澳大利亚西北陆架盆地天然气水合物成矿地质条件及资源潜力

澳大利亚西北陆架盆地已被证实具有丰富的油气资源,而天然气水合物的相关研究尚未开展。本文利用天然气水合物地震识别技术,同时结合对澳大利亚西北陆架盆地天然气水合物成矿地质条件的分析,认为澳大利亚西北陆架盆地天然气水合物储量巨大,初步估计天然气水合物分布区蕴含甲烷量达18万亿m3。澳大利亚西北陆架盆地的构造演化是天然气水合物成藏所具备物化条件的基础,因此是天然气水合物成矿的重要影响因素之一。     

印度克里希纳-戈达瓦里盆地天然气水合物饱和度特征

印度国家天然气水合物计划(NGHP01)于2016年实施第1次钻探,证实了天然气水合物在印度大陆边缘的广泛分布。选择位于克里希纳-戈达瓦里盆地(KG盆地)的NGHP01-07D和NGHP01-15A钻孔,基于测井数据和岩心样品估算天然气水合物饱和度,分析天然气水合物赋存状态并探讨其形成机制。基于各向同性介质模型利用电阻率和声波测井计算NGHP01-15A钻孔的天然气水合物饱和度为0. 2%～33. 0%,平均值为9. 6%,在NGHP01-07D钻孔利用电阻率计算获得的天然气水合物饱和度高于岩心氯离子异常和气体释放获得的结果,但是基于各向同性岩石物理模型利用声波测井计算的天然气水合物饱和度与岩心结果一致,平均值为5. 0%。前人研究认为NGHP01-10D钻孔中天然气水合物以相对较高饱和度富集在高角度裂隙中。结合前人研究结果推断在克里希纳-戈达瓦里盆地存在3种不同的天然气水合物储层,即泥岩中砂质夹层各向同性储层、泥质/粉砂质高角度低连通性的低饱和度裂隙储层和泥岩中高角度高连通性的高饱和度裂隙储层,并提出对应的3种天然气水合物储层模型。     

琼东南盆地深水区浅层运聚系统及其对天然气水合物成藏的控制

以琼东南盆地连片三维地震资料为基础,精细识别盆地浅层多种类型运移通道,系统总结了盆地深水区浅层运聚系统发育特征,并探讨其对天然气水合物成藏的控制,预测了天然气水合物有利目标区。研究结果表明:琼东南盆地浅层运移通道主要包括断层、气烟囱、裂隙、大型侵蚀不整合面和盆缘大型储集体,多种类型运移通道空间上相互组合,共同构建成盆地浅层流体运聚系统;不同区域浅层流体运移通道发育程度不一样,陵南-松南低凸起浅层流体运移通道最为发育,中央坳陷发育程度次之,浅水区相对不发育;琼东南盆地深水区浅层流体运聚系统控制着天然气水合物的分布,对中深层天然气勘探也具有重要的指示作用。总之,琼东南盆地浅层流体运移通道较发育,其中最为发育的陵南-松南低凸起是盆地天然气水合物规模成藏最为有利的场所,松南-宝岛凹陷陆坡区也具备优越的水合物成藏条件。     

天然气水合物的地球物理识别技术

地球物理识别技术是天然气水合物识别技术中的重要技术,即以自然界天然气水合物的赋存模型为指导,以含天然气水合物沉积层的岩石物性分析为基础,以地质、地球物理模式为桥梁,以现代计算机技术为手段,用地震正、反演的方法系统地、定量地研究各种天然气水合物地震标志(如BSR)的形成原因和形成机理,为天然气水合物的地球物理识别提供科学依据。     

基于深水区宽频地震的天然气水合物识别方法

仅利用地震似海底反射(BSR)识别琼东南盆地深水区天然气水合物存在一定的局限性,从而影响天然气水合物的勘探成效。笔者利用天然气水合物已钻井数据,分析该盆地深水区天然气水合物岩石弹性参数特征,用以查明天然气水合物的岩石物理规律;同时,利用地震正演模拟,明确了研究区发育的孔隙型、烟囱型水合物的地震反射特征。在此基础上,利用AVO正演判识真假BSR:天然气水合物底界面反射具有Ⅲ类AVO且存在AVO异常,此为真BSR反射;而块体流(MTD)底界面虽类似BSR反射,但其AVO为Ⅳ类且AVO无异常特征。利用宽频地震数据和三维地震速度体进行速度模型下的宽频确定性反演,并通过高速异常、高阻抗异常描述天然气水合物发育情况。总之,利用地震反射特征、AVO特征、无井宽频地震反演等手段,实现了琼东南盆地深水区多种类型天然气水合物的地震识别,判识圈定了水合物矿藏。     

