Ultraviolet absorption spectrum of trifluoro-bromo-methane,difluoro-dibromo-methane and difluoro-bromo-chloro-methane in the vapor phase

Ultraviolet absorption cross-sections of trifluoro-bromo-methane (CF₃Br-Halon 1301), difluoro-dibromo-methane (CF₂Br₂-Halon 1202) and of difluoro-bromo-chloro-methane (CF₂BrCl-Halon 1211) are measured in the wavelength interval 172–304 nm for temperatures ranging from 210 to 295 K with uncertainties of between 2 and 4%. They are compared with previous measurements available at room temperature. Temperature effects are discussed and parametrical formulae are proposed to compute the absorption cross-sections for wavelengths and temperatures useful in atmospheric modelling calculations. Photodissociation coefficients are presented and their temperature dependence is discussed.     

Temperature-dependence of ultraviolet absorption cross-sections of alternative chlorofluoroethanes

The absorption cross-sections of HCFC-123 (CF₃–CHCl₂), HCFC-141b (CH₃–CFCl₂) and HCFC-142b (CH₃–CF₂Cl) are measured between 170 and 250 nm for temperatures ranging from 295 to 210 K with uncertainties between 2 and 4%. They are compared with other available determinations. Temperature effects are discussed and parametrical formulae are proposed to compute the absorption cross-section for wavelengths and temperatures useful in atmospheric modelling calculations. Photodissociation coefficients are presented and their temperature-dependence is discussed.     

Ultraviolet absorption cross-sections of chloro and chlorofluoro-methanes at stratospheric temperatures

Absorption cross-sections of nine halomethanes (CCl₄, CHCl₃, CH₂Cl₂, CH₃Cl, CFCl₃, CF₂Cl₂, CF₃Cl, CHFCl₂, and CHF₂Cl), measured between 174 and 250 nm for temperatures ranging from 225 to 295 K, are presented with uncertainties ranging from 2 to 4% and compared with previous determinations made for comparable temperature ranges.The largest temperature effect which takes place near the absorption threshold, decreases the absorption cross-section up to 50% for highly chlorinated methanes, but is negligible for molecules highly stabilized by hydrogen and/or fluorine. Extrapolated values for temperatures of aeronomical interest are presented, as well as parametrical formulas which give absorption cross-section values for given wavelength and temperature ranges.     

The equilibrium constant of NO2 with N2O4 and the temperature dependence of the visible spectrum of NO2: A critical review and the implications for measurements of NO2 in the polar stratosphere

Measurements of stratospheric NO₂ by ground-based visible spectrometers rely on laboratory measurements of absorption cross-sections. We review low-temperature laboratory measurements, which disagree by amounts claimed to be significant. Our recalculation of their errors shows that in general disagreements are not significant and that errors in the ratios of cross-sections at low to room temperature are between ±3% and ±8.8%. Of these errors, up to ±3.5% was contributed by errors in the equilibrium constant,K _p, in those measurements where the pressure was above 0.1 mbar.We review measurements and calculations ofK _p, which were accurate to ±5% from 300 to 233 K. Each method was potentially flawed. For example, infrared measurements of the partial pressure of NO₂ ignored the dependence of absorption on total pressure. From thermodynamic theory, formulae forK _pcan be derived from expressions for the variation of heat capacity with temperature. Contrary to common belief, coefficients in the formulae used by spectroscopists were not derived from the thermodynamic quantities. Rather, they were fitted to measurements or to calculations. Hence, they are empirical and it is dangerous to extrapolate below 233 K, the lowest temperature of the measurements.There are no measurements of NO₂ cross-sections below 230 K. Extrapolation of these cross-sections to analysis of measurements of NO₂ at the low temperatures of the Arctic and Antarctic stratosphere is also dangerous. For satisfactory analysis of polar spectra, the NO₂ cross-sections should be measured at temperatures down to 190 K with a relative accuracy of ±1%. This difficult experiment would need a cell of minimum length 32 m whose length can be adjusted. Because their effects are circular, many errors cannot be removed simply. Although circular errors also arise in the measurements ofK _pand of the infrared spectrum, their weights differ from those in the visible spectrum. The optimum experiment might therefore simultaneously measure the visible and infrared spectra andK _p.     

The NO2 absorption spectrum. I: Absorption cross-sections at ambient temperature in the 300–500 nm region

New laboratory measurements of NO₂ absorption cross-sections have been performed between 300 and 500 nm at ambient temperature with improved experimental conditions: low gas pressures, long absorption paths, suitable absorbance values, narrow spectral bandwidths. The data, stored at 0.01 nm intervals, have been compared to those of the more recent studies and some reasons of disagreement are discussed.In the photolysis region below 400 nm, our absorption cross-sections are larger than those previously published, suggesting that the photodissociation coefficient calculated from the current data sets is underestimated. In the structured region of the spectrum above 400 nm, improvement of the resolution gives more precise values useful for optical measurements in atmosphere.Unité de Recherche Associée au CNRS.     

Climatic change in Britain: Is SO2 more significant than CO2?

Summary Many climate scientists have suggested that anthropogenic emissions of greenhouse gases may create severe climate problems for Britain; however, the potential cooling effects of sulphur dioxide are widely acknowledged. In this investigation, we analyze British mean annual temperature, mean annual precipitation, and mean diurnal air temperature range over the period 1929–1988. Our analyses of these records reveal (a) a shift in the early 1950s away from warming and toward cooling, (b) a relative decline in maximum air temperatures when compared to minimum air temperatures, (c) a strong decline in the diurnal air temperature range and (d) a significant linkage between diurnal temperature range and precipitation. Given these signals in the observed climate record, it would appear that SO₂ rather than CO₂ has been the major anthropogenic climate influence in Britain over the past four decades.With 6 Figures     

The NO2 Absorption Spectrum. IV: The 200–400 nm Region at 220 K

Previous experiments in the 400–500 nm region (Coquart et al., 1995) have been extended to the 200–400 nm region to determine the absorption cross-sections of NO₂ at 220 K. The NO₂ and N₂O₄ cross-sections are obtained simultaneously from a calculation applied to the data resulting from measurements at low pressures. A comparison between the NO₂ cross-sections at 220 K and at ambient temperature shows that the low temperature cross-sections are generally lower, except in the region of the absorption peaks. Comparisons are also made with previous data at temperature close to 220 K.     

NO<Subscript>3</Subscript> Vertical Profile Measurements from Remote Sensing Balloon-Borne Spectrometers and Comparison with Model Calculations

Eleven vertical profiles of stratospheric NO₃ have been obtained since 1992 using the AMON and SALOMON balloon-borne UV-visible spectrometers. The measurements are compared to the SLIMCAT 3D model and calculations based on the steady-state hypothesis for NO₃. The calculations cannot reproduce some parts of the profiles which exhibit strong concentration fluctuations over few kilometres, as a consequence of the dependence of NO₃ on local temperature variations. A statistical use of the data allows us to estimate the influence of the temperature dependence of the absorption cross-section on the data analysis, and the validity of the recommended reaction rates available in the literature. Discrepancies exist between the model based on recommended kinetics and observations at warmer temperatures. Nevertheless, the analysis is biased by local temperature inhomogeneities, and only a low-resolution vertical shape of the NO₃ profiles can be retrieved.     

A study on NO and NO2 absorption properties by using line-tunable CO laser

The absorption properties of NO in 5.2 μm band and NO2 in 6.2 μm band are measured for some definite wavelengths by using line-tunable CO laser and long-path absorption cell. The absorption coefficients for 49 CO laser wavelengths are given and variations of absorption withpartial and total pressures are analysed. Fur-thermore, the experimental errors and the interference of water vapour with the absorption at definite laser lines are also discussed.     

