Metamorphic differentiation at Einasleigh,Northern Queensland

Biotite‐muscovite‐garnet gneisses at Einasleigh contain quartz‐feldspar veins composed of the same minerals as found in the enclosing rock. The vein‐gneiss boundaries are commonly irregular and on a microscopic scale, gradational.

Certain amphibolite layers contain quartz‐feldspar veins composed of the same minerals as found in the amphibolite. Hornblende‐rich extraction zones surround these veins, and material balance calculations show that all or nearly all of the vein‐forming matter was locally derived. Variation in the abundance of hornblende and plagioclase in the amphibolite as a function of distance from a quartz‐feldspar vein can be expressed by error‐function curves, thus suggesting that the mineral‐segregation process was diffusion‐controlled. During the mineral rearrangement, the Na and Ca contents of plagioclase have evidently remained unchanged, but the vein hornblende has become slightly richer in Fe+3, Mg, and Ca, and poorer in Si and Al relative to hornblende in the adjacent amphibolite.

A certain biotite‐plagioclase rock forms layers and boudins in the gneisses and contains pegmatite veins composed of the same minerals as found in the host rock. The plagioclase in these veins is more sodic than that in the host rock while the biotite contains slightly more Ti and Fe+² and less Si and Mg than the biotite of the enclosing rock.

The data indicate that significant portions of the vein‐forming matter at Einasleigh were locally derived. The chemistry of some minerals has changed slightly during the segregation process, resulting possibly from different diffusion rates for the different mineral‐forming constituents.     

Does continental crust transform during eclogite facies metamorphism?

Eclogites within exhumed continental collision zones indicate regional burial to depths of at least 60 km, and often more than 100 km in the coesite‐stable, ultra‐high pressure (UHP) eclogite facies. Garnet, omphacitic pyroxene, high‐Si mica, kyanite ± coesite should grow at the expense of low‐P minerals in most felsic compositions, if equilibrium obtained at these conditions. The quartzofeldspathic rocks that comprise the bulk of eclogite facies terranes, however, contain mainly amphibolite facies, plagioclase‐bearing assemblages. To what extent these lower‐P minerals persisted metastably during (U)HP metamorphism, or whether they grew afterwards, reflects closely upon crustal parameters such as density, strength and seismic character. The Nordfjord area in western Norway offers a detailed view into a large crustal section that was subducted into the eclogite facies. The degree of transformation in typical pelite, paragneiss, granitic and granodioritic gneiss was assessed by modelling the equilibrium assemblage, comparing it with existing parageneses in these rocks and using U/Th–Pb zircon geochronology from laser ablation ICPMS to establish the history of mineral growth. U–Pb dates define a period of zircon recrystallization and new growth accompanying burial and metamorphism lasting from 430 to 400 Ma. Eclogite facies mafic rock (~2 vol.% of crust) is the most transformed composition and records the ambient peak conditions. Rare garnet‐bearing pelitic rocks (<10 vol.% of crust) preserve a mostly prograde mineral evolution to near‐peak conditions; REE concentrations in zircon indicate that garnet was present after 425 Ma and feldspar broke down after 410 Ma. Felsic gneiss – by far the most abundant rock type – is dominated by quartz + biotite + feldspar, but minor zoisite/epidote, phengitic white mica, garnet and rutile point to a prograde HP overprint. Relict textures indicate that much of the microstructural framework of plagioclase, K‐feldspar, and perhaps biotite, persisted through at least 25 Ma of burial, and ultimately UHP metamorphism. The signature reaction of the eclogite facies in felsic rocks – jadeite/omphacite growth from plagioclase – cannot be deduced from the presence of pyroxene or its breakdown products. We conclude that prograde dehydration in orthogneiss leads to fluid absent conditions, impeding equilibration beyond ~high‐P amphibolite facies.     

Geology of the mineralized zone of the Wanapitei complex,Grenville Front,Ontario

The Wanapitei Complex (6 km×2.5 km), lying 0.4 km southeast of the Grenville Front, consists of a northwestern zone of gabbro and folded injection breccia and a southeastern layer of intensely folded hornblendeplagioclase gneiss. Disseminated Ni-Cu sulphides are unevenly distributed in a zone between the injection breccia and the folded gneiss.Rocks of the mineralized zone occur in southeastern and northeastern areas. The former area consists of hornblende norite, the major host rock of the sulphides, and olivine norite. Steeply-dipping cross-bedded primary layers and chemical trends indicate the top faces southeast. In the latter area olivine norite, hornblende norite, and hornblende gabbro grade eastward into recrystallized rocks and breccia. The olivine norites are characterized by corona reaction rims. Reactions are: olivine+plagioclase bronzite+diopside-spinel; olivine+pyroxene bronzite; and pyroxene+plagioclase diopside-spinel. Molecular proportion ratio variation diagrams suggest that rocks evolved from a common parent magma that underwent fractionation dominated by olivine and plagioclase. Sulphide mineralization (pyrrhotite, chalcopyrite, pentlandite, pyrite) is interstitial to the silicates and appears to be of primary magmatic origin.Northeasterly-trending shear zones, felsic dikes, and matic dikes are metamorphosed to the same degree as the rocks they cut (amphibolite facies). The sequence of events for the mineralized zone are: intrusion deep in the crust; tilting; brecciation; shearing; felsic and mafic dike emplacement; metamorphism; and injection of granite pegmatite dikes.Deceased (8-16-1986)     

Fluid generation and evolution during exhumation of deeply subducted UHP continental crust: Petrogenesis of composite granite–quartz veins in the Sulu belt,China

Composite granite–quartz veins occur in retrogressed ultrahigh pressure (UHP) eclogite enclosed in gneiss at General's Hill in the central Sulu belt, eastern China. The granite in the veins has a high‐pressure (HP) mineral assemblage of dominantly quartz+phengite+allanite/epidote+garnet that yields pressures of 2.5–2.1 GPa (Si‐in‐phengite barometry) and temperatures of 850–780°C (Ti‐in‐zircon thermometry) at 2.5 GPa (~20°C lower at 2.1 GPa). Zircon overgrowths on inherited cores and new grains of zircon from both components of the composite veins crystallized at c. 221 Ma. This age overlaps the timing of HP retrograde recrystallization dated at 225–215 Ma from multiple localities in the Sulu belt, consistent with the HP conditions retrieved from the granite. The ε_Hf(t) values of new zircon from both components of the composite veins and the Sr–Nd isotope compositions of the granite consistently lie between values for gneiss and eclogite, whereas δ¹⁸O values of new zircon are similar in the veins and the crustal rocks. These data are consistent with zircon growth from a blended fluid generated internally within the gneiss and the eclogite, without any ingress of fluid from an external source. However, at the peak metamorphic pressure, which could have reached 7 GPa, the rocks were likely fluid absent. During initial exhumation under UHP conditions, exsolution of H₂O from nominally anhydrous minerals generated a grain boundary supercritical fluid in both gneiss and eclogite. As exhumation progressed, the volume of fluid increased allowing it to migrate by diffusing porous flow from grain boundaries into channels and drain from the dominant gneiss through the subordinate eclogite. This produced a blended fluid intermediate in its isotope composition between the two end‐members, as recorded by the composite veins. During exhumation from UHP (coesite) eclogite to HP (quartz) eclogite facies conditions, the supercritical fluid evolved by dissolution of the silicate mineral matrix, becoming increasingly solute‐rich, more ‘granitic’ and more viscous until it became trapped. As crystallization began by diffusive loss of H₂O to the host eclogite concomitant with ongoing exhumation of the crust, the trapped supercritical fluid intersected the solvus for the granite–H₂O system, allowing phase separation and formation of the composite granite–quartz veins. Subsequently, during the transition from HP eclogite to amphibolite facies conditions, minor phengite breakdown melting is recorded in both the granite and the gneiss by K‐feldspar+plagioclase+biotite aggregates located around phengite and by K‐feldspar veinlets along grain boundaries. Phase equilibria modelling of the granite indicates that this late‐stage melting records P–T conditions towards the end of the exhumation, with the subsolidus assemblage yielding 0.7–1.1 GPa at <670°C. Thus, the composite granite–quartz veins represent a rare example of a natural system recording how the fluid phase evolved during exhumation of continental crust. The successive availability of different fluid phases attending retrograde metamorphism from UHP eclogite to amphibolite facies conditions will affect the transport of trace elements through the continental crust and the role of these fluids as metasomatic agents interacting with the mantle wedge in the subduction channel.     

Polymetamorphism in the mainland Lewisian complex,NW Scotland – phase equilibria and geochronological constraints from the Cnoc an t’Sidhean suite

The metamorphic evolution of rocks cropping out near Stoer, within the Assynt terrane of the central region of the mainland Lewisian complex of NW Scotland, is investigated using phase equilibria modelling in the NCKFMASHTO and MnNCKFMASHTO model systems. The focus is on the Cnoc an t’Sidhean suite, garnet‐bearing biotite‐rich rocks (brown gneiss) with rare layers of white mica gneiss, which have been interpreted as sedimentary in origin. The results show that these rocks are polymetamorphic and experienced granulite facies peak metamorphism (Badcallian) followed by retrograde fluid‐driven metamorphism (Inverian) under amphibolite facies conditions. The brown gneisses are inferred to have contained an essentially anhydrous granulite facies peak metamorphic assemblage of garnet, quartz, plagioclase and ilmenite (±rutile, K‐feldspar and pyroxene) with biotite, hornblende, muscovite, chlorite and/or epidote as hydrous retrograde minerals. P–T constraints imposed by phase equilibria modelling imply conditions of 13–16 kbar at >900 °C for the Badcallian granulite facies metamorphic peak, consistent with the field evidence for partial melting in most lithologies. The white mica gneiss comprises a muscovite‐dominated matrix containing porphyroblasts of staurolite, corundum, kyanite and rare garnet. Previous studies have suggested that staurolite, corundum, kyanite and muscovite all grew at the granulite facies peak, with partial melting and melt loss producing a highly aluminous residue. However, at the inferred peak P–T conditions, staurolite and muscovite are not predicted to be stable, suggesting they are retrograde phases that grew during amphibolite facies retrograde metamorphism. The large proportion of mica suggests extensive H₂O‐rich fluid‐influx, consistent with the retrograde growth of hornblende, biotite, epidote and chlorite in the brown gneisses. P–T conditions of 5.0–6.5 kbar at 520–550 °C are derived for the Inverian event. In situ dating of zircon from samples of the white mica gneiss yield apparent ages that are difficult to interpret. However, the data are permissive of granulite facies (Badcallian) metamorphism having occurred at c. 2.7–2.8 Ga with subsequent fluid driven (Inverian) retrogression at c. 2.5–2.6 Ga, consistent with previous interpretations.     

Petrogenetic significance of orthopyroxene-free garnet + clinopyroxene + plagioclase ± quartz-bearing metabasites with respect to the amphibolite and granulite facies

Orthopyroxene‐free garnet + clinopyroxene + plagioclase ± quartz‐bearing mineral assemblages represent the paragenetic link between plagioclase‐free eclogite facies metabasites and orthopyroxene‐bearing granulite facies metabasites. Although these assemblages are most commonly developed under P–T conditions consistent with high pressure granulite facies, they sometimes occur at lower grade in the amphibolite facies. Thus, these assemblages are characteristic but not definitive of high pressure granulite facies. Compositional factors favouring their development at amphibolite grade include Fe‐rich mineral compositions, Ca‐rich garnet and plagioclase, and Ti‐poor hornblende. The generalized reaction that accounts for the prograde development of garnet + clinopyroxene + plagioclase ± quartz from a hornblende + plagioclase + quartz‐bearing (amphibolite) precursor is Hbl + Pl + Qtz=Grt + Cpx + liquid or vapour, depending on whether the reaction occurs above or below the solidus. There are significant discrepancies between experimental and natural constraints on the P–T conditions of orthopyroxene‐free garnet + clinopyroxene + plagioclase ± quartz‐bearing mineral assemblages and therefore on the P–T position of this reaction. Semi‐quantitative thermodynamic modelling of this reaction is hampered by the lack of a melt model and gives results that are only moderately successful in rationalizing the natural and experimental data.     

内蒙古锡林浩特地区中元古代锡林浩特岩群的厘定及其意义

通过大比例尺填图和剖面研究, 将内蒙古锡林浩特地区的"锡林郭勒杂岩"解体分为3大部分: 一套表壳岩、晚元古代基性-超基性侵入岩和早古生代酸性侵入岩.在此基础上根据变质岩的岩性组合和变形变质特点, 可将其中的表壳岩化分为4个岩性段: 黑云(石榴石)斜长片麻岩, 间夹多层条纹状斜长角闪岩, 在其顶部多见薄层含磁铁石英岩; 中粗粒黑云斜长片麻岩和细粒长英质片麻岩; 混合岩化条带状黑云(角闪)斜长片麻岩, 含石榴石黑云二长片麻岩夹条纹状斜长角闪岩组合; 夕线石黑云斜长片麻岩, 条纹状黑云斜长片麻岩, 间夹含石榴石黑云母石英片岩.通过对比区域内宝音图群、艾勒格庙组、白乃庙群等古老地块的岩石组合, 发现在原岩建造、变质级别、沉积环境等特征上均有区别, 应将这套表壳岩单独厘定为锡林浩特岩群, 它们组成了锡林郭勒微陆块前寒武变质基底岩系, 其地质特征的研究对锡林郭勒微陆块基底的形成和演化及华北板块与西伯利亚板块的构造关系演化有重要意义.      

High to ultrahigh temperature contact metamorphism and dry partial melting of the Tasiuyak paragneiss,Northern Labrador

Contact aureoles of the anorthositic to granitic plutons of the Mesoproterozoic Nain Plutonic Suite (NPS), Labrador, are particularly well developed in the Palaeoproterozoic granulite facies, metasedimentary, Tasiuyak gneiss. Granulite facies regional metamorphism (M_R), c. 1860 Ma, led to biotite dehydration melting of the paragneiss and melt migration, leaving behind biotite‐poor, garnet–sillimanite‐bearing quartzofeldspathic rocks. Subsequently, Tasiuyak gneiss within a c. 1320 Ma contact aureole of the NPS was statically subjected to lower pressure, but higher temperature conditions (M_C), leading to a second partial melting event, and the generation of complex mineral assemblages and microstructures, which were controlled to a large extent by the textures of the M_R assemblage. This control is clearly seen in scanning electron microscopic images of thin sections and is further supported by phase equilibria modelling. Samples collected within the contact aureole near Anaktalik Brook, west of Nain, Labrador, mainly consist of spinel–cordierite and orthopyroxene–cordierite (or plagioclase) pseudomorphs after M_R sillimanite and garnet, respectively, within a quartzofeldspathic matrix. In addition, some samples contain fine‐grained intergrowths of K‐feldspar–quartz–cordierite–orthopyroxene inferred to be pseudomorphs after osumulite. Microstructural evidence of the former melt includes (i) coarse‐grained K‐feldspar–quartz–cordierite–orthopyroxene domains that locally cut the rock fabric and are inferred to represent neosome; (ii) very fine‐ to medium‐grained cordierite–quartz intergrowths interpreted to have formed by a reaction involving dissolution of biotite and feldspar in melt; and (iii) fine‐scale interstitial pools or micro‐cracks filled by feldspar interpreted to have crystallized from melt. Ultrahigh temperature (UHT) conditions during contact metamorphism are supported by (i) solidus temperatures >900 °C estimated for all samples, coupled with extensive textural evidence for contact‐related partial melting; (ii) the inferred (former) presence of osumilite; and (iii) titanium‐in‐quartz thermometry indicating temperatures within error of 900 °C. The UHT environment in which these unusual textures and minerals were developed was likely a consequence of the superposition of more than one contact metamorphic event upon the already relatively anhydrous Tasiuyak gneiss.     

