激发频率对高氢稀释下纳米晶硅薄膜生长特性的影响

利用等离子体增强化学气相沉积技术,在高氢稀释条件下,研究不同激发频率对纳米晶硅薄膜生长特性的影响.剖面透射电子显微镜(TEM)分析结果显示,不同激发频率下制备的纳米晶硅薄膜晶化区均呈锥状结构生长,但13.56 MHz激发频率下制备的纳米晶硅薄膜最初生长阶段存在非晶态孵化层,即纳米晶硅薄膜的形成经历了由非晶态孵化层到晶态结构层的转变.而高激发频率(40.68 MHz)下硅纳米晶则能直接在非晶态衬底上生长形成.Raman谱和红外吸收谱测量结果表明高激发频率(40.68 MHz)下制备的纳米晶硅薄膜不但具有较高     

采用Si薄膜的光子计数成像系统性能的研究

在陶瓷基底上利用电子束蒸镀方法制备了Si薄膜,用作感应读出方式光子计数成像系统的电荷感应层,并研究了薄膜的结构特征和表面形态.X射线衍射(XRD)测试和场发射扫描电子显微镜(FESEM)图像表明,沉积的Si薄膜为无定形态,由于陶瓷晶界的存在,薄膜较粗糙.搭建了相应的实验系统,对比了采用不同厚度Si薄膜时系统的空间分辨率、计数率、脉冲高度分布曲线等,发现薄膜的厚度对探测器的计数率影响较大.此外,实验还对比了采用相同电阻值的Si薄膜和常用的Ge薄膜时系统的性能.研究表明,采用Si薄膜时系统的畸变较小、计数率高     

0216号台风引起内陆降雨的水汽分析

本文主要对0216号台风登陆时的水汽变化，利用GMS-5水汽图、NOAA-16——AMSUB微波图以及一些常规资料进行分析阐明台风登陆后低层水汽输送首先被切断，如果后面有热带气旋的水汽流与前—登陆台风的水汽流接通，并与冷锋水汽流相汇合，在内陆将产生更大降水。     

近50 a来杭州湾冲淤变化规律与机制研究

使用杭州湾1959-2010年的水下地形图, 结合过去数十年来长江入海水沙量和钱塘江河口段冲淤变化状况, 分析了近50 a来杭州湾在长江入海泥沙量锐减和治江围涂等人类活动作用下的冲淤变化规律及其物理机理。结果表明, 乍浦以上区域近50 a来处于较显著的淤积状态, 且有自上向下发展的趋势, 这种淤积主要是由于钱塘江河口治江缩窄工程所引起的;湾内地形发生了局部调整, 部分小型潮流槽脊系统趋于消亡, 地形趋于平坦化, 湾口北部2003年以后有转淤为冲的趋势, 这与长江入海泥沙量锐减和该区域围垦工程等因素有关;1959-2003和2003-2010年两个时段, 湾内泥沙淤积的年平均值分别为0.91×108和1.66×108 m3。对于整个钱塘江河口系统而言, 即自杭州湾湾口至钱塘江河口段的闸口断面, 长江入海泥沙量减少所产生的影响尚不明显, 2003年以后泥沙淤积速率甚至有所上升。杭州湾近50 a的冲淤变化是人为强烈干预下的大流域-河口系统响应与中小流域-河口系统响应的调整结果。     

环渤海区域大气水份平衡特征的研究

利用１９８１￣１９９０年环渤海地区的地面气象资料，探空资料和土地利用资料，计算了该地区大气水份平衡方程中各分量，分析了其变化特征，并对它们之间的相互关系进行了研究。     

