新疆东准噶尔老鸦泉碱性岩及相关锡矿的岩石地球化学特征

老鸦泉富碱花岗岩杂岩体与侵入其中的富碱花岗斑岩岩体及云英岩型锡矿体、石英脉型锡矿体等REE配分曲线类似,均具有强烈的Eu亏损,它们的微量元素蛛网图等岩石地球化学特征也类似,是同源岩浆结晶分异演化的结果。锡矿体是老鸦泉富碱岩浆分异演化及以钠质为主的强烈碱交代自变质作用的最终产物。侵入于老鸦泉岩体内的花岗斑岩为锡矿体的直接围岩,它是岩浆结晶分异更晚期混入了更多地壳组分,并向酸性方向演化的产物,该花岗斑岩经自变质热液蚀变作用造成锡的富集并成矿。因此,碱性岩浆结晶分异晚期混有地壳组分,岩浆向酸性演化可能是碱性花岗岩形成锡矿的重要条件之一。     

安徽铜陵矿集区斑岩型铜钼金矿床地质特征及成矿背景

铜陵矿集区以发育大型和为数众多的矽卡岩型矿床而闻名于世,而近年来作为该区找矿的重要成果和突破则是斑岩型矿床和矿化的陆续发现。本文以铜陵矿集区3个代表性斑岩型矿床为研究对象,在详细的野外地质调查和室内显微观察研究的基础上,开展了较为系统的矿床地质和地球化学研究,阐述了斑岩型矿床的地质特征,确定了含矿侵入岩体的地质和地球化学特征,分析了矿床蚀变特征和流体包裹体特征,探讨了成岩成矿的大地构造背景,并与世界典型斑岩型矿床进行了对比。研究表明,铜陵矿集区斑岩型铜钼金矿床通常发育于含矿岩体的围岩或盖层为砂岩、砂页岩或硅质岩的条件下,含矿岩体为富碱低镁高钾准铝质钙碱性系列中浅成侵入岩体,具有与埃达克岩一致的地球化学特征;与世界典型斑岩型矿床含矿岩体对比,岩体侵位较深,有些矿区多期多相特征不明显;含矿岩体发育钾硅酸盐化、黄铁绢英岩化、青磐岩化等热液蚀变且有一定的分带性,但各矿床蚀变特征略有不同;矿床矿石矿物中富气相、富液相和含子晶多相包裹体共生,流体包裹体均一温度和盐度演化特征显示具有岩浆作用控制的高温热液型矿床特征。结合区域构造演化,作者确定铜陵矿集区斑岩型矿床属大陆环境斑岩型矿床,成矿作用发生于陆内造山作用由挤压向拉张转化的动力学背景之下,斑岩型矿床与矽卡岩型矿床及热液脉状矿床共同构成受统一的岩浆热液系统控制的矿床系列。     

大庙斜长岩杂岩体及铁磷矿的稀土元素地球化学研究

大庙斜长岩杂岩体是中国唯一的岩体型斜长岩杂岩体。稀土元素(REE)地球化学研究表明,控杂岩体中斜长岩、苏长岩、铁磷矿属同源斜长—苏(辉)长质岩浆不同演化阶段的产物。成岩(矿)作用具液态分异和结晶分异双重性。REE和Sc的丰度、Eu/Eu比值等参量能为铁磷矿勘查提供示踪判据。     

金堆城与沙坪沟小岩体型斑岩钼矿床对比研究

金堆城和沙坪沟钼矿床为东秦岭—大别钼矿带最典型的2个大(超大)型小岩体型斑岩钼矿床。通过对其基本特征、成矿时代、物质来源等特征综述及对其成矿动力学背景、成矿机制的探讨,结果表明:二者的成矿类型、含矿斑岩体化学组成、矿体产状形态、围岩蚀变分带、成岩成矿时间等具有相似性,矿化均受小斑岩体控制,岩控特征明显。沙坪沟钼矿化的高品位、大储量与其发育的爆破角砾岩、更充分的"流体化作用"、较长时间的热液活动及矿化斑岩体的侵位空间等因素密切相关。二者具有相似的小岩体成大矿的成矿机制,即与含矿小岩体同源同成因的深源浅成的花岗岩基在深部发生分异演化,为浅部的含矿小斑岩体提供大量的热液和矿物质,在小斑岩体头部(或浅部)、以上和以外更大范围的构造岩或围岩中成矿。     