胶东海阳所堆积辉长岩的变质反应结构、石榴石形成及P—T演化

海阳所堆积辉长岩由橄长岩、橄榄辉长岩和辉长岩组成。在橄长岩和橄榄辉长岩中发育有典型的变质反应结构：主要为橄榄石与斜长石之间形成由斜方辉石、尖晶石、角闪石和石榴石等矿物组成的多期次次变边，并有三个不同世代变质矿物，早期Cpx＋Opx＋Spl，中期Amp，晚期Grt；期次是钛铁矿与斜长石之间形成石榴石次变边，相对比较简单，只有一个世代变质矿物，为Grt＋Amp＋Rut或Grt＋Rut岩中石榴石是通过斜长石与角闪石或斜长石与钛铁矿之间的变质反应形成的，虽为峰值变质作用的产物，但变质反应的期次及类型不同导致了所形成石榴石的温度和压力有所不同。堆积辉长岩形成演化的温压计算表明，堆积辉长岩在经过近等压降温的岩浆作用之后的变质作用早期，仍为近等压降温，而晚期则表现为近等温升压。这一特殊的P－T演化可能反映了堆积辉长冷侵位与深俯冲特征。     

Olivine‐bearing symplectites in fractured garnet from eclogite,Moldanubian Zone (Bohemian Massif) – a short‐lived,granulite facies event

Recent petrological studies on high‐pressure (HP)–ultrahigh‐pressure (UHP) metamorphic rocks in the Moldanubian Zone, mainly utilizing compositional zoning and solid phase inclusions in garnet from a variety of lithologies, have established a prograde history involving subduction and subsequent granulite facies metamorphism during the Variscan Orogeny. Two temporally separate metamorphic events are developed rather than a single P–T loop for the HP–UHP metamorphism and amphibolite–granulite facies overprint in the Moldanubian Zone. Here further evidence is presented that the granulite facies metamorphism occurred after the HP–UHP rocks had been exhumed to different levels of the middle or upper crust. A medium‐temperature eclogite that is part of a series of tectonic blocks and lenses within migmatites contains a well‐preserved eclogite facies assemblage with omphacite and prograde zoned garnet. Omphacite is partly replaced by a symplectite of diopside + plagioclase + amphibole. Garnet and omphacite equilibria and pseudosection calculations indicate that the HP metamorphism occurred at relatively low temperature conditions of ~600 °C at 2.0–2.2 GPa. The striking feature of the rocks is the presence of garnet porphyroblasts with veins filled by a granulite facies assemblage of olivine, spinel and Ca‐rich plagioclase. These minerals occur as a symplectite forming symmetric zones, a central zone rich in olivine that is separated from the host garnet by two marginal zones consisting of plagioclase with small amounts of spinel. Mineral textures in the veins show that they were first filled mostly by calcic amphibole, which was later transformed into granulite facies assemblages. The olivine‐spinel equilibria and pseudosection calculations indicate temperatures of ~850–900 °C at pressure below 0.7 GPa. The preservation of eclogite facies assemblages implies that the granulite facies overprint was a short‐lived process. The new results point to a geodynamic model where HP–UHP rocks are exhumed to amphibolite facies conditions with subsequent granulite facies heating by mantle‐derived magma in the middle and upper crust.     

Quartz‐in‐garnet and Ti‐in‐quartz thermobarometry: Methodology and first application to a quartzofeldspathic gneiss from eastern Papua New Guinea

