从反射太阳光谱反演大气气溶胶体积谱分布的理论研究

由大气顶射出太阳辐射的形式解出发,结合球形粒子的米散射理论,由反射太阳光谱推导获得了反演整层大气气溶胶粒子体积谱分布的权重函数。在权重函数特征分析的基础上,根据一个简单的线性反演算法,利用大气辐射传输计算模拟的大气顶反射太阳光谱,反演获得了不同气溶胶浓度和复折射率条件下的气溶胶粒子体积谱。结果表明,初步建立了一套自洽的大气气溶胶体积谱分布的反演方法。通过米散射计算获得的反演参数考虑了波长对粒子半径的权重特征,使气溶胶体积谱的反演具有了明确的物理依据;同目前常用的查算表方法相比,简化了反演方案中参数化的复杂程度。     

变分伴随方法应用于大气化学初值和参数反演研究

将结合正则化思想的变分伴随方法应用于大气平流层中臭氧破坏催化反应过程的浓度初始值和反应速率参数的反演问题,推导了在整体资料和末端时刻局部资料反演的伴随模式和泛函梯度,并进行了一组理想数值试验.试验结果表明了变分伴随方法运用于大气化学过程的反演研究的有效性,特别是局部资料联合反演中可以运用正则化思想克服反演的不适定性.     

兰州城区冬季大气气溶胶粒子谱的反演研究

从实测的兰州城市冬季大气气溶胶多波段光学厚度资料出发,应用消光法反演了大气柱气溶胶粒子谱,并对反演程序的可行性、反演结果的可靠性进行了分析讨论。结果表明,反演出的大气柱气溶胶粒子谱分布都为三峰型分布。通过正算方法计算出的光学厚度值检验反演方法,检验结果说明,反演程序是可行的,结果是可靠的。     

利用多通道MODIS遥感资料反演沙尘气溶胶尺度分布的个例试验

为了利用水面进行大气气溶胶粒子尺度分布的反演,需要水体光谱反射率资料;本文利用水库上空MODIS观测的表观反射率资料来订正出实际的水体光谱反射率。假设在干旱的春季水库水面反射率变化不大,用订正的水库水面光谱反射率平均值进行大气气溶胶尺度分布的反演。从两天个例研究来看,利用多通道MODIS资料可以反演出大气气溶胶粒子的尺度变化。结合天气分析2002年4月11日水库上空气溶胶光学厚度增加、粒子变粗,是由于上游区域的沙尘在高空强西北气流引导下到达本地区。     

利用MODIS资料遥感水体上空气溶胶粒子尺度的数值试验

利用卫星探测辐射的光谱依赖性来反演大气气溶胶粒子尺度分布,首先要建立反演算法并检验其可行性。本文参照文献[1]对暗的海洋上空MODIS资料的处理方法,针对大陆水库上空卫星探测MODIS辐射信号,利用6S(Second Simulation of the Satellite Signal in the Solar Spectrum)辐射模式建立一个查算表(Look-up table:LUT)来反演大气气溶胶粒子尺度分布;然后通过数值试验对所建立的查算表进行检验,讨论其方法的可行性。数值试验结果表明,查算表对大陆性气溶胶尺度分布有反演能力,但拟合误差sεl值随着气溶胶光学厚度的增加而增加。     

地基多波段遥感西藏当雄地区 气溶胶光学特性

根据1998年5、6月份在西藏当雄地区进行的为期两个月的气溶胶地面多波段观测结果,讨论了仪器的定标、气溶胶光学特性及其变化规律,并反演了粒子谱分布。结果表明,当雄地区气溶胶光学厚度较小,光学厚度与大气相对湿度呈正相关。干季气溶胶光学厚度日变化大,光学厚度最小值出现在中午前后,而湿季日变化相对要小,光学厚度也小于干季。反演的粒子谱符合干洁大陆气溶胶的特性。     

消光法反演腾格里沙漠地区沙尘气溶胶谱分布

对腾格里沙漠4～9月份的整层大气气溶胶的光学遥感观测结果进行了分析。结果表明,由于消光因子对大粒径粒子消光效应的不敏感性,决定了消光法仅可较好地反演粒径在0.1～5μm之间的气溶胶谱分布特征,特别是对0.1～1μm的大粒子谱分布的反演结果更为稳定;腾格里沙漠气溶胶粒度谱分布基本符合Junge谱;浮尘天气的谱分布同干洁晴好天气的谱分布有着很大的差异,浮尘天气下粒径在0.1～1.0μm的大粒子以及粒径>1.0μm的巨粒子数有明显的增加,浓度要比干洁天气下的大几个量级。在干洁晴好天气下,腾格里沙漠的气溶胶是均一的、稳定的,而且>1μm的大粒子浓度很小;气溶胶的谱分布几乎是一致的,谱形大致为Junge谱,在粒度0.4～1.0μm范围内有一明显峰值。     

多波段光度计和大气气溶胶测量

近年来对大气气溶胶的观测受到越来越多的重视。很多国家都利用对太阳光谱的观测来推算大气气溶胶,并且对计算气溶胶谱分布的反演方法也进行了很多理论上的分析。这里,我们介绍一种计算谱分布的简便方法及某些观测结果。一、方法从太阳直接辐射的测量可以算出大气总的光学厚度,在扣除空气分子的影响后,便得到大气气溶胶的光学厚度式中。n(r)——气溶胶谱分布 r——粒子半径Q_(ex)(r,λ,m)——削弱的有效因子 m——气溶胶折射率如果测出不同波长的大气气溶胶光学厚度,即可由(1)式反演出气溶胶谱分布。为了使反演过程简单化,引入以下两项假定:     

大气气溶胶的粒度谱分布函数及其随高度的变化

本文对用光学粒子计数器在飞机上测量的大气气溶胶数密度-粒度谱分布进行了分析研究.根据对气溶胶谱形成过程的分析,指出大气气溶胶是四种气溶胶体系的混合物,需要用四个正态分布函数的和来描述大气气溶胶的体积-粒度谱分布.用非线性最小二乘法计算了谱分布函数的经验参数;研究了粒子浓度、体积、及粒度谱分布函数随高度的变化.观测资料表明,在大气温度和湿度水平均匀、层结稳定的情况下,气溶胶粒子浓度水平分布不均匀,而且垂直方向上也并不随高度单调递减.     

宽带消光法反演气溶胶光学厚度与AERONET北京站探测结果的对比研究

该文简要介绍了遥感气溶胶光学厚度的宽带消光法, 重点比较与分析了2001～2002年间北京地区宽带消光法和全球气溶胶探测网(AERONET)气溶胶光学厚度的探测结果.对比结果表明, 两类探测结果在无云晴天的条件下具有很好的吻合, 二者的相关系数达到90%以上.另外, 作者还针对宽带消光法反演月平均气溶胶光学厚度问题, 提出了一个减小云对反演结果影响的方法, 即月平均光学厚度约束法, 并与全球气溶胶探测网探测结果做对比分析.二者结果的一致性表明该约束方法的有效性.     

大气气溶胶尺度分布分形特征研究

气溶胶作为大气环境中的重要组成部分,具有复杂的尺度分布结构。为研究其尺度分布特征,采用分形理论首先论述了常用的气溶胶谱分布函数具有分形不变性,然后在分形理论的指导下分别建立了气溶胶粒子和体积分形统计模型,而且以AERONET相关数据验证了分形模型的有效性和实用性,并采用分段分形的方法改进了气溶胶体积分形模型。最后分析研究了分维数的实用意义和分布情况,讨论了气溶胶分维数变化和粒度分布的关系。结果表明：气溶胶粒子数和体积分维数之间存在线性关系,上半年的大气溶胶粒子数分维数的变化幅度明显小于下半年的变化幅度;研究区域大气气溶胶中细粒子分布比较密集,大粒子分布比较分散。分形理论为研究大气气溶胶的尺度分布特征提供了新的方法与手段,具有广阔的研究与应用前景。     

南京地区气溶胶谱分布的湿度相关性分析和等效复折射率预测

通过实验收集大气颗粒物，对南京地区大气气溶胶谱分布进行了描述，对气溶胶分布与相对湿度的相关性进行了探讨。建立了南京地区7—11月气溶胶化学组分的月平均模型，得出气溶胶等效复折射率的预测方法。结果表明：南京地区的大气气溶胶颗粒物，峰值粒径在80~100 nm范围，属于典型的城市型气溶胶。数浓度与相对湿度的相关性与季节和粒径大小有关，在6—9月，相对湿度与细粒子数浓度呈负相关，与粗粒子呈正相关，在10—11月相反，且易受极端天气影响。建立的干气溶胶等效复折射率月平均模型，结合湿度修正模型得到某一日的复折射率，与AERONET站点数据进行了对比，结果较为一致，误差范围在0~0.03。     

Simultaneous determination of aerosol size distribution and refractive index and surface albedo from radiance- Part III: Parametrization and application

Based on the radiative transfer calculation results, three approximate expressions of the sky radiance in almucantar and its increment caused by surface albedo are presented. They are simple, but accurate enough. The dependence of the fitted aerosol scattering phase functions on refractive index is also studied, and its reasonable form is given. For Junge size distribution, the approximate equations of the phase functions with some special scattering angles are obtained. These approximate equations significantly simplify the retrieval algorithm of simultaneous determination of aerosol size distribution and its refractive index and surface albedo. This method can be realized with a microcomputer, and has been used to process and analyse the experimental data measured in Hefei of Anhui Province.     

