雷琼新生代玄武岩中地幔岩包体矿物中的流体—熔体包裹体的REE组成特征

雷琼地区新生代玄武岩中地幔岩包体的１２件单矿物稀土元素中子活化分析表明，雷州和琼北地幔岩包体中不含流体－熔体包裹体的同类矿物的ＲＥＥ组成有明显差异，反映了雷州与琼北玄武岩地幔源区ＲＥＥ组成的不均一性。通过对比同一地幔岩包体中含包裹体与不含包裹体相同矿物的微量元素组成，发现雷琼地幔岩包体矿物中的流体－熔体包裹体富含ＲＥＥ，尤其是ＬＲＥＥ；并且不同产地地幔包体同类矿物中和同一包体不同矿物中包裹体的丰度     

雷琼新生代玄武岩中地幔岩包体矿物中的流体─熔体包裹体的REE组成特征

雷琼地区新生代玄武岩中地幔岩包体的１２件单矿物稀土元素中子活化分析表明，雷州和琼北地幔岩包体中不含流体－熔体包裹体的同类矿物的ＲＥＥ组成有明显差异，反映了雷州与琼北玄武岩地幔源区ＲＥＥ组成的不均一性。通过对比同一地幔岩包体中含包裹体与不含包裹体相同矿物的微量元素组成，发现雷琼地幔岩包体矿物中的流体－熔体包裹体富含ＲＥＥ，尤其是ＬＲＥＥ；并且不同产地地幔包体同类矿物中和同一包体不同矿物中包裹体的丰度及其ＲＥＥ含量也有明显差异，表明地幔流体本身也存在不均一性。     

东太平洋海隆13°N附近分离结晶压力:模拟计算方法

在东太平洋海隆13°N附近在过去的30年里,尤其是在发现海底热液活动以来,对海隆内部玄武岩进行过大量详细的研究.研究表明洋中脊玄武岩地幔源区组成具有不一致性,并且即使在很小的区域范围玄武岩的同位素组成也表现具有差异性(Allègre和Condomines,1982;Niu,2002;Rudge等,2005;Anderson,2006).而一般地球化学家不倾向于利用微量元素限定地幔源区的微量元素的富集程度(O'Hara,2002),这是由于微量元素在岩浆过程中受到多种因素的影响,如:①地幔熔融程度,地幔熔融程度对不相容微量元素在熔体相中的富集程度影响很大,不同微量元素的相容性的差异性更增加了对地幔源区组成的不确定性;②参与部分熔融的地幔源区矿物组成的不确定性,在尖晶石一二辉橄榄岩源区微量元素的富集主要受控于单斜辉石的熔融程度;③地幔熔融的形式,分离部分熔融将比批式熔融对地幔不相容微量的亏损程度影响更大;④原始岩浆在迁移上升过程中受到岩浆分离结晶作用、岩浆混合及与围岩混染作用的影响.     

华北克拉通基性火山岩高场强元素对Ar-Pt界限及新生代地幔源区特征的示踪

华北克拉通不同时代基性火山岩存在向富集方向演化的趋势,并出现明显的Ａｒ－Ｐｔ界限和新生代异常．元古宙基性火山岩比太古宙富集大部分高场强元素（ＨＦＳＥ）和轻稀土元素（ＬＲＥＥ）,ＲＥＥ分异程度显著增加,而且相容性接近的不相容元素（如Ｎｂ,Ｔａ）的相对不相容性发生了改变．新生代玄武岩ＨＦＳＥ及Ｎｉ高度富集,ＲＥＥ强烈分异,δ（Ｅｕ）值最高．Ａｒ－Ｐｔ界限可能与地幔熔融时物理条件（如氧逸度）的改变和地幔富集作用有关．新生代玄武岩独特的地球化学特征可能主要反映了地幔源区的特殊性———“似ＯＩＢ型”富集地幔,其形成既可能有携带远洋沉积物的俯冲古老玄武岩洋壳部分熔融残余的贡献,也可能有直接循环（如通过拆沉作用）的陆壳物质的贡献,同时还可能涉及了地幔柱活动的影响．     