黔西南戈塘金矿成因再认识

文章通过对戈塘金矿硅质角砾岩的地质特征、地球化学特征综合分析,认为矿区的角砾硅化灰岩、硅化黏土岩等蚀变地质体为热液成因,其中硅质来源可分为成岩期与成矿期:成岩期硅质来自热泉型生物沉积;成矿期硅质来自成矿流体。成矿流体是来源于深部流体与天水、地层建造水的混合作用形成的混合流体。根据矿石结构构造特征及含金蚀变地质体产状特征,结合在戈塘地区茅口组底部及以下地层中新近发现呈筒状产出的含金蚀变角砾岩,认为戈塘金矿矿区含金角砾岩具有隐爆角砾岩的特征,得出戈塘金矿成因类型可能为隐爆角砾岩型金矿的新认识。此认识可供黔西南金矿成矿理论研究、探讨新的找矿方向和成矿预测提供参考。     

江西金山金矿床稀土元素地球化学特征及意义

稀土元素在地质体中的丰度及分布形式与地质体的发生发展及物质组成有关.通过对比分析矿床的稀土元素组成特征及分布模式,研究矿床围岩、蚀变带及各类矿石的稀土元素地球化学行为,认为在高水/岩比值下热液蚀变作用使其稀土元素产生明显的带入和带出,但成岩和成矿物质具有继承性演化的特点.含金石英脉的稀土元素地球化学特征表明成矿流体具有多源性.石英脉成因不同,是不同成矿阶段热液与构造共同作用的产物.本次工作发现的硅质岩,其地球化学特征表明是一种混有火山物质或陆源物质的过渡类型热水沉积岩,可能指示该矿床早期存在热水喷流成岩成矿作用.     

红卓斑岩型铜矿床地球化学特征及找矿模型研究

红卓铜矿具有很好的斑岩铜矿找矿前景,研究区岩体的地球化学特征表明铜矿床为岛弧型斑岩铜矿,成矿岩体具有壳幔混合岩的特点;通过对斑岩体、蚀变分带及找矿标志研究,建立了红卓斑岩型铜矿找矿模型.     

满洲里—西旗斑岩铜多金属成矿系列REE地球化学特征及应用

对该区燕山期斑岩铜多金属成矿系列进行了REE地球化学研究,并结合岩石化学、包体、微量元素、氢氧同位素综合分析。各(蚀变)岩体REE分布模式可分为三种类型。在乌山矿床Q-Kf、Q-Ser、I-H三个蚀变带中REE分别呈氯化物、F~-络合物、F~-、CO_3~(2-)络合物形式。蚀变是两期叠加的,REE的淋滤、沉淀伴随成矿元素的再活化、再富集。首次发现铕亏损对矿化具有指示意义,蚀变岩δEu愈小,矿化愈好。提出了斑岩体含矿性的五条判别标志,据此对外围岩体含矿性进行了判别排队。     

内蒙古额仁陶勒盖花岗岩成因与银矿床的形成

对额仁陶勒盖花岗岩的地质学、地球化学的研究表明，它为岩浆成因，是壳幔混合源岩浆演化的产物；岩体在成岩过程中发生了强烈的结晶分异作用，导致岩浆后期及期后热液中银的富集，银矿床与石英斑岩（花岗岩结晶分异的产物）在地质及地球化学诸多方面存在着显著的成因联系。     

成矿流体对德兴斑岩铜矿床中伊利石结晶度的控制作用

伊利石广泛存在于铜厂大型斑岩铜矿床内,是特征的热液蚀变矿物,其结晶度和膨胀层含量受携带矿质的热液流体量控制。以浸染状强矿化为特征的斑岩体中上部及接触带附近伊利石结晶程度较好,主要是高水／岩比作用的结果。同时指示出伊利石结晶程度好的部位,矿化品位高,蚀变程度也强。     

Minor-element and Sr-isotope geochemistry of tertiary stocks,Colorado mineral belt