测井技术在水合物储层识别中的应用前景

海洋天然气水合物是一种潜在的巨大能源。地球物理测井在天然气水合物探测与储量评价领域发挥了重要作用,并且随着以勘探天然气水合物为目的的钻井数量的增多日益受到重视。主要介绍了常规测井方法、成像测井和核磁测井在识别天然气水合物储层中的应用,发展海洋天然气水合物的识别技术,准确了解天然气水合物的分布与蕴藏量,对我国海洋天然气水合物产业的建立具有关键作用。     

海洋沉积物的磁化率——天然气水合物的新指标

天然气水合物是21世纪最具开发潜力的新型能源。它在低温、高压条件下稳定存在,主要分布于大陆边缘、深水盆地及冻土带,在环境和灾害等方面都具有重要影响。目前,人们已发展了地质、地球物理、地球化学等多种天然气水合物的识别方法和指标,但不同的方法或指标具有各自的局限性和适用范围,同时天然气水合物是否存在也需要多种识别技术的集成...     

海洋天然气水合物合成的模拟实验研究

为了研究海洋天然气水合物生成过程中元素的地球化学行为,研制了一套天然气水合物实验装置和一套实验流程.利用这套实验装置,在天然海水-甲烷体系中合成天然气水合物.探讨了不同影响因素,包括温度、压力、振动、过滤方式等对天然气水合物合成实验结果的影响.     

海洋天然气水合物的地球物理勘探技术

天然气水合物将成为21世纪的替代能源，地球物理方法是勘探天然气水合物的重要手段。本文比较全面地分析和总结了天然气水合物的各种地球物理识别技术以及地震资料的特殊处理和分析方法，详细地介绍了水平地震剖面、垂直地震剖面、测井以及旁侧声纳剖面上天然气水合物的表现和识别方法。特别地，针对海洋地震资料的特点以及天然气水合物在地震剖面上的识别标志BSR、振幅空白带等特征，文章引入了真振幅处理、子波处理以及多项式拟合等处理方法来提高天然气水合物识别标志在地震剖面上的显示效果。最后，为了全面了解海底天然气水合物的分布 以及微细结构，文章介绍了AVO分析、全波形反演速率分析、叠加速度分析和走时反演等正、反演技术。     

珠江口和琼东南盆地天然气水合物形成和稳定分布的地球化学边界条件及其分布区

通过对南海北部陆缘珠江口和琼东南盆地气田的天然气形成水合物的地球化学计算模拟及地质地球化学条件分析，对珠江口和琼东南盆地天然气形成水合物的地球化学边界条件及分布区进行了研究。认识到南海北部陆缘琼东南和珠江口盆地内的断裂构造是天然气向海底渗漏的通道，为天然气水合物在海底的形成提供了物源；盆地内巨厚的第四纪富有机质沉积也为天然气水合物形成提供了充足的细菌成因生物气源。在海底温度2－16℃范围内，琼东南盆地气田10种天然气和珠江口盆地气田18种天然气形成水合物的压力有比较大的范围，随温度增高，天然气水合物形成的压力增高；盆地间和各天然气样品之间形成水合物的压力均是不一致的。在南海海水平均盐度3．4％条件下，结合海底温度与水深变化资料，珠江口和琼东南盆地天然气水合物形成和稳定分布的海区是不同的，珠江口盆地小于230m水深的海区没有天然气水合物的形成，在230－760m水深的海区可能有天然气水合物的存在，天然气水合物的稳定分布区应该在大于860m水深的深水区；在琼东南盆地水深小于320m的海区不可能有天然气水合物的形成，在320－650m水深的海区可能有天然气水合物的存在，大于650m水深的海区是天然气水合物的稳定分布区。     

Fracture characteristics and stress directions in the quaternary sediments of the Ulleung Basin,East Sea: Based on resistivity image log data

Abstract

Geophysical evidence indicating the presence of gas hydrate has been found in the Ulleung Basin, which lies off the east coast of the Korean Peninsula; however, hydrate distribution in the basin is not well understood. Logging-while-drilling data for 13 sites in the Ulleung Basin, East Sea, were obtained to investigate the distribution pattern of gas hydrate. Most of the sites yielded log data indicating the presence of gas hydrate. Prominent fractures (both resistive and conductive fractures) were clearly identified on the resistivity borehole images, particularly at seismic chimney sites. Resistive fractures, which contain large amounts of gas hydrate, are prominent in the seismic chimney sites. The strike and dip of each fracture was calculated and displayed on a stereographic plot and rosette diagram. From the fracture orientations on the stereographic plots, the maximum horizontal stress is NW–SE, reflecting the regional stress regime around the Ulleung Basin, although the fracture orientations are broadly distributed, indicating that the fracture pattern is not well-ordered on the rosette diagram. The fracture dips are between 36.46° and 63.66°; the range of dip azimuths is 0.94°–359°, and exhibit little change with depth. The dip azimuths are generally westerly to southwesterly.     

Time–frequency spectral signature of Pelotas Basin deep water gas hydrates system

Pelotas Basin has the largest gas hydrate occurrence of the Brazilian coast. The reserves are estimated in 780 trillion cubic feet, covering an area of 45,000 km². In this work we apply spectral decomposition technique in order to better understand a gas hydrate deep water system, performing a continuous time–frequency analysis of seismic trace, where frequency spectrum is the output for each time sample of the seismic trace. This allows a continuous analysis on the effects of the geologic structures and lithology over frequency content of the seismic wave. Spectral anomalies found were interpreted as variations of hydrates concentration inside the Gas Hydrate Stability Zone (GHSZ), as well free gas accumulations beneath and Below the GHSZ and gas chimneys. We concluded that this technique has a good potential to assist seismic study of structures associated with gas hydrates accumulations.     

Seismic imaging of a fractured gas hydrate system in the Krishna–Godavari Basin offshore India

Gas hydrate was discovered in the Krishna–Godavari (KG) Basin during the India National Gas Hydrate Program (NGHP) Expedition 1 at Site NGHP-01-10 within a fractured clay-dominated sedimentary system. Logging-while-drilling (LWD), coring, and wire-line logging confirmed gas hydrate dominantly in fractures at four borehole sites spanning a 500 m transect. Three-dimensional (3D) seismic data were subsequently used to image the fractured system and explain the occurrence of gas hydrate associated with the fractures. A system of two fault-sets was identified, part of a typical passive margin tectonic setting. The LWD-derived fracture network at Hole NGHP-01-10A is to some extent seen in the seismic data and was mapped using seismic coherency attributes. The fractured system around Site NGHP-01-10 extends over a triangular-shaped area of ∼2.5 km² defined using seismic attributes of the seafloor reflection, as well as “seismic sweetness” at the base of the gas hydrate occurrence zone. The triangular shaped area is also showing a polygonal (nearly hexagonal) fault pattern, distinct from other more rectangular fault patterns observed in the study area. The occurrence of gas hydrate at Site NGHP-01-10 is the result of a specific combination of tectonic fault orientations and the abundance of free gas migration from a deeper gas source. The triangular-shaped area of enriched gas hydrate occurrence is bound by two faults acting as migration conduits. Additionally, the fault-associated sediment deformation provides a possible migration pathway for the free gas from the deeper gas source into the gas hydrate stability zone. It is proposed that there are additional locations in the KG Basin with possible gas hydrate accumulation of similar tectonic conditions, and one such location was identified from the 3D seismic data ˜6 km NW of Site NGHP-01-10.     

Mass-transport deposits and gas hydrate occurrences in the Ulleung Basin,East Sea – Part 2: Gas hydrate content and fracture-induced anisotropy

Mass-transport-deposits (MTDs) and hemipelagic mud interbedded with sandy turbidites are the main sedimentary facies in the Ulleung Basin, East Sea, offshore Korea. The MTDs show similar seismic reflection characteristics to gas-hydrate-bearing sediments such as regional seismic blanking (absence of internal reflectivity) and a polarity reversed base-reflection identical to the bottom-simulating reflector (BSR). Drilling in 2007 in the Ulleung Basin recovered sediments within the MTDs that exhibit elevated electrical resistivity and P-wave velocity, similar to gas hydrate-bearing sediments. In contrast, hemipelagic mud intercalated with sandy turbidites has much higher porosity and correspondingly lower electrical resistivity and P-wave velocity.At drill-site UBGH1-4 the bottom half of one prominent MTD unit shows two bands of parallel fractures on the resistivity log-images indicating a common dip-azimuth direction of about ∼230° (strike of ∼140°). This strike-direction is perpendicular to the seismically defined flow-path of the MTD to the north-east. At Site UBGH1-14, the log-data suggest two zones with preferred fracture orientations (top: ∼250°, bottom: ∼130°), indicating flow-directions to the north-east for the top zone, and north-west for the bottom zone. The fracture patterns may indicate post-depositional sedimentation that gave rise to a preferred fracturing possibly linked to dewatering pathways. Alternatively, fractures may be related to the formation of pressure-ridges common within MTD units.For the interval of observed MTD units, the resistivity and P-wave velocity log-data yield gas hydrate concentrations up to ∼10% at Site UBGH1-4 and ∼25% at Site UBGH1-14 calculated using traditional isotropic theories such as Archie's law or effective medium modeling. However, accounting for anisotropic effects in the calculation to honor observed fracture patterns, the gas hydrate concentration is overall reduced to less than 5%. In contrast, gas hydrate was recovered at Site UBGH1-4 near the base of gas hydrate stability zone (GHSZ). Log-data predict gas hydrate concentrations of 10–15% over an interval of 25 m above the base of GHSZ. The sediments of this interval are comprised of the hemipelagic mud and interbedded thin sandy turbidites, which did contain pore-filling gas hydrate as identified from pore-water freshening and core infra-red imaging. Seismically, this unit reveals a coherent parallel bedding character but has overall faint reflection amplitude. This gas-hydrate-bearing interval can be best mapped using a combination of regular seismic amplitude and seismic attributes such as Shale indicator, Parallel-bedding indicator, and Thin-bed indicator.     

Potential for gas hydrate formation at the northwest New Zealand shelf margin - New insights from seismic reflection data and petroleum systems modelling

In this study we provide evidence for methane hydrates in the Taranaki Basin, occurring a considerable distance from New Zealand's convergent margins, where they are well documented. We describe and reconstruct a unique example of gas migration and leakage at the edge of the continental shelf, linking shallow gas hydrate occurrence to a deeper petroleum system. The Taranaki Basin is a well investigated petroleum province with numerous fields producing oil and gas. Industry standard seismic reflection data show amplitude anomalies that are here interpreted as discontinuous BSRs, locally mimicking the channelized sea-floor and pinching out up-slope. Strong reverse polarity anomalies indicate the presence of gas pockets and gas-charged sediments. PetroMod™ petroleum systems modelling predicts that the gas is sourced from elevated microbial gas generation in the thick slope sediment succession with additional migration of thermogenic gas from buried Cretaceous petroleum source rocks. Cretaceous–Paleogene extensional faults underneath the present-day slope are interpreted to provide pathways for focussed gas migration and leakage, which may explain two dry petroleum wells drilled at the Taranaki shelf margin. PetroMod™ modelling predicts concentrated gas hydrate formation on the Taranaki continental slope consistent with the anomalies observed in the seismic data. We propose that a semi-continuous hydrate layer is present in the down-dip wall of incised canyons. Canyon incision is interpreted to cause the base of gas hydrate stability to bulge downward and thereby trap gas migrating up-slope in permeable beds due to the permeability decrease caused by hydrate formation in the pore space. Elsewhere, hydrate occurrence is likely patchy and may be controlled by focussed leakage of thermogenic gas. The proposed presence of hydrates in slope sediments in Taranaki Basin likely affects the stability of the Taranaki shelf margin. While hydrate presence can be a drilling hazard for oil and gas exploration, the proposed presence of gas hydrates opens up a new frontier for exploration of hydrates as an energy source.     

南海北部揭阳凹陷天然气水合物的地震异常特征分析

大量研究表明南海北部珠江口盆地是天然气水合物发育区,但是该盆地东部揭阳凹陷水合物研究较少。本文利用揭阳凹陷新采集三维地震资料,对该三维地震资料进行成像道集优化和叠前时间偏移处理,得到针对水合物的新处理地震数据体,并通过高精度网格层析反演得到层速度数据体。利用该数据开展叠后约束稀疏脉冲反演,获得含天然气水合物地层波阻抗异常,综合分析反演与地震属性识别水合物。从新处理地震资料看,该区域似海底反射(bottom simulation reflection,BSR)反射呈连续、不连续与地层斜交等特征,BSR发育在一个继承性小型水道上,且下部断裂和气烟囱发育。通过分析BSR特征及BSR上下地层的速度、波阻抗、振幅、频率、相干等属性异常,结合水合物成藏条件,发现了南海北部新的天然气水合物有利富集区,为该区域水合物勘探提供基础。     

Geothermal modeling of the gas hydrate stability zone along the Krishna Godavari Basin

A wide-spread bottom simulating reflector (BSR), interpreted to mark the thermally controlled base of the gas hydrate stability zone, is observed over a close grid of multichannel seismic profiles in the Krishna Godavari Basin of the eastern continental margin of India. The seismic data reveal that gas hydrate occurs in the Krishna Godavari Basin at places where water depths exceed 850 m. The thickness of the gas hydrate stability zone inferred from the BSR ranges up to 250 m. A conductive model was used to determine geothermal gradients and heat flow. Ground truth for the assessment and constraints on the model were provided by downhole measurements obtained during the National Gas Hydrate Program Expedition 01 of India at various sites in the Krishna Godavari Basin. Measured downhole temperature gradients and seafloor-temperatures, sediment thermal conductivities, and seismic velocity are utilized to generate regression functions for these parameters as function of overall water depth. In the first approach the base of gas hydrate stability is predicted from seafloor bathymetry using these regression functions and heat flow and geothermal gradient are calculated. In a second approach the observed BSR depth from the seismic profiles (measured in two-way travel time) is converted into heat flow and geothermal gradient using the same ground-truth data. The geothermal gradient estimated from the BSR varies from 27 to 67°C/km. Corresponding heat flow values range from 24 to 60 mW/m². The geothermal modeling shows a close match of the predicted base of the gas hydrate stability zone with the observed BSR depths.     

Multiple seismic attribute analyses for determination of bottom simulating reflector of gas hydrate seismic data in the Ulleung Basin of Korea

The bottom simulating reflector (BSR), the boundary between the gas hydrate and the free gas zone, is considered to be the most common evidence in seismic data analysis for gas hydrate exploration. Multiple seismic attribute analyses of reflectivity and acoustic impedance from the post-stack deconvolution and complex analysis of instantaneous attribute properties including the amplitude envelope, instantaneous frequency, phase, and first derivative of the amplitude of seismic data have been used to effectively confirm the existence of a BSR as the base of gas hydrate stability zone. In this paper, we consider individual seismic attribute analysis and integrate the results of those attributes to locate the position of the BSR. The outputs from conventional seismic data processing of the gas hydrate data set in the Ulleung Basin were used as inputs for multiple analyses. Applying multiple attribute analyses to the individual seismic traces showed that the identical anomalies found in two-way travel time (TWT) between 3.1 and 3.2 s from the results of complex analyses and l ₁ norm deconvolution indicated the location of the BSR.     

南海神狐水合物钻探区不同形态流体地震反射特征与水合物产出的关系

天然气水合物的分布在很大程度上受到含气流体运移的影响。南海北部陆坡区,尤其是珠江口盆地的白云凹陷,普遍存在流体渗漏的现象,暗示了水合物赋存的良好前景。神狐海域水合物钻探区内的高分辨率地震资料显示,区域内发育大量流体运移通道,在地震剖面上表现为不同形态的地震反射模糊带,根据其形态特征,可以划分为花冠状和穹顶状两大类模糊反射带。模糊反射带的存在意味着研究区内具有良好的含气流体运移条件,能够为甲烷气体的垂向运移提供通道。神狐海域水合物的钻探结果表明,水合物的分布与模糊反射带的分布范围具有良好的空间匹配关系,其中,花冠状地震反射模糊带侧翼部与中尺度正断层相连,促进了含气流体的侧向运移,顶部与可能的微裂隙相通,气体可向上运移至水合物稳定带,形成了水合物藏;而穹顶状地震反射模糊带顶部则通过疑似流体通道与海底沟通,这种结构极易形成气体逃逸而无法形成水合物。因此,不同形态特征的模糊反射带可能对水合物的分布具有一定的指示意义。     

Reservoir characterization of gas hydrate in the Northwestern part of the Ulleung Basin,East Sea

An analysis of 3D seismic data from the northwestern part of the Ulleung Basin, East Sea, revealed that the gas hydrate stability zone (GHSZ) consists of five seismic units separated by regional reflectors. An anticline is present that documents activity of many faults. The seismic indicators of gas hydrate occurrence included bottom simulating reflector (BSR) and acoustic blanking in the gas hydrate occurrence zone (GHOZ). By the analysis of the seismic characteristics and the gradient of the sedimentary strata, the GHOZ was divided into four classes: (1) dipping strata upon strong BSR, (2) dipping strata below strong BSR, (3) parallel strata with acoustic blanking, and (4) parallel strata below weak BSR. Seismic attributes such as reflection strength and instantaneous frequency were computed along the GHOZ. Low reflection strength and high instantaneous frequency were identified above the BSR, indicating the occurrence of gas hydrate. A remarkably high reflection strength and low instantaneous frequency indicated the presence of free gas below the BSR. Considering the distribution of the gas hydrate and free gas, two gas migration processes are suggested: (1) stratigraphic migration through the dipping, permeable strata and (2) structural migration from below the GHSZ along faults.