西南天山托云地区白垩纪-早第三纪玄武岩地球化学及其成因机制

托云玄武岩主要分布于托云盆地东侧，按形成时代可分为白垩纪玄武岩和早第三纪玄武岩。白垩纪玄武岩包括早白垩世玄武岩和晚白垩世玄武岩，以碱玄岩和碱性橄榄玄武岩为主，碱性程度高；早第三纪玄武岩包括早第三纪玄武岩及脉岩，以碱性橄榄玄武岩、碱性橄榄辉绿岩为主，碱性程度低。所有岩石稀土元素(REE)、微量元素分布模式相似，REE均为向右陡倾型，富集不相容元素。白垩纪玄武岩的∑REE、Rb、Ba、Th、K、Sr、Nb和Ta等元素富集程度均高于早第三纪玄武岩，相容元素富集程度大体较低。微量元素和同位素特征显示，玄武岩起源于与洋岛玄武岩源区相似的富集地幔源。玄武岩中赋存有交代地幔捕虏体，这表明玄武岩浆可能是交代地幔经不同程度部分熔融的产物。微量元素的特征同时显示，早白垩世玄武岩部分熔融程度较低，早第三纪玄武岩部分熔融程度较高，且在不断的部分熔融过程中，形成的岩浆又有结晶分异作用发生。托云玄武岩形成于大陆板内拉伸环境，在形成过程中经历了较弱的壳幔相互作用。     

中国东部新生代玄武岩的地球化学（Ⅱ）Sr、Nd、Ce同位素组成

对有代表性的中国东部新生代玄武岩的Ｓｒ、Ｎｄ和Ｃｅ同位素组成进行了系统的研究，结合系统的微量元素研究结果，进一步阐明其地幔源区同位素组成的不均一性；利用Ｃｅ、Ｎｄ同位素地球化学给出的信息，探讨富集Ⅰ型（ＥＭⅠ）地幔端元的成因。     

中国东部新生代玄武岩的地球化学（II）Sr,Nd,Ce同位素组成

对有代表性的中国东部新生代玄武岩的Ｓｒ、Ｎｄ和Ｃｅ同位素组成进行了系统的研究，结合系统的微量元素研究结果，进一步阐明其地幔源区同位素组成的不均一性；利用Ｃｅ、Ｎｄ同位素地球化学给出的信息，探讨富集Ｉ型（ＥＭ Ｉ）地幔端元的成因。     

六合—仪征第三纪碱性玄武岩的钕—锶同位素组成

本文报道了六合－仪征碱性玄武岩分布区１１个样品的同位素组成，１４３Ｎｄ／１４４Ｎｄ为０．５１２８４９～０．５１２９９３，８７Ｓｒ／８６Ｓｒ为０．７０３３６～０．７０４０４，类似于大洋玄武岩同位素体系中的ＰＲＥＭＡ地幔端元．玄武岩源区同位素和微量元素的解耦特征表明地幔源区演化的多阶段性。     

湘南汝城盆地火山岩岩石地球化学及其成因意义

汝城盆地基性火山岩系由辉绿岩、玄武岩和玄武质火山碎屑岩组成，属于低钾拉斑玄武岩系。基性火山岩系具有同一岩浆源区。岩石微量元素出现弱的LILE富集和Ta，Nb，Ti的亏损。强不相容元素比值反映岩浆源区明显偏离原始地幔组分，具有富集型异常地幔岩浆源区特征。岩浆源区同时受到地壳物质混染和来自先前消减残留板片流体或熔体交代的双重改造作用。在陆内拉张构造条件下富集型异常地幔岩浆源区的部分熔融是制约汝城盆地基性火山岩形成的主要因素。     

大别造山带南坡晚白垩世玄武岩源区地幔特征

大别造山带南坡中生代断陷盆地中出露大量晚白垩世碱性玄武岩类。因岩浆受结晶分异和陆壳混染影响微弱,其成分基本可代表本区原生玄武岩浆。在微量元素原始地幔标准化蛛网图上,本区玄武岩具有地壳富集组分Pb、K、Rb、Ba等的正异常和Nb、P、Hf等高场强元素的负异常。同位素和微量元素特征显示,玄武岩浆来自亏损地幔(DM)和富集地幔(EM+EM)混合源区。玄武岩源区地幔中Pb的富集和Nb、P、Hf等的亏损基本可由中国东部亏损地幔与榴辉岩的混合获得,由此揭示富集地幔端元组成特征可能与晚白垩世前造山带根部榴辉岩拆沉并参与地幔再循环有关。     

