Black carbon relationships with emissions and meteorology in Xi'an, China

Aerosol black carbon (BC) was measured every 5 min at Xi'an, China from September 2003 to August 2005. Daily BC concentrations ranged from 2 to 65 μg m^− 3, averaging 14.7 ± 9.5 μg m^− 3 and displayed clear summer minima and winter maxima. BC typically peaked between 0800 and 1000 LST and again between 2000 and 2200 LST, corresponding with morning and evening traffic combined with nighttime residential cooking and heating. The nocturnal peak was especially evident in winter, when more domestic heating is used and pollutant-trapping surface-inversions form earlier than in summer. BC frequency distributions the most commonly occurring concentrations occurred between 5 and 10 μg m^− 3 in all four seasons. BC ranged from 1.6% and 15.6%, and averaged 8.3% of PM_2.5. A clear inverse relationship between BC and wind speed (WS) was found when WS was below 2.5 to 3.0 m s^− 1, implying a local origin for BC. Mixed layer depths (MLDs) were shallower during BC episodes compared to cleaner conditions.     

Characteristics of organic and elemental carbon in PM2.5 samples in Shanghai, China

Shanghai is the largest industrial and commercial city in China, and its air quality has been deteriorating for several decades. However, there are scarce researches on the level and seasonal variation of fine particle (PM_2.5) as well as the carbonaceous fractions when compared with other cities in China and around the world. In the present paper, abundance and seasonal characteristics of PM_2.5, organic carbon (OC) and elemental carbon (EC) were studied at urban and suburban sites in Shanghai during four season-representative months in 2005–2006 year. PM_2.5 samples were collected with high-vol samplers and analyzed for OC and EC using thermal-optical transmittance (TOT) protocol. Results showed that the annual average PM_2.5 concentrations were 90.3–95.5 μg/m³ at both sites, while OC and EC were 14.7–17.4 μg/m³ and 2.8–3.0 μg/m³, respectively, with the OC/EC ratios of 5.0–5.6. The carbonaceous levels ranked by the order of Beijing > Guangzhou > Shanghai > Hong Kong. The carbonaceous aerosol accounted for  30% of the PM_2.5 mass. On seasonal average, the highest OC and EC levels occurred during fall, and they were higher than the values in summer by a factor of 2. Strong correlations (r = 0.79–0.93) between OC and EC were found in the four seasons. Average level of secondary organic carbon (SOC) was 5.7–7.2 μg/m³, accounting for  30% of the total OC. Strong seasonal variation was observed for SOC with the highest value during fall, which was about two times the annual average.     

Size-resolved aerosol chemical concentrations at rural and urban sites in Central California, USA

Aerosol size distributions were measured with Micro Orifice Uniform Deposit Impactor (MOUDI) cascade impactors at the rural Angiola and urban Fresno Supersites in California's San Joaquin Valley during the California Regional PM₁₀/PM_2.5 Air Quality Study (CRPAQS) winter campaign from December 15, 2000 to February 3, 2001. PM_2.5 filter samples were collected concurrently at both sites with Sequential Filter Samplers (SFS). MOUDI nitrate (NO₃⁻) concentrations reached 66 μg/m³ on January 6, 2001 during the 1000–1600 PST (GMT-8) period. Pair-wise comparisons between PM_2.5 MOUDI and SFS concentrations revealed high correlations at the Angiola site (r > 0.93) but more variability (r < 0.85) at the Fresno site for NO₃⁻, sulfate (SO₄⁼), and ammonium (NH₄⁺). Correlations were higher at Fresno (r > 0.87) than at Angiola (r < 0.7) for organic carbon (OC), elemental carbon (EC), and total carbon (TC). NO₃⁻ and SO₄⁼ size distributions in Fresno were multi-modal and wider than the uni-modal distributions observed at Angiola. Geometric mean diameters (GMD) were smaller for OC and EC than for NO₃⁻ and SO₄⁼ at both sites. OC and EC were more concentrated on the lowest MOUDI stage (0.056 µm) at Angiola than at Fresno. The NO₃⁻ GMD increased from 0.97 to 1.02 µm as the NO₃⁻ concentration at Angiola increased from 43 to 66 µg m^− 3 during a PM_2.5 episode from January 4–7, 2001. There was a direct relationship between GMD and NO₃⁻ and SO₄⁼ concentrations at Angiola but no such relationships for OC or EC. This demonstrates that secondary aerosol formation increases both concentration and particle size for the rural California environment.     

