北京秋季城市热岛效应及其气象影响因子

应用北京地区地面气象观测台1990～2004年10月的气温资料,分析了近15年来北京秋季城市热岛的特征,结果表明,北京秋季夜间城市热岛要强于白天.此外,对比分析了一个强热岛和一个弱热岛的特征及其气象影响因子,结果表明,北京秋季夜间特定条件下存在强热岛,白天城市强热岛会减弱消失,城市强热岛的日变化非常明显.夜间城市强热岛形成和维持是多个因子综合作用的结果.白天日照充足的晴夜,北京城郊地面风场很弱(≤1.0 m·s-1),同时城区垂直方向47 m以下大气风场持续很弱(≤1.0 m·s-1),城区320 m以下大气持续存在强逆温.日落后郊区地面大气降温速率和幅度远大于城区,促使夜间强热岛的形成和维持.白天日出后太阳辐射的加热作用所引起的郊区地面大气升温速率和幅度大于城区,城区大气稳定度的减弱以及城区大气逆温的消失是夜间强热岛减弱并最终消失的重要原因.     

北京北部城区 SO2和NO2浓度垂直分布特点初探

2001年1～3月在中国科学院大气物理研究所320 m铁塔10个不同高度(320、240、200、140、100、80、47、15、8 m和地面)使用无动力扩散采样器对SO2和NO2日平均总量及夜间平均浓度进行了观测.结果表明,200m以下高度SO2和NO2浓度较大.北京城区不同高度大气中SO2的浓度1月份最高.NO2浓度1月份和2月份呈现高值.不同高度SO2和NO2浓度与逆温强度有明显的正相关.     

长光程与传统点式污染气体监测技术对比

结合2类大气成分观测仪器的技术特点,对OPSIS AB DOAS系统和Thermo SCIENTIFIC EMS系统分别监测的南京郊区2009年冬季和2010年春季O3、NO2、SO2质量浓度数据进行了质量控制和分析对比,简要分析了这3种气体浓度的季节变化特征．对2009年秋季分别采用2种仪器观测的南京城区和郊区的污染情况进行了对比,分析了城郊差异．结果表明:2套系统对相同气体的测量结果相关性较好,DOAS系统的测量值受大气中水汽和气溶胶影响较大,普遍高于EMS系统,绝对值相差范围在14％～25％之间;南京郊区冬季大气中SO2和NO2质量浓度较高,O3质量浓度较低,春季反之;NO2质量浓度曲线与O3呈负相关;秋季城区NO2质量浓度较高,日变化呈双峰型,郊区呈单峰型;城郊O3日变化均呈单峰型,城区日变化幅度较大;SO2日变化在城区呈单峰型,在郊区呈双峰型．     

北京北部城区SO2和NO2浓度垂直分布特点初探

2001年1－3月在中国科学院大气物理研究所320m铁塔10个不同高度（320、240、200、140、100、80、47、15、8m和地面）使用无动力扩散采样器对SO2和NO2日平均总量及夜间平均浓度进行了观测。结果表明，200m以下高度SO2和NO2浓度大。北京城区不同高度大气中SO2的浓度1月份最高。NO2浓度1月份和2月份呈现高值。不同高度SO2和NO2浓度与逆温强度有明显的正相关。     

北京市秋季城区和郊区大气边界层参数观测分析

应用2001年9月北京城区和郊区同步大气边界层观测资料,对大气边界层热力和动力参数进行了计算分析.结果表明:北京市秋季,逆温出现的时间城区滞后于郊区;逆温层高度城区大于郊区,200m通常为郊区的逆温层顶和城区的逆温层底部;逆温层强度城区弱于郊区;城市热岛强度为3℃;城区感热通量的输送大于郊区;城区下垫面粗糙度远大于郊区;郊区总辐射和紫外辐射的强度明显大于城区.     

边界层臭氧浓度变化特征及相关因子分析

根据广州市城区麓湖、郊区花都测站的2004年污染物监测数据和气象资料,采用统计分析软件SPSS和Excel分析了广州市臭氧浓度的时间变化特征,包括臭氧浓度的年季变化、周变化及日变化特征,并分析了O3与污染物CO、NOx（NO和NO2）、SO2、PM10以及与气象条件之间的相关性。结果表明：广州市臭氧浓度一年出现2个峰值,分别为6月和10月并且郊区浓度大于城区;一周之中最大浓度出现在周末;O3日平均浓度与NOx、NO、CO、相对湿度负相关性较显著,与PM10和气温正相关性较显著;在气温较高、湿度较低的晴朗少云天气时,易造成广州市臭氧的高浓度。     

边界层臭氧浓度变化特征及相关因子分析

根据广州市城区麓湖、郊区花都测站的2004年污染物监测数据和气象资料,采用统计分析软件SPSS和Excel分析了广州市臭氧浓度的时间变化特征,包括臭氧浓度的年季变化、周变化及日变化特征,并分析了O3与污染物CO、NOx(NO和NO2)、SO2、PM10以及与气象条件之间的相关性。结果表明:广州市臭氧浓度一年出现2个峰值,分别为6月和10月并且郊区浓度大于城区;一周之中最大浓度出现在周末;O3日平均浓度与NOx、NO、CO、相对湿度负相关性较显著,与PM10和气温正相关性较显著;在气温较高、湿度较低的晴朗少云天气时,易造成广州市臭氧的高浓度。     

珠三角城市扩张对春季主要气象参数和O3浓度的影响

利用新一代大气化学在线耦合模式WRF-Chem研究城市扩张对珠三角地区春季气象条件的改变及其对地面O3浓度的影响。研究结果表明:受城市扩张的影响,珠三角城区的月平均气温上升0.35℃;城区夜间相对湿度下降幅度为4%～6%,影响程度大于白天;风速在白天和夜间都有不同程度的下降,城市月平均风速下降1.89 m/s;边界层高度在白天和夜间均升高,城市月平均边界层高度上升39.82 m。城市扩张后,城市月平均O3浓度增加0.89 ppbv,增幅大于1.5 ppbv的区域主要在佛山和东莞,白天O3浓度增幅为0.6～1.5 ppbv,夜间增幅及影响范围都大于白天,O3浓度增加区域与主要气象要素变化的区域相一致;白天14:00城区混合层内总臭氧柱浓度增加了80 ppbv;O3浓度对气象要素的敏感程度表现为:温度>边界层高度>风速>相对湿度;白天O3浓度增幅呈U型,其中14:00的O3增幅最小,为0.2 ppbv;夜间O3增幅呈倒V型,其中20:00的增幅最大(>1.5 ppbv)。     

北京夏季强热岛分析及数值模拟研究

应用北京地区20个常规地面气象站、2个自动气象站和中国科学院大气物理研究所325m气象铁塔的资料，对北京2003年7月热岛状况进行了统计分析，发现北京夏季夜间存在强热岛效应，夏季夜间存在强热岛效应的天数占到了1/3，强弱热岛天数合计占到了大约4/5。进一步分析7月1日强热岛特征及其气象影响因子，结果表明：夜间存在强热岛时，郊区所有测站的地面气温都要低于主城区地面气温，城市强热岛的高温中心在天安门和白家庄连线的主城区；白天日照充足的晴夜，日落后城区320m以下低层大气存在逆温和弱的风速，城区地面气温下降速率和幅度均远小于郊区，城市强热岛因此得以形成和维持。日出后至正午，北京北部郊区日照时间比城区长，郊区地面大气得到来自太阳辐射的能量多于城区，而太阳辐射的加热作用使城区低层大气逆温消失，大气稳定度减弱，并使郊区地面气温上升速率和幅度大于城区，最终导致夜间出现的强热岛减弱、消失。此外，应用MM5模式对强热岛进行了初步数值模拟研究，发现在MM5中考虑城市人为热和热储存，可以改善模式对热岛的数值模拟，表明城市人为热和热储存在夏季强热岛的形成中有重要作用。     

北京春季城市热岛特征及强热岛影响因子

应用北京地区地面气象观测台1990-2004年4月的气温资料,分析了近15a北京春季城市热岛特征,结果表明：春季夜间城市热岛要强于白天。还分析了春季一个强热岛形成和减弱消失过程的气象影响因子,结果表明：北京春季夜间特定条件下存在强热岛,强热岛中心在白家庄、天安门、公主坟连线的主城区;白天强热岛会减弱消失。强热岛在夜间形成的原因是日落后郊区地面大气降温速率和幅度远大于城区地面大气。白天有日照的晴夜北京城、郊地面风场很弱（≤1．0m／s）,多个测站甚至出现静风,同时城区垂直方向上15m高度以下持续存在很弱（≤1．5m／s）的风场,城区320m高度以下大气持续存在强逆温,这些因素共同促使春季强热岛的形成和维持。强热岛在白天减弱消失的原因是日出后太阳辐射的加热作用引起郊区地面大气升温速率和幅度大于城区地面大气,同时城区大气稳定度减弱、城区大气逆温消失、城郊地面风速增加。     

Tropospheric NO2 Columns over Northeastern North America： Comparison of CMAQ Model Simulations with GOME Satellite Measurements

We present comparisons of the NO2 regional Chemical Transport Model （CTM） simulations over North-eastern North America during the time period from May to September, 1998 with hourly surface NO2 observations and the NO2 columns retrieved from the GOME （Global Ozone Monitoring Experiment） satellite instrument. The model calculations were performed using the Mesoscale Meteorological Model 5 （MM5）, Sparse Matrix Operator Kernal Emissions （SMOKE）, and Community Multiscale Air Quality （CMAQ） modeling systems, using the emission data from the National Emissions Inventory （NEI） databases of 1996 （U.S.） and 1995 （Canada）. The major objectives were to assess the performance of the CMAQ model and the accuracy of the emissions inventories as they affected the simulations of this important short-lived atmospheric species. The modeled （NcMAQ） and measured （NGOME） NