农田生态系统温室气体排放研究进展

自1985年起,中国科学院大气物理研究所利用自行设计制造的自动观测仪器系统,历时十六年先后对我国四大类主要水稻产区的甲烷排放规律及其与土壤、气象条件和农业管理措施的关系进行了系统野外观测实验,并对稻田甲烷产生、转化和输送机理进行了理论研究,探讨了控制稻田甲烷排放的实用措施,建立了估算和预测稻田甲烷排放的数值模型.在甲烷排放的时空变化规律和转化率研究方面有一系列新的发现,在稻田甲烷产生率、排放率及其与环境条件的关系方面取得一系列新的成果,以充分证据改变了国际上关于全球和中国稻田甲烷排放总量的估算.在对稻田甲     

Methane and the greenhouse-gas footprint of natural gas from shale formations

We evaluate the greenhouse gas footprint of natural gas obtained by high-volume hydraulic fracturing from shale formations, focusing on methane emissions. Natural gas is composed largely of methane, and 3.6% to 7.9% of the methane from shale-gas production escapes to the atmosphere in venting and leaks over the life-time of a well. These methane emissions are at least 30% more than and perhaps more than twice as great as those from conventional gas. The higher emissions from shale gas occur at the time wells are hydraulically fractured—as methane escapes from flow-back return fluids—and during drill out following the fracturing. Methane is a powerful greenhouse gas, with a global warming potential that is far greater than that of carbon dioxide, particularly over the time horizon of the first few decades following emission. Methane contributes substantially to the greenhouse gas footprint of shale gas on shorter time scales, dominating it on a 20-year time horizon. The footprint for shale gas is greater than that for conventional gas or oil when viewed on any time horizon, but particularly so over 20 years. Compared to coal, the footprint of shale gas is at least 20% greater and perhaps more than twice as great on the 20-year horizon and is comparable when compared over 100 years.     

Greenhouse gas emissions from Indian livestock

Livestock constitutes an integral component of Indian agriculture sector and also a major source of GHGs emissions. The study presents a detailed inventory of GHG emissions at district/state level from different age-groups, indigenous and exotic breed of different Indian livestock categories estimated using the recent census 2003 and country-specific emission coefficients based on IPCC guidelines. The total methane emission including enteric fermentation and manure management of livestock was estimated at 11.75 Tg/year for the year 2003. Enteric fermentation constitutes ~91 % of the total methane emissions from Indian livestock. Dairy buffalo and indigenous dairy cattle together contribute 60 % of the methane emissions. The total nitrous oxide emission from Indian livestock for the year 2003 is estimated at 1.42 Gg/year, with 86.1 % contribution from poultry. The total GHGs emission from Indian livestock is estimated at 247.2 Mt in terms of CO₂ equivalent emissions. Although the Indian livestock contributes substantially to the methane budget, the per capita emission is only 24.23 kgCH₄/animal/year. Using the remote sensing derived potential feed/fodder area available for livestock, the average methane flux was calculated as 74.4 kg/ha. The spatial patterns derived in GIS environment indicated the regions with high GHGs emissions that need to be focused subsequently for mitigation measures. The projected estimates indicate a likely increase of 40 % in methane emissions from buffalo population.     

Hiatus of wetland methane emissions associated with recent La Niña episodes in the Asian monsoon region

The variability of methane emissions from wetlands in the tropics and northern temperate regions can explain more than 70% of the interannual variation in global wetland methane emissions, which are largely driven by climate variability. We use climate reanalysis, remote sensing wetland area dataset and simulations from 11 land models contributing to Global Methane Budget to investigate the interannual variation and anomalies of wetland methane emissions in the Asian Monsoon region. Methane emissions in this region steadily increased over 2000–2012. However, abnormally low methane emissions were found in equatorial fully humid (Af), warm temperate winter dry (Cw), and warm temperate fully humid (Cf) Asian Monsoon climate sub-regions in 2008, 2009 and 2011, respectively. These spatially-shifting low emissions occurred simultaneously with observed wetland area shrinkage due to abnormally low precipitation. Interannual variability of wetland methane emissions in Asian Monsoon region are primarily driven by South Asian Monsoon system. However, the abnormally low emissions are related to strong La Niña events, and its accompanying effect of weakened East Asian Monsoon system and eastward Western Pacific subtropical high, which drives the shifting pattern of rainfall, and thus the spatial pattern of methane emission anomalies.     

Leaking methane from natural gas vehicles: Implications for transportation policy in the greenhouse era

A model of the U.S. automobile market is used to test the role that natural gas vehicles (NGVs) might play in reducing greenhouse-gas emissions. Since natural gas (primarily methane) emits less CO₂ per unit of energy than petroleum products, NGVs are an obvious pathway to lower CO₂ emissions. High-and low-demand scenarios are used to forecast the emissions from unrestricted growth and a modest program of conservation, respectively. Based on these scenarios, a reference scenario is developed that projects a possible future path of automobile use and efficiency. It is found that without a dramatic increase in automobile use, fuel consumption and greenhouse-gas emissions from automobiles in the United States will probably decrease in the future, provided that efficiency continues to improve at modest rates. In theory, NGVs can help shift emissions even further down.A second objective is to quantify the role that leaking methane might play in offsetting some of the greenhouse advantages of NGVs. To do this, a simple atmospheric chemistry model is applied to the reference scenario; several leak rates and feedback factors are used to test the sensitivity of the projected green-house forcing from now until 2050. Committed warming beyond 2050 is not included, and the results should be interpreted with that in mind.It is highly unlikely that switching automobiles from gasoline to natural gas will appreciably lower future greenhouse forcing. Constraints on vehicle miles travelled as well as continued improvements in vehicle efficiency will make a much larger contribution towards controlling global warming.     

Sensitivity of multi-gas climate policy to emission metrics

The Global Warming Potential (GWP) index is currently used to create CO₂-equivalent emission totals for multi-gas greenhouse targets. While many alternatives have been proposed, it is not possible to uniquely define a metric that captures the different impacts of emissions of substances with widely disparate atmospheric lifetimes, which leads to a wide range of possible index values. We examine the sensitivity of emissions and climate outcomes to the value of the index used to aggregate methane emissions using a technologically detailed integrated assessment model. The methane index is varied between 4 and 70, with a central value of 21, which is the 100-year GWP value currently used in policy contexts. We find that the sensitivity to index value is, at most, 10–18 % in terms of methane emissions but only 2–3 % in terms of the maximum total radiative forcing change, with larger regional emissions differences in some cases. The choice of index also affects estimates of the cost of meeting a given end of century forcing target, with total two-gas mitigation cost increasing by 7–9 % if the index is increased, and increasing in most scenarios from 4 to 23 % if the index is lowered, with a slight (1 %) decrease in total cost in one case. We find that much of the methane abatement occurs as the induced effect of CO₂ abatement rather than explicit abatement, which is one reason why climate outcomes are relatively insensitive to the index value. We also find that the near-term climate benefit of increasing the methane index is small.     

Mitigating methane emissions from livestock: a global analysis of sectoral policies

Methane emissions from livestock enteric fermentation and manure management represent about 40% of total anthropogenic greenhouse gas emissions from the agriculture sector and are projected to increase substantially in the coming decades, with most of the growth occurring in non-Annex 1 countries. To mitigate livestock methane, incentive policies based on producer-level emissions are generally not feasible because of high administrative costs and producer transaction costs. In contrast, incentive policies based on sectoral emissions are likely administratively feasible, even in developing countries. This study uses an economic model of global agriculture to estimate the effects of two sectoral mitigation policies: a carbon tax and an emissions trading scheme based on average national methane emissions per unit of commodity. The analysis shows how the composition and location of livestock production and emissions change in response to the policies. Results illustrate the importance of global mitigation efforts: when policies are limited to Annex 1 countries, increased methane emissions in non-Annex 1 countries offset approximately two-thirds of Annex 1 emissions reductions. While non-Annex 1 countries face substantial disincentives to enacting domestic carbon taxes, developing countries could benefit from participating in a global sectoral emissions trading scheme. We illustrate one scheme in which non-Annex 1 countries collectively earn USD 2.4 billion annually from methane emission permit sales when methane is priced at USD 30/t CO₂-eq.     

Atmospheric methane budget in Africa

This assessment of the atmospheric methane budget for the African Continent is based on a set of experimental data obtained in tropical Africa including methane emission from various biogenic sources, and biomass burning, and methane consumption in savanna and forest soils. Emission rates from the various sources, uptake rates of soils, and complementary data from the litterature allow calculation of regional methane fluxes by means of different data bases. Biomass burning, animals and natural wetlands are the three dominant sources of methane in Africa while rice paddy fields and termites appear as minor sources. The total methane emission is estimated to be in the range 20–40 MT of CH₄ per year, methane uptake by soils being less than 2 MT per year. Net methane emission from the African continent accounts for less than 10% of global emissions from terrestrial ecosystems.     

NUMERICAL SIMULATION OF METHANE EMISSIONS FROM RICE PADDY FIELDS IN THE YANGTZE DELTA OF CHINA*

A numerical simulation model is presented in this paper,which comprises the processes of crop growth,soil organic carbon decomposition,and methane emissions in agroecosystems.Simulation results show that the model can simulate the main process of methane emissions well,and the correlation coefficient between the simulated values and observed data is 0.79 with 239 samples,which passed a significance test of 0.01.The average error of methane emission simulation in whole growth period is about 15%.Numerical analysis of the model indicates that the average temperature during rice growth period has much impacts on methane emissions,and the basic trend of interannual methane emissions is similar to that of average temperature.The amount of methane emissions reduces about 34.93%,when the fertilizer is used instead of manure in single rice paddy.     

NUMERICAL SIMULATION OF METHANE EMISSIONS FROM RICE PADDY FIELDS IN THE YANGTZE DELTA OF CHINA

A numerical simulation model is presented in this paper,which comprises the processes ofcrop growth,soil organic carbon decomposition,and methane emissions in agroecosystems.Simulation results show that the model can simulate the main process of methane emissions well,and the correlation coefficient between the simulated values and observed data is 0.79 with 239samples,which passed a significance test of 0.01.The average error of methane emissionsimulation in whole growth period is about 15%.Numerical analysis of the model indicates that theaverage temperature during rice growth period has much impacts on methane emissions,and thebasic trend of interannual methane emissions is similar to that of average temperature.The amountof methane emissions reduces about 34.93%,when the fertilizer is used instead of manure in singlerice paddy.     

Methane emission from the oligotrophic bog massif in the Northwestern Russia

Results of measuring methane emissions from the Lammin-Suo oligotrophic bog massif are considered. It is shown that emission intensity depends on the methane transport from the active layer of the peat bed. The highest emission intensity is observed in the sedge-sphagnum microlandscape and over swampy hollows of the hummock-ridge complex. It is found that the methane flux intensity approaches zero when the wetland level drops by 30–35 cm from the bog surface. Spatial methane emission variability is estimated within dominating bog landscapes. The methane emission reaches its maximum values (207%) in microlandscapes with oriented microrelief (hummock-ridge complex); in the central bog (sphagnum-suffrutescent-cottongrass landscape afforested with pine), it reaches its lowest level (76%). A model of methane emissions from bogs is developed. The model has been verified from the observational data. The comparison of model calculations with experimental data is indicative of their good agreement, which makes it possible to use the model in different calculations and assessments of the influence of natural factors on the methane emission intensity.     

Transient Behaviour of Tropospheric Ozone Precursors in a Global 3-D CTM and Their Indirect Greenhouse Effects

The global three-dimensional Lagrangian chemistry-transport model STOCHEM has been used to follow the changes in the tropospheric distributions of the two major radiatively-active trace gases, methane and tropospheric ozone, following the emission of pulses of the short-lived tropospheric ozone precursor species, methane, carbon monoxide, NO_x and hydrogen. The radiative impacts of NO_x emissionswere dependent on the location chosen for the emission pulse, whether at the surface or in the upper troposphere or whether in the northern or southern hemispheres. Global warming potentials were derived for each of the short-lived tropospheric ozone precursor species by integrating the methane and tropospheric ozone responses over a 100 year time horizon. Indirect radiative forcing due to methane and tropospheric ozone changes appear to be significant for all of the tropospheric ozone precursor species studied. Whereas the radiative forcing from methane changes is likely to be dominated by methane emissions, that from tropospheric ozone changes is controlled by all the tropospheric ozone precursor gases, particularly NO_xemissions. The indirect radiative forcing impacts of tropospheric ozone changes may be large enough such that ozone precursors should be considered in the basket of trace gases through which policy-makers aim to combat global climate change.     

Implementing CDM for the Indian dairy sector: prospects and issues

What is the potential for developing small-scale CDM projects in India to reduce enteric methane emissions from cattle and buffaloes? The issue of baseline setting for prospective CDM projects is a complex one in the Indian context. The baselines constructed on the basis of aggregate emission rates at the national level are unlikely to be precise as methane emission rates are influenced by the livestock and feed characteristics, which vary widely across regions in an agro-climatically diverse country like India. This calls for establishing a project specific baseline underpinned with regional methane emission rates. The various aspects of sustainable development that merit consideration in formulating a CDM project in the Indian dairy sector include; increasing the productivity of animals, increasing the net income of producers, decreasing the cost of milk production and the transfer of safe technologies. The projects in the sector would be able to meet the ‘additionality’ conditions of the CDM. However, there are a number of constraints in implementing the enteric methane mitigation strategies through a CDM project at the field level. The article discusses these technical, financial, socio-cultural and institutional barriers along with possible responses to these constraints.     

中国稻田甲烷产生和排放研究 Ⅰ.产生和排放机理及其影响因子

综合论述了近 2 0年来中国稻田甲烷排放的研究状况 ,包括中国稻田甲烷排放通量的观测 ,稻田甲烷生成的生物学机理及产生、转化、传输的机理研究 ,稻田甲烷排放的影响因子 ,主要介绍了稻田甲烷产生和氧化过程、影响甲烷排放的因子     

Relative radiative forcing consequences of global emissions of hydrocarbons, carbon monoxide and NOx from human activities estimated with a zonally-averaged two-dimensional model

A global two-dimensional (altitude-latitude) chemistry transport model is used to follow the changes in the tropospheric distribution of the two major radiatively active trace gases, methane and ozone, following step changes to the sustained emissions of the short-lived trace gases methane, carbon monoxide and non-methane hydrocarbons. The radiative impacts were dependent on the latitude chosen for the applied change in emissions. Step change global warming potentials (GWPs) were derived for a range of short-lived trace gases to describe their time-integrated radiative forcing impacts for unit emissions relative to that of carbon dioxide. The GWPs show that the tropospheric chemistry of the hydrocarbons can produce significant indirect radiative impacts through changing the tropospheric distributions of hydroxyl radicals, methane and ozone. For aircraft, the indirect radiative forcing impact of the NO _x emissions appears to be greater than that from their carbon dioxide emissions. Quantitative results from this two-dimensional model study must, however, be viewed against the known inadequacies of zonally-averaged models and their poor representation of many important tropospheric processes.     

一个基于打靶法的大气污染源反演自适应算法

污染源反演对大气污染预报及控制有重要意义。目前普遍采用的源反演统计方法存在对观测误差、源清单先验估计误差敏感等弱点。基于打靶法思想的各种算法以其精度高、程序简单、实用性强的特点被广泛应用于系统控制领域。本文提出的基于打靶法思想的大气污染源反演自适应算法在精度高、算法简明的基础上弥补了统计方法的不足:能处理源清单中的大误差、初值大误差、观测值在个别时间点的大误差;无需先验分布假设及误差估计。本文还以简单模型的理想试验为例,展示了该自适应算法的计算效果。     

大气甲烷浓度长期变化及未来趋势

应用初步建立的全球二维大气化学模式,对工业革命以来甲烷的长期变化进行了模拟研究。模式将CH4、CO和NOx排放源方案进行了参数化。在考虑了CH4排放源以及对OH浓度有重要影响的CO和NOx排放源的长期变化的基础上,模拟了CH4和OH浓度自1840年到20世纪90年代的长期变化趋势。结果表明,工业革命前的大气甲烷体积分数和年排放总量分别为760×10-9和280Tg,1991年大气甲烷的体积分数和年排放总量分别为1611.9×10-9和533.9Tg。而对流层中OH的数密度则由1840年的7.17×105cm-3变化到1991年的5.79×105cm-3,下降了19%。如果CH4、CO及NOx这三种排放源继续按给定的方案增长,那么到2020年大气甲烷的体积分数和年排放总量将增加为2090.7×10-9和966.2Tg,而OH的数密度将为5.47×105cm-3,比1840年降低24%。     

Investigation of parameterization effect on the methane flux estimation from the regional climate model of the main geophysical observatory for the territory of Russia

An effect is studied of parameterization method of the methane flux from the wetlands of Siberia on the results of model estimates carried out using the one-dimensional model of heat transfer in the soils. The results of computations of the regional climate model of the Main Geophysical Laboratory are used as the input data of this model. The computation estimates of seasonal methane flux variations at certain observation points are compared with the measured values of the methane flux. It is shown that the optimal choice of methane flux parameterization at the use of the grid climate model data as the forcing should correspond to the conditions of prevailing subgrid natural complex of one or another type of wetlands. A spatial distribution of methane emission intensity under conditions of the present-day climate and at the end of the 21st century is obtained. The analysis revealed that the methane fluxes in Western Siberia will increase by 1.5–2.5 times by the end of the 21st century.     

Application of stable isotope analysis for improved understanding of the methane budget: comparison of TROICA measurements with TM3 model simulations

Presented is a detailed comparison of CH₄ and δ¹³C–CH₄ measurements with simulations of the global transport model TM3. Experimental data were obtained during campaigns along the Trans-Siberian railroad in the framework of the TROICA project. Two summer (1999 and 2001) and one spring (2003) expeditions are evaluated. Model simulations include sensitivity tests to further investigate the isotopic composition of natural gas and emissions from Siberian wetlands. Comparison of the average mixing ratio of methane and its isotopic composition (δ¹³C) has been performed for different geographic zones, including the European part of Russia, Western Siberia and Central Siberia. Simulations are in reasonable agreement with the measurements for the European part of Russia and confirm a high contribution of natural gas to the observed methane levels. An increase of emission from bogs shifts the simulated methane isotopic composition closer to the observations. The relative importance of the Western Siberia emissions in current inventories is underestimated in comparison with other wetland regions in the former USSR. Simulated average mixing ratios are in a good agreement with the observations in Central Siberia, while ¹³C(CH₄) values tend to be higher than measured in all considered scenarios. These results point to a bias in the modeled source mixture over Russia, which could be repaired by shifting emissions from isotopically heavy methane sources (e.g. coal, oil or biomass burning) to light sources (e.g. wetlands, ruminants, waste treatment). Alternatively, the average isotopic signature of Siberian wetlands may be lighter than expected.     

Methane emission measurements in urban areas in Eastern Germany

We have investigated methane emissions from urban sources in the former East Germany using innovative measurement techniques including a mobile real-time methane instrument and tracer release experiments. Anthropogenic and biogenic sources were studied with the emphasis on methane emissions from gas system sources, including urban distribution facilities and a production plant. Methane fluxes from pressure regulating stations ranged from 0.006 to 24. l/min. Emissions from diffuse sources in urban areas were also measured with concentration maps and whole city flux experiments. The area fluxes of the two towns studied were 0.37 and 1.9 g/m²/s. The emissions from individual gas system stations and total town emissions of this study are comparable to results of similar sites examined in the United States.