage of quartz + calcite + realgar ± orpiment ± native arsenic ± stibnite ± cinnabar ± dolomite (stage III). Bitumen in the gold deposits is commonly present as a migrated hydrocarbon product in mineralized host rocks, particularly close to high grade ores, but is absent in barren sedimentary rocks. Bitumen dispersed in the mineralized rocks is closely associated and/or intergrown with the main stage jasperoidal quartz, arsenian pyrite, and arsenopyrite. Bitumen occurring in hydrothermal veins and veinlets is paragenetically associated with stages II and III mineral assemblages. These observations suggest an intimate relationship between bitumen precipitation and gold mineralization. In the paleo-petroleum reservoirs that typically occur in Permian reef limestones, bitumen is most commonly observed in open spaces, either alone or associated with calcite. Where bitumen occurs with calcite, it is typically concentrated along pore/vein centers as well as along the wall of pores and fractures, indicating approximately coeval precipitation. In the gold deposits, aqueous fluid inclusions are dominant in the early stage barren quartz veins (stage I), with a homogenization temperature range typically of 230°C to 270°C and a salinity range of 2.6 to 7.2 wt% NaCl eq. Fluid inclusions in the main and late-stage quartz and calcite are dominated by aqueous inclusions as well as hydrocarbon- and CO₂-rich inclusions. The presence of abundant hydrocarbon fluid inclusions in the gold deposits provides evidence that at least during main periods of the hydrothermal activity responsible for gold mineralization, the ore fluids consisted of an aqueous solution and an immiscible hydrocarbon phase. Aqueous inclusions in the main stage quartz associated with gold mineralization (stage II) typically have a homogenization temperature range of 200–230°C and a modal salinity around 5.3 wt% NaCl eq. Homogenization temperatures and salinities of aqueous inclusions in the late-stage drusy quartz and calcite (stage III) typically range from 120°C to 160°C and from 2.0 to 5.6 wt% NaCl eq., respectively. In the paleo-oil reservoirs, aqueous fluid inclusions with an average homogenization temperature of 80°C are dominant in early diagenetic calcite. Fluid inclusions in late diagenetic pore- and fissure-filling calcite associated with bitumen are dominated by liquid C₂H₆, vapor CH₄, CH₄–H₂O, and aqueous inclusions, with a typical homogenization temperature range of 90°C to 180°C and a salinity range of 2–8 wt% NaCl eq. It is suggested that the hydrocarbons may have been trapped at relatively low temperatures, while the formation of gold deposits could have occurred under a wider and higher range of temperatures. The timing of gold mineralization in the Youjiang basin is still in dispute and a wide range of ages has been reported for individual deposits. Among the limited isotopic data, the Rb–Sr date of 206 ± 12 Ma for Au-bearing hydrothermal sericite at Jinya as well as the Re–Os date of 193 ± 13 Ma on auriferous arsenian pyrite and ⁴⁰Ar/³⁹Ar date of 194.6 ± 2 Ma on vein-filling sericite at Lannigou may provide the most reliable age constraints on gold mineralization. This age range is comparable with the estimated petroleum charging age range of 238–185 Ma and the Sm–Nd date of 182 ± 21 Ma for the pore- and fissure-filling calcite associated with bitumen at the Shitouzhai paleo-oil reservoir, corresponding to the late Indosinian to early Yanshanian orogenies in South China. The close association of Carlin-type gold deposits and paleo-oil reservoirs, the paragenetic coexistence of bitumens with ore-stage minerals, the presence of abundant hydrocarbons in the ore fluids, and the temporal coincidence of gold mineralization and hydrocarbon accumulation all support a coeval model in which the gold originated, migrated, and precipitated along with the hydrocarbons in an immiscible, gold- and hydrocarbon-bearing, basinal fluid system.     

Gold ore-forming fluids of the Tanami region, Northern Australia

Fluid inclusion studies have been carried out on major gold deposits and prospects in the Tanami region to determine the compositions of the associated fluids and the processes responsible for gold mineralization. Pre-ore, milky quartz veins contain only two-phase aqueous inclusions with salinities ≤19 wt% NaCl eq. and homogenization temperatures that range from 110 to 410°C. In contrast, the ore-bearing veins typically contain low to moderate salinity (<14 wt% NaCl eq.), H₂O + CO₂ ± CH₄ ± N₂-bearing fluids. The CO₂-bearing inclusions coexist with two-phase aqueous inclusions that exhibit a wider range of salinities (≤21 wt% NaCl eq.). Post-ore quartz and carbonate veins contain mainly two-phase aqueous inclusions, with a last generation of aqueous inclusions being very CaCl₂-rich. Salinities range from 7 to 33 wt% NaCl eq. and homogenization temperatures vary from 62 to 312°C. Gold deposits in the Tanami region are hosted by carbonaceous or iron-rich sedimentary rocks and/or mafic rocks. They formed over a range of depths at temperatures from 200 to 430°C. The Groundrush deposit formed at the greatest temperatures and depths (260–430°C and ≤11 km), whereas deposits in the Tanami goldfield formed at the lowest temperatures (≥200°C) and at the shallowest depths (1.5–5.6 km). There is also evidence in the Tanami goldfield for late-stage isothermal mixing with higher salinity (≤21 wt% NaCl eq.) fluids at temperatures between 100 and 200°C. Other deposits (e.g., The Granites, Callie, and Coyote) formed at intermediate depths and at temperatures ranging from 240 to 360°C. All ore fluids contained CO₂ ± N₂ ± CH₄, with the more deeply formed deposits being enriched in CH₄ and higher level deposits being enriched in CO₂. Fluids from deposits hosted mainly by sedimentary rocks generally contained appreciable quantities of N₂. The one exception is the Tanami goldfield, where the quartz veins were dominated by aqueous inclusions with rare CO₂-bearing inclusions. Calculated δ ¹⁸O values for the ore fluids range from 3.8 to 8.5‰ and the corresponding δD values range from −89 to −37‰. Measured δ ¹³C values from CO₂ extracted from fluid inclusions ranged from −5.1 to −8.4‰. These data indicate a magmatic or mixed magmatic/metamorphic source for the ore fluids in the Tanami region. Interpretation of the fluid inclusion, alteration, and structural data suggests that mineralization may have occurred via a number of processes. Gold occurs in veins associated with brittle fracturing and other dilational structures, but in the larger deposits, there is also an association with iron-rich rocks or carbonaceous sediments, suggesting that both structural and chemical controls are important. The major mineralization process appears to be boiling/effervescence of a gas-rich fluid, which leads to partitioning of H₂S into the vapor phase resulting in gold precipitation. However, some deposits also show evidence of desulfidation by fluid–rock interaction and/or reduction of the ore-fluid by fluid mixing. These latter processes are generally more prevalent in the higher crustal-level deposits.     