Mineral inclusions are ubiquitous in metamorphic rocks and elastic models for host‐inclusion pairs have become frequently used tools for investigating pressure–temperature (P–T) conditions of mineral entrapment. Inclusions can retain remnant pressures () that are relatable to their entrapment P–T conditions using an isotropic elastic model and P–T–V equations of state for host and inclusion minerals. Elastic models are used to constrain P–T curves, known as isomekes, which represent the possible inclusion entrapment conditions. However, isomekes require a temperature estimate for use as a thermobarometer. Previous studies obtained temperature estimates from thermometric methods external of the host‐inclusion system. In this study, we present the first P–T estimates of quartz inclusion entrapment by integrating the quartz‐in‐garnet elastic model with titanium concentration measurements of inclusions and a Ti‐in‐quartz solubility model (QuiG‐TiQ). QuiG‐TiQ was used to determine entrapment P–T conditions of quartz inclusions in garnet from a quartzofeldspathic gneiss from Goodenough Island, part of the (ultra)high‐pressure terrane of Papua New Guinea. Raman spectroscopic measurements of the 128, 206, and 464 cm^?1 bands of quartz were used to calculate inclusion pressures using hydrostatic pressure calibrations (), a volume strain calculation (), and elastic tensor calculation (), that account for deviatoric stress. values calculated from the 128, 206, and 464 cm^?1 bands’ hydrostatic calibrations are significantly different from one another with values of 1.8 ± 0.1, 2.0 ± 0.1, and 2.5 ± 0.1 kbar, respectively. We quantified elastic anisotropy using the 128, 206 and 464 cm^?1 Raman band frequencies of quartz inclusions and stRAinMAN software (Angel, Murri, Mihailova, & Alvaro, 2019,  234 :129–140). The amount of elastic anisotropy in quartz inclusions varied by ~230%. A subset of inclusions with nearly isotropic strains gives an average and of 2.5 ± 0.2 and 2.6 ± 0.2 kbar, respectively. Depending on the sign and magnitude, inclusions with large anisotropic strains respectively overestimate or underestimate inclusion pressures and are significantly different (<3.8 kbar) from the inclusions that have nearly isotropic strains. Titanium concentrations were measured in quartz inclusions exposed at the surface of the garnet. The average Ti‐in‐quartz isopleth (19 ± 1 ppm [2σ]) intersects the average QuiG isomeke at 10.2 ± 0.3 kbar and 601 ± 6°C, which are interpreted as the P–T conditions of quartzofeldspathic gneiss garnet growth and entrapment of quartz inclusions. The P–T intersection point of QuiG and Ti‐in‐quartz univariant curves represents mechanical and chemical equilibrium during crystallization of garnet, quartz, and rutile. These three minerals are common in many bulk rock compositions that crystallize over a wide range of P–T conditions thus permitting application of QuiG‐TiQ to many metamorphic rocks.     

全吉地块花岗片麻岩中镁铁质岩包体的矿物演化和锆石定年与古元古代区域变质作用

全吉地块中段古元古代早期的德令哈二长花岗片麻岩中发育一个来自围岩的变质镁铁质岩包体。该包体的岩性从核部到边缘依次为角闪斜长辉石岩、斜长角闪岩和石榴石角闪片岩。角闪斜长辉石岩的显微结构指示三个世代的矿物演化,世代Ⅰ为单斜辉石+棕绿色普通角闪石+斜长石+石英+钛铁矿,世代Ⅱ为蓝绿色普通角闪石+斜长石+石榴子石,世代Ⅲ为阳起石+钠长石+黝帘石。世代Ⅰ指示其峰期变质达高角闪岩相条件。角闪斜长辉石岩的锆石全部为浑圆状多晶面晶体,其CL图像具高温变质结晶特征。LA ICPMS技术测定获得上交点U Pb年龄为（1 913±38） Ma（MSWD=015）,指示峰期变质发生在古元古代末。研究表明,全吉地块中区域性分布的古元古代早期的二长花岗片麻岩与达肯大坂岩群在响应全球Columbia超大陆汇聚事件中一起发生了区域变质作用。     

Crustal reworking in a shear zone: transformation of metagranite to migmatite

This study uses field, microstructural and geochemical data to investigate the processes contributing to the petrological diversity that arises when granitic continental crust is reworked. The Kinawa migmatite formed when Archean TTG crust in the São Francisco Craton, Brazil was reworked by partial melting at ~730 °C and 5–6 kbar in a regional‐scale shear zone. As a result, a relatively uniform leucogranodiorite protolith produced compositionally and microstructurally diverse diatexites and leucosomes. All outcrops of migmatite display either a magmatic foliation, flow banding or transposed leucosomes and indicate strong, melt‐present shearing. There are three types of diatexite. Grey diatexites are interpreted to be residuum, although melt segregation was incomplete in some samples. Biotite stable, H₂O‐fluxed melting is inferred via the reaction Pl + Kfs + Qz + H₂O = melt and geochemical modelling indicates 0.35–0.40 partial melting. Schlieren diatexites are extremely heterogeneous; residuum‐rich domains alternate with leucocratic quartzofeldspathic domains. Homogeneous diatexites have the highest SiO₂ and K₂O contents and are coarse‐grained, leucocratic rocks. Homogeneous diatexites, quartzofeldspathic domains from the schlieren diatexites and the leucosomes contain both plagioclase‐dominated and K‐feldspar‐dominated feldspar framework microstructures and hence were melt‐derived rocks. Both types of feldspar frameworks show evidence of tectonic compaction. Modelling the crystallization of an initial anatectic melt shows plagioclase appears first; K‐feldspar appears after ~40% crystallization. In the active shear zone setting, shear‐enhanced compaction provided an essentially continuous driving force for segregation. Thus, Kinawa migmatites with plagioclase frameworks are interpreted to have formed by shear‐enhanced compaction early in the crystallization of anatectic melt, whereas those with K‐feldspar frameworks formed later from the expelled fractionated melt. Trace element abundances in some biotite and plagioclase from the fractionated melt‐derived rocks indicate that these entrained minerals were derived from the wall rocks. Results from the Kinawa migmatites indicate that the key factor in generating petrological diversity during crustal reworking is that shear‐enhanced compaction drove melt segregation throughout the period that melt was present in the rocks. Segregation of melt during melting produced residuum and anatectic melt and their mixtures, whereas segregation during crystallization resulted in crystal fractionation and generated diverse plagioclase‐rich rocks and fractionated melts.     