大别山北部饶拔寨超镁铁岩体微量元素地球化学

本文报道了饶拔寨超镁铁岩体的5个钻孔15个岩心样品的主量元素和微量元素成分。该岩体由上、下两部分构成。岩性以方辉橄榄岩为主，纯橄榄岩和二辉橄榄岩次之。主量元素成分表明岩体由饱满地幔经过不同程度部分熔融，形成了亏损程度不同的大陆岩石圈地幔。总体上下部岩体较上部亏损程度大。原始地幔标准化REE等不相容微量元素丰度模式表明岩体在熔融作用后又经过了地幔交代作用，形成不同程度LREE和LILE的富集。样品中有角闪石和金云母等含水矿物，表明有实性地幔交代作用。对比LREE与LILE的富集特征，表明可能有两类地幔交代作用，有两种不同性质的交代介质，LREE和Sr等的富集可能与硅酸盐熔体有关，而Rb、Ba、K等的富集可能与俯冲带流体活动有关。总体上下部岩体的交代作用较上部岩体的强。     

Partial melting below Tubuai (Austral Islands, French Polynesia)

Process identification diagrams based on trace element data show that mafic lavas from Tubuai, including alkali basalts, basanites, analcitites and nephelinites, result from different degrees of partial melting of an isotopically homogeneous mantle source. Our fractionation-corrected data are consistent with a batch melting model or a dynamic melting model involving a threshold value for melt separation close to 1% and degrees of melting ranging from 5–8% (alkali basalts) to 1.5–3% (nephelinites). The relative source concentration pattern, calculated using an inverse numerical method, shows an enrichment in highly incompatible elements. We propose that the Tubuai lava suite was derived from a two-stage partial melting process. Melting first affected the plume material located within the transition zone between garnet and spinel domains, producing alkali basalts and basanites. Then, the melting zone migrated upwards to the base of the overlying spinel-bearing lithospheric mantle, producing highly silica-undersaturated lavas. The lower lithosphere had previously been enriched by intrusion of pyroxenite veins representing plume-derived melts which percolated away from the main magma conduits. Received: 11 June 1996 / Accepted: 8 January 1997     

Xenolith evidence for lithospheric melting above anomalously hot mantle under the northern Canadian Cordillera

A comparison of mantle xenolith suites along the northern Canadian Cordillera reveals that the xenoliths from three suites exhibit bimodal populations whereas the xenoliths from the other four suites display unimodal populations. The bimodal suites contain both fertile lherzolite and refractory harzburgite, while the unimodal suites are dominated by fertile lherzolite xenoliths. The location of the three bimodal xenolith suites correlates with a newly discovered P-wave slowness anomaly in the upper mantle that is 200 km in width and extends to depths of 400–500 km (Frederiksen AW, Bostock MG, Van Decar JC, Cassidy J, submitted to Tectonophysics). This correlation suggests that the bimodal xenolith suites may either contain fragments of the anomalously hot asthenospheric mantle or that the lithospheric upper mantle has been affected by the anomalously hot mantle. The lherzolite xenoliths in the bimodal suites display similar major element compositions and trace element patterns to the lherzolite xenoliths in the unimodal suites, suggesting that the lherzolites represent the regional lithospheric upper mantle. In contrast, the harzburgite xenoliths are highly depleted in terms of major element composition, but their clinopyroxenes [Cpx] have much higher incompatible trace element contents than those in the lherzolite xenoliths. The major element and mildly incompatible trace element systematics of the harzburgite and lherzolite xenoliths indicate that they could be related by a partial melting process. The lack of textural and geochemical evidence for the former existence of garnet argues against the harzburgite xenoliths representing actual fragments of the deeper anomalous asthenospheric mantle. Furthermore, the calculated P-wave velocity difference between harzburgite and lherzolite end-members is only 0.8%, with the harzburgites having higher P-wave velocities. Therefore the 3% P-wave velocity difference detected teleseismically cannot be produced by the compositional difference between the lherzolite and harzburgite xenoliths. If temperature is responsible for the observed 3% P-wave velocity perturbation, the anomalous mantle is likely to be at least 200 °C higher than the surrounding mantle. Taken together these data indicate that the refractory harzburgite xenoliths represent the residue of 20–25% partial melting of a lherzolite lithospheric mantle. The incompatible trace element enrichment of the harzburgites suggests that this melting was accompanied by the ingress of fluids. The association of the bimodal xenolith suites with the mantle anomaly detected teleseismically suggests that anomalously hot asthenospheric mantle provided both the heat and volatiles responsible for the localized melting and enrichment of the lithospheric mantle. Received: 16 May 1997 / Accepted: 25 October 1997     

The Scourie dyke suite: Petrogenesis and geochemical nature of the Proterozoic sub-continental mantle