Rocks of the northeast portion of the Colorado mineral belt form two petrographically, chemically and geographically distinct rock suites: (1) a silica oversaturated granodiorite suite; and (2) a silica saturated, high alkali monzonite suite. Rocks of the granodiorite suite generally have Sr contents less than 1000 ppm, subparallel REE patterns and initial ⁸⁷Sr/ ⁸⁶Sr ratios greater than 0.707. Rocks of the monzonite suite are restricted to the northeast part of the mineral belt, where few rocks of the granodiorite suite occur, and generally have Sr contents greater than 1000 ppm, highly variable REE patterns and ⁸⁷Sr/⁸⁶Sr initial ratios less than 0.706.Despite forming simple, smooth trends on major element variation diagrams, trace element data for rocks of the granodiorite suite indicate that they were not derived from a single magma. These rocks were derived from magmas having similar REE patterns, but variable Rb and Sr contents, and Rb/Sr ratios. The preferred explanation for these rocks is that they were derived by partial melting of a mixed source, which yielded pyroxene granulite or pyroxenite residues.The monzonite suite is chemically and petrographically more complex than the granodiorite suite. It is subdivided here into alkalic and mafic monzonites, and quartz syenites, based on the textural relations of their ferromagnesian phases and quartz. The geochemistry of these three rock types require derivation from separate and chemically distinct magma types. The preferred explanation for the alkalic monzonites is derivation from a heterogeneous mafic source, leaving a residue dominated by garnet and clinopyroxene. Early crystallization of sphene from these magmas was responsible for the severe depletion of the REE observed in the residual magmas. The lower Sr content and higher Rb/Sr ratios of the mafic monzonites requires a plagioclase-bearing source.The Sr-isotope systematics of the majority of these rocks are interpreted to be largely primary, and not the result of crustal contamination. The positive correlation of Rb/Sr and ⁸⁷Sr/⁸⁶Sr ratios for the least fractionated samples indicate that the sources from which parent magmas of both the granodiorite and monzonite suites were derived are Precambrian in age.     

Rare earth element distributions among coexisting granulite facies minerals,Scourian complex,NW Scotland

The major rock-forming mineral phases (pyroxenes, plagioclase, garnet, hornblende) of a suite of granulite-facies gneisses from the Scourian complex, NW Scotland, have been analyzed for their rare earth element (REE) content. Although host rock compositions range from felsic to ultramafic, REE abundances and patterns for each mineral group show only limited variation. The REEs exhibit regular and consistent distribution patterns for each mineral which suggest, together with major element and textural considerations, that the observed distribution coefficients approach equilibrium. Total REE content follows the sequence hornblende>clinopyroxene>garnet>plagioclase >orthopyroxene and mass balance calculations show that even in the felsic gneisses>60% of the REEs reside in the major rock-forming minerals. Comparisons of both relative REE abundances and distribution coefficients with those in other rock types reveal a striking resemblance with patterns observed in mineral-liquid pairs of dacitic rocks. These similarities may have arisen during a partial melting episode in which granite-granodiorite melts were generated and removed from the Scourian complex; leaving a residuum which is severely depleted in the incompatible elements, including the REEs.     

新疆富蕴希力库都克地区岩浆混合作用及其成矿意义

新疆北部希力库都克地区为-斑岩型铜钼金矿区,含矿的花岗闪长岩体中广泛发育4种暗色岩微粒包体似隐晶状安山玄武岩、细粒闪长岩、少斑状安山(玢)岩和安山玢岩,矿区还产有安山玢岩、英安斑岩、正长岩等脉岩.花岗闪长岩及其包体的岩相学、矿物化学和岩石地球化学特征表明该区发生了岩浆混合作用,其中酸性的花岗闪长质与基性的闪长质岩浆混合,形成了过渡相岩石--安山玢岩质岩浆混合岩.本区矿化与暗色微粒包体有关矿化较好的地段暗色微粒包体较多,有些包体中磁铁矿微粒普遍发育,有时甚至含少量黄铁矿和黄铜矿等硫化物.研究发现,本区岩浆混合岩--安山玢岩,与蚀变矿化的花岗闪长岩虽然在野外产状和岩石结构上截然有别,但二者的化学成分相当接近在哈克图上二者的投影点靠近;稀土元素和微量元素上,标准化曲线型式相似(或相同),表明二者具有相似的成因,换言之,岩浆混合作用可能伴随了热液蚀变和矿化的发生.推测本区岩浆混合作用可能是幔源基性岩浆与陆壳花岗质岩浆的混合,由此产生的中酸性岩浆经过分异和流体作用造就了本区的铜钼金矿化.     

