Dynamics of Russian Forests and the Carbon Budget in 1961–1998: An Assessment Based on Long-Term Forest Inventory Data

Development trends of Russian forests and their impact on the global carbon budget were assessed at the national level on the basis of long-term forest inventory data (1961–1998). Over this period, vegetation of Russian forest lands are estimated as a carbon sink, with an annual average level of carbon sequestration in vegetational organic matter of 210 ± 30 Tg C · yr^–1 (soil carbon is not considered in this study), of which 153 Tg C · yr^–1 were accumulated in live biomass and 57 Tg C · yr^–1 in dead wood. The temporal variability of the sink is very large; for the five-year averages used in the analysis, the C sequestration varies from about 60 to above 300 Tg C· yr^–1. It is shown that long-term forest inventory data could serve as an important information base for assessing crucial indicators of full carbon accounting of forests.     

Decadal Methane Emission Trend Inferred from Proxy GOSAT XCH4 Retrievals: Impacts of Transport Model Spatial Resolution

In recent studies, proxy XCH₄ retrievals from the Japanese Greenhouse gases Observing SATellite (GOSAT) have been used to constrain top-down estimation of CH₄ emissions. Still, the resulting interannual variations often show significant discrepancies over some of the most important CH₄ source regions, such as China and Tropical South America, by causes yet to be determined. This study compares monthly CH₄ flux estimates from two parallel assimilations of GOSAT XCH₄ retrievals from 2010 to 2019 based on the same Ensemble Kalman Filter (EnKF) framework but with the global chemistry transport model (GEOS-Chem v12.5) being run at two different spatial resolutions of 4° × 5° (R4, lon × lat) and 2° × 2.5° (R2, lon × lat) to investigate the effects of resolution-related model errors on the derived long-term global and regional CH₄ emission trends. We found that the mean annual global methane emission for the 2010s is 573.04 Tg yr ^–1 for the inversion using the R4 model, which becomes about 4.4 Tg yr ^–1 less (568.63 Tg yr ^–1) when a finer R2 model is used, though both are well within the ensemble range of the 22 top-down results (2008–17) included in the current Global Carbon Project (from 550 Tg yr ^–1 to 594 Tg yr ^–1). Compared to the R2 model, the inversion based on the R4 tends to overestimate tropical emissions (by 13.3 Tg yr ^–1), which is accompanied by a general underestimation (by 8.9 Tg yr ^–1) in the extratropics. Such a dipole reflects differences in tropical–mid-latitude air exchange in relation to the model’s convective and advective schemes at different resolutions. The two inversions show a rather consistent long-term CH₄ emission trend at the global scale and over most of the continents, suggesting that the observed rapid increase in atmospheric methane can largely be attributed to the emission growth from North Africa (1.79 Tg yr ^–2 for R4 and 1.29 Tg yr ^–2 for R2) and South America Temperate (1.08 Tg yr ^–2 for R4 and 1.21 Tg yr ^–2 for R2) during the first half of the 2010s, and from Eurasia Boreal (1.46 Tg yr ^–2 for R4 and 1.63 Tg yr ^–2 for R2) and Tropical South America (1.72 Tg yr^–2 for R4 and 1.43 Tg yr ^–2 for R2) over 2015–19. In the meantime, emissions in Europe have shown a consistent decrease over the past decade. However, the growth rates by the two parallel inversions show significant discrepancies over Eurasia Temperate, South America Temperate, and South Africa, which are also the places where recent GOSAT inversions usually disagree with one other.     

