安徽金寨岩体地质和地球化学特征及LA-ICP-MS锆石U-Pb年龄

安徽金寨岩体为一钾长花岗岩体,位于大别造山带北淮阳构造带,LA-ICP-MS锆石U-Pb定年获得岩体侵位年龄为129.7±1.5Ma,属早白垩世岩浆活动产物。岩体周边发现有数个铅锌多金属矿点,与区域岩浆作用及其矿化一致。岩体富硅(SiO_2=72.47%~77.80%)、富碱(K_2O+Na_2O=7.48%~8.16%)、贫钙(CaO=0.15%~1.47%);稀土配分曲线呈现"海鸥式"分布特征,显示强烈的Eu负异常(δEu=0.18~0.40);微量元素特征显示具有较高的Ga(21.68×10~(-6)~24.12×10~(-6))、Zr(127.68×10~(-6)~196.75×10~(-6))、Nb(33.31×10~(-6)~60.53×10~(-6))和Y(14.57×10~(-6)~27.51×10~(-6))含量,较低的Sr(8.15×10~(-6)~138.52×10~(-6))、Ba(23.04×10~(-6)~332.63×10~(-6))含量,在微量元素原始地幔标准化蛛网图上显示明显的Ba、Sr、P、和Ti的负异常。以上特征表明金寨钾长花岗岩为A型花岗岩,可能是下地壳源岩部分熔融的产物。金寨钾长花岗岩是形成于造山后伸展环境下的板内A1型花岗岩,不是形成于非造山大地构造背景下的碱性花岗岩。     

内蒙古大苏计斑岩钼矿床花岗质杂岩年代学、地球化学、Hf同位素组成及其地质意义

内蒙古卓资县大苏计斑岩钼矿化与区内花岗质杂岩(石英斑岩、正长花岗斑岩和花岗斑岩)有密切的成因联系。LA-ICP-MS锆石U-Pb定年获得石英斑岩、正长花岗斑岩和花岗斑岩的结晶年龄分别为(234±3)Ma、(225±4)Ma和(220±4)Ma。杂岩体富硅(w(SiO_2)=70.37%~78.84%)、富碱(w(Na_2O+K_2O)=4.52%~8.77%),均属高钾钙碱性系列,普遍具有低的w(Na_2O)(0.15%~2.69%)和高的铝指数(ASI介于1.13~3.35)。稀土元素总量介于48.2×10~(-6)~527.0×10~(-6),石英斑岩稀土元素含量(48.2×10~(-6)~83.1×10~(-6))最低,正长花岗斑岩稀土元素含量(272.1×10~(-6)~527.0×10~(-6))最高,花岗斑岩稀土元素含量为162.5×10~(-6)~236.8×10~(-6);杂岩体δEu介于0.15~0.93之间,(La/Yb)N介于3.0~65.5,自正长花岗斑岩、花岗斑岩到石英斑岩,其Eu负异常逐渐増大,而(La/Yb)N逐渐减小。岩体普遍富集Rb、Th、U、K、Nd、Zr、Hf等,强烈亏损Sr、P、Ti等。正长花岗斑岩具有中等Ba、Ta、Nb亏损。石英斑岩和花岗斑岩均属于高分异花岗岩,而正长花岗斑岩属于I型花岗岩。主量、稀土和微量元素特征表明,杂岩体具有后碰撞或后造山花岗岩特征,形成于后碰撞或后造山环境。杂岩体锆石的Hf同位素显示,3种岩石的εHf(t)值介于-21.1~-8.1,二阶段模式年龄tDM2介于1775~2587 Ma。石英斑岩来自于古元古代地壳物质的部分熔融;正长花岗斑岩来自于古元古代晚期地壳物质的部分熔融;花岗斑岩也主要来自于古元古代地壳物质的部分熔融,但有少量新太古代地壳物质参与。     

武夷山中段司前花岗岩体形成时代、地球化学特征及地质意义

本文对武夷山中段的司前岩体进行了系统的岩石学、地球化学、年代学及Lu-Hf同位素研究。结果表明,司前岩体形成于(140±1)Ma,主要由黑云母二长花岗岩组成,富碱(K_2O+Na_2O=6.67 wt%~8.25 wt%),富钾(K_2O/Na_2O=1.16~2.41),A/CNK值介于1.01~1.25之间。岩体具有较高的∑REE(177.73×10~(-6)~427.88×10~(-6))、Zr+Nb+Y+Ce含量(262.6×10~(-6)~581.5×10~(-6))和Zr饱和温度(平均824°C),FeOt/MgO(3.06~3.93)和10 000×Ga/Al(2.64~3.28)比值均较高,属典型的铝质-过铝质A型花岗岩。岩体的锆石εHf(t)值均为负值(–18.6~–7.9),暗示其源于古老的地壳物质重熔。综合上述结果和区域背景推测,司前岩体的源岩为新元古代麻源群变质火山-碎屑岩,源岩可能经历早古生代和白垩纪两期熔融事件,地幔岩浆为花岗岩的形成提供了热源,但并未贡献物质,岩体的形成与古太平洋板块俯冲过程中因俯冲板片后撤诱发的弧后扩张作用有关。     

上黑龙江盆地二十一站岩体角闪石和黑云母成分特征及成岩成矿意义

二十一站岩体位于黑龙江省东北部大兴安岭地区塔河县境内,该岩体产出的岩石类型包括早白垩世二长岩和石英二长斑岩及早侏罗世花岗岩和二长岩等,在该岩体中已发现斑岩型铜金矿床,但是该岩体形成的物理化学条件和岩石成因尚不清楚,不同岩性岩浆岩的成矿潜力也不明确。鉴于此,本文以二十一站岩体中不同时代的花岗岩、二长岩、石英二长斑岩的黑云母和角闪石为研究对象,结合偏光显微镜、电子探针背散射图像和电子探针化学成分,对该岩体的岩石学、矿物学特征进行了研究,并对岩浆结晶的物理化学条件、岩石成因和成矿意义进行了探讨。结果显示:早白垩世二长岩中角闪石化学成分显示:角闪石富钙(CaO 11.21%~11.78%)、富镁(MgO 13.61%~14.85%)、贫钠(Na2O 0.80%~1.11%)和贫钾(K2O 0.40%~0.54%),属于镁角闪石,结晶温度为704.92~805.58℃,平均温度为761.82℃,压力为73.83~115.93MPa,对应岩浆侵位深度为2.8~4.4km,结晶时岩浆氧逸度为△NNO+1.63,含水量为H2O=4.92%,反映出岩浆结晶时高温、高氧逸度、富含水分、浅侵位的特征。黑云母的Fe2+/(Fe2++Mg)比值比较均一,反映黑云母未遭受后期流体改造,均为原生岩浆成因的黑云母。其中早侏罗世花岗岩和二长岩所代表的A类黑云母化学成分上富铁(TFeO 19.92%~22.42%)贫镁(MgO 7.99%~10.46%),属于铁质黑云母,早白垩世二长岩和石英二长斑岩所代表的B类黑云母相比于A类黑云母更富镁(MgO 12.38%~14.45%)和钛(TiO21.90%~2.75%),贫铁(TFeO 16.64%~17.97%)和铝(Al2O315.00%~16%.79),属于镁质黑云母。A类和B类黑云母对应岩浆结晶温度分别为720~740℃和750~780℃;压力为202.20~443.49MPa和158~231MPa,对应岩浆侵位深度为6.67~14.64km和5.24~7.24km;结晶时岩浆氧逸度分别为10-15~10-16和10-12~10-13;岩浆来源为壳源,且B类黑云母对应岩浆有地幔物质参与。因此,可以认为二十一站岩体中早白垩世二长岩和石英二长斑岩具有中高温,高氧逸度应含水量,岩浆主要来源于地壳物质的部分熔融,并有部分地幔物质参与,侵位深度较浅的特点,具有形成大型斑岩矿床的潜力。早侏罗世花岗岩和二长岩氧逸度相对较低,侵位较深,物质来源为地壳,因此不具备成矿潜力。     

新疆和静县备战铁矿岩浆岩地球化学特征及意义

新疆和静备战铁矿地处新疆西天山阿吾拉勒山东段,矿区晚古生代岩浆岩发育,出露有钾长花岗岩和钾长花岗斑岩。地球化学特征表明,SiO2=74.24%~75.88%,里特曼指数σ=2.11~2.3,全碱含量(Na2O+K2O)为8.32~8.65,A/CNK=0.868~1.009,属准铝质岩类,属高钾钙碱性系列,I型花岗岩。微量元素特征显示其岩浆源区组成比较复杂,显示了地壳组分参与的影响。ΣREE=96.38×10-6~158.02×10-6,LREE富集,具明显的δEu负异常,δEu=0.07~0.29,δCe=0.54~1.17,LREE/HREE=3.897~12.02。其产出环境为后碰撞构造环境,其花岗岩源区为下部地壳。     

