离子水合力与电荷号大小的顾函数标度

“水汽化学”这一门新科学已由顾宏堪实验室通过超痕量分析发现并创立。顾函数表明,水蒸发为水汽时携带的痕量金属离子的浓度,正相关于比电子亲和常数Iz／Z,负相关于离子体积V和配位数N。而这一键参数函数相当于量子力学Schrodinger方程中的电子位函数。同为正二价的不同离子,水一汽转移的浓度可以有较大的差异,表明不同的正二价离子与水的引力（水合力）有所不同,此差别可通过顾函数以相对能量值或“＋”号的大小标出。     

海水中铋(Ⅲ)的微分电位溶出分析

利用微分电位溶出分析法研究了海水中痕量铋（III）的最适测定条件。结果表明，实验条件选择电解电位（E）为-1．10V，溶出上限电位（E上）为-0.70V，溶出下限电位（E下）为-0．00V，工作电极旋转速度2500rpm.洗电极时间和富集时间分别为30s和600s。适宜的盐度和酸度为5．8－29．0×10-2mol／L和1．00-2.00×10-mol／LHNO3。对在海水中加入5μg／L铋（III）的样品8次测定的相对标准偏差为53％。校正曲线方程为Y=4.77＋55X,相关系数（γ）为0．9993。对青岛沿岸海水测定的加入回收率为96．5％。1994年利用该方法测定青岛沿岸海水中铋（III）的浓度为0．017－0．103μg／L。     

有机锡对海洋微藻的生理效应 Ⅰ.三苯基锡和三丁基锡对光合色素含量的影响

于1991年4月－1992年五月，以金藻和扁藻为材料，用室内一次培养法研究三苯基锡（TPTC）和三丁基锡（TBTC）化合物对光合色素含量的影响。结果表明，两种有机锡对两种藻均有影响，在0．2—0．4μg／L的浓度时有轻微毒性；浓度大于0．5μg／L时，能使光合色素明显减少。对于两种藻叶绿素a72hEC50影响结果：TBTC和TPTC对金藻的均为0．59μg／L；对扁藻的，TBTC是0．87μg／L，而TPTC本出现半效应浓度。对于两种藻的类胡萝卜素72hEC50影响结果：金藻，TPTC是0．57μg／L，TBTC是0．49μg／L；扁藻，TBTC是0．89μg／L，TPTC也未出现半效应浓度。认为，两种有机锡对光合色素有明显的破坏作用。     

水样及生物体内微量锌、锰、硒的极谱催化波同时测定

本文提出了在酒石酸盐-乙二胺-高氯酸-亚硫酸钠-高碘酸钾-EDTA体系中同时测定微量锌、锰、硒的极谱催化波，波峰敏锐，波形稳定。Zn2 浓度在0．4～40μg／dm3，Mn2 浓度在1．6～80μg／dm3，Se（Ⅳ）浓度在0．02～3．0μg／dm3范围内浓度与峰电流呈线性关系。取天然水样平行12份测定，变异系数在10％以内。     

饵料密度、温度和体质量对大西洋浪蛤滤水率的影响

2004年4月～7月采用实验生态学方法对浙江引种养殖的大西洋浪蛤（Spisula solidissima）繁殖培育的一龄蛤进行滤水率的研究。结果表明：（1）以新月菱形藻为饵料，在适宜的饵料密度范围内大西洋浪蛤的滤水率随着饵料密度的增加而增大，它们之间呈函数关系；（2）体质量对滤水率的影响呈幂函数关系y=0．1622W^0.848（R^2=0．9988）；（3）在一定温度范围内，随温度升高滤水率增加；超过一定温度范围，随温度升高滤水率下降。当温度为21℃时滤水率达到最大值0．77L／h。     

氮磷营养盐与有机汞联合作用对微氏海链藻生长的影响

探讨在高营养盐（氮、磷、硅分别为浮游植物生长的营养盐阚值≥40、50、9倍）条件下，氮浓度及氮磷摩尔比值[n（N）／n（P）]变化、汞（甲基汞和乙基汞）对微氏海链藻（Thalassiosira weissflogii）生长的影响。结果表明，高营养盐区海链藻的生长遵循营养盐限制的唯一因子论；氮浓度和氮磷比提高促进生长，当n（N）／n（P）=64则呈抑制效应；生长初期，甲基汞和乙基汞均产生毒性抑制作用，生长中后期，适量甲基汞（浓度≤1．0μg／L）、乙基汞（浓度≤0．5μg／L）却呈兴奋效应，促进生长；汞形态不同，剂量-效应关系不同。氮和有机汞是海链藻生长的刺激因子。适度有机汞污染与氮富营养化对微氏海链藻的生长产生协同效应。     