High‐T and low‐P metamorphism in the Xilingol Complex of central Inner Mongolia,China: An indicator of extension in a previous orogeny

The Xilingol Complex comprises biotite gneisses and amphibolite interlayers with extensive migmatization. Four representative samples were documented and found to record either two or three metamorphic stages. Phase modelling using thermocalc suggests that the observed assemblages represent the final stages that underwent cooling from temperature peaks, and are consistent with a fluid‐absent solidus in P–T pseudosections. Their P–T conditions are further constrained to be 5–6 kbar/680–725°C and 4–5 kbar/650–680°C for two garnet‐bearing gneiss samples, 4–5 kbar/660–730°C for a cordierite‐bearing gneiss sample, and 4–5 kbar/680–710°C for an amphibolite sample based on mineral composition isopleths, involving measured Mg content in biotite, anorthite in plagioclase, grossular and pyrope in garnet and Ti content in amphibole. The peak temperature conditions recovered are 760–790°C or >760°C at 5–6 kbar based on the composition isopleths of plagioclase, biotite, garnet and especially the comparison of melt contents between the calculated and observed. A pre‐peak heating process with slight decompression can be suggested for some samples on the basis of the core–rim increase in the plagioclase anorthite, and the stability of ilmenite. Zircon U–Pb dating using the LA‐ICP‐MS method provides systemic constraints on the metamorphic ages of the Xilingol Complex to be 348–305 Ma, interpreted to represent the post‐peak cooling stages. Moreover, metagabbroic dykes that intruded into the Xilingol Complex yield 317 ± 3 Ma from magmatic zircon, and are considered to have played a significant role for heat advection triggering the high‐T and low‐P metamorphism. Thus, the clockwise P–T paths involving pre‐peak heating, peak and post‐peak cooling recovered for the Xilingol Complex are consistent with an extensional setting in the Carboniferous that developed on a previous orogen in response to addition of mantle‐derived materials probably together with upwelling of the asthenospheric mantle.     

Plagioclase zonation styles in hornblende gabbro inclusions from Little Glass Mountain,Medicine Lake volcano,California: implications for fractionation mechanisms and the formation of composition gaps

The rhyolite of Little Glass Mountain (73–74% SiO₂) is a single eruptive unit that contains inclusions of quenched andesite liquid (54–61% SiO₂) and partially crystalline cumulate hornblende gabbro (53–55% SiO₂). Based on previous studies, the quenched andesite inclusions and host rhyolite lava are related to one another through fractional crystallization and represent an example of a fractionation-generated composition gap. The hornblende gabbros represent the cumulate residue associated with the rhyolite-producing and composition gap-forming fractionation event. This study combines textural (Nomarski Differential Interference Contrast, NDIC, imaging), major element (An content) and trace element (Mg, Fe, Sr, K, Ti, Ba) data on the style of zonation of plagioclase crystals from representative andesite and gabbro inclusions, to assess the physical environment in which the fractionation event and composition gap formation took place. The andesite inclusions (54–61% SiO₂) are sparsely phyric with phenocrysts of plagioclase, augite and Fe-oxide±olivine, +/–orthopyroxene, +/–hornblende set within a glassy to crystalline matrix. The gabbro cumulates (53–55% SiO₂) consist of an interconnected framework of plagioclase, augite, olivine, orthopyroxene, hornblende and Fe-oxide along with highly vesicular interstitial glass (70–74% SiO₂). The gabbros record a two-stage crystallization history of plagioclase+olivine+augite (Stage I) followed by plagioclase+orthopyroxene+ hornblende+Fe-oxide (Stage II). Texturally, the plagioclase crystals in the andesite inclusions are characterized by complex, fine-scale oscillatory zonation and abundant dissolution surfaces. Compositionally (An content) the crystals are essentially unzoned from core-to-rim. These features indicate growth within a dynamic (convecting?), reservoir of andesite magma. In contrast, the plagioclase crystals in the gabbros are texturally smooth and featureless with strong normal zonation from An₇₄ at the core to around An₃₀. K, and Ba abundances increase and Mg abundances decrease steadily towards the rim. Ti, Fe, and Sr abundances increase and then decrease towards the rim. The trace element variations are fully consistent with the two-stage crystallization sequence inferred from the gabbro mineralogy. These results indicate progressive closed-system in situ crystallization in a quiescent magmatic boundary layer environment located along the margins of the andesite magma body. The fractional crystallization that generated the host rhyolite lava is one of inward solidification of a crystallizing boundary layer followed by melt extraction and accumulation of highly evolved interstitial liquid. This mechanism explains the formation of the composition gap between parental andesite and rhyolite magma compositions.     

