铜陵天马山硫金矿床地质特征及成因探讨

天马山硫金矿床的矿体分为层状矿体、接触带矿体和穿层矿体。层状矿体和穿层矿体受石炭系黄龙组、船山组地层层位和层间断裂控制。接触带矿体受接触带控制 ,具矽卡岩型矿体典型特征。矿床的形成受地层、构造及岩浆岩控制 ,矿床成因为层控矽卡岩型硫金矿床     

湖北钟祥莲花山矿区磷矿体地质特征

莲花山矿区存在15个磷矿体,其中,工业矿体6个,低品位矿体6个,小规模矿体3个。工业矿体以大型为主,低品位矿体以中型为主。矿体形态呈褶曲、向型和单斜层状。工业矿体产于Ph_1和Ph_3中,低品位矿体主要产于Ph_3中,小规模矿体产于Ph_2中。Ph_3低品位矿体与工业矿体密切共生。Ph_1层位成矿好于Ph_3,F98断裂以北成矿好于以南。矿床为热水生物化学沉积成因。本区找矿层位主要为Ph_1,次为Ph_3。     

山东莱芜接触交代—热液铁矿矿体形态研究

在对莱芜接触交代铁矿地质特征研究中发现以往地质报告在矿体连接上存在混乱,使矿体形态失真。为便于今后矿体对比和成矿规律的认识,提出了矿体形态分类原则,并以三分法对矿体形态进行分类。指出矿体产状变化是矿体膨胀收缩、分支复合和尖灭再现的结果。根据矿体形态分类指出了找矿方向。不同的矿体形态反映不同的控矿构造,反映不同的矿体规模,反映不同的成矿岩体形态产状。单斜缓倾矿体的成矿岩体是岩床,控矿较小;陡倾矿体和背向斜矿体的成矿岩体是岩盖,控矿较大。     

固体矿产勘查中矿体外推问题探讨

固体矿产勘查储量计算过程中,矿体圈连时不可避免地会涉及到矿体外推的地质问题。其中,矿体外推的介质为储量计算剖面图和矿体中段水平投影图,矿体外推方式根据外推介质的不同分为沿走向外推和沿倾向外推。此外,根据有无探矿工程的限制可分为有限外推和无限外推,矿体外推起点为有探矿工程控制的矿体边缘样品工程,矿体外推长度分为"尖灭1/2工程间距、尖推=1/2工程间距、平推=1/4工程间距",外推矿体任何部位厚度必须小于矿体外推起点处矿体厚度。矿体外推与资源/储量分类关系密切,一般情况下外推矿体的资源量类型应为333。     

胶西北地区“焦家式”典型金矿床深部与浅部矿体特征对比研究

以近几年来胶西北地区几个大型以上规模“焦家式”典型金矿床的深部勘查资料为基础,从矿体形态、规模及产状变化、蚀变及矿化,主要有益组分金、银含量及变化、金矿物特征等方面对矿床深部和浅部矿体特征进行了综合分析对比研究。研究结果显示,矿床深部矿体规模变大,产状变缓,大部分矿体无明显的侧伏,矿体形态由复杂到简单;矿体主要有益组分金、银含量在矿体浅部的中上部相对较高,向下逐渐变贫;深部矿体总体品位较浅部低,较均匀,变化较小;在主矿体之下远离主裂面分布在黄铁绢英岩化花岗岩带内的矿体,金品位明显高于主矿体,品位变化较大;由浅而深金银品位比值有逐渐增大趋势。     

河南崤山金矿半宽金矿区1号矿脉微量元素统计特征

研究认为,Au、Ag、Cu、Pb、As和Sb是崤山金矿及外围异常检查、深部预测和找矿评价的指示元素。Au、Ag、As和Sb 4个元素是1号矿脉浅部矿体的特征指示元素。矿体浅部矿化样品、矿体中部矿化样品和矿体深部矿化样品的归类十分明确,可用作判断地表矿体的剥蚀程度及地表矿体向下延深情况。     

广西大福楼锡多金属矿床流体包裹体特征

大福楼锡多金属矿床是大厂锡矿田东矿带一个主要的锡石硫化物矿床,位于丹池大背斜的东翼,矿床主要由3个工业矿体组成:0号矿体、21号矿体和22号矿体。其中,0号矿体为陡倾斜切层大脉状矿体,长1200余米,深500余米,厚2m左右;21号和22号矿体为产于下泥盆统泥质页岩中的似层状矿矿体,长600～1100m,宽200～400m,厚1.5～2.2m。本矿床主要工业矿物有:锡石、磁黄铁矿、黄铁矿、毒砂、铁闪锌     

下庄铀矿田竹山下矿床探采对比新认识

利用矿床井下采场地质编录和室内综合研究方法,对下庄铀矿田竹山下矿床代表性矿体开展探采对比分析。通过编制矿体水平中段探采对比图、矿体横剖面探采对比图、矿体纵投影探采对比图等系列图件,分析代表性矿体形态、厚度、品位、面积和体积在地质勘查和实采阶段的变化差异。查明矿体资源量变化的原因,总结影响资源量负变的因素。     