Carbonaceous materials in size-segregated atmospheric aerosols from urban and coastal-rural areas at the Western European Coast

A high-volume cascade impactor, equipped with a PM10 inlet, was used to collect size-segregated aerosol samples during the summer of 2004 at two Portuguese locations: a coastal-rural area (Moitinhos) and an urban area (Oporto). Concentrations of airborne particulate matter (PM), total carbon (TC), organic carbon (OC), elemental carbon (EC), and water-soluble organic carbon (WSOC) were determined for the following particle size ranges: < 0.49, 0.49–0.95, 0.95–3.0, and 3.0–10 µm. The total PM mass concentrations at the urban and coastal-rural sites ranged from 22.8 to 79.6 μg m^− 3 and 19.9 to 28.2 μg m^− 3, respectively, and more than 56% of the total aerosol mass was found in the fractions below 3.0 μm. At both locations the highest concentrations of OC and EC were found in the submicrometer size range. The regional variability for the OC and EC concentrations, with the highest concentrations being found in the urban area, was related to the contribution of local primary sources (mostly traffic emissions). It was also verified an enrichment of the small size particles in WSOC, representing on average 37.3(± 12.4)% and 59.7(± 18.0)% of OC in the very fine aerosol at the coastal-rural and urban areas, respectively. The amount of secondary OC calculated by the minimum OC/EC ratio method indicates that secondary organic aerosol formation was important throughout the study at both sites. The obtained results suggest that long-range transport and favourable summer conditions for photochemical oxidation are key factors determining secondary OC formation in the coastal-rural and urban areas. The ultraviolet absorption properties of the chromophoric constituents of the WSOC fractions were also different among the different particle size ranges and also between the two sampling locations, thus suggesting the strong impact of the diverse emission sources into the composition of the size-segregated organic aerosol.     

Statistical analysis of microphysical properties and the parameterization of effective radius of warm clouds in Beijing area

In this paper warm cloud microphysical parameters including cloud droplet number concentration (N_c), liquid water content (q_l) and effective radius (r_e) from 75 flights around the Beijing area during 2005 and 2006 are summarized. Average N_c (cm^− 3) for Cu, Sc, Ac, As and Ns are 376 ± 290, 257 ± 226, 147 ± 112, 60 ± 35 and 60 ± 84, respectively. Many records of high N_c above 1000 cm^− 3 are observed. The large standard deviations indicate a large variation of N_c and q_l in this region. The maxima of q_l reach 1.4 g m^− 3 in Cu and 1.0 g m^− 3 in Sc, respectively. Different parameterizations of effective radius are examined with the in-situ data in this area. There are different ways to obtain the prefactor representing the relationship between effective radius and mean volume radius. Significant systematic errors are found to be at the large sizes when the prefactor is expressed with relative dispersion under the Gamma Distribution. Fixed prefactor of 1, which was widely used, even produces much larger error. A prefactor of 1.22 is found to be better than the former two methods by fitting with the observed data. The effective radius is further parameterized as functions of mean volume radius, liquid water content and cloud droplet number concentration. We suggest that the effective radius can be parameterized as r_e,p ≈ 1.20r_v + 0.22–1.28/r_v², which is a practical and more accurate scheme without too much computation complexity.     