新疆东天山地区三岔口铜矿床的成因:岩石学、年代学和地球化学证据

三岔口铜矿床位于新疆东天山大南湖岛弧带的东北缘。目前对于三岔口铜矿床的成因类型及成矿年代还存在争议。三岔口铜矿床中赋矿岩体为闪长岩-花岗闪长岩,发育黑云母化、硅化、绢英岩化、青磐岩化等。测得三岔口铜矿床辉钼矿Re-Os年龄为416Ma±6.4 Ma,含矿闪长岩中锆石LA-ICP-MS U-Pb年龄为425 Ma±3.9 Ma,反映该矿床形成于中志留世。矿区内闪长岩-花岗闪长岩w(Na_2O+K_2O)为3.88%~4.68%,A/NCK值均大于1,为铝饱和岩石。岩体贫钾(w(K_2O)0.47%~1.18%)富钠(w(Na_2O)_2.83%~4.23%),w(TiO_2)偏低(0.41%~0.46%),多属于低钾拉斑系列。岩体富集w(Ba)(260×10~(-6)~4 810×10~(-6)),w(Sr)(644×10~(-6)~797×10~(-6))等大离子亲石元素,亏损w(Nb)(2.1×10~(-6)~2.6×10~(-6)),w(Ta)(0.1×10~(-6)),w(Zr)(11.2×10~(-6)~13.1×10~(-6))等高场强元素,具岛弧岩浆岩的特征。岩体富Na贫K,K_2O/Na_2O0.42,且具有高w(Al_2O_3)(≥16.65%),w(SiO_2)(≥61.3%),w(Sr)(≥644×10~(-6))以及较低的w(Y)(≤13.7×10~(-6))和w(Yb)(≤1.41×10~(-6)),具O型埃达克岩的特征,表明三岔口铜矿床形成于俯冲岛弧环境。结合研究区域内铜(钼)矿床的成矿时代及矿床类型,得出东天山地区有三期斑岩型矿床成矿作用:志留纪的三岔口、玉海斑岩型铜矿床,石炭纪的土屋-延东、延西等斑岩型铜矿床,以及三叠纪的东戈壁、白山斑岩型钼矿床。     

壳幔岩浆混合作用与陆内环境高Sr/Y斑岩的形成及成矿：实例与探讨

产于陆内环境的含矿斑岩往往具有高Sr/Y特征,多数学者认为与岩浆起源于加厚或拆沉的下地壳有关。然而,目前这一模式仍存在较大争议。本文以敖仑花斑岩矿床为例,新报道了矿区内不成矿岩体的岩石学和地球化学特征,与同期成矿岩体进行对比,探讨含矿斑岩高Sr/Y原因及控制是否成矿的可能因素。相对于含矿斑岩,敖仑花贫矿黑云母花岗岩具有高SiO2(74%~78%)、低MgO(0.2%)和CaO(0.2%~1.1%)、贫Sr(30×10-6~251×10-6)和Cr(1×10-6~6×10-6)的特征,显示准铝质到过铝质性质(A/CNK=0.9~1.2),Mg#值(2~30)与玄武岩实验熔体成份相似,说明岩浆可能主要来自基性下地壳源区的部分熔融。而已有的研究表明含矿斑岩为壳幔岩浆混合成因,富集地幔起源的偏基性岩浆的加入提升了寄主长英质岩浆的Mg#值、大离子亲石元素(Sr、La等)含量及其氧逸度(fO2)。我们认为幔源岩浆的混合可能是导致陆内环境含矿斑岩高Sr/Y及有利成矿的根本原因;相反,来自纯壳源的花岗质熔体因缺乏富水、高fO2幔源岩浆的参与而不利于形成斑岩Cu±Au±Mo矿床。     