中深成系脉型金矿矿体分段富集律及成生机制--以玲珑金矿田九曲矿段为例

通过对玲珑金矿田九曲矿段矿体地质的研究,阐述了中深成系脉型金矿的矿体分段富集,包括矿脉中矿体的产出特征和矿体的分布规律,并进一步探讨了矿体分段富集律的成生机制,指出矿体分段富集律的形成是受内因和外因（温度、流体动力学条件、构造应力场等）制约的。     

金川铜镍矿床58号矿体亲铜和亲铁元素特征及其地质意义

通过对金川铜镍硫化物矿床中58号矿体地质特征、亲铜和亲铁元素地球化学特征等方面的研究,发现其具有不同于24号矿体、1号矿体和2号矿体的地质和地球化学特征。58号矿体产于Ⅲ号岩体上盘围岩中,矿体总体走向为NNE,倾向NW。与金川矿床其他几个矿体比较,该矿体具较高的Cu、Ni和PGE含量。研究独立的58号矿体对全面理解整个金川超基性岩体的成矿规律,指导今后找矿工作具有重要意义。笔者认为58号矿体的硫化物是从PGE微弱亏损的苦橄质岩浆中熔离出来的,其硫化物熔体具有不同的分异演化过程。     

Wavelength-dispersive X-ray fluorescence spectrometric determination of Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites

Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.     

Viscous, cohesive, non-Newtonian, depositing, radial slurry flow

Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.     

Bellechester,Minnesota, USA,lagoon collapses

Bellechester, Minnesota, is a small community of approximately 155 residents located on the county line between Goodhue and Wabasha counties in southeast Minnesota's karst region. Bellechester is served by a 21-year-old wastewater treatment facility (WWTF) consisting of three waste-stabilization ponds. On 28 April 1992 six sinkholes were discovered to have drained cell 2 of the WWTF resulting in the loss of approximately 8.7×10⁶ 1 of partially treated effluent and about 600 m³ of soil into previously undetected subsurface voids of unknown dimensions. In the week following the collapse, approximately 200 water wells located within a 5-km radius of the WWTF were sampled in an after-the-fact, emergency sampling program. Twelve samples with elevated fecal coliform levels, 18 samples with nitrate-nitrogen greater than the 10 mg/1 standard, and no samples with elevated chlorides were found. However, the elevated levels could not be unambiguously attributed to the WWTF collapse. This is the third WWTF to fail by sinkhole collapse in southeast Minnesota since 1974. All three collapsed lagoons have been located in similar geomorphic and stratigraphic settings. However, at least two lagoons have collapsed in the adjacent area in northeast Iowa, and these lagoons are located at different stratigraphic positions. Twenty-two WWTFs constructed in southeast Minnesota's karst region in the last 25 years have been identified as subject to potential sinkhole collapse. An unknown but significant number of manure storage lagoons, flood control structures, etc., have also been constructed in the karst region and are at risk. Public agencies are beginning to develop plans to deal with the risk associated with existing and future waste lagoons in this environment. The critical hydrogeologic parameters that can be used to prioritize the risk of collapse at existing facilities include: (1) the lithology of the first bedrock beneath each lagoon, (2) the thickness of surficial materials between the lagoon and the bedrock surface, (3) the presence and construction of liners (seepage rate), and (4) the proximity to existing sinkholes.     

滇东南花岗岩与锡、银、铜、铅、锌多金属矿床的成因关系

滇东南锡、银、铅、锌多金属矿床主要分布在个旧、白牛厂、都龙3个矿区,而滇东南较大的3个花岗岩体又分别出露在3个矿区或附近.花岗岩体均形成于燕山晚期,岩石化学、矿物成分相似,富含锡、银、铅、锌、钨、铜等成矿元素.矿床主金属元素组合与岩体之间的距离由远而近出现由锡、钨、(铍、铌、钽)→锡、钨、(铁)、铜、铟→锡、铅、锌、银、铟、(锑)有规律的变化.花岗岩浆是成矿物质来源和成矿热源.岩浆侵入初期使上覆地层隆起产生背斜(凹陷部位成向斜);同时使地层产生一系列裂隙、压性断层或层间断裂;岩浆侵入晚期,这些断层再次活动,表现为张性,岩浆产生的含矿热液沿由其活动所造成的断裂迁移、充填、交代、沉淀而形成矿床.     

硅酸盐类样品中硅、铁、铝、钛、锰、钙、镁、钾、钠和磷的x射线荧光光谱测定

本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。     

Slope hummock development, Fosheim Peninsula, Ellesmere Island, Nunavut, Canada

Slope hummocks, a type of nonsorted patterned ground, are composed of stratified, organic, silty sand, and develop through the interaction of niveo-eolian deposition, solifluction, slopewash, and vegetation growth. Fields of hummocks show consistent patterns: forms on convex slopes increase in height downslope until the channel is reached, whereas those on convexo-concave slopes increase on the upper convexity but are buried by niveo-eolian deposition downslope of the snowbank remnant. These trends can be reproduced using a simple numerical model based on measured slope and snow depth profiles, sediment concentrations in the snow and solifluction rates. The model indicates that hummocks transit slopes of 20-40 m in about 2-4 ka, a time-frame that is plausible given site emergence, measured rates of solifluction, and published dates for organic horizons within hummocks on northern Ellesmere Island. Sensitivity analyses show that long-term effect of climate warming on hummock heights may differ depending on whether it is accompanied by precipitation increase or decrease. The required combination of two-sided freezing to promote plug-like movement, incomplete vegetation cover and thin snow that enable eolian erosion during winter and spring, and vegetation growth in snow-bed sites to stabilize niveo-eolian deposits may explain why these forms are important regionally but apparently are not present throughout the Arctic.     