Aliphatic alkanes and polycyclic aromatic hydrocarbons in atmospheric PM10 aerosols from Baoji, China: Implications for coal burning

Normal alkanes and PAHs in atmospheric PM₁₀ aerosols collected during 2008 winter and spring in Baoji, a mid-scale inland city of China, were determined on a molecular level. Concentrations of n-alkanes ranged from 232 to 3583 ng/m³ with an average of 1733 ng/m³ in winter and from 124 to 1160 ng/m³ with an average of 449 ng/m³ in spring, while PAHs in the PM₁₀ samples were 594 ± 405 and 128 ± 82 ng/m³ in the two seasons. Molecular compositions showed that CPI (odd/even) values of n-alkanes were close to unity for all the samples especially in winter, and diagnostic ratios of PAHs (e.g., Phe/(Phe + Ant), CPAH/ΣPAHs and IcdP/(IcdP + BghiP)) were found similar to those in coal burning smoke with a strong linear relationship (R² ≥ 0.85) between PAHs and fossil fuel derived n-alkanes, demonstrating that coal burning is the main source of n-alkanes and PAHs in the city, especially in winter due to house heating. Concentrations of the determined compounds in Baoji are much higher than those in Chinese mega-cities, suggesting that air pollution in small cities in the country is more serious and need more attention.     

The remarkable wide range spatial scaling of TRMM precipitation

The advent of space borne precipitation radar has opened up the possibility of studying the variability of global precipitation over huge ranges of scale while avoiding many of the calibration and sparse network problems which plague ground based rain gage and radar networks. We studied 1176 consecutive orbits of attenuation-corrected near surface reflectivity measurements from the TRMM satellite PR instrument. We find that for well-measured statistical moments (orders 0 < q < 2) corresponding to radar reflectivities with dBZ < 57 and probabilities > 10^− 6, that the residuals with respect to a pure scaling (power law) variability are remarkably low: ± 6.4% over the range 20,000 km down to 4.3 km. We argue that higher order moments are biased due to inadequately corrected attenuation effects. When a stochastic three — parameter universal multifractal cascade model is used to model both the reflectivity and the minimum detectable signal of the radar (which was about twice the mean), we find that we can explain the same statistics to within ± 4.6% over the same range. The effective outer scale of the variability was found to be 32,000 ± 2000 km. The fact that this is somewhat larger than the planetary scale (20,000 km) is a consequence of the residual variability of precipitation at the planetary scales. With the help of numerical simulations we were able to estimate the three fundamental parameters as α ≈ 1.5, C₁ = 0.63 ± 0.02 and H = 0.00 ± 0.01 (the multifractal index, the codimension of the mean and the nonconservation parameter respectively). There was no error estimate on α since although α = 1.5 was roughly the optimum value, this conclusion depended on assumptions about the instrument at both low and high reflectivities. The value H = 0 means that the reflectivity can be modeled as a pure multiplicative process, i.e. that the reflectivity is conserved from scale to scale. We show that by extending the model down to the inner “relaxation scale” where the turbulence and rain decouple (in light rain, typically about 40 cm), that even without an explicit threshold, the model gives quite reasonable predictions about the frequency of occurrence of perceptible precipitation rates.While our basic findings (the scaling, outer scale) are almost exactly as predicted twenty years ago on the basis on ground based radar and the theory of anisotropic (stratified) cascades, they are incompatible with classical turbulence approaches which require at least two isotropic turbulence regimes separated by a meso-scale “gap”. They are also incompatible with classical meteorological phenomenology which identifies morphology with mechanism and breaks up the observed range 4 km–20 000 km into several subranges each dominated by different mechanisms. Finally, since the model specifies the variability over huge ranges, it shows promise for resolving long standing problems in rain measurement from both (typically sparse) rain gage networks and radars.     