原始天然水由Zn2+等饱和的水蒸气形成

顾等分析表明[1,2,7],中国近海天然海水和河水痕量Zn2+等离子的浓度是相近似的,从而判断天然水蒸发循环时必然带着这些离子;离子与悬浮体之间在天然水pH条件下没有重要的平衡转移;离子随水循环可能是水的携带,不依于离子本身的蒸发能。     

青岛湾潮间带沉积物中叶绿素的分析

为了解潮间带沉积物中底栖微藻的现存状况，于2003年10月至2004年4月，分4次测定分析了青岛湾潮间带沉积物中的叶绿素a和脱镁叶绿酸含量。结果表明，0-2cm层沉积物中叶绿素a的含量在1．73-5．71μg/g，脱镁叶绿酸含量在0．02-1．89μg／g，2-5cm层沉积物中叶绿素a的含量在0．51-4．32μg/g，脱镁叶绿酸含量在0．12-1．58μg/g。随深度增加，叶绿素含量减少；叶绿素a是主要存在形式，脱镁叶绿酸含量占叶绿素a含量的10％-75％；同时分析了水质和沉积物粒度对叶绿素含量的影响，结果表明叶绿素的含量和组成比例与水质有关；粒度越细的沉积物，叶绿素含量较高而且稳定。     

正己烷/海水微乳液形成的相图研究

用相图方法研究正己烷／海水微乳液的形成。体系相图由水（或人工海水，盐度分别为０，１３．６９６，３０．０７０和４１．１１８）／油（正己烷）／表面活性剂（ＡＳ，ＣＴＡＢ及ＢＲＩＪ３５）／助表面活性剂（正丁醇）在４０℃时构成。分别研究表面活性剂类型，油及醇含量和海水盐度对微乳液形成的影响。结果表明：醇与表面活性剂的摩尔浓度比值大于１时，最适宜于形成微乳液；形成微乳液区的面积随正己烷含量增加而减少；含离子     

象山港潮滩底栖微型藻类现存量和初级生产力

作者于1992年2、5、6、8和10月在象山港湖头渡,5月和6月在大佳河（港顶部）、西沪港（港中部）和横山（近港口区）4条断面潮滩进行了底栖微型藻现存生物量和初级生产力的观测研究．结果表明,潮滩表层叶绿素a浓度分布具有明显的空间区域性和时间变异性特征．港顶部的浓度高于港中部和近港口区;滩面表层的平均叶绿素a浓度,5月[（10．36±8．08）μg／g湿重]高于6月[（2．94±1．21）μg／g湿重]．由于光的限制,沉积物中的叶绿素a主要分布在表层0～1cm,随深度的增加浓度下降,但其降解产物──脱镁叶绿素的浓度却增大．松软、平整、稳定的滩面有利于底栖微型藻类的生长,5、6月湖滩表层平均初级生产力为（45．1±46．8）mg／（m2·h）（C）．湖头渡潮滩叶绿素a浓度以夏季最高,春、秋季次之,冬季最低;初级生产力仍以夏季最高,春、冬季较低,秋季最低．     

Empirical relationship between sea surface temperature and water vapor: Improvement of the physical model with remote sensing derived data

We have improved the previous model quantifying the bulk relationship between two key geophysical parameters, sea surface temperature (SST) and water vapor (WV) based on 14-year accumulated datasets. This improvement is achieved by the modification of the physical model derived by Stephens in 1990 and Gaffen et al. in 1992. With this improved model, we estimated WV between 2002 and 2004 using historical SST measurements. The estimated WV was compared with those derived from Tropical Rainfall Measuring Mission (TRMM) Microwave Imager (TMI) observation and National Centers for Environmental Predictions (NCEP) reanalysis. Discrepancies of −1.16 mm and 3.19 mm with TMI-and NCEP-derived WV were obtained, respectively, suggesting a reliable retrieval of WV using the improved model. The improved model can potentially be used to calibrate and validate the WV measurements from other observations or model reanalyses, given that the accurate measurement of WV over a wide range of spatial and temporal scales has been a challenging task hitherto. Due to the limited time span of the current data, the temporal variation of WV in parts of the tropical oceans is not captured in this improved model, which we should study further with additional accumulation of SST and WV datasets in the future.     