Mass Fractions of S,Cu, Se,Mo, Ag,Cd, In,Te, Ba,Sm, W,Tl and Bi in Geological Reference Materials and Selected Carbonaceous Chondrites Determined by Isotope Dilution ICP‐MS

Mass fractions of S, Cu, Se, Mo, Ag, Cd, In, Te, Ba, Sm, W and Tl were determined by isotope dilution sector field ICP‐MS in the same sample aliquot of reference materials using HF‐HNO₃ digestion in PFA beakers in pressure bombs and glassy carbon vessels in a high‐pressure asher (HPA‐S) for comparison. Additionally, Bi was determined by internal standardisation relative to Tl. Because isobaric and oxide interferences pose problems for many of these elements, efficient chromatographic separation methods in combination with an Aridus desolvator were employed to minimise interference effects. Repeated digestion and measurement of geological reference materials (BHVO‐1, BHVO‐2, SCo‐1, MAG‐1, MRG‐1 and UB‐N) gave results with < 5% relative intermediate precision (1s) for most elements, except Bi. Replicates of NIST SRM 612 glass digested on a hot plate were analysed by the same methods, and the results agree with reference values mostly within 2% relative deviation. Data for the carbonaceous chondrites Allende, Murchison, Orgueil and Ivuna are also reported. Digestion in a HPA‐S was as efficient as in pressure bombs, but some elements displayed higher blank levels following HPA‐S treatment. Pressure bomb digestion yielded precise data for volatile S, Se and Te, but may result in high blanks for W.     

电感耦合等离子体发射光谱法同时测定卤水中锂钠钾钙镁硼硫氯

建立了电感耦合等离子体发射光谱法(ICP-AES)同时测定碳酸盐型、硫酸盐型、氯化物型三种类型卤水中Li、Na、K、Ca、Mg、B、S、Cl等高低含量元素的分析方法。选择仪器最佳的工作条件为射频功率1400W,炬管位置位于-3,载气流量0.60 L/min。确定了各元素测定谱线,使用ICP-AES的双向观测模式、轴向观测模式测定Li、Ca、B、S、Cl以及低含量的K、Mg,径向观测模式测定高含量的Na、K、Mg,可确保卤水中不同含量的元素同时检出。Li、Na、K、Ca、Mg、B、S的检测下限为0.07～3.00 mg/L,Cl的测定下限为165mg/L。方法精密度(RSD,n=10)均小于5%,回收率为92.4%～109.7%。其中Na、K、Mg、S、Cl测定结果与传统方法测定结果基本吻合。     

Regional distribution of Al,B, Ba,Ca, K,La, Mg,Mn, Na,P, Rb,Si, Sr,Th, U and Y in terrestrial moss within a 188,000 km2 area of the central Barents region: influence of geology,seaspray and human activity

Five hundred and ninety-eight samples of terrestrial moss (Hylocomium splendens and Pleurozium schreberi) collected from a 188,000 km² area of the central Barents region (NE Norway, N Finland, NW Russia) were analysed by ICP-AES and ICP-MS. Analytical results for Al, B, Ba, Ca, K, La, Mg, Mn, Na, P, Rb, Si, Sr, Th, U and Y concentrations are reported here. Graphical methods of data analysis, such as geochemical maps, cumulative frequency diagrams, boxplots and scatterplots, are used to interpret the origin of the patterns for these elements. None of the elements reported here are emitted in significant amounts from the smelting industry on the Kola Peninsula. Despite the conventional view that moss chemistry reflects atmospheric element input, the nature of the underlying mineral substrate (regolith or bedrock) is found to have a considerable influence on moss composition for several elements. This influence of the chemistry of the mineral substrate can take place in a variety of ways. (1) It can be completely natural, reflecting the ability of higher plants to take up elements from deep soil horizons and shed them with litterfall onto the surface. (2) It can result from naturally increased soil dust input where vegetation is scarce due to harsh climatic conditions for instance. Alternatively, substrate influence can be enhanced by human activity, such as open-cast mining, creation of ‘technogenic deserts’, or handling, transport and storage of ore and ore products, all of which magnify the natural elemental flux from bedrock to ground vegetation. Seaspray is another natural process affecting moss composition in the area (Mg, Na), and this is most visible in the Norwegian part of the study area. Presence or absence of some plant species, e.g., lichens, seems to influence moss chemistry. This is shown by the low concentrations of B or K in moss on the Finnish and Norwegian side of the (fenced) border with Russia, contrasting with high concentrations on the other side (intensive reindeer husbandry west of the border has selectively depleted the lichen population).