Elemental and organic carbon in atmospheric aerosols at downtown and suburban sites in Prague

Organic and elemental carbon (OC and EC) content in PM₁₀ was studied at two sites in Prague, which were located in a suburb and in the downtown. Similar overall average levels were found for both species and also for the PM₁₀ mass at the two sites (i.e., 5.5 and 4.8 μg/m³ for OC, 0.74 and 0.80 μg/m³ for EC, and 33 μg/m³ and 37 μg/m³ for the PM₁₀ mass at the suburb and downtown site, respectively), but substantial differences were observed between the two sites in some seasons and/or meteorological situations. Approximately three times higher values were found for OC in winter compared to summer, with a higher winter/summer ratio for the suburban site. The differences for EC were smaller, but still, compared to summer, more than two times higher EC levels were observed during autumn at the suburban site and 1.5 higher EC levels in winter and autumn at the downtown site. The lowest OC to EC ratios at the suburban site were 3.4, while they were around 1.3 for the downtown site. It was found that the origin of the air masses had a major impact on the observed PM₁₀ mass and OC levels, with largest concentrations noted for air masses recirculating over central Europe and arriving from southeastern Europe in winter. Trajectories coming from the west and northwest originating above the Atlantic Ocean and the Artic brought the cleanest air masses to the sites. For EC the largest difference between the two sites was observed for northwesterly winds during the non-heating season when the suburban site was upwind of Prague.     

Charge source of cloud-to-ground lightning and charge structure of a typical thunderstorm in the Chinese Inland Plateau

GPS-synchronized measurements of electric (E) field changes induced by lightning flashes were recorded at six stations in the northeastern verge of the Tibetan Plateau. The height and magnitude of charge neutralized by 65 return strokes, including 16 negative cloud-to-ground (CG) flashes and 2 positive CG flashes, have been fitted with the nonlinear least-square method based on the E field changes of CG flashes observed in a typical thunderstorm with larger-than-usual lower positive charge center (LPCC). Results show that the height of the charge region neutralized by negative CG flashes ranges from 3 km to 5 km above the ground, corresponding to an ambient temperature between − 2 °C and − 15 °C. For the two positive CG flashes, the neutralized charge regions are located at a height of about 5.5 km and the ambient temperature is about − 18 °C, indicating the existence of upper positive charge in the thunderstorm.     

Concentration and gas/particle partitioning of polychlorinated biphenyls (PCBs) at an industrial site at Bursa, Turkey

Gas and particle phase concentrations of atmospheric polychlorinated biphenyls (PCBs) were measured at an urban/industrial site in the city of Bursa, Turkey. PCB concentration levels were presented between July 2004 and May 2005. Average particle and gas phase concentrations of individual PCB congeners ranged from 0.08 (PCB-183) to 6.86 (PCB-49) pg m^− 3 and from 0.01 (PCB-209) to 47.2 (PCB-33) pg m^− 3, respectively. The mean concentration of total (gas + particle) PCBs varied between 24.27 and 666.21 pg m^− 3 with an average of 287.27 ± 174.80 pg m^− 3. PCB concentrations at the sampling site were higher than the concentrations reported at non-urban sites. PCBs partitioned between gas and particle phases and the partitioning was examined according to different approaches such as logK_p–logP_L^o, logK_p–logK_OA and the Junge–Pankow model. In order to present possible interactions, a correlation matrix based on PCB congeners and meteorological parameters was constructed. Application of the Clausius–Clapeyron equation yielded a low slope value indicating possible emissions from local and regional sources originating mainly from urban/industrial areas, landfill and waste incineration plant. Then, likely dry deposition fluxes were estimated depending on reported dry deposition velocity and atmospheric concentration values.     

One year measurements of aerosol optical properties over an urban coastal site: Effect on local direct radiative forcing

We present results of direct aerosol radiative forcing over a French Mediterranean coastal zone based on one year of continuous observations of aerosol optical properties during 2005–2006. Monthly-mean aerosol optical depth at 440 nm ranged between 0.1 and 0.34, with high Angstrom coefficient (α > 1.2). The single scattering albedo (at 525 nm) estimated at the surface ranged between 0.7 and 0.8, indicating significant absorption. The presence of aerosols over the Mediterranean zone during summer decreases the shortwave radiation reaching the surface by as much as 26 ± 3.9 W m^− 2, and increases the top of the atmosphere reflected radiation by as much as 5.2 ± 1.0 W m^− 2. The shortwave atmospheric absorption translates to an atmospheric heating of 2.5 to 4.6 K day^− 1. Concerted efforts are needed for investigating the possible impact of the increase in heating rate on the maintenance of heat-waves frequently occurring over this coastal region during summer time.     

Study of small ions concentration in the air above Athens, Greece

Measurements of positive and negative small atmospheric ion concentrations have been made regularly since 1968 at the National Observatory of Athens (NOA). In this paper the 17-year period 1968–1984 is summarized. The diurnal and annual variations are examined, and Fourier analysis is also used for the study of the diurnal variation. The concentrations of small ions follow a double diurnal course. The maxima occur near 3–5 h and 13–16 h local time (LT = GMT + 2 h). The minima are observed at 6–8 h and 21–23 h. The annual course of small ions presents maximum concentration values around the summer season. The mean of the small ion concentration (SIC) for the 17-year period (1968–1984) is n₊ = 188.8 ions/cm³ for positive ions and n₋ = 151.1 ions/cm³ for negative ions. Their ratio is equal to 1.25. The year-to-year variation of SIC for the examined period shows a negative trend. The results from multiple regression analysis show that wind speed and SIC are positively correlated, while relative humidity, smoke and sulphur dioxide are negatively correlated.     

Correlation between black carbon aerosols, carbon monoxide and tropospheric ozone over a tropical urban site

Black carbon aerosols plays an important role in the earth's radiative balance and little is known of their concentrations, distributions, source strength, and especially the aerosol chemistry of the developing world. The present study addresses the impact of back carbon aerosols on different atmospheric species like CO and tropospheric ozone over an urban environment, namely Hyderabad, India. Ozone concentration varies from 14 to 63 ppbv over the study area. Diurnal variations of ozone suggest that ozone concentration starts increasing gradually after sunrise, attaining a maximum value by evening time and decreasing gradually thereafter. Black carbon (BC) aerosol mass concentrations varies from 1471 to 11,175 ng m⁻³. The diurnal variations of BC suggest that the concentrations are increased by a factor of 2 during morning (06:00–09:00 h) and evening hours (18:00 to 22:00 h) compared to afternoon hours. Positive correlation has been observed between BC and CO (r²=0.74) with an average slope of 6.4×10⁻³ g BC/g CO. The slope between black carbon aerosol mass concentration and tropospheric ozone suggests that every 1 μg m⁻³ increase in black carbon aerosol mass concentration causes a 3.5 μg m⁻³ reduction in tropospheric ozone. The results have been discussed in detail in the paper.     

Major ionic composition of precipitation in the Nam Co region, Central Tibetan Plateau

A total of 48 precipitation samples have been collected from individual precipitation events at the Nam Co Monitoring and Research Station for Multisphere Interactions (Nam Co Station, 30°47′N, 90°58′E; 4730 m a.s.l) located in the central Tibetan Plateau from August 2005 to August 2006. All samples were analyzed for major cations (NH₄⁺, Na⁺, K⁺, Ca²⁺ and Mg²⁺) and anions (Cl⁻, NO₃⁻ and SO₄²⁻), conductivity and pH. Precipitation pH values ranged from 6.03 to 7.38 with an average value of 6.59. The high pH is due to large inputs of crustal aerosols in the atmosphere, which contain a large fraction of carbonate. Ca²⁺ is the dominant cation in precipitation with an average value of 65.58 μeq L^− 1 (4.91–301.41 μeq L^− 1), accounting for 54% of the total cations in precipitation. HCO₃⁻ is the predominant anion, accounting for 62% of the total anions. When compared with data from a snow pit in the Zhadang Glacier 50 km away (5800 m a.s.l), major ion concentration in precipitation at the Nam Co Station is much higher due to local aerosol inputs. Correlation and empirical orthogonal function (EOF) analysis indicate that regional crustal aerosols and species from combustion emissions of residents are the major sources for these ions, lake salt aerosols from the Nam Co nearby and regional mineral aerosols from dry lake sediments are secondary sources, and sea salt contribution is the least due to the long distance transport.     

The daily and annual effects of dew, frost, and snow on a non-ventilated net radiometer

The formation of dew, deposition of frost and accumulation of snow mainly on the upper domes of a non-ventilated net radiometer seriously affect the measurement of available energy (net radiation). Net radiometers measure radiation, and energy balances and are widely used for estimation of evapotranspiration throughout the world. To study the effects of dew, frost, and snow on a non-ventilated net radiometer, a radiation station was set up which uses 2 CM21 Kipp & Zonen pyranometers (one inverted), 2 CG1 Kipp & Zonen pyrgeometers (one inverted), along with a Q7.1 net radiometer (Radiation & Energy Balance Systems, Inc.; REBS) in a semi-arid mountainous valley in Logan, Utah, U.S.A. The pyranometers and pyrgeometers were ventilated using 4 CV2 Kipp & Zonen ventilation systems. The net radiometer was not ventilated. The ventilation of pyranometers and pyrgeometers prevents dew and frost deposition and snow accumulation which otherwise would disturb measurements. All sensors were installed at about 3.0 m above the ground, which was covered with natural vegetation during the growing season (May–September). The incoming and outgoing solar or shortwave radiation, the incoming (atmospheric) and outgoing (terrestrial) longwave radiation, and the net radiation have been continuously measured by pyranometers, pyrgeometers and a net radiometer, respectively, since 1995. These parameters have been measured every 2 s and averaged into 20 min. To evaluate the effects of dew, frost, and snow, three days were chosen: 26 April 2004 with early morning dew, 6 January 2005 with an early morning frost, and the snowy day of 24 February 2005. Dew formation, frost deposition, and snow accumulation occurred mainly on the upper dome of the non-ventilated Q7.1 net radiometer on the related days, while the ventilated Kipp & Zonen system was free of dew, frost and snow. Net radiation measured by the non-ventilated net radiometer R_n,unvent. during dew and frost periods of the above-mentioned days was greater than ventilated ones R_n,vent. (− 0.2 MJ m^− 2 vs. − 0.8 MJ m^− 2 during almost 4 h on 26 April 2004, and − 0.2 MJ m^− 2 vs. − 0.7 MJ m^− 2 during almost 6.5 h on 6 January 2005). The reason for higher reading by the non-ventilated net radiometer during dew and frost periods was due to emission of additional longwave radiation from water and ice crystals formed mainly on the upper dome of the Q7.1 net radiometer. In contrast, during the snowy day of 24 February 2005, the R_n,unvent. was less than R_n,vent. (− 4.00 MJ m^− 2 vs. 0.77 MJ m^− 2, mainly from sunrise to sunset). The extremely low R_n,unvent. measured by the non-ventilated net radiometer on 24 February 2005 is due to blocking of the incoming solar radiation (mainly diffuse radiation) by the snow-covered upper dome.     

The climate of the coast and fog zone in the Tarapacá Region, Atacama Desert, Chile

In the Atacama Desert, the narrow littoral plain and the adjacent mountain range have a unique climate. This area is locally called the “coastal desert with abundant cloudiness”, and extends from the coastline up to an elevation of 1000 m. The climate is designated as being BWn according to Köppen's Climate Classification as adapted for Chile. In the original classification the acronym (Bn) is used for foggy environments. Toward the east a “normal desert” climate (BW) is found. This is known as one of the most extreme deserts of the world. In the BWn areas there are meteorological differences between low and high elevation zones. The climate of the coastal plains and the mountains is described in this paper in order to show that there is an area where the climate differs from those classified as BWn and BW in the Chilean Climate Classification. This area is located between 650 and 1200 m a.s.l. and contains several fog oases or lomas vegetation, rich in biodiversity and endemism.The weather is warmer near sea level, with an annual average temperature of 18 °C. At high elevation sites like Alto Patache, the temperature decreases at a rate of 0.7 °C for every 100-m increase in altitude. The average annual minimum temperature often approaches 1 °C in winter, while the mean annual temperature range is significant (8.3 °C in Los Cóndores). The mean monthly relative humidity in Alto Patache is over 80%, except during the summer months. During autumn, winter and spring high elevation fog is present in the study area at altitudes ranging from 650 m up to 1060 m, giving annual water yields of 0.8 to 7 L m^− 2 day^− 1. If vegetation is used as an indicator, the foggy zone lies between 650 m a.s.l. and 1200 m a.s.l. About 70% of the mountain range experiences the foggy climate, as opposed to the coastal plains that are characterized by a cloudy climate.     

Observational study of surface ozone at an urban site in East China

In this study, we present the observational data of near surface ozone and some meteorological parameters during 2004, at an urban site (36°42′ N, 117°08′ E, 34.5 m a.s.l.) of Jinan, China. Hourly ozone concentrations exceeding the standard value of China, 100 ppbv, were observed for 65 h (in 23 days) from April to October, and values exceeding US NAAQS (National Ambient Air Quality Standard) for 1 h ozone, 120 ppbv, were observed for 15 h (in 7 days) from late May to early July. Ozone formation presented the phenomenon of “weekend effect”, especially in summer. Monthly variation of ozone coincided with temperature except for July and August. The low ozone levels in July and August may be due to the short sunshine duration and much rainfall during this period. Among these meteorological parameters, daily averaged ozone shows a significant correlation with temperature (r = 0.66) in the year and with relative humidity (r = − 0.75) in summer. Throughout the year, high ozone concentrations were mainly associated with the wind from 180 to 247.5°, while high ozone concentration seemed to have no obvious correlation with a given wind direction in summer. An anomalous nocturnal high ozone episode during 23–25 May 2004 was investigated. Growth fractions of ozone during the nighttime episode were 62.2% and 71.1% for 23 and 24 May, respectively. Synoptic analysis shows that favorable synoptic condition had presumably elevated the background ozone level in this region. Backward trajectory analysis shows that the increase of ozone concentration and the relatively constant high ozone concentrations during the night of May 23 might originate from the transport of ozone rich air mass above boundary layer. Transport of ozone from Yangtze Delta and East Central China might be a significant process for the high ozone level during night May 24 at Jinan.     

Chemical and strontium isotope characterization of rainwater at an urban site in Loess Plateau, Northwest China

Major ion concentrations and strontium isotopic ratios (⁸⁷Sr/⁸⁶Sr) were measured in rainwater samples collected at the urban site of Lanzhou, a city located on the Loess Plateau in the arid and semi-arid areas of northwest China. The rainwater samples possessed alkaline pH, at a reference level of 5.6, with a range of 6.82 to 8.28 and a volume-weighted mean (VWM) pH value of 7.70. The alkaline character of rainwater in Lanzhou is due to the result of neutralization caused by the alkaline soil dusts which contain large amount of CaCO₃. It was observed that Ca²⁺ was the most abundant cation with a VWM value of 886 µeq l^− 1 (115–2184 µeq l^− 1), accounting for 87.8% of the total cations. Without considering HCO₃⁻, SO₄²⁻ and NO₃⁻ were dominant among the anions, accounting for 64.2% and 23.0%, respectively, of the total measured anions. Using Na as an indicator of marine origin and Al for terrestrial inputs, the proportions of sea salt and non-sea-salt elements were estimated from elemental ratios. The precipitation in this region has typical continental characteristics. The Sr concentrations varied from 0.004 to 0.885 µmol l^− 1, and strontium isotopic ratios (⁸⁷Sr/⁸⁶Sr) lay in the range of 0.71025–0.71302, with an average of 0.71143. The ⁸⁷Sr/⁸⁶Sr ratios of Lanzhou rainwater are higher than that of seawater, which reflects contributions from the radiogenic Sr sources of the aerosols. The most suitable candidate for the source would be the soil dust originating from local and distant loess and desert areas. The ⁸⁷Sr/⁸⁶Sr ratios were used to characterize different sources of base cations in rainwater, suggesting that the samples could be interpreted in terms of combinations of at least three components: soil dust derived from the Loess Plateau and desert areas in northwest China (with ⁸⁷Sr/⁸⁶Sr ~ 0.7130), seawater (with ⁸⁷Sr/⁸⁶Sr ~ 0.70917), and anthropogenic inputs (with ⁸⁷Sr/⁸⁶Sr ~ 0.7103). The high ⁸⁷Sr/⁸⁶Sr ratio and Ca and Sr content in the rainwater from Lanzhou can be attributed to the dissolution of calcium carbonate in soil dust.     