云南凤庆邦漂地区花岗伟晶岩地球化学及其成因北大核心CSCD

滇西凤庆邦漂地区发育大量花岗伟晶岩脉,为揭示花岗伟晶岩脉群的成因和地球动力学背景,对其进行了全岩地球化学和锆石U-Pb年代学研究。伟晶岩样品具高硅(w(SiO_(2))=74.2%~78.6%,平均75.7%)、富碱(w(Na_(2)O+K_(2)O)=7.63%~11.11%,平均9.03%)、低镁值(Mg^(#)=16.6~39.0,平均28.6)、弱过铝质(A/CNK=0.85~1.12,平均1.01)特征,属弱过铝质高钾钙碱性—钾玄岩系列。样品具低固结指数(SI=0.44~1.02),高分异指数(DI=95.1~97.3),w(Ba)(18.600×10^(-6)~99.300×10^(-6))、w(Sr)(6.200×10^(-6)~13.200×10^(-6))、w(Ti)(42.430×10^(-6)~106.140×10^(-6))、w(Eu)(0.023×10^(-6)~0.065×10^(-6))元素负异常,Nb/Ta(3.48~10.37)、Zr/Hf(13.18~30.06)值明显低于球粒陨石和大陆地壳的相应比值特征,指示岩浆演化高分异特性;样品富含过铝质矿物白云母,弱过铝质和偏低的锆石饱和温度(平均666℃),总体与S型花岗岩特征吻合,综合表明其属高分异S型花岗岩。花岗伟晶岩结晶年龄为221.4±1.9 Ma,略晚于三叠纪花岗岩成岩年龄(239~224 Ma),与岩浆演化顺序一致;二者微量元素配分曲线相似,Ba,Sr和Eu亏损,在w(Zr)-w(Hf)图上呈线性正相关关系,反映二者存有亲缘关系。综上认为,花岗伟晶岩是三叠纪花岗岩晚期岩浆热液高度结晶分异的结果,起源于古元古代地壳(富黏土泥质岩)的部分熔融,形成于晚三叠世保山—思茅地块后碰撞阶段。     

安徽丁里岩体地质和地球化学特征及LA-ICP-MS锆石U-Pb年龄

安徽丁里岩体是徐淮地区出露规模最大的花岗岩体。LA-ICP-MS锆石U-Pb定年获得侵位年龄为(180±2.4)Ma,属于早侏罗世岩浆活动产物。岩体富硅[w(SiO_2)=76.10%～76.65%]、富碱[w(K_2O+Na_2O)=8.53%～8.56%]、贫钙[w(CaO)=0.39%～0.45%];稀土配分曲线呈现明显的Eu负异常(δEu=0.21～0.26);微量元素特征显示具有较高的Ga(23.0×10~(-6)～23.5×10~(-6))、Nb(46.7×10~(-6)～48.4×10~(-6))和Y(18.4×10~(-6)～20.7×10~(-6))含量,较低的Sr(10.7×10~(-6)～12.1×10~(-6))、Ba(10.7×10~(-6)～15.5×10~(-6))含量,在微量元素原始地幔标准化蛛网图上显示明显的Ba、Sr和Ti的负异常。以上特征表明:丁里花岗岩为A型花岗岩,可能是地幔玄武岩浆演化或玄武岩浆上升后受地壳不同程度混染或亏损地壳熔融的产物。丁里花岗岩是形成于造山后的伸展环境下的板内花岗岩。     

冈底斯带别若则错地区美苏组高Nb-Ta酸性火山岩锆石U-Pb年龄、地球化学特征及地质意义

别若则错地区美苏组构造上处于北冈底斯南缘,其中流纹岩的LA-ICP-MS锆石~(206)Pb/~(238)U年龄为39.62±0.77Ma,时代为晚始新世。岩石具高Si O_2(72.85%~78.54%)、富碱(Alk=6.36%~8.47%)、贫Ca O(0.33%~1.56%)和Mg O(0.08%~0.58%)特征,A/CNK=0.99~1.35,属于弱铝质-过铝质碱性系列。稀土元素总量为122.52×10~(-6)~208.35×10~(-6),(La/Yb)_N值为7.27~16.11,δEu=0.13~0.26,在球粒陨石标准化稀土元素分布模式上表现为Eu的右倾V字形。微量元素Nb(38.1×10~(-6)~88.7×10~(-6))、Ta(3.36×10~(-6)~6.35×10~(-6))高,Rb、K、Th、Ce、Zr、Hf相对富集,Ba、Sr、P、Ti强烈亏损。岩石地球化学特征表明,别若则错地区美苏组酸性火山岩"集壳幔特性于一身",是初始熔体为富碱和富Nb、Ta的幔源玄武质岩浆与壳源岩浆以某一特定比例混合/混染的产物。初步认为,美苏组酸性火山岩产出于大陆板内伸展(裂谷)环境,其地球动力学背景与南侧新特提斯洋壳向北俯冲,导致高原内部的陆内俯冲、走滑剪切与地壳缩短有关。     