Paleontological,mineralogical and chemical studies of syngenetic and epigenetic Pb–Zn–Ba–P mineralizations at the stratotype of the K/P boundary (El Kef area,Tunisia)

The El Kef area, Tunisia, is host of the official stratotype of the K/P boundary and of a complex metallic and non-metallic mineralization at Djebel Sekarna, encompassing syn(dia)genetic shale- and carbonate-hosted Zn–P and epigenetic Pb–Zn–Ba ore mineralizations. Micropaleontological, geological, mineralogical, and chemical studies (major and minor elements, C- and O-isotopes) of Upper Santonian to Lower Eocene calcareous-siliciclastic sediments resulted in a subdivision of this mineralization into eight mineralizing stages. Stages 1 and 2 (late Cretaceous–early Paleogene) are representative of syn(diagenetic) shale- and carbonate-hosted sulfidic and siliceous (Fe)–Zn–P mineralization deposited in shallow marine to slightly brackish sediments. Stages 3–5 (early Eocene respectively—pre- and post-Nummulites involutus-exilis zones) are representatives of epigenetic sulfidic and sulfatic (Fe)–Zn–Pb–Ba mineralizations at temperatures as high as 170/200°C and stages 6 and 7 (early Eocene respectively—post-Alveolina oblonga zone) cover the non-sulfidic Zn–(Pb) mineralization at temperatures as high as 60°C which is transitional from hypogene into supergene mineralization (“epithermal calamine deposits”). Stage 8 represents alteration of the pre-existing mineral assemblages in course of the Holocene weathering. The Cretaceous through Paleogene aquatic system is characterized by a poisoning of the sea with base metals, mainly Zn, and the atmosphere was chocked with clouds of fine-grained volcanic ejecta. Both processes contributed to the build-up of Zn–(Pb) deposits and vast, but uneconomic bentonitic clay deposits around the K/P boundary. Ore mineralization in the El Kef area is a multiple-phase process which reached its climax during the early Eocene as indicated by the large foram zones. These inorganic concentration processes resulting in the formation of mineral deposits had obviously also a negative effect on the long-term course of regional Earth’s biological history during the late Cretaceous–early Eocene period with lethal consequences for some species. The joint studies of inorganic and organic data reveal that such extraordinary metallogenetic processes close to the K/P boundary in its stratotype area in Tunisia were “strictly terrestrial”.     

Reconstruction of the differentiated long-term exhumation history of Fuerteventura, Canary Islands, Spain, through fission-track and (U-Th–Sm)/He data

Miocene Intrusives and Lower Cretaceous siliciclastic sedimentary rocks from the Basal Complex in western-Fuerteventura were analyzed with low-temperature thermochronometric methods such as fission-track, and (U–Th–Sm)/He dating, in order to reveal the evolution of the island’s exhumation history. The obtained thermochronometric data yields a very slow rate of cooling in the order of 1.5–3°C/Myr from ~50 to 20 Ma for the Early Cretaceous siliciclastic rocks. These sedimentary units have never been heated significantly above 240°C after deposition and still record the submarine onset of the island’s formation in the Eocene. Intrusive bodies associated with the early Miocene magmatic activity of the central volcanic complex of the island show rapid initial cooling rates of 50–70°C/Myr from ~20 to 14 Ma. Contemporaneous with the intrusions the cooling rate of the Cretaceous sedimentary units increased to 25–35°C/Myr and it is inferred that this increase is associated with enhanced uplift and erosion of the Central Volcanic Complex. After ~14 Ma rates slowed down to 3–6°C/Myr. Palaeosols overlying the sedimentary units are themselves covered by Pliocene basalt flows and reveal that the sedimentary rocks reached the surface before ~5 Ma. The thermochronometric data obtained in this study for central Fuerteventura is difficult to reconcile with the cooling history derived from previously obtained fission-track and K–Ar data from the north-western part of the island. This inconsistency is likely to indicate that the exhumation history of Fuerteventura is more complex and regionally subdivided than previously believed.