福建南部一次初春大雾过程分析

2010年2月9—10日,闽南-粤东沿海地区出现较大范围的大雾天气过程,并造成重大的交通事故。分析表明:本次大雾过程发生在冷空气影响过后,大气层结相对稳定;但低空为较强的西南暖湿气流。文中还统计分析了初春大雾过程的气象要素特征,为以后建立初春时期大雾的预报方法提供参考依据。     

Assessment of the Jason Microwave Radiometer's Measurement of Wet Tropospheric Path Delay Using Comparisons to SSM/I and TMI

The Jason microwave radiometer (JMR) provides a crucial correction due to water vapor in the troposphere, and a much smaller correction due to liquid water, to the travel time of the Jason-1 altimeter radar pulse. An error of any size in the radiometer's measurement of wet path delay translates as an error of equal size in the measurement of sea surface height, the ultimate quantity that the altimetric system should yield. The estimate of globally-averaged sea surface height change associated with climate change, requires that uncertainties in the trends in such a global average be accurate to much better than the signal of 1-2 mm/yr. We first compare the JMR observations to those from the TOPEX/Poseidon radiometer (TMR) over approximately six months, since the intent of Jason is to continue the 10-year time series of precision ocean surface topography initiated by T/P. We then assess the stability of the JMR measurement by comparing its wet path delay to those of other orbiting radiometers over 22 months, specifically the Special Sensor Microwave Imager aboard the Defense Meteorological Satellite Program (DMSP-SSM/I) series of satellites, and the Tropical Rainfall Mapping Mission's Microwave Imager (TMI), as well as the European Center for Medium Range Weather Forecasting's (ECMWF) atmospheric numerical model estimate of water vapor. From the combined set, we obtain a robust assessment of the stability of JMR measurements. We find, that JMR is in remarkable agreement with TMR, only 2.5 mm longer, and 6-7 mm standard deviation on their difference in 0.5 degree averages; that JMR has experienced a globally-averaged step-function change, yielding an apparent shortening in wet path delay estimates of 4-5 mm around October 2002 (Jason cycles 28-32); that this step-function is visible only in the 23.8 GHz channel; and that the 34 GHz channel appears to drift at a rate of -0.4K/year. In addition, we find that, while in 2002 there was no evidence of sensitivity to the Jason satellite's attitude (a correlation of the wet path delay with yaw state), in 2003 there are strong (2-3 mm, up to 7 mm globally averaged) changes associated with such yaw state. These JMR issues were all found in the first 22 months of Jason's geophysical data records (GDR) data, and thus they apply to any investigations that use such data without further corrections.     

Assessment of the Jason Microwave Radiometer's Measurement of Wet Tropospheric Path Delay Using Comparisons to SSM/I and TMI

The Jason microwave radiometer (JMR) provides a crucial correction due to water vapor in the troposphere, and a much smaller correction due to liquid water, to the travel time of the Jason-1 altimeter radar pulse. An error of any size in the radiometer's measurement of wet path delay translates as an error of equal size in the measurement of sea surface height, the ultimate quantity that the altimetric system should yield. The estimate of globally-averaged sea surface height change associated with climate change, requires that uncertainties in the trends in such a global average be accurate to much better than the signal of 1–2 mm/yr. We first compare the JMR observations to those from the TOPEX/Poseidon radiometer (TMR) over approximately six months, since the intent of Jason is to continue the 10-year time series of precision ocean surface topography initiated by T/P. We then assess the stability of the JMR measurement by comparing its wet path delay to those of other orbiting radiometers over 22 months, specifically the Special Sensor Microwave Imager aboard the Defense Meteorological Satellite Program (DMSP-SSM/I) series of satellites, and the Tropical Rainfall Mapping Mission's Microwave Imager (TMI), as well as the European Center for Medium Range Weather Forecasting's (ECMWF) atmospheric numerical model estimate of water vapor. From the combined set, we obtain a robust assessment of the stability of JMR measurements. We find, that JMR is in remarkable agreement with TMR, only 2.5 mm longer, and 6–7 mm standard deviation on their difference in 0.5 degree averages; that JMR has experienced a globally-averaged step-function change, yielding an apparent shortening in wet path delay estimates of 4–5 mm around October 2002 (Jason cycles 28–32); that this step-function is visible only in the 23.8 GHz channel; and that the 34 GHz channel appears to drift at a rate of ?0.4K/year. In addition, we find that, while in 2002 there was no evidence of sensitivity to the Jason satellite's attitude (a correlation of the wet path delay with yaw state), in 2003 there are strong (2–3 mm, up to 7 mm globally averaged) changes associated with such yaw state. These JMR issues were all found in the first 22 months of Jason's geophysical data records (GDR) data, and thus they apply to any investigations that use such data without further corrections.     