长江中游鄂东南铜矿集区土壤铜环境地球化学特征

对鄂东南铜矿集区的山间谷地、长江冲积平原和低山丘陵三种地形土壤的系统测定表明：（1）土壤母质是影响土壤全量铜的主要因素，土壤有效态铜总体上受土壤全量铜的制约；在相同地理和气候条件下，土壤pH值是控制铜垂向分布的重要条件之一；中生代含铜花岗闪长岩是长江中游沿江铜矿庥区内区域土壤铜污染的主要自然源。（2）矿集区内土壤铜污染主要有自然污染和人为污染两类，两类土壤污染在土壤全量铜、有效态铜和铜含量垂向分布及土壤pH、R（电导）等理化性质方面有着明显的区别。     

西藏驱龙斑岩铜矿铜同位素研究

本文通过Cu的同位素组成示踪斑岩型铜矿床Cu的来源,探讨岩浆-热液过程中Cu同位素的分馏.选择驱龙矿区从早到晚的三期热液脉以及早期钾硅酸盐化蚀变同期的样品,挑选新鲜的黄铜矿,测定其Cu同位素组成.早期A脉:为不规则石英-钾长石脉、石英-硬石膏脉及黑云母脉,δ~(65)Cu的范围为-0.44‰～-0.09‰,集中在-0.44‰～-0.31‰,平均值-0.29‰;B脉,为石英+硬石膏+黄铜矿±辉钼矿±黄铁矿脉和绿帘石-石英脉,δ~(65)Cu的范围为-0.42‰～+0.14‰,集中在-0.25‰～-0.18‰,平均值-0.18‰;晚期D脉,为板状黄铜矿-黄铁矿及黄铁矿脉,δ~(65)Cu的范围为-0.27‰～+0.47‰,集中在-0.27‰～-0.05‰,平均值-0.02‰;早期钾硅酸盐蚀变带,δ~(65)Cu的范围为-0.47‰～-0. 1‰,平均值-0.29‰.矿区铜同位素组成基本同岩浆岩一致(Zhu et al.,2000,2002;Maréchal et al.,1999,2002),表明Cu主要来自斑岩岩浆.不同期次热液的Cu同位素具有明显的分馏,早期相对富集~(63)Cu,晚期相对亏损~(63)Cu,A脉与B脉的同位素组成的差异可能与岩浆-热液演化过程有关,D脉的同位素组成差异可能是大气降水大量混入的结果.     

Comparison of Cu,Zn and Fe bioleaching from Cu-metallurgical slags in the presence of Pseudomonas fluorescens and Acidithiobacillus thiooxidans

Metal leaching from metallurgical wastes (slags) by means of environmentally friendly approaches is promising for practical applications. The goal of this study was to compare the feasibility of metal bioleaching from Cu slags by means of Pseudomonas fluorescens and Acidithiobacillus thiooxidans. Two size particles (<0.3 mm and 1–2 mm) of two types of Cu slags (massive crystalline slag and granulated amorphous slag) were used to study metal (Cu, Zn and Fe) bioleaching. The 40-days bioleaching experiments with P. fluorescens began at circumneutral pH (7.0), whereas the experiments with A. thiooxidans were started under acidic (pH 2.5) conditions. The results demonstrated that A. thiooxidans catalyzes metal leaching from both slag types investigated. After 21 days of incubation, optimal leaching was achieved and up to 79% Cu, 76% Zn and 45% Fe could be extracted from crystalline slag under conditions of 1 wt.% pulp density and particle size <0.3 mm. The optimal efficiency achieved with amorphous slag was 81% Cu, 79% Zn and 22% Fe when 1% pulp density and 1–2 mm particle size were used. The use of P. fluorescens resulted in poor leaching efficiencies as compared to the performance of A. thiooxidans, presumably due to the higher pH conditions maintained during the P. fluorescens incubations. The maximum metal leaching efficiencies with P. fluorescens were achieved at 1% pulp density and particle size <0.3 mm and did not exceed 10% Cu, 4% Zn, 0.3% Fe for crystalline slag and 4% Cu, 3% Zn, 0.7% Fe for amorphous slag. Both slags exhibited a good potential for bioleaching with A. thiooxidans, however; further optimization of the process parameters (e.g. pulp density, particle size and pH) is needed to improve the efficiency.     