Atmospheric deposition of nitrogen, sulfur and chloride in Thessaloniki, Greece

In the present study, the wet and dry depositions of particulate NO₃⁻, SO₄²⁻, Cl⁻ and NH₄⁺ were measured using a wet/dry sampler as a surrogate surface. Gas phase compounds of nitrogen, sulfur and chloride (HNO₃, NH₃, SO₂ and HCl) were measured by an annular denuder system (ADS) equipped with a back up filter for the collection of particles with diameter ≤ 5 μm. Ambient concentrations of NO, NO₂ and SO₂ were also taken into consideration. Sampling was conducted at an urban site in the center of the city of Thessaloniki, northern Greece. The presence of the aerosol species was examined by cold/warm period and the possible compounds in dry deposits were also considered. Dry deposition fluxes were found to be well correlated with ambient particle concentrations in order to be used for the calculation of particle deposition velocity. Average particulate deposition velocities calculated were 0.36, 0.20, 0.20 and 0.10 cm s^− 1 for Cl⁻, NO₃⁻, SO₄²⁻ and NH₄⁺, respectively. Total dry deposition fluxes (gas and particles) were estimated at 3.24 kg ha^− 1 year^− 1 for chloride (HCl + p-Cl), 9.97 kg ha^− 1 year^− 1 for nitrogen oxidized (NO + NO₂ + HNO₃ + p-NO₃), 5.32 kg ha^− 1 year^− 1 for nitrogen reduced (NH₃ + p-NH₄) and 15.77 kg ha^− 1 year^− 1 for sulfur (SO₂ + p-SO₄). 70–90% total dry deposition was due to gaseous species deposition. The contribution of dry deposition to the total (wet + dry) was at the level of 60–70% for sulfur and nitrogen (oxidized and reduced), whereas dry chloride deposition contributed 35% to the total. The dry-to-wet deposition ratio of all the studied species was found to be significantly associated with the precipitation amount, with nitrogen species being better and higher correlated. Wet, dry and total depositions measured in Thessaloniki, were compared with other countries of Europe, US and Asia.     

Composition and sources of organic matter in atmospheric PM10 over a two year period in Beijing, China

The solvent-extractable organic compounds of atmospheric PM₁₀ samples, collected over two years beginning in 2003 at urban and suburban sites of Beijing, were characterized using gas chromatography–mass spectrometry (GC–MS). The elemental carbon (EC) contents were determined and ranged from 4.3 to 42 μg m^− 3. Organic compounds in total extracts were identified and included unresolved complex mixture (UCM) and series of n-alkanes, n-alkanols, n-alkanoic acids, polycyclic aromatic hydrocarbons (PAHs); saccharides, alkanedioic acids, steroids, and other biomarkers and source tracers. The seasonal variations of their relative abundances are discussed. The abundance order for the major molecular classes in the particulate organic matter (POM) was the following: UCM > saccharides > n-alkanoic acids >n-alkanes > n-alkanols > PAHs > hydroxy-PAHs > other biomarker tracers. Based on the genetic significance of the molecular tracers, the dominant sources of POM are proposed for the two sampling sites. The emissions from fossil fuel use (both coal and petroleum products), biomass combustion, other pyrolysis sources, higher plant wax, and secondary products contribute > 98.0% of the POM mass. The fossil fuel use (average = 65% of POM) is the largest contributor and derives mainly from vehicular traffic.