Interactive effects of elevated [CO2] and temperature on growth and development of a short- and long-season peanut cultivar

Temperature and CO₂ are two of the main environmental factors associated with climate change. It is generally expected that elevated [CO₂] will increase crop production. However, other environmental factors such as temperature along with management practices could further modify a crop’s response to CO₂. The goal of this study was to determine the interactive effects of elevated [CO₂] and above-optimum temperature on growth, development and yield of two peanut (Arachis hypogaea L.) cultivars, e.g., Pronto and Georgia Green. One of the objectives was to determine if there was any variation in response between these two cultivars with respect to possible adaptation to climate change. Peanut plants were grown in controlled environment chambers in the University of Georgia Envirotron under conditions of non-limiting water and nutrient supply. Plants were exposed to day/night air temperatures of 33/21°C (T _A), 35.5/23.5°C (T _A + 2.5°C), and 38/26°C (T _A + 5°C) along with CO₂ treatments of 400 and 700 μmol CO₂ mol^???1 air. The selected range of temperatures was based on the temperatures that are common for southwest Georgia during the summer months. The results showed that LAI of both cultivars responded positively, e.g., 28.3% for Pronto and 49.3% for Georgia Green to elevated [CO₂]. Overall, elevated [CO₂] alone resulted in a significant increase in total biomass at final harvest across all temperatures (P?< 0.0001), but decreased final seed yield (P?< 0.0005), except for Georgia Green at (T _A + 5°C). The higher temperatures compared to T _A reduced the relative response of total biomass to CO₂ for both cultivars. It can be concluded that final seed yield response to CO₂ depends on the sensitivity of individual cultivars to temperature, especially during the reproductive development stage.     

General circulation model simulation of mild nuclear winter effects

The climatic effects of an elevated uniform global layer of purely absorbing smoke of absorption optical depth 0.2 have been simulated using a version of the 9-level spectral model of McAvaney et al. (1978). The model was run at rhomboidal wave number 21 with convective adjustment, prognostic precipitation and soil hydrology, but fixed zonally averaged climatological cloud and fixed sea surface temperature, for constant January and July conditions with and without smoke absorption. Results show a reduction in convective rainfall in the tropics and monsoonal regions of the order of 50%, with diurnal average soil surface coolings of several degrees C except in those locations where the reduction in soil moisture is sufficient to effectively stop evaporation at the surface. In that case, small increases in temperature may occur. Results over Australia are consistent with the zonal mean picture. Run in a diurnal cycle mode, the model shows that daily maximum temperatures are more strongly affected, with soil surface coolings of the order of 2°–3° C in summer (with some local warmings) and 4°–6° C in winter. Overninght minimum temperatures cool by only 1°–2° C in both summer and winter. Possible effects of a lowering of sea surface temperature, variations in cloud cover, neglect of scattering by smoke, and infrared absorption and emission by the smoke are discussed.     

An open path,fast response infrared absorption gas analyzer for H2O and CO2

An open path infrared absorption based instrument for fast response measurements of H₂O and CO₂ fluctuations is described. This instrument performed reliably in several field experiments in both terrestrial and marine environments, on both fixed (tower) and mobile (boat, plane) flux platforms. Noise levels for H₂O and CO₂ concentrations were less than 10 mg/m³ and 300 g/m³, respectively for frequencies between 0.005 and 10 Hz. Drifts in instrument output, associated with changes in instrument temperature, are compensated for electronically.     

Temperature, CO2 and the growth and development of wheat: Changes in the mean and variability of growing conditions

The experiment described here resulted from simulation analyses of climate-change studies that highlighted the relative importance of changes in the mean and variance of climatic conditions in the prediction of crop development and yield. Growth and physiological responses of four old cultivars of winter wheat, to three temperature and two carbon dioxide (CO₂) regimes (350 or 700 ppmv) were studied in controlled environment chambers. Experimental results supported the previous simulation analyses. For plants experiencing a 3 °C increase in day and night temperatures, relative to local long-term mean temperatures (control treatment), anthesis and the end of grain filling were advanced, and grain and dry matter yields were reduced by 27% and 18%, respectively. Increasing the diurnal temperature range, but maintaining the same mean temperature as the control, reduced the maximum leaf area (27%) and grain yield (13%) but did not affect plant development. Differences among the temperature treatments in both phyllochron interval and anthesis date may have resulted from differences between measured air, and unmeasured plant, temperatures, caused by evaporative cooling of the plants. Thermal time (base = 0 °C), calculated from air temperature, from anthesis to the end of grain filling was about 650 °C d for all cultivars and treatments. Doubling ambient CO₂ concentration to 700 ppmv reduced maximum leaf area (21%) but did not influence plant development or tiller numbers.     

A Note on an improved expression for the atmospheric CO2, N2O,CH4 and O2 integral transmission function: Research note

Abstract

A new analytical expression for the integral transmission function corresponding to the uniformly mixed atmospheric gases (CO₂, N₂O, CH4 and O₂) is proposed for solar radiation models. The expression is based on the latest known spectral absorption data of the gases as well as on the Ñeckel and Labs (1981) extraterrestrial solar spectrum, which is the best currently available. The proposed formula is compared with the known expressions for the integral transmission function of the uniformly mixed gases and the results of this comparison are discussed.     

Effects of temperature rise and increase in CO2 concentration on simulated wheat yields in Europe

A crop-growth-simulation model based on SUCROS87 was used to study effects of temperature rise and increase of atmospheric CO₂ concentration on wheat yields in several regions in Europe. The model simulated potential and water-limited crop production (growth with ample supply of nutrients and in the absence of damage by pests, diseases and weeds). Historic daily weather data from 13 sites in Western Europe were used as starting point.For potential production (optimal water) a 3 °C temperature rise led to a yield decline due to a shortening of the growing period on all locations. Doubling of the CO₂ concentration caused an increase in yield of 40% due to higher assimilation rates. It was found that effects of higher temperature and higher CO₂ concentration were nearly additive and the combination of both led to a yield increase of 1–2 ton ha^-1. A very small CO₂-temperature interaction was found: the effect of doubled CO₂ concentration on crop yield was larger at higher temperatures. The inter-annual yield variability was hardly affected.When water was limiting crop-production effects of temperature rise and higher CO₂ levels were different than for the potential production. Rise in temperature led to a smaller yield reduction, doubled CO₂ concentration to a larger yield increase and combination of both led to a large yield increase (3 ton ha^-1) in comparison with yields simulated for the present situation. Both rise in temperature and increase in the CO₂ concentration reduced water requirements of the crop. Water shortages became smaller, leading to a reduction in inter-annual variability. It is concluded that when no major changes in precipitation pattern occur a climate change will not affect wheat yields since negative effects of higher temperatures are compensated by positive effects of CO₂ enrichment.     

Recent climatic change in Australia: Implications for a CO2-warmed earth

A significant change in mean precipitation occurred over much of Australia between 1913–45 and 1946–78. This is described on a seasonal basis and related to possible changes in the atmospheric circulation. It now appears that during this time mean surface temperatures in the mid southern latitude zone increased by up to 1 °C. This temperature change could be at least partly due to an increase in atmospheric CO₂ concentrations from about 260 ppmv in the early nineteenth century. In any case the observed temperature increase is similar to the predicted future effects of a 50% increase in atmospheric CO₂ concentrations. Thus the climatic change which occurred earlier this century is at least a good analogy for the effects of a CO₂-induced global warming which is expected to occur over a similar time interval in the future. This allows the construction of more detailed and quantitative climate scenarios. The most noteworthy conclusion is that marked changes in the seasonally of precipitation should be anticipated, with seasonal changes in some areas being of the order of 50% or more for a doubling of CO₂ content. The results are in general consistent with earlier more qualitative scenarios for Australia.     