新疆东昆仑喀拉曲哈铜矿地球化学特征

喀拉曲哈铜矿是东昆仑西段古尔嘎金铜成矿远景区中的一个受断裂构造控制的蚀变岩型矿床，本文重点介绍了喀拉曲哈铜矿床的地球化学特征及矿床地质特征。     

西范坪斑岩铜矿的次生富集作用研究

通过对3000余米岩芯的观察研究。发现西范坪斑岩铜矿床存在完整的氧化带，氧化剖面由上向下可以分为氧化带，次生富集带和原生带。原生矿石的裂隙越发育，原生矿化强度越大，则其次生富集作用越发育。应用质量平均方法计算了氧化过程中铜的迁移规律，提出在次生富集作用中铜队了发生垂向（由上向下）迁移外，也存在侧向迁移（带入或带出）。在矿床中部，由于铜的垂向富集和侧向带入而形成富矿石和厚大矿体，因此次生富集对西范斑岩铜矿床富矿体的形成起到了重要的作用。     

Fluid Inclusion and Carbon-Oxygen Isotope Studies of the Hujiayu Cu Deposit, Zhongtiao Mountains, China: Implications for Syn-metamorphic Copper Remobilization

The Hujiayu Cu deposit,representative of the "HuBi-type" Cu deposits in the Zhongtiao Mountains district in the southern edge of the North China Craton,is primarily hosted in graphitebearing schists and carbonate rocks.The ore minerals comprise mainly chalcopyrite,with minor sphalerite,siegenite[(Co,Ni)_3S_4],and clausthalite[Pb(S,Se)].The gangue minerals are mainly quartz and dolomite,with minor albite.Four fluid inclusion types were recognized in the chalcopyrite-pyrite-dolomite-quartz veins,including CO_2-rich inclusions(type Ⅰ),low-salinity,liquid-dominated,biphase aqueous inclusions(type Ⅱ),solid-bearing aqueous inclusions(type Ⅲ),and solid-bearing aqueous-carbonic inclusions(type Ⅳ).Type I inclusion can be further divided into two sub-types,i.e.,monophase CO_2 inclusions(type Ⅰa) and biphase CO_2-rich inclusions(with a visible aqueous phase),and type Ⅲ inclusion is divided into a subtype with a halite daughter mineral(type Ⅲa) and a subtype with multiple solids(type Ⅲb).Various fluid inclusion assemblages(FIAs) were identified through petrographic observations,and were classified into four groups.The group-1 FIA,consisting of monophase CO_2 inclusions(type Ⅰa),homogenized into the liquid phase in a large range of temperatures from-1 to 28℃,suggesting post-entrapment modification.The group-2 FIA consists of type Ⅰb,Ⅲb and Ⅳ inclusions,and is interpreted to reflect fluid immiscibility.The group-3 FIA comprises type Ⅱ and Ⅲa inclusions,and the group-4FIA consists of type Ⅱ inclusions with consistent phase ratios.The group-1 and group-2 FIAs are interpreted to be entrapped during mineralization,whereas group-3 and group-4 FIAs probably represent the post-mineralization fluids.The solid CO_2 melting temperatures range from-60.6 to56.6℃ and from-66.0 to-63.4℃ for type Ⅰa and type Ⅳ inclusions,respectively.The homogenization temperatures for type Ⅱ inclusions range from 132 to 170℃ for group-3 FIAs and115 to 219℃ for group-4 FIAs.The halite melting temperatures range from 530 to 562℃ for typeⅢ b and Ⅳ inclusions,whereas those for type Ⅲa inclusions range from 198 to 398℃.Laser Raman and SEM-EDS results show that the gas species in fluid inclusions are mainly CO_2 with minor CH_4,and the solids are dominated by calcite and halite.The calcite in the hosting marble and dolomite in the hydrothermal veins have δ~(13)C_(V-pdb) values of-0.2 to 1.2‰ and-1.2 to-6.3‰,and δ~(18)O_(v-smow) values of 14.0 to 20.8 ‰ and 13.2 to 14.3‰,respectively.The fluid inclusion and carbon-oxygen isotope data suggest that the ore-forming fluids were probably derived from metamorphic fluids,which had reacted with organic matter in sedimentary rocks or graphite and undergone phase separation at 1.4-1.8 kbar and 230-240℃,after peak metamorphism.It is proposed that the Hujiayu Cu deposit consists of two mineralization stages.The early stage mineralization,characterized by disseminated and veinlet copper sulfides,probably took place in an environment similar to sediment-hosted stratiform copper mineralization.Ore minerals formed in this precursor mineralization stage were remobilized and enriched in the late metamorphic hydrothermal stage,leading to the formation of thick quartz-dolomite-sulfides veins.     

西准噶尔达尔布特南构造-岩浆岩带斑岩型铜-钼矿新发现及找矿思路

西准噶尔仅有较少的斑岩型多金属矿床产出,这与其所在的巨型中亚成矿域的哈萨克斯坦环巴尔喀什-新疆西准噶尔成矿省这一重要的构造部位可能并不相称,有必要深入成矿研究和拓宽找矿思路。近年来笔者在该区的区域地质矿产调查和关键岩体初步研究的基础上,新发现了本文报道的吐克吐克、宏远和红山铜-钼矿点。据此类矿点以及包古图斑岩铜金矿的时空分布和赋矿岩体岩石类型等,提出建立达尔布特南构造岩浆带斑岩型Cu-Mo成矿区这一思路。今后的找矿思路是加强该带斑岩体时空分布、岩石成因类型、成矿物质来源以及矿化特征、成矿对比、区域构造等研究,建立找矿模型,用模型指导勘探找矿,而非仅仅利用物化探异常或仓促的大量勘探进行工程验证。     

吉林长白-朝鲜惠山地区铜矿成矿特征及成因研究

吉林东南部长白地区与朝鲜惠山地区均位于元古宙辽吉裂谷内,地质背景相似.本文分析了我国临江铜矿与朝鲜惠山铜矿产出的地质背景,对地层、岩体、构造控矿进行了解析.研究认为临江铜矿为夕卡岩型铜矿,惠山铜矿具有斑岩型铜矿的地质特征,两铜矿同属斑岩-夕卡岩型成矿系统.指出长白沿江地区具有良好的找矿前景.今后找矿工作应注意：北西向、北东向断裂与近东西向断裂交汇部位矿化线索;燕山期中酸性侵入岩与前寒武纪地层接触部位矿化勘查以及斑岩型特征矿化蚀变的甄别.     

青海省兴海县赛什塘铜矿的斑岩型矿化特征及其找矿前景

青海省兴海县赛什塘铜矿床中局部具斑岩型矿化的特征,该矿区中酸性侵入岩发育并具明显的多期次和多类型.该类铜矿化发生于中-酸性岩浆侵入活动末期的闪长玢岩、花岗闪长斑岩、斜长花岗斑岩、石英斑岩、爆破角砾岩中,围岩蚀变强烈且具分带性.加强对蚀变闪长玢岩、花岗闪长斑岩、斜长花岗斑岩、石英斑岩、爆破角砾岩发育地段的找矿工作,有望实现本区找矿新突破.     

Biogeochemical studies of metallophytes from four copper-enriched sites along the Yangtze River, China

The area along middle and lower reaches of the Yangtze River is one of the biggest Cu belts in China. In the present study, the metallophytes growing in four copper (Cu)-enriched sites along the Yangtze River were surveyed to get detailed information about vegetation composition and their Cu uptake characteristics. In all sampling sites, Cu concentrations of soils were high; whereas the organic matter, acidity and salinity of most soils were on normal levels. Totally 82 plant species belonging to 45 families were recorded. All the species recorded in the present study exhibited high tolerances for Cu although they differed greatly in their abilities to accumulate Cu. Except for Rumex acetosa and Phytolacca acinosa, most species were Cu-excluders and no Cu hyperaccumulator was found. The Cu translocation factors (TFs) and bioconcentration factors (BCFs) of the 12 dominant species were fairly low, indicating low concentrations of Cu were translocated to the shoots of these species. On this basis, the potential utilization of these metallophytes for phytoremediation was discussed.