江西冷水火山—侵入杂岩体岩石化学及地球化学特征

冷水银铅锌矿的火山—侵入杂岩体出露于信江中生代火山盆地南缘。岩石化学、微量元素、稀土元素和铷锶同位素分析表明冷水火山岩及次火山岩是同源产物,是同熔岩浆分异的结果。岩浆中成矿物质Cu、Fe、Pb、Zn、S、H_2O的数量与下地壳、上地慢或洋壳物质的部分熔融程度有关。冷水火山—侵入杂岩是钙碱性岩浆于不同演化阶段形成的岩石组合并具有化学成分上的相似性和继承性。岩浆房中具有良好的分带现象,上部为富钾的流纹质岩浆,向下逐渐变为基性岩浆。岩浆由钙碱性向偏碱性演化,促使成矿元素大量富集,在一定条件下形成矿床。     

Rare Earth Elements in Hydrothermally Altered Granitic Rocks in the Ranong and Takua Pa Tin‐Field,Southern Thailand

Geochemical studies were conducted on the hydrothermally altered granitic rocks in the Ranong and Takua Pa tin‐fields in southern Thailand in order to investigate the mode of occurrence of REE (rare earth elements), with emphasis placed on a potential REE resource associated with granitic rocks in the Southeast Asian Tin Belt. The total REE (ΣREE) content of altered granitic rocks ranges from 130 to 350 ppm at Haad Son Paen (which is presently mined for kaolin clay) in the Ranong tin‐field, and that of altered granitic rocks and kaolinite veinlets reaches up to 424 ppm and 872 ppm, respectively, at Nok Hook in the Takua Pa tin‐field. Rare earth elements in the altered granitic rocks and kaolinite veinlets show a relatively flat chondrite‐normalized pattern, thus enriched in heavy REE compared with the original granitic rocks and their weathered crusts. At Nok Hook (Takua Pa), the ΣREE content of kaolinite separated from an altered granitic rock by elutriation is 1313 ppm, a ΣREE amount about four times higher than that of whole‐rock composition of the altered granitic rock. Chondrite‐normalized REE patterns of the elutriated kaolinite and of the altered granite are relatively flat. Sequential extraction experiments suggest that 41 and 85 percent of REE are present as ion exchangeable‐form in the altered granitic rock, and in the kaolinite veinlets, respectively. In addition, more than 90% of REE in the kaolinite veinlets are present as the acid‐soluble state. On the other hand, the ΣREE content of kaolinite veinlets and of the kaolinite concentrated by elutriation from an altered granitic rock at Haad Som Paen (Ranong) is 70 ppm and 75 ppm, respectively, thus enrichment of REE in kaolinite was not confirmed. In addition, by the sequential extraction experiments, 23% and 4% of REE were extracted from the altered granitic rock and the kaolinite veinlets at Haad Som Paen. In the altered granitic rocks at Haad Som Paen, REE are present as refractory phases, and REE in the acid‐soluble states had been leached by hydrothermal fluid.     

江西相山潜火山岩中淬冷包体的发现及其成因机制探讨

在江西相山大型塌陷式火山盆地北部的潜火山岩岩墙中，笔者发现了闪长质的岩石包体，这种包体具典型的反向脉及淬冷边，且淬冷边内含有大量针状磷灰石。在包体内部或包体与寄主岩的边界均见有钾长石及斜长石捕虏晶，这种捕虏晶是包体岩浆从寄主岩岩浆中捕获的，常被熔蚀成筛状或浑圆状。包体与寄主岩（次斑状花岗闪长岩）的稀土元素曲线和不相容元素蛛网图的形态非常相似。因此，相山潜火山岩岩墙中的闪长质岩石包体是不同成分、不同温度的岩浆经对流及不均一岩浆混合作用而形成，在成因类型上属淬冷包体。     

Geochemistry and petrogenesis of a peralkaline granite complex from the Midian Mountains, Saudi Arabia

A zoned intrusion with a biotite granodiorite core and arfvedsonite granite rim represents the source magma for an albitised granite plug near its eastern margin and radioactive siliceous veins along its western margin. A study of selected REE and trace elements of samples from this complex reveals that the albitised granite plug has at least a tenfold enrichment in Zr, Hf, Nb, Ta, Y, Th, U and Sr, and a greatly enhanced heavy/light REE ratio compared with the peralkaline granite. The siliceous veins have even stronger enrichment of these trace elements, but a heavy/light REE ratio and negative eu anomaly similar to the peralkaline granite. It is suggested that the veins were formed from acidic volatile activity and the plug from a combination of highly fractionated magma and co-existing alkaline volatile phase. The granodiorite core intrudes the peralkaline granite and has similar trace element geochemistry. The peralkaline granite is probably derived from the partial melting of the lower crust in the presence of halide-rich volatiles, and the granodiorite from further partial melting under volatile-free conditions.     