The characteristics of sea fog with different airflow over the Huanghai Sea in boreal spring

Using the observations from ICOADS datasets and contemporaneous NCEP/NCAR reanalysis datasets during 1960-2002, the study classifies the airflows in favor of sea fog over the Huanghai (Yellow) Sea in boreal spring (April-May) with the method of trajectory analysis, and analyzes the changes of proportions of warm and cold sea fogs along different paths of airflow. According to the heat balance equation, we investigate the relationships between the marine meteorological conditions and the proportion of warm and cold sea fog along different airflow paths. The major results are summarized as follows. (1) Sea fogs over the Huanghai Sea in spring are not only warm fog but also cold fog. The proportion of warm fog only accounts for 44% in April, while increases as high as 57% in May. (2) Four primary airflow paths leading to spring sea fog are identified. They are originated from the northwest, east, southeast and southwest of the Huanghai Sea, respectively. The occurrence ratios of the warm sea fog along the east and southeast airflow paths are high of 55% and 70%, while these along the southwest and northwest airflow paths are merely 17.9% and 50%. (3) The key physical processes governing the warm/cold sea fog are heat advection transport, longwave radiation cooling at fog top, solar shortwave warming and latent heat flux between airsea interfaces. (4) The characteristics of sea fog along the four airflow paths relate closely to the conditions of water vapor advection, and the vertical distribution of relative humidity.     

海洋表面大气下行辐射遥感估算

在海-气相互作用研究中,大气下行辐射的准确估算具有重要意义。在气象站点分布密集的地区,大气下行辐射可通过常规的仪器测量获取。但海洋表面布点成本高,维护比较困难,严重影响我们对海区辐射特征的认识和了解。遥感可提供良好的时空连续性和多层次数据,是研究大气下行辐射的有效手段。本文模拟了不同大气条件下海表的长波下行辐射,考虑到大气下行辐射不仅与所在层的大气有关,还受临近大气层的影响,我们通过增加大气水汽含量重新参数化大气比辐射率,改进Brutsaert模型,建立基于MODIS数据遥感估算海洋表面大气下行辐射的模型,并利用"中国近海海洋综合调查与评价"项目中黄海区观测的海-气通量观测资料对所提出的模型进行检验。结果表明,本文所改进的参数化模型在模拟数据中的均方误差(RMSE)为11.2 W/m~2;在实际数据验证中,RMSE为20.9 W/m~2;模型的精度基本达到了海-气作用研究中对瞬时大气下行辐射的精度要求。     

南、北极雪、冰、水中的痕量元素离子与水汽化学

应用水汽化学的方法学和理论,研究南,北极雪,冰,水中的Ｚｎ＾２＋等离子,南北,极雪,冰,水中Ｚｎ＾２＋,Ｃｄ＾２＋,Ｐｂ＾２＋,Ｃｕ＾２＋,Ｓｎ＾４＋,Ｂｉ＾３＋离子含量的空间变化很小,与水汽化学原理计算的离子总平均含量Ｚｎ＾２＋,５．０μｇ／Ｌ,Ｐｂ＾２＋＋０．０３０μｇ／Ｌ,Ｃｕ＾２＋＋０．７０μｇ／Ｌ,Ｓｎ＾４＋＋０．９９μｇ／Ｌ,Ｂｉ＾３＋＋０．１８μｇ／Ｌ相一致。南北极Ｚｎ＾２＋等离子处     

基于非差精密单点定位技术反演大气综合水汽含量

比较了Saastamoinen模型、UNB3模型和改进的Hopfield模型受纬度、高程和时间影响的不同特性。采用SuomiNet提供的数据进行计算验证,给出适合水汽反演的对流层延迟模型。依据估计的对流层天顶湿延迟反演大气综合水汽含量,通过与网解值对比,验证非差精密单点定位技术反演的大气综合水汽含量,能够达到双差网解方式的精度。     

激发频率对高氢稀释下纳米晶硅薄膜生长特性的影响

利用等离子体增强化学气相沉积技术,在高氢稀释条件下,研究不同激发频率对纳米晶硅薄膜生长特性的影响.剖面透射电子显微镜(TEM)分析结果显示,不同激发频率下制备的纳米晶硅薄膜晶化区均呈锥状结构生长,但13.56 MHz激发频率下制备的纳米晶硅薄膜最初生长阶段存在非晶态孵化层,即纳米晶硅薄膜的形成经历了由非晶态孵化层到晶态结构层的转变.而高激发频率(40.68 MHz)下硅纳米晶则能直接在非晶态衬底上生长形成.Raman谱和红外吸收谱测量结果表明高激发频率(40.68 MHz)下制备的纳米晶硅薄膜不但具有较高     

利用地物光谱仪数据研究水汽对太阳辐射的吸收

论文将在介绍太阳辐射衰减理论的基础上,利用地物光谱仪、太阳辐射计和臭氧监测仪测量所得到的海面入射的太阳直射辐射光谱数据及大气衰减数据,提出了一种研究水汽在近红外波段对太阳辐射吸收作用的新方法,利用该方法得到的水汽吸收系数与前人研究结果非常一致。在可见光波段,大气对太阳辐射的吸收主要体现为臭氧的吸收。在近红外波段,臭氧的吸收非常小,对大气起吸收作用的主要为水汽。