CH4 emission from various rice fields in P.R. China

Summary The CH₄ emission rates from Chinese rice fields have been measured in five typical areas representing all of the five major rice culture regions in People's Republic of China (P.R. China). Four types of diurnal variations (afternoon peak, night peak, afternoon-night double peaks and random pattern) of CH₄ emission rates have been found. The first pattern was normally found in clear weather, the second and the third types were only found occasionally in particular place, while the fourth were found in cloudy or rainy weather. Due to the irregular pattern of the methane production observed in the morning-afternoon comparison experiment, the transport pathway influenced by certain factors, may be the major factor governing the diurnal variation of CH₄ emission. Seasonal variation patterns of CH₄ emission differ slightly with different field locations, where climate system, cropping system and other factors are different. Two and three emission peaks were generally found during single and early rice vegetation periods, with the peak magnitude and time of appearance differing to small degree in individual sites. A decreasing trend of seasonal variation was always observed in late rice season. A combination of seasonal change of transport efficiency and that of CH₄ production rate in the paddy soil explains well the CH₄ emission. The role of rice plant in transporting CH₄ varied over a large range in different rice growing stages. The reasons for internnual changes of CH₄ flux are not yet clear.Great spatial variation of the CH₄ emission has been found, which can be attributed to the differences in soil type and soil properties, local climate condition, rice species, fertilizer and water treatment. Experiments showed that while the application of some mineral fertilizers will reduce the CH₄ emission and CH₄ production in the soil, the application of organic manure will enhance CH₄ emission and CH₄ production in the soil. Any measures which can get off easily decomposed carbon from organic manure may reduce C supply for CH₄ production, and hence reduce CH₄ emission. Fermented sludges from biogas generators and farmyard-stored manure seem to be promising. In some parts of China, separate application of the organic and mineral manure instead of mixed application could be another option. Frequent Scientific drainage and ridge cultivation, which are often used water management techniques in Chinese rice agriculture, have been proved in the experiments to be a very efficient mitigation measures to reduce CH₄ emission from rice fields.By summarizing the present available data, China's rice fields contribute about 13.3 Tg yr^–1 (11.4–15.2) CH₄ to the atmosphere. The total methane emission from global rice fields can be estimated 33–60 Tg yr^–1, much less than the estimates made before.If we extrapolate the measured data in China with a consideration of measured data in other Asian country, the total global emission of CH₄ from rice fields are estimated to be about 35–60 Tg yr^–1 With 2 Figures     

Formulation and Evaluation of IMS, an Interactive Three-Dimensional Tropospheric Chemical Transport Model 2. Model Chemistry and Comparison of Modelled CH4, CO, and O3 with Surface Measurements

In part two of this series of papers on the IMS model, we present the chemistry reaction mechanism usedand compare modelled CH₄, CO, and O₃ witha dataset of annual surface measurements. The modelled monthly and 24-hour mean tropospheric OH concentrationsrange between 5–22 × 10⁵ moleculescm^–3, indicating an annualaveraged OH concentration of about 10 × 10⁵ moleculescm^–3. This valueis close to the estimated 9.7 ± 0.6 × 10⁵ moleculescm^–3 calculated fromthe reaction of CH₃CCl₃ with OH radicals.Comparison with CH₄ generally shows good agreementbetween model and measurements, except for the site at Barrow where modelledwetland emission in the summer could be a factor 3 too high.For CO, the pronounced seasonality shown in the measurements is generally reproduced by the model; however, the modelled concentrations are lower thanthe measurements. This discrepancy may due to lower the CO emission,especially from biomass burning,used in the model compared with other studies.For O₃, good agreement between the model and measurements is seenat locations which are away from industrial regions. The maximum discrepancies between modelled results and measurementsat tropical and remote marine sites is about 5–10 ppbv,while the discrepancies canexceed 30 ppbv in the industrial regions.Comparisons in rural areas at European and American continental sites arehighly influenced by the local photochemicalproduction, which is difficult to model with a coarse global CTM.The very large variations of O₃ at these locations vary from about15–25 ppbv in Januaryto 55–65 ppbv in July–August. The observed annual O₃amplitude isabout 40 ppbv compared with about 20 ppbv in the model. An overall comparison of modelled O₃ with measurements shows thatthe O₃seasonal surface cycle is generally governed bythe relative importance of two key mechanisms that drivea springtime ozone maximum and asummertime ozone maximum.     