The petrogenesis of bronzite-picrite, olivine-gabbro, norite and quartz-tholeiite dykes, which make up the 2.39 b.y. Scourie dyke swarm cutting the Archaean Lewisian gneisses of N.W. Scotland, is interpreted on the basis of their major and trace element geochemistry. Most of the dykes bear primary amphibole and/or phlogopite and, with one exception, are all hypersthene- or quartz-normative. Apart from one tholeiite dyke which shows relative light rare-earth element depletion, all the dykes show enrichment in light rare-earths and large-ion lithophile elements. They do not however show an equivalent enrichment in other incompatible high field strength ions such as Nb and Ta, and in this respect resemble island arc and calc-alkaline basalts. The different dyke types have distinctive rare-earth patterns and other trace element ratios which are maintained over a range of major element compositions.Petrogenetic modelling of the major and trace element compositions of the various dykes demonstrates that very few can be related by fractional crystallisation. Indeed, even with partial melting mechanisms at least two different mantle sources, with different major and trace element compositons, are required to explain the compositional differences between the major dyke types. The high degrees of mantle melting implied for the generation of the magnesium-rich bronzite-picrites suggests that their rare earth and other trace element patterns closely reflect those of their mantle source. Similar arguments, though less well constrained, can be advanced for the other dyke types. The results suggest that the sub-continental mantle source feeding the dykes was heterogeneous with respect to both major and trace elements, and that their mantle sources must have been enriched in lithophile elements. Enrichment at the time the Lewisian gneisses were generated (i.e. 2.92 b.y. ago) would be compatible with the initial ⁸⁷Sr/⁸⁶Sr ratios of the dykes and the inferred Rb/Sr ratios of their mantle sources. The sub-continental mantle sources have thus retained the geochemical signature of the crustgenerating processes some 500 m.y. earlier.     

造山带中富集型上地幔的成因——以萨尔托海蛇绿岩块为例

发育于造山带中的蛇绿岩,其剖面下部的地幔橄榄岩部分是造山带地区富集型上地幔的直接标本。其地球化学特点是:主要元素Al_2O_3、TiO_2、CaO、Na_2O、K_2O强烈亏损,而REE,痕量元素和87Sr/86Sr则强烈富集;同时,143Nd/144Nd<0.511836,亦表明它们属于一个富集型的源区。 形成富集型上地幔的主要机制是地幔交代作用,富含不相容元素的低熔岩浆和富Ca-LREE流体与已亏损的地幔橄榄岩发生脉状交代和渗透交代反应,从而造成上地幔中不相容元素的富集。造山带富集型上地幔形成的构造环境是:洋壳从扩张脊向两侧运移并最终拼入造山带这段时间内。富集型上地幔不但存在于大陆区,而且亦存在于造山带地区,它可能是一种全球性的地球内部的化学作用。     

Trace Element Geochemistry of Tertiary Continental Alkali Basalts from the Liuhe—Yizheng Area,Jiangsu Province,China

Reported in this paper are the chemical compositions and trace element (REE,Ba,Rb,Sr,Nb,Zr,Ni,Cr,V,Ga,Y,Sc,Zn,Cu,etc)abundances of Tertiary continental alkali basalts from the Liube-yizheng area,Jiangsu Province,China.The olivine basalt,alkali olivine basalt and basanite are all derived from evolved melts which were once af-fected by different degrees of fractional crystallization of olivine and clinopyroxene(1:2)under high pres-sures.The initial melts were derived from the garnet lherzolite-type mantle source through low-degree par-tial melting.The mantle source has been affected by recent mantle-enrichment events(e.g.mantle metasomatism),resulting in incompatible trace element enrichment and long-term depletion of radiogenic isotopic compositions of Sr and Nd.     

西藏西南部休古嘎布蛇绿岩的成因:岩石学和地球化学证据

休古嘎布蛇绿岩块位于雅鲁藏布缝合带(YZSZ)西段,主要由地幔橄榄岩和侵入其中的基性岩墙所组成。基性岩墙具有弧后盆地地球化学亲缘性,其LREE亏损,(La/Yb)N为0.39~0.55;具有明显的Nb、Ti负异常及Sr、Ba正异常。Sr、Nd同位素特征表明它们起源于亏损地幔,并且受到了板片析出流体的影响。4个基性岩墙的Sm-Nd同位素样品获得内部等时线年龄为126.2±9.1Ma(MSWD=0.44)。地幔橄榄岩具有汤勺形和U形两组REE分布型式,显示出不同程度部分熔融和地幔交代作用的特征,具有弧-盆体系地球化学亲缘性。第一组橄榄岩的LREE弱富集或近于平坦,尖晶石的Cr#值低而且变化不大,部分熔融程度较低(15%~20%),可能形成于弧后扩张盆地;第二组橄榄岩的LREE明显富集,尖晶石的Cr#值高而且变化较大(0.4~0.77),部分熔融程度较高(25%~30%),并经历了强烈的交代富集作用,可能与洋内岛弧有关。     

Geochemistry and origin of basaltic lavas from Marquesas Archipelago,French Polynesia

The Marquesas Archipelago, a volcanic chain in French Polynesia (south-central Pacific Ocean), is predominantly composed of alkalic, transitional and tholeiitic basalts. The variation trends in these intraplate basaltic rocks imply that the magmas were derived from different upper mantle sources. Model calculations using the total inverse method show that the peridotite source of most Marquesas basalts was enriched in incompatible elements compared to a primordial mantle and had higher than chondritic ratios of several elements such as La/Yb, Ti/V and P/Ce. A metasomatic enrichment event is suggested by the sequence of element enrichment in the source relative to the primordial mantle (Ba>Nb>La>Ce>Sr>Sm>Eu> Zr>Hf>Ti>Y>Yb). On the other hand, some lavas including tholeiites of Ua Pou and alkalic basalts of Hiva Oa, were probably derived from relatively depleted upper mantle. In some islands such as Hatutu, the different types of basalts were generated from sources with rather similar compositions. The residual phases of the Marquesas magmas included garnet. The sources of these magmas were similar in trace element chemistry to the oceanic mantle below Hawaii.     

Geochemical variation in peridotite xenoliths and their constituent clinopyroxenes from Ray Pic (French Massif Central): implications for the composition of the shallow lithospheric mantle

Anhydrous mantle peridotite xenoliths from a single volcanic vent in the French Massif Central are compositionally varied, ranging from relatively fertile lherzolites to refractory harzburgites. Fertile lherzolites closely resemble previous estimates of undepleted mantle compositions but the average of the Ray Pic xenoliths is much less enriched in LILE and LREE than McDonough's (1990) average mantle [McDonough, W.F., 1990. Constraints on the composition of the continental lithospheric mantle. Earth Planet. Sci. Lett., 101, 1–18]. The wide geochemical variation in the bulk rocks reflects significant heterogeneities that can be attributed to two major processes within the shallow lithospheric mantle. The first process is depletion, related to variable degrees of partial melting and melt extraction from an originally near-chondritic mantle. This process has largely controlled the major elements and much of the trace element variation between fertile lherzolites and refractory peridotites. LREE-depleted compositions are also produced by this process. During partial melting, HREE behaved coherently with the major oxides and the moderately incompatible trace elements (Y, V and Sc). A subsequent process of enrichment is indicated by high concentrations of incompatible trace elements in many of the xenoliths. Sr, Ba, K, Th, U, Nb and LREE abundance are independent of major oxide variations and reflect enrichment related to infiltration by alkaline silicate melts/fluids. Both fertile and refractory mantle were enriched but harzburgites were particularly affected. Modal metasomatism occurred only rarely and is indicated by Cr-diopside-rich veins and patches in a few samples. Their chemistry suggests that they were also formed by migration of similar magmas/fluids from the asthenospheric mantle, although the presence of wehrlitic patches may indicate interaction with carbonate melts. In both depleted and enriched xenoliths, trace element patterns for separated clinopyroxenes closely reflect those of the bulk rock, except for Rb, Ba and Nb, which are probably hosted by other phases.     

俯冲循环组分对大洋地幔不均一性的定量约束

大洋地幔内部存在广泛的不均一性,其成因可有多种模式,其中俯冲循环作用对地幔组成的变化具有重要影响. 为明确各循环组分对亏损地幔的改造作用及其在富集源区中的相对贡献,系统总结了不同循环组分（远洋沉积物、俯冲洋壳、陆壳）的平均微量元素特征,计算了各循环组分在俯冲过程中经历的化学变化. 基于改造后的循环组分,开展与亏损地幔源区的混合和熔融模拟. 结果表明,HIMU型玄武岩可以由纯俯冲洋壳（≤10%）与亏损地幔（≥90%）混合形成的源区,经较低程度熔融（0.5%~1.5%）形成;而EMI型玄武岩可以由俯冲洋壳（≤10%）、俯冲剥蚀的下陆壳物质（≤3%）、亏损地幔（≥90%）混合形成的源区,经较低程度熔融（1%~2%）形成;EMII型玄武岩可以由俯冲洋壳（≤10%）、GLOSS-II（全球俯冲沉积物）或上陆壳物质（≤0.8%）与亏损地幔（≥90%）混合形成的源区,经较低程度熔融（1%~1.5%）形成.