不锈钢表面纳米SnO2/TiO2复合薄膜制备及防腐蚀性能

采用溶胶凝胶法在不锈钢基体(304ss)上制备叠层式纳米SnO2/TiO2复合薄膜。使用X射线衍射(XRD)、扫描电子显微镜(SEM)表征纳米复合薄膜材料的晶体结构和微观形貌,通过交流阻抗技术(EIS)和极化曲线(Polarization Curves)电化学方法研究不锈钢表面纳米复合薄膜在模拟海水体系中的腐蚀行为。结果表明:制备叠层式纳米复合薄膜TiO2为锐钛矿型,SnO2为金红石型;不锈钢表面构筑叠层式纳米SnO2/TiO2复合薄膜颗粒粒径小,分布均匀且表面致密。电化学测试表明,叠层式纳米SnO2/TiO2复合薄膜阻抗值高于TiO2薄膜,且对不锈钢基体阳极反应有明显钝化过程,具有良好防腐蚀性能;同时叠层式纳米SnO2/TiO2复合薄膜存在最优叠加SnO2层数,叠加3层SnO2的纳米SnO2/TiO2复合薄膜电极防腐蚀性能最佳。     

一种具有平顶陡边响应的长波长光探测器

在PIN型光探测器的基础上制备了一种适用于波分复用系统的具有平顶陡边响应的长波长光探测器。利用低压金属有机化学气相沉积(LP-MOCVD)设备在GaAs衬底上二次外延生长了具有台阶结构的GaAs/AlGaAs滤波腔和InP基PIN光探测器。高质量的GaAs/InP异质外延采用了低温缓冲层生长工艺;具有台阶结构的Fabry-Pérot(F-P)滤波腔采用了纳米量级台阶的制备方法。通过理论计算优化了实现平顶陡边光谱响应特性的器件结构;并通过实验成功制备出了具有平顶陡边响应性能的光探测器,器件的工作波长位于1 549nm,峰值量子效率大于25%,0.5dB光谱响应线宽为3.9nm,3dB光谱响应线宽为4.2nm,响应速率达到17GHz。     

Pb(Zr0.3Ti0.7)O3铁电薄膜激光感生电压效应

采用脉冲激光沉积(PLD)技术在LaSrAlTaO₃(LSATO),LaAlO₃(LAO)和SrTiO₃(STO)的单晶倾斜衬底上成功制备了Pb(Zr_0.3Ti_0.7)O₃(PZT)薄膜,在三种倾斜衬底上生长的PZT薄膜中都首次发现了LIV效应.对PZT/LSATO薄膜在a,c轴两种不同取向择优生长下的LIV效应做了研究,发现在薄膜c轴取向择优生长     

Thermal effect mechanism of magnetoresistance in p-type diamond films

Based on the analysis and the discussion of the influence of thermal ionization energy and various scatterings on magnetoresistance(MR) of p-type diamond films, a revised model of valence band split-off over temperature is put forward, and a corresponding calculation formula is given for the MR of p-type diamond films (Corbino discs). It is shown that the theoretical calculation that the MR of diamond films changes with temperature is consistent with the experiment. The influence of Fermi energy level on MR of diamond films is discussed. Additionally, the thermal effect mechanism of MR in p-type diamond films is also explored.     

Sediment deposition and production in SE-Asia seagrass meadows

Seagrass meadows play an important role in the trapping and binding of particles in coastal sediments. Yet seagrass may also contribute to sediment production directly, through the deposition of detritus and also the deposition of the associated mineral particles. This study aims at estimating the contribution of different seagrass species growing across an extensive range of deposition to inorganic (carbonate and non-carbonate) and organic sediment production. Total daily deposition measured with sediment traps varied from 18.8 (±2.0) g DW m⁻² d⁻¹ in Silaqui (Philippines) to 681.1 (±102) g DW m⁻² d⁻¹ in Bay Tien (Vietnam). These measurements correspond to a single sampling event and represent sedimentation conditions during the dry season in SE-Asia coastal areas. Enhalus acoroides was the most common species in the seagrass meadows visited and, together with Thalassia hemprichii, was present at sites from low to very high deposition. Halodule uninervis and Cymodocea species were present in sites from low to medium deposition. The mineral load in seagrass leaves increased with age, and was high in E. acoroides because it had the largest and long-lived leaves (up to 417 mg calcium carbonate per leaf and 507 mg non-carbonate minerals per leaf) and low in H. uninervis with short-lived leaves (4 mg calcium carbonate per leaf and 2 mg non-carbonate minerals per leaf). In SE-Asia seagrass meadows non-carbonate minerals accumulate at slower rates than the production of calcium carbonate by the epiphytic community, consequently the final loads supported by fully grown leaves were, as average, lower than calcium carbonate loads. Our results show that organic and inorganic production of the seagrasses in SE-Asia represents a small contribution (maximum of 15%) of the materials sedimented on a daily base by the water column during the sampling period. The contribution of the carbonate fraction can be locally significant (i.e. 34% in Silaqui) in areas where the depositional flux is low, but is minor (<1%) in sites were siltation is significant (i.e. Umalagan and all the visited sites in Vietnam).     

Atmospheric Pb and Cd input into the Baltic Sea: a new estimate based on measurements

Bulk deposition samples were collected during a summer (1997) and a winter (1998) measurement campaign at four coastal stations along the southern Baltic Sea coast and on the Island of Gotland. The data were used to construct Pb and Cd deposition fields over the Baltic Sea. A weak gradient with decreasing deposition rates from the southwest towards the east and north was obtained for Pb. In the case of Cd, the spatial distribution pattern was characterized by an extreme deposition maximum at the Polish station on the Hel Peninsula. The total atmospheric input of Pb and Cd into the Baltic Sea was 550 and 33 t/year, respectively, and exceeds the riverine input by approximately about 50%. Previous measurement-based estimates were higher by a factor 2–3 and indicate a decrease of the atmospheric deposition during the past 10–15 years. The comparison with modelled deposition data yielded partly large differences and was impaired by the fact that 1990 emission inventories were used whereas our measurements were performed in 1997/1998.Relating our deposition estimate and the Pb/Cd input by rivers to the mean concentrations in Baltic Sea water, residence times of 0.29 and 3.6 years were obtained for Pb and Cd, respectively.     

胶州湾铅-210比活度的分布模式及百年尺度的沉积速率

2006年6月在胶州湾采集柱状岩心并对岩心沉积物中铅-210比活度进行测试分析,结果表明,铅-210沿岩心的垂向分布具有两段、三段模式和异常的多段、倒置模式等。基于铅-210的CIC(constant initial concentration)计年模式和铯-137时标,并且结合历史海底地形对比,计算出近百年来胶州湾海域的现代沉积速率为1.49~24.96 mm/a,沉积通量为0.17~2.62 g/(cm2.a)。除沧口水道末端个别区域外,胶州湾多数区域(包含水道)的沉积速率较低,量级为100mm/a,湾内水道主要呈现出微淤甚至侵蚀,表明近百年来胶州湾沉积环境相对稳定,在可作为航道资源的湾内水道并未出现显著淤积。     

盐城滨海港区防波堤建设对水下地形的影响研究

利用双频测深仪和声学多普勒流速仪对滨海港区附近海域进行了区域测深和定点全潮水文观测,通过与以往调查研究资料的对比,分析了防波堤建成前后海底冲淤变化特征。研究结果表明:近20年以来水下岸坡为侵蚀最剧烈的区域,海底平原则处于相对稳定状态;受自然侵蚀的影响,水下岸坡继续向岸内移,目前最强侵蚀区已内移至–8~–12 m水深的水下岸坡;近年来自然侵蚀明显减弱,年均侵蚀速率约为前10年的1/4;受防波堤挡流效应的影响,口门南侧已由往复流转变为旋转流;目前已出现三大淤积区域,其中以口门处淤积最严重,最大淤积厚达3.5 m,已造成口门处水深不足–10 m;防波堤对周边海域直接影响范围约13.4 km~2,最远可达废黄河口。分析认为,防波堤建设是引起港区海底冲淤格局发生变化的主因。该研究为防波堤的后续维护及滨海港区30万t级航道工程论证提供了基础资料。     

Two fundamentally different types of submarine canyons along the continental margin of Equatorial Guinea