A New Method for Aerosol Retrieval Based on Lidar Observations in Beijing

Lidar has been used extensively in the area of atmospheric aerosol measurement. Two unknowns at the reference altitude, the lidar ratio and the backscatter coefficient, need to be resolved from the lidar equation. In the actual application, these two values are difficult to obtain, particularly the backscatter coefficient. To better characterize the optical properties of aerosols, optical thickness, and attenuated backscatter obtained by other instruments are usually used as the input for joint inversion. However, this method is limited by location and time. In this study, the authors propose a new method for aerosol retrieval by using Mie scatter- ing lidar data to solve this problem. The authors take the horizontal aerosol extinction coefficient as the con- straint to begin the iteration until a self-consistent aerosol vertical profile was obtained. By comparing their results with Aerosol Robotic Network （AERONET） data, the authours determine that the aerosol extinction coefficient obtained by combining horizontal and vertical lidar observations is more pre- cise than that obtained by using the traditional Fernald method. This new method has been adopted for re- trieving the extinction coefficient of aerosols during the observation days.     

SIMULTANEOUS DETERMINATION OF AEROSOL SIZE DISTRIBUTION AND REFRACTIVE INDEX AND SURFACE ALBEDO FROM RADIANCE-PART III: PARAMETRIZATION AND APPLICATION

Based on the radiative transfer calculation results, three approximate expressions of the sky radiance in almucantar and its increment caused by surface albedo are presented. They are simple, but accurate enough. The dependence of the fitted aerosol scattering phase functions on refractive index is also studied, and its reasonable form is given. For Junge size distribution, the approximate equations of the phase functions with some special scattering angles are obtained. These approximate equations significantly simplify the retrieval algorithm of simultaneous determination of aerosol size distribution and its refractive index and surface albedo. This method can be realized with a microcomputer, and has been used to process and analyse the experimental data measured in Hefei of Anhui Province.     

西安市一次晴空气溶胶粒子的观测分析

1982年夏季,我国第一架装有PMS粒子测量系统的气象科研考察飞机在西安市首次进行大气物理科学考察。本文仅对6月8日西安城市晴天大气气溶胶粒子观测。资料进行了初步分析。结果表明:西安市晴天气溶胶粒子(直径0.5-8μm)浓度值范围在4×10~0-3.8×10~1个/cm~3,分布趋势随高度递减,逆温层对粒子垂直输送有阻滞作用。同时对气溶胶粒子谱分布及谱分布函数作了探讨,并对一些参数进行理论计算。     

Elemental particle size distributions. Measured and estimated dry deposition in Sfax region (Tunisia)

Mass size distribution of the crustal elements (Al, Ca, Fe, Mg, Si, Ti), anthropogenic elements (Zn, Mn, Cr, Cu, K, P, Pb) and sea elements (Na, Cl) were obtained from measurements carried out with an inertial cascade impactor in Sfax. A fitting procedure by data inversion was applied to those data. This procedure yields accurate size distributions of aerosols in the diameter range 0.1–25 μm in two different sites. In a coastal industrial site, the mass distribution of the aerosol showed a bimodal structure; and in urban area, the lower particle mode cannot be observed. The elemental dry deposition flux was calculated as a function of particle size. The element flux size distribution increased rapidly with particle size. The modelling results indicate that the majority of the crustal and anthropogenic elements flux (>90%) was due to particles larger than 3 μm in diameter.     

On the distribution of physical and chemical particle properties in the atmospheric aerosol

Consideration of sources and growth dynamics of aerosols has led to the conclusion that there may be a distribution or variation of chemical composition and physical structure among atmospheric aerosol particles as a function of size, and within a narrow size range as well. A mathematical representation of these particle properties in terms of an additional dimension to the number size distribution is described. Examples of the relevance of this aspect of aerosol characterization for physical and chemical processes in the atmosphere are discussed. A review of the available techniques shows that several methods are available which can and have provided quantitative results on the distribution of particle properties. Examples of data from the literature have been selected and are presented as three-dimensional distributions illustrating the wide range of particle properties which may exist in narrow size intervals. An evaluation of these results reiterates the value of taking the distribution of particle properties in the atmosphere into account for sampling and modeling purposes.