Sink Potential of Canadian Agricultural Soils

Net greenhouse gas (GHG) emissions from Canadian crop and livestock production were estimated for 1990, 1996 and 2001 and projected to 2008. Net emissions were also estimated for three scenarios (low (L), medium (M) and high (H)) of adoption of sink enhancing practices above the projected 2008 level. Carbon sequestration estimates were based on four sink-enhancing activities: conversion from conventional to zero tillage (ZT), reduced frequency of summerfallow (SF), the conversion of cropland to permanent cover crops (PC), and improved grazing land management (GM). GHG emissions were estimated with the Canadian Economic and Emissions Model for Agriculture (CEEMA). CEEMA estimates levels of production activities within the Canadian agriculture sector and calculates the emissions and removals associated with those levels of activities. The estimates indicate a decline in net emissions from 54 Tg CO₂–Eq yr^–1 in1990 to 52 Tg CO₂–Eq yr^–1 in 2008. Adoption of thesink-enhancing practices above the level projected for 2008 resulted in further declines in emissions to 48 Tg CO₂–Eq yr^–1 (L), 42 TgCO₂–Eq yr^–1 (M) or 36 Tg CO₂–Eq yr^–1 (H). Among thesink-enhancing practices, the conversion from conventional tillage to ZT provided the largest C sequestration potential and net reduction in GHG emissions among the scenarios. Although rates of C sequestration were generally higher for conversion of cropland to PC and adoption of improved GM, those scenarios involved smaller areas of land and therefore less C sequestration. Also, increased areas of PC were associated with an increase in livestock numbers and CH₄ and N₂O emissions from enteric fermentation andmanure, which partially offset the carbon sink. The CEEMA estimates indicate that soil C sinks are a viable option for achieving the UNFCCC objective of protecting and enhancing GHG sinks and reservoirs as a means of reducing GHG emissions (UNFCCC, 1992).     

NDVI-based increase in growth of temperate grasslands and its responses to climate changes in China

This study analyzes the temporal change of Normalized Difference Vegetation Index (NDVI) for temperate grasslands in China and its correlation with climatic variables over the period of 1982–1999. Average NDVI of the study area increased at rates of 0.5% yr⁻¹ for the growing season (April–October), 0.61% yr⁻¹ for spring (April and May), 0.49% yr⁻¹ for summer (June–August), and 0.6% yr⁻¹ for autumn (September and October) over the study period. The humped-shape pattern between coefficient of correlation (R) of the growing season NDVI to precipitation and growing season precipitation documents various responses of grassland growth to changing precipitation, while the decreased R values of NDVI to temperature with increase of temperature implies that increased temperature declines sensitivity of plant growth to changing temperature. The results also suggest that the NDVI trends induced by climate changes varied between different vegetation types and seasons.     

Potential Soil C Sequestration on U.S. Agricultural Soils

Soil carbon sequestration has been suggested as a means to help mitigate atmospheric CO₂ increases, however there is limited knowledge aboutthe magnitude of the mitigation potential. Field studies across the U.S. provide information on soil C stock changes that result from changes in agricultural management. However, data from such studies are not readily extrapolated to changes at a national scale because soils, climate, and management regimes vary locally and regionally. We used a modified version of the Intergovernmental Panel on Climate Change (IPCC) soil organic C inventory method, together with the National Resources Inventory (NRI) and other data, to estimate agricultural soil C sequestration potential in the conterminous U.S. The IPCC method estimates soil C stock changes associated with changes in land use and/or land management practices. In the U.S., the NRI provides a detailed record of land use and management activities on agricultural land that can be used to implement the IPCC method. We analyzed potential soil C storage from increased adoption of no-till, decreased fallow operations, conversion of highly erodible land to grassland, and increased use of cover crops in annual cropping systems. The results represent potentials that do not explicitly consider the economic feasibility of proposed agricultural production changes, but provide an indication of the biophysical potential of soil C sequestration as a guide to policy makers. Our analysis suggests that U.S. cropland soils have the potential to increase sequestered soil C by an additional 60–70 Tg (10¹²g) C yr^{– 1}, over present rates of 17 Tg C yr^–1(estimated using the IPCC method), with widespread adoption of soil C sequestering management practices. Adoption of no-till on all currently annually cropped area (129Mha) would increase soil C sequestration by 47 Tg C yr^–1. Alternatively, use of no-till on 50% of annual cropland, with reduced tillage practices on the other 50%, would sequester less – about37 Tg C yr^–1. Elimination of summer fallow practices and conversionof highly erodible cropland to perennial grass cover could sequester around 20 and 28Tg C yr^–1, respectively. The soil C sequestration potentialfrom including a winter cover crop on annual cropping systems was estimated at 40Tg C yr^–1. All rates were estimated for a fifteen-yearprojection period, and annual rates of soil C accumulations would be expected to decrease substantially over longer time periods. The total sequestration potential we have estimated for the projection period (83 Tg C yr^–1) represents about 5% of 1999total U.S. CO₂ emissions or nearly double estimated CO₂ emissionsfrom agricultural production (43 Tg C yr^–1). For purposes ofstabilizing or reducing CO₂ emissions, e.g., by 7% of 1990 levels asoriginally called for in the Kyoto Protocol, total potential soil C sequestration would represent 15% of that reduction level from projected 2008 emissions(2008 total greenhouse gas emissions less 93% of 1990 greenhouse gasemissions). Thus, our analysis suggests that agricultural soil C sequestration could play a meaningful, but not predominant, role in helping mitigate greenhouse gas increases.     