广西河塘岩体地质地球化学特征及成矿作用

河塘杂岩体的组成由早而晚为:早期侵入相石英闪长岩→主体侵入相花岗闪长岩→补充侵入相二长花岗岩.岩石化学体现出由基→酸的变化规律;稀土配分模式形态相似,Eu轻、中亏损,反映了杂岩体各类岩石之间成因上不可分割的内在联系.在岩体及接触带主要形成Au、Cu、Fe多金属矿化,表现为具有两类不同性质的成矿作用,即岩浆自源成矿作用和岩浆他源成矿作用,并共同构成一个时空上规律组合的成矿系统.     

Behavior of major and rare-earth elements during the postmagmatic alteration of kimberlites

During serpentinization and subsequent alteration in the absence of brucite, kimberlites accumulate uncompensated silica. Its amount can be calculated from the average compositions of the rock-forming minerals (olivine, calcite, phlogopite) and the chemical compositions of the rocks. The contents of rock-forming oxides and REE were determined in 12 kimberlite pipes of the Yakutian kimberlite province, in 413 samples from secondary-alteration zones and of unaltered kimberlites. Columns of successive kimberlite alterations were constructed for each pipe on the basis of secondary-quartz data; here, the behavior of rock-forming oxides and REE was assessed. All the studied rocks had experienced different degrees of postmagmatic hydrothermal metasomatism at different depths in all the pipes. The changes were reflected in the supply/loss of rock-forming oxides and REE. The supply of REE during the hydrothermal metasomatism enriched the kimberlites with TiO₂, P₂O₅, and CaO. During the removal of REE, most of the rock-forming oxides were partially lost. The maximum REE supply was 67% in the Udachnaya-Vostochnaya pipe and 59% in the Nyurbinskaya pipe as compared with the unaltered kimberlites. The maximum REE loss was 87% in the Aikhal pipe and 81% in the Internatsional’naya pipe as compared with the unaltered kimberlites. The initial REE contents of the postmagmatically altered kimberlites changed considerably in all the studied cases. This conclusion was drawn owing to the use of normative-quartz content as a criterion for secondary alteration.     

Geochemistry of the shawmere anorthosite complex,kapuskasing structural zone,Ontario

The Archean Shawmere Anorthosite Complex, at the southern end of the Kapuskasing Structural Zone, consists dominantly of anorthosite (An_{65 –85}) with minor gabbroic and ultramafic units, which are completely enclosed and cut by tonalites. Both the anorthosites and the tonalites are themselves cut by narrow dikes of gabbroic anorthosite. All of the rocks have undergone high grade metamorphism and are recrystallized so that few igneous textures remain.The anorthosites, gabbros and ultramafic rocks of this complex are cumulates which contain calcic plagioclase (An_65–95) and have atomic Mg/(Mg + Fe²⁺) ratios (Mg#) greater than 0.6; less than 3 ppm Rb; 150–210 ppm Sr; and less than 60 ppm Ba. REE abundanees range from 0.2 to 10 times chondritic and exhibit both light-enriched and light-depleted REE patterns. The lower Mg^# for the samples having more enriched light REE indicates substantial fractions of ferromagnesian minerals crystallized in addition to plagioclase during fractional crystallization, suggesting that the parent magma was basaltic, and not anorthositic. The ranges in Sr, Ba and REE abundances required for the magmas are typical of those for tholeiitic basalts from Archean greenstone belts. Thus the Shawmere Anorthosite Complex may represent cumulates of a crustal-level magma chamber which could have been the immediate source of basic Archean volcanics.One gabbroic anorthositic dike sample has a steeply fractionalted REE pattern with heavy REE abundances less than chondrites and a large positive Eu anomaly. The proposed interpretations is that this rock formed by partial melting of mafic cumulates, perhaps those of the Shawmere Anorthosite Complex itself.