Ar/Ar Single Grain Dating and Mineral Chemistry of Hornblendes South of the Red River Shear Zone (Vietnam): New Evidence for Early Proterozoic Tectonothermal Event

The pre-Mesozoic metamorphic belt runs parallel to the Day Nui Con Voi - Red River shear zone in Vietnam to the south. The belt is mainly composed of hornblende gneisses, amphibolite lenses and mica-schists. Five hornblendes from a gneiss and an amphibolite were analyzed chemically and chronologically by Electron Probe Micro Analysis (EPMA) and ⁴⁰Ar/³⁹Ar methods. EPMA analyses show that hornblendes in the gneiss and the amphibolite have significant amount of edenite component and similar average composition. However, the recalculated Fe³⁺ content is significantly heterogeneous in a thin section while total Fe is nearly the same among the analyses. The rim of each crystal is higher in Fe³⁺/(Fe³⁺ + Fe²⁺) than the core. These chemical and petrological features suggest that the hornblendes have suffered significant oxidation, in particular, largely in the gneiss.

⁴⁰Ar/³⁹Ar analyses showed that the gneiss has a significant variation of plateau ages (2089±14, 1977±19 and 1873±13 Ma) among three hornblende grains, whereas the amphibolite gives the same plateau ages (2056±14 and 2044±21 Ma) for two grains. All grains of both samples have excess ages in the first few fractions at low temperatures and partial-loss ages between the excess and plateau spectra. The Ca/K ratios indicate some disturbed phases for the lower temperature spectra but the partial-loss ages are also derived from hornblende phase. These facts suggest that hornblende in the gneiss has experienced partial argon loss by oxidation and/or thermally activated argon diffusion process. However, the gneiss and the associated amphibolite have preserved the early Proterozoic tectono-metamorphic event in the hornblende crystals except for their rims, giving new evidence for the early Proterozoic event within the pre-Mesozoic metamorphic belt (northern Vietnam) south of the Red River shear zone in Indochina.     

An electron‐optical study of melt‐related microstructures in granulite facies rocks from the Torngat Orogen

Cordierite–quartz and plagioclase–quartz intergrowths in a paragneiss from northern Labrador (the Tasiuyak Gneiss) were studied using SEM, STEM and TEM. The gneiss experienced granulite facies conditions and partial melting during both regional and, subsequently, during contact metamorphism. The microstructures examined all results from the contact metamorphism. Cordierite–quartz intergrowths occur on coarse and fine scales. The former sometimes exist as a ‘geometric’ intergrowth in which the interface between cordierite and quartz appears planar at the resolution of the optical microscope and SEM. The latter exists in several microstructural variants. Plagioclase is present as a minor component of the intergrowth in some examples of both the coarse and fine intergrowth. Grain boundaries in cordierite–quartz intergrowths are occupied by amorphous material or a mixture of amorphous material and chlorite. Cordierite and quartz are terminated by crystal faces in contact with amorphous material. Chlorite is sometimes found on cordierite surfaces and penetrating into cordierite grains along defects. Quartz contains (former) fluid inclusions 10–20 nm in maximum dimension. The presence of planar interfaces between cordierite and the amorphous phase is reminiscent of those between crystals and glass in volcanic rocks, but in the absence of compelling evidence that the amorphous material represents former melt, it is interpreted as a reaction product of cordierite. Plagioclase–quartz intergrowths occur in a number of microstructural variants and are commonly associated with cordierite–quartz intergrowths. The plagioclase–quartz intergrowths display simple, non‐planar interfaces between plagioclase and quartz. Quartz contains (former) fluid inclusions of dimensions similar to those observed in cordierite–quartz intergrowths. The boundary between quartz and enclosing K‐feldspar is cuspate, with quartz cusps penetrating a few tens of nanometres into K‐feldspar, commonly along defects in K‐feldspar and sometimes with very low dihedral angles at their tips. This cuspate microstructure is interpreted as melt pseudomorphs. The plagioclase–quartz intergrowths share some features with myrmekite, but differ in some respects: the composition of the plagioclase (An₃₇Ab₆₂Or₁–An₃₈Ab₆₁Or₁); the association with cordierite–quartz intergrowths; and microstructures that are atypical of myrmekite (e.g. quartz vermicules shared with cordierite–quartz intergrowths). It is inferred that the plagioclase–quartz intergrowths may have formed from, or in the presence of, melt. Inferred melt‐related microstructures preserved on the nanometre scale suggest that melt on grain boundaries was more pervasive than is evident from light optical and SEM observations.     

Contrasting pressure–temperature–deformation history across a vestigial craton–mobile belt boundary: the western margin of the Eastern Ghats Belt at Deobhog, India