Constraints on the temperature sensitivity of global soil respiration from the observed interannual variability in atmospheric CO2

Carbon cycle feedbacks have been shown to be very important in predicting climate change over the next century. The response of the terrestrial carbon cycle to climate change depends on the competition between increased respiration due to warmer temperatures and increased uptake due to elevated CO₂levels. Whether the terrestrial carbon cycle remains a sink for anthropogenic carbon, or switches to become a source, depends particularly on the response of soil respiration to temperature. Here we use observed global atmospheric CO₂concentration to constrain the behaviour of soil respiration in a coupled climate–carbon cycle GCM.     

The NO2 absorption spectrum. II. Absorption cross-sections at low temperatures in the 400–500 nm region

With improved experimental conditions already used for measurements at ambient temperature (Mérienneet al., 1994), new values have been found for the absorption cross-sections of NO₂ at 240 and 220 K in the 400–500 nm spectral region. Using a better resolution than in previous studies we show that the temperature effect is not negligible and should be taken into account for the optical measurements of atmospheric NO₂ amounts by differential absorption methods.Unité de Recherche Associée au CNRS.     

Projected global climate change impact on water temperatures in five north central U.S. streams

The effect of projected global climate change due to a doubling of atmospheric CO₂ on water temperatures in five streams in Minnesota was estimated using a deterministic heat transport model. The model calculates heat exchange between the atmosphere and the water and is driven by climate parameters and stream hydrologic parameters. The model is most sensitive to air temperature and solar radiation. The model was calibrated against detailed measurements to account for seasonally variable shading and wind sheltering. Using climate projections from the GISS, GFDL and OSU GCMs as input; stream temperature simulations predict a warming of freely flowing river reaches by 2.4 °C to 4.7 °C when atmospheric CO₂ doubles. In small shaded streams water temperatures are predicted to rise by an additional 6 °C in summer if trees along stream banks should be lost due to climate change or other human activities (e.g. logging). These projected water temperature changes have significant consequences for survival and growth of fishes. Simulation with the complete heat budget equations were also used to examine simplified water temperature/air temperature correlations.     

Past and future polar amplification of climate change: climate model intercomparisons and ice-core constraints

Climate model simulations available from the PMIP1, PMIP2 and CMIP (IPCC-AR4) intercomparison projects for past and future climate change simulations are examined in terms of polar temperature changes in comparison to global temperature changes and with respect to pre-industrial reference simulations. For the mid-Holocene (MH, 6,000 years ago), the models are forced by changes in the Earth’s orbital parameters. The MH PMIP1 atmosphere-only simulations conducted with sea surface temperatures fixed to modern conditions show no MH consistent response for the poles, whereas the new PMIP2 coupled atmosphere–ocean climate models systematically simulate a significant MH warming both for Greenland (but smaller than ice-core based estimates) and Antarctica (consistent with the range of ice-core based range). In both PMIP1 and PMIP2, the MH annual mean changes in global temperature are negligible, consistent with the MH orbital forcing. The simulated last glacial maximum (LGM, 21,000 years ago) to pre-industrial change in global mean temperature ranges between 3 and 7°C in PMIP1 and PMIP2 model runs, similar to the range of temperature change expected from a quadrupling of atmospheric CO₂ concentrations in the CMIP simulations. Both LGM and future climate simulations are associated with a polar amplification of climate change. The range of glacial polar amplification in Greenland is strongly dependent on the ice sheet elevation changes prescribed to the climate models. All PMIP2 simulations systematically underestimate the reconstructed glacial–interglacial Greenland temperature change, while some of the simulations do capture the reconstructed glacial–interglacial Antarctic temperature change. Uncertainties in the prescribed central ice cap elevation cannot account for the temperature change underestimation by climate models. The variety of climate model sensitivities enables the exploration of the relative changes in polar temperature with respect to changes in global temperatures. Simulated changes of polar temperatures are strongly related to changes in simulated global temperatures for both future and LGM climates, confirming that ice-core-based reconstructions provide quantitative insights on global climate changes. An erratum to this article can be found at