Most submarine canyons are erosive conduits cut deeply into the world’s continental shelves through which sediment is transported from areas of high coastal sediment supply onto large submarine fans. However, many submarine canyons in areas of low sediment supply do not have associated submarine fans and show significantly different morphologies and depositional processes from those of ‘classic’ canyons. Using three-dimensional seismic reflection and core data, this study contrasts these two types of submarine canyons and proposes a bipartite classification scheme.The continental margin of Equatorial Guinea, West Africa during the late Cretaceous was dominated by a classic, erosional, sand-rich, submarine canyon system. This system was abandoned during the Paleogene, but the relict topography was re-activated in the Miocene during tectonic uplift. A subsequent decrease in sediment supply resulted in a drastic transformation in canyon morphology and activity, initiating the ‘Benito’ canyon system. This non-typical canyon system is aggradational rather than erosional, does not indent the shelf edge and has no downslope sediment apron. Smooth, draping seismic reflections indicate that hemipelagic deposition is the chief depositional process aggrading the canyons. Intra-canyon lateral accretion deposits indicate that canyon concavity is maintained by thick (>150 m), dilute, turbidity currents. There is little evidence for erosion, mass-wasting, or sand-rich deposition in the Benito canyon system. When a canyon loses flow access, usually due to piracy, it is abandoned and eventually filled. During canyon abandonment, fluid escape causes the successive formation of ‘cross-canyon ridges’ and pockmark trains along buried canyon axes.Based on comparison of canyons in the study area, we recognize two main types of submarine canyons: ‘Type I’ canyons indent the shelf edge and are linked to areas of high coarse-grained sediment supply, generating erosive canyon morphologies, sand-rich fill, and large downslope submarine fans/aprons. ‘Type II’ canyons do not indent the shelf edge and exhibit smooth, highly aggradational morphologies, mud-rich fill, and a lack of downslope fans/aprons. Type I canyons are dominated by erosive, sandy turbidity currents and mass-wasting, whereas hemipelagic deposition and dilute, sluggish turbidity currents are the main depositional processes sculpting Type II canyons. This morphology-based classification scheme can be used to help predict depositional processes, grain size distributions, and petroleum prospectivity of any submarine canyon.     

太湖大气氮、磷营养元素干湿沉降率研究

分析了2002年7月—2003年6月太湖周边地区太湖站、拖山岛、东山站、无锡、苏州、湖州、常州、金坛等8个站、点大气TN、TP沉降通量和降水化学组成观测资料,测定和计算了水气界面TN、TP的表观总沉降率(RT)、湿沉降率(RW)和干沉降率(RD)。太湖大气TN的年平均RT为4226kg/(km2.a),TP的年平均RT为306kg/(km2.a)。大气TN、TP的年沉降负荷分别占由环湖河道等点污染源输入的N、P总负荷的48.8%和46.2%。指出形成太湖大气TN污染的主要途径是湿沉降,而大气TP污染则主要来自气溶胶等固体物质的干沉降;小雨携带入湖的大气TN、TP污染物通量高于中雨和大雨。TN总沉降率曲线在春季3—5月出现高峰值的现象对太湖水体的富营养化具有潜在的促进影响。     

Spatial and temporal variability of a coarse-sand anomaly on a sandy inner shelf,northeastern Gulf of Mexico

A 10-km² area of anomalously uniform coarse sand and low relief, in 30 m water depth off Panama City, Florida, USA, exists as a palimpsest hardbottom within the prevailing sand-wave system. Side-scan sonar observations over a ten-year period document the morphologic response of the anomaly to the bottom—wave—current interaction regime. The anomaly and surrounding sand waves remained fixed during this period. Ripples form within the anomaly in response to seasonal storms and decay during quiescent periods. Hurricane response includes minor realignment of sand waves, formation of megaripples, and deposition of a thin mud layer.     

Optimisation of arrays of flap-type oscillating wave surge converters

In this paper a finite array of hinged flap-type wave energy converters are modelled using a mathematical approach. These are illustrative of the Oyster device of Aquamarine Power Ltd.¹ A novel semi-analytic solution method is presented for a set of boundary-value problems involving the scattering and radiation of waves by thin barriers used to model the device hydrodynamics. The approach makes use of the geometry to apply Fourier transforms, deriving non-singular integral equations in terms of the jumps in pressure across the flaps. These are then solved numerically using a highly efficient Galerkin expansion method. The focus of the results is on optimisation. We suggest optimal parameters for a single device, identifying flap length as crucial to device performance. This optimisation is then carried through to arrays with optimal arrangements and spacings being determined for a model sea state. Here, the lateral displacement of the devices emerges as a critical factor in optimal array configuration.     

Spatial distribution and deposition history of nonylphenol and bisphenol A in sediments from the Changjiang River (Yangtze River) Estuary and its adjacent East China Sea

Nonylphenol(NP) and bisphenol A(BPA) are endocrine disruptors causing harmful effects including feminization and carcinogenesis to various organisms,and consequently,their contamination in natural environment has received wide concerns.This study reports the distribution characteristics of NP and BPA in surface sediments and their deposition history based on a dated sediment core in the Changjiang River(Yangtze River) Estuary and its adjacent East China Sea.The contents of NP and BPA in surface sediments ranged from 1.56-35.8 and 0.72-13.2 ng/g(dry mass),respectively,with high values recorded in the two mud zones,the Changjiang River Estuarine Mud Zone and the Zhejiang Coastal Mud Zone.High values in the Zhejiang Coastal Mud Zone suggest the possibility of long distance transport of both contaminants through the Changjiang riverine plume.The contents were not correlated with the distance from the pollution source,indicating other factors including particle deposition rate and sediment grain size obviously affecting the distribution pattern.NP was also detected in a sediment core at layers deposited from the year of 1971 to 2001 with contents of up to 20.9 ng/g(dry mass).The deposition fluxes of NP varied from 0.68 to 17.9 ng/(cm2 · a) with peaks and valleys reflecting the traces of economic development history in China during the previous three decades.BPA was detected at sediment layers deposited from 1973 to 2001 with contents of up to 3.66 ng/g.The fluxes of BPA varied from 0.62 to 3.13 ng/(cm2 · a) showing a similar pattern as NP.The contents of NP and BPA also indicated potential risks on benthic organisms in the study area.     

杭州湾枯季水沙若干特征分析

根据2014年1月及2017年2月杭州湾大、小潮水沙资料,计算了流速、含沙量、单宽潮量、单宽输沙量,进而分析了潮周期断面净潮量、净输沙量和区域冲淤分布。研究发现杭州湾涨、落潮平均流速比值整体较20世纪八九十年代增大,绝大部分区域大于1.0,涨潮流相对增强,澉浦南岸和金山北岸尤为显著。含沙量平面上分布澉浦、杭州湾南岸两个高值区(大潮大于3 kg/m³,小潮大于1.3 kg/m³)以及北岸湾口至乍浦之间的低值区(大潮小于2 kg/m³,小潮小于0.9 kg/m³),随潮汛变化显著,最大含沙量浓度通常滞后于急流时刻。各测站涨、落潮量和输沙量呈现“大涨大落”和“大进大出”的特征,造成杭州湾短时间尺度内的“大冲大淤”。大潮两涨两落金山与乍浦、乍浦与澉浦之间区域净输沙量可达几千万吨,净冲淤则在几百万吨。     

1998年夏季南海和盂加拉湾地区的大尺度经向水汽输送诊断分析

本文诊断分析了1998年夏季长江流域洪涝的平均经向大尺度水汽输送的特征，结果表明，1998年夏季盂加拉湾地区和南海地区经向水汽输送大小是因月份、高度而异。进一步分析结果表明，在印度季风和南海季风不同的位相阶段，盂加拉湾地区和南海地区的经向水汽输送也是各不相同的，这也和各月经向水汽输送变化基本一致。