At Deobhog, migmatitic gneisses and granulites of the Eastern Ghats Belt are juxtaposed against a cratonic ensemble of banded augen gneiss, amphibolite and calcsilicate gneiss, intruded by late hornblende granite and dolerite. In the migmatitic gneiss unit, early isoclinal folds (syn‐D_1M and D_2M) are reoriented along N–S‐trending and E‐dipping shear planes (S_3M), with (S_1M–S_3M) intersection lineations having steep to moderate plunges. The near‐peak P–T condition was syn‐D_3M (≥900 °C, 9.5 kbar), as inferred from syn‐D_3M Grt+Opx‐bearing leucosomes in mafic granulites, and from thermobarometry on Grt (corona)–Opx/Cpx–Pl–Qtz assemblages. The P–T values are consistent with the occurrence of Opx–Spr–Crd assemblages in spatially associated high‐Mg–Al pelites. A subsequent period of cooling followed by isothermal decompression (800–850 °C, c. 7 kbar) is documented by the formation of coronal garnet and its decomposition to Opx+Pl symplectites in mafic granulites. Hydrous fluid infiltration accompanying the retrograde changes is manifested in biotite replacing Opx in some lithologies. The cratonic banded gneiss–granite unit also documents two phases of isoclinal folding (D_1B & D_2B), with the L_2B lineation girdle different from the lineation spread in the migmatitic gneiss unit. Calcsilicate gneiss (Hbl–Pl–Cpx–Scap–Cal) and amphibolite (Hbl–Pl±Grt±Cpx) within banded gneisses record syn‐D_2B peak metamorphic conditions (c. 700 °C, 6.5 kbar), followed by cooling (to c. 500 °C) manifested in the stabilization of coronal clinozoisite–epidote. The D_3B shear deformation post‐dates granite and dolerite intrusions and is characterized by top‐to‐the‐west movement along N–S‐trending, E‐dipping shear planes. Deformation mechanisms of quartz and feldspar in granites and banded gneisses and amphibole–plagioclase thermometry within shear bands in dolerites document an inverted syn‐D_3B thermal gradient with temperature increasing from 350 to 550 °C in the west to ≥700 °C near the contact with the migmatitic gneiss unit. The thermal gradient is reflected in the stabilization of chlorite after hornblende in S_3B shears to the west, and post‐D_2B neosome segregation along D_3B folds and shears to the east. The contrasting lithologies, early structures and peak metamorphic conditions in the two units indicate unconnected pre‐D₃P–T –deformation histories. The shared D₃ deformation in the two units, the syn‐D₃ inverted thermal gradient preserved in the footwall cratonic rocks and the complementary cooling and hydration of the hanging wall granulites across the contact are attributed to westward thrusting of ‘hot’ Eastern Ghats granulites on ‘cool’ cratonic crust. It is suggested that the Eastern Ghats migmatitic gneiss unit is not a reworked part of the craton, but a para‐autochthonous/allochthonous unit emplaced on and amalgamated to the craton.     

Diffusion-controlled olivine corona textures in granitic rocks from Lofoten, Norway: calculation of Onsager diffusion coefficients, thermodynamic modelling and petrological implications

Reactions occurring during cooling of charnockitic intrusives on the Lofoten Islands produce characteristic diffusion-controlled textures around fayalite and Fe–Ti oxides. Thermobarometry indicates the corona textures formed at 780–840 °C and pressures of 4–10 kbar, whereas the magmatic assemblage of the charnockite (clinopyroxene–olivine–quartz) crystallized at about 850–870 °C and 4 kbar. The succession olivine|orthopyroxene+magnetite|orthopyroxene+garnet and olivine|orthopyroxene+magnetite|amphibole developed where olivine reacted with adjacent plagioclase or K-feldspar, but the modes and the thicknesses of the corona textures vary according to the feldspar type, indicating that the primary magmatic ternary feldspar was already exsolved into albitic plagioclase and alkali feldspar when the corona formation began. Simultaneously, in other parts of the rock, primary magmatic clinopyroxene reacted to amphibole and Fe–Ti oxides reacted to orthopyroxene+garnet coronas or to amphibole. Textures demonstrate significant Al diffusion in the rocks under granulite facies conditions and they suggest that no pervasive fluid influx occurred and that amphibole formation was dependant on a local source of H₂O probably related to water-release during the last stages of magmatism. Calculation of the net reaction by accounting for all observed reactions at different sites in the rock indicates that the system can be regarded as balanced on a hand-specimen scale with respect to all elements except for Na and H₂O. The larger variety of textures developed in rocks of granitic bulk composition provide more constraints than textures from gabbroic compositions, and permitted calculation of a set of relative diffusion coefficients which also reproduce textures in the gabbroic and anorthositic rocks from the Lofoten Islands. The following set of relative diffusion coefficients (L_i/L_Fe) reproduces the observed textures in the Lofoten rocks: Si=0.82, Mg=0.59, Mn=0.05, Na=0.38, K=0.39, Al=0.05 and Ca=0.07.     

Metamorphism of the Basement of the Qilian Fold Belt in the Minhe-Ledu Area, Qinghai Province, NW China

The basement of the central Qilian fold belt exposed along the Minhe-Ledu highway consists of psammitic schists, metabasitic rocks, and crystalline limestone. Migmatitic rocks occur sporadically among psammitic schist and metabasitic rocks. The mineral assemblage of psammitic schist is muscovite + biotite + feldspar + quartz ± tourmaline ± titanite ± sillimanite and that of metabasitic rocks is amphibole + plagioclase + biotite ± apatite ± magnetite ± pyroxene ± garnet ± quartz. The migmatitic rock consists of leucosome and restite of various volume proportions; the former consists of muscovite + alkaline feldspar + quartz ± garnet ± plagioclase while the latter is either fragments of psammitic schist or those of metabasitic rock. The crystalline limestone consists of calcite that has been partly replaced by olivine. The olivine was subsequently altered to serpentine. Weak deformations as indicated by cleavages and fractures were imposed prominently on the psammitic schists, occasionally on me