Domestic Combustion of Biomass Fuels in Developing Countries: A Major Source of Atmospheric Pollutants

Biomass burning has important impacts on atmospheric chemistry and climate. Fires in tropical forests and savannas release large quantities of trace gases and particulate matter. Combustion of biofuels for cooking and heating constitutes a less spectacular but similarly widespread biomass burning activity. To provide the groundwork for a quantification of this source, we determined in rural Zimbabwe the emissions of CO₂, CO, and NO from more than 100 domestic fires fueled by wood, agricultural residues, and dung. The results indicate that, compared to open savanna fires, emissions from domestic fires are shifted towards products of incomplete combustion. A tentative global analysis shows that the source strength of domestic biomass burning is on the order of 1500 Tg CO₂–C yr^–1, 140 Tg CO–C yr^–1, and 2.5 Tg NO–N yr^–1. This represents contributions of about 7 to 20% to the global budget of these gases.     

Possible climatic impacts of land cover transformations,with particular emphasis on tropical deforestation

The climatic impact of albedo changes associated with land-surface alterations has been examined. The total surface global albedo change resulting from major land-cover transformations (i.e. deforestation, desertification, irrigation, dam-building, urbanization) has been recalculated, modifying the estimates of Sagan et al., (1979). Tropical deforestation (11.1 million ha yr^-1, or 0.6% yr^-1, Lanly, 1982) ranks as a major cause of albedo change, although uncertainties in the areal extent of desertification could conceivably render this latter process of similar significance. The maximum total global albedo change over the last 30 yr for the various processes lies between 0.000 33 and 0.000 64, corresponding to a global temperature decrease of between 0.06 K and 0.09 K (scaled from the 1-D radiative convective model of Hansen et al., 1981), which falls well below the interannual and longer period variability.An upper bound to the impact of tropical deforestation was obtained by concentrating all vegetation change into a single region. The magnitude of this modification is equivalent to 35–50 yr of global deforestation at the current rate, but centered on the Brazilian Amazon. The climatic consequences of such tropical deforestation were simulated, using the GISS GCM (Hansen et al., 1983). In the simulation, a total area of 4.94 × 10⁶ km² of tropical moist forest was removed and replaced by a grass/crop cover. Although surface albedo increased from 0.11 to 0.19, the effect upon surface temperature was negligible. However, other climate parameters were altered. Rainfall decreased by 0.5–0.7 mm day^-1 and both evapotranspiration and total cloud cover were reduced. The absence of a temperature decrease in spite of the increased surface albedo arises because the reduction in evapotranspiration has offset the effects of radiative cooling. The decrease in cloud cover also counteracts the increase in surface albedo. These locally significant changes had no major impact on regional (Hadley or Walker cells) or the global circulation patterns.We conclude that the albedo changes induced by current levels of tropical deforestation appear to have a negligibly small effect on the global climate.     

Global distribution of natural freshwater wetlands and rice paddies,their net primary productivity,seasonality and possible methane emissions

A global data set on the geographic distribution and seasonality of freshwater wetlands and rice paddies has been compiled, comprising information at a spatial resolution of 2.5° by latitude and 5° by longitude. Global coverage of these wetlands total 5.7×10⁶ km² and 1.3×10⁶ km², respectively. Natural wetlands have been grouped into six categories following common terminology, i.e. bog, fen, swamp, marsh, floodplain, and shallow lake. Net primary productivity (NPP) of natural wetlands is estimated to be in the range of 4–9×10¹⁵ g dry matter per year. Rice paddies have an NPP of about 1.4×10¹⁵ g y^–1. Extrapolation of measured CH₄ emissions in individual ecosystems lead to global methane emission estimates of 40–160 Teragram (1 Tg=10¹² g) from natural wetlands and 60–140 Tg from rice paddies per year. The mean emission of 170–200 Tg may come in about equal proportions from natural wetlands and paddies. Major source regions are located in the subtropics between 20 and 30° N, the tropics between 0 and 10° S, and the temperate-boreal region between 50 and 70° N. Emissions are highly seasonal, maximizing during summer in both hemispheres. The wide range of possible CH₄ emissions shows the large uncertainties associated with the extrapolation of measured flux rates to global scale. More investigations into ecophysiological principals of methane emissions is warranted to arrive at better source estimates.     

Emission of nitrous oxide from temperate forest soils into the atmosphere

N₂O emission rates were measured during a 13-month period from July 1981 till August 1982 with a frequency of once every two weeks at six different forest sites in the vicinity of Mainz, Germany. The sites were selected on the basis of soil types typical for many of the Central European forest ecosystems. The individual N₂O emission rates showed a high degree of temporal and spatial variabilities which, however, were not significantly correlated to variabilities in soil moisture content or soil temperatures. However, the N₂O emission rates followed a general seasonal trend with relatively high values during spring and fall. These maxima coincided with relatively high soil moisture contents, but may also have been influenced by the leaf fall in autumn. In addition, there was a brief episode of relatively high N₂O emission rates immediately after thawing of the winter snow. The individual N₂O emission rates measured during the whole season ranged between 1 and 92 g N₂O-N m^–2 h^–1. The average values were in the range of 3–11 g N₂O-N m^–2 h^–1 and those with a 50% probability were in the range of 2–8 g N₂O-N m^–2 h^–1. The total source strength of temperate forest soils for atmospheric N₂O may be in the range of 0.7–1.5 Tg N yr^–1.     

The measurement of natural sulfur emissions from soils and vegetation: Three sites in the Eastern United States revisited

Sulfur fluxes from bare soils, naturally vegetated surfaces and from several agricultural crops were measured at two mid-continent sites (Ames, Iowa and Celeryville, Ohio) and from one salt water marsh site (Cedar Island, North Carolina) during a field program conducted jointly by the NOAA Aeronomy Laboratory, Washington State University Laboratory for Atmospheric Research and University of Idaho Department of Chemistry during July and August 1985. The sites were chosen specifically because they had been characterized by previous studies (Anejaet al., 1979; Adamset al., 1980, 1981). The NOAA gas chromatographic/dynamic-enclosure measurements yielded bare soil surfaces fluxes from the mid-continent sites composed predominantly of COS, H₂S, CH₃–S–CH₃ (DMS) and CS₂, all of which were strongly correlated with air temperature. Net fluxes of approximately 5 and 15 ng S/m² min were observed in Iowa and Ohio, respectively, at appropriate weighted mean July temperatures. These fluxes are roughly a factor of 10 smaller than the earlier measurements, the greatest difference being in the measurement of the H₂S flux. The presence of growing vegetation was observed to measurably increase the flux of H₂S, significantly increase that of DMS and to decrease that of COS. Sulfur fluxes in the Cedar Island environs were observed to be both spatially and temporally much more variable and to include CH₃SH as a measurable contributor. Net fluxes, composed predominantly of DMS and H₂S, were estimated to be about 300 ngS/m²min during August; again about a factor of 10 lower than previous estimates. All measurements were corroborated to within about a factor of 2 by those of the other participating laboratories.     

Emission of nitric oxide from soils and termite nests in a Trachypogon savanna of the Orinoco basin

Nitric oxide fluxes from soils in the Trachypogon savanna of the Orinoco basin were determined during the dry season using the static chamber method. The emission from dry soils fluctuated from 0.4 to 3 ng N m^–2 s^–1 and increased up to 25 ng N m^–2 s^–1 after moderate watering or light rain-falls (1 to 5 mm). The mean emission values are up to 6 times lower than one observed earlier at the Chaguaramas site, but up to 10 times higher than one recorded at the Guri site, indicating an important spatial variability in NO fluxes of the Venezuelan savanna region. The changes observed after the addition of nitrogen to the soil, in the form of ammonium and/or nitrate, indicate a high denitrification potential in this acidic soil. Burning of the surface vegetation produced an increase by a factor of 10 in the emission rate of NO, but the effect was relatively short in time, about 5 days. It was estimated for the savanna region that burning increases the total NO soil emission during the dry season by 15% compared to the unburnt case. Soils with termite nests emit 10 times more NO than soil without nests, but the contribution from this source is less than 2% of the total savanna soil flux.     

Organic matter of the troposphere — V: Application of molecular marker analysis to biogenic emissions into the troposphere for source reconciliations

Organic matter in tropospheric aerosols is derived from two major sources and is admixed depending on the geographic area. These sources are biogenic detritus and anthropogenic emissions. The biogenic materials in the solvent-extractable organic matter are comprised predominantly of higher plant waxes, with lesser amounts of resin and microbial detritus and the anthropogenic components are primarily vehicular emissions (e.g. oils, soot, etc.) and input from combustion (e.g. charcoal, thermally-altered biogenic matter, etc.). Both biogenic detritus and anthropogenic emissions contain organic compounds (C₁₂–C₄₀₊), which can be identified with unique and distinguishable distribution patterns. Molecular composition analysis has been applied to such extracts after suitable chemical separation into subfractions (i.e. hydrocarbons, ketones, aldehydes, carboxylic acids, alcohols, and wax esters). Both homologous compound series and specific natural products (e.g. phytosterols, terpenes, etc.) are identified as molecular markers.Aerosols from rural and remote areas in the western United States, South America, Nigeria and Australia have been analyzed and all contained predominantly plant waxes. The loadings of hydrocarbons ranged approximately from 10–1400 ng/m³ of air, of fatty acids from 10–450 ng/m³ and of fatty alcohols from 10–1650 ng/m³. These higher molecular weight lipids primarily from flora comprise a major component of the organic carbon in rural and remote aerosols. They are thus important indicators for regional biogenic sources in the global cycling of organic carbon.Presented in part at the International Symposium on Biosphere-Atmosphere Exchange, Mainz, E.R. Germany, March 16–22, 1986, for Part IV see Simoneit et al. (1988) Atmos. Environ. 22, 983–1004.     

A global three-dimensional model of the tropospheric sulfur cycle

The tropospheric part of the atmospheric sulfur cycle has been simulated in a global three-dimensional model. The model treats the emission, transport, chemistry, and removal processes for three sulfur components; DMS (dimethyl sulfide), SO₂ and SO₄ ^2– (sulfate). These processes are resolved using an Eulerian transport model, the MOGUNTIA model, with a horizontal resolution of 10° longitude by 10° latitude and with 10 layers in the vertical between the surface and 100 hPa. Advection takes place by climatological monthly mean winds. Transport processes occurring on smaller space and time scales are parameterized as eddy diffusion except for transport in deep convective clouds which is treated separately. The simulations are broadly consistent with observations of concentrations in air and precipitation in and over polluted regions in Europe and North America. Oxidation of DMS by OH radicals together with a global emission of 16 Tg DMS-S yr^–1 from the oceans result in DMS concentrations consistent with observations in the marine boundary layer. The average turn-over times were estimated to be 3, 1.2–1.8, and 3.2–6.1 days for DMS, SO₂, and SO₄ ^2– respectively.     

Nitrous Oxide Flux Estimates for South-Eastern Australia

Nitrous oxide (N₂O) fluxes for south-easternAustralia have been estimated using a combination ofthe in situ N₂O and radon (Rn) measurementsmade at the Cape Grim Baseline Air Pollution Station,in north-west Tasmania. The average N₂O fluxesfrom the south-eastern mainland of Australia and fromTasmania over the nine years of record analysed (1985–1993) have beenfound to be 130 ± 30 kgN km^-2yr^-1 and 160 ± 45 kgN km^-2yr^-1respectively. These fluxes are larger than expectedand a significant dependence of the flux on rainfallis observed, with greater fluxes in the spring (October–December) andduring periods of positive SouthernOscillation Index. A large flux (1,300 ± 500kgN km^-2 yr^-1) from a nearby island (KingIsland) was also estimated from the data record,indicating a strong source, although the small size ofthe island means that it is not a significant sourcefor Australia.     

Field measurements of emission of nitric oxide from fertilized and unfertilized forest soils in Sweden

Application of nitrate fertilizers on two types of forest soils led to a marked increase in the NO emission rate indicating a large potential for NO production in these soils. The largest fluxes on the fertilized plots were up to 60 ng NO–N m^–2 s^–1. About 0.35% of the applied nitrogen was lost as NO within about 14 days after fertilization. The fluxes from the unfertilized forest soils were in the range 0.1 to 0.8 ng NO–N m^–2 s^–1 with a median value of 0.3 ng NO–N m^–2 s^–1. If this value, obtained during June and August to September, is representative for the growing season (150 days), it corresponds to an annual emission of 0.04 kg NO–N ha^–1. This is about 30% of the value obtained for an unfertilized agricultural soil. Because of the large areas occupied by forests in Sweden the flux of NO from forest soils represents a significant contribution to the total flux of NO from soils in Sweden.Earlier observations of equilibrium concentrations for NO have been verified. These were found to range from 0.2 to 2 ppbv for an unfertilized forest soil and up to 170 ppbv for a fertilized soil. At the rural site in Sweden where these measurements were performed the ambient concentrations where found to be less than this equilibrium concentration, and consequently there was generally a net emission of NO.There are still large uncertainties about the global flux of NO from soils. Using direct measurements on three different types of ecosystems and estimates based on a qualitative discussion for the remaining land areas, a global natural source for NO of the order of 1 Tg N a^–1 was obtained. If 0.35% of the total annual production of fertilizer nitrogen is lost as NO, fertilization of soils may contribute with 20% to the natural flux from soils.     

Emission and flux of DMS from the Australian Antarctic and Subantarctic Oceans during the 1988/89 summer

DMS emissions and fluxes from the Australasian sector of the Antarctic and Subantarctic Oceans, bound by 46–68° S and 65.5–142.6° E, were determined from a limited number of samples (n=32) collected during three summer resupply voyages to Australian Antarctic continental research bases between November 1988 and January 1989 (a 92 day period). The maximum DMS emission from this sector of the Antarctic Ocean was in an area near the Antarctic Divergence (60–63° S) and the minimum DMS emission was from the Antarctic coastal and offshelf waters. The greatest emission of DMS from this sector of the Southern Ocean was from the Subantarctic waters. DMS flux from the Australasian Antarctic Ocean was 64.3×10⁶ (±115) mol d^–1 or 5.9 (±10.6)×10⁹ mol based on an emission of 10.9 (±19.5) µmol m^–2 d^–1 (n=26). The flux of DMS from the Australasian sector of the Subantarctic Ocean was probably twice the flux of DMS from the adjacent Antarctic Ocean.     

Assessment of Major Pools and Fluxes of Carbon in Indian Forests

The major pools including phytomass, soil, litter, and fluxes of carbon (C)due to litterfall and landuse changes were estimated for Indian forests. Basedon growing stock-volume approach at the state and district levels, the Indianforest phytomass was estimated in the range of 3.8–4.3 PgC. The totalsoil organic pool in the top 1m depth was estimated as 6.8 PgC, usingestimated soil organic carbon densities and Remote Sensing (RS) based area byforest types. Based on 122 published Indian studies and RS-based forest area,the total litterfall carbon flux was estimated as 208.8 MgCha^–1 yr^–1.The cumulative net carbon flux (1880–1996) from Indian forests(1880–1996) due to landuse changes (deforestation, afforestation andphytomass degradation) was estimated as 5.4 PgC, using a simple book-keepingapproach. The mean annual net C flux due to landuse changes during1985–1996 was estimated as 9.0 TgC yr^–1. For the recentperiod, the Indian forests are nationally a small source with some regionsacting as small sinks of carbon as well. The improved quantification of poolsand fluxes related to forest carbon cycle is important for understanding thecontribution of Indian forests to net carbon emissions as well as theirpotential for carbon sequestration in the context of the Kyoto protocol.     

Automobile Emissions of Acetonitrile: Assessment of its Contribution to the Global Source

Based on an estimated global fuel consumption of 2.57 × 10¹⁵g(C) y^–1 and the assumption thatthe fossil fuel burned in Austria is globallyrepresentative, an upper limit of 0.021 (+150%, –50%)Tg y^–1 for global CH₃CN emission dueto fossil fuel burning was obtained from the relativeenhancement of the concentrations of toluene, benzene,and acetonitrile (methyl cyanide) during strong,short-term traffic pollution. This is less than 6% ofthe total global budget of CH₃CN, which is dominatedby an emission rate of 0.8 Tg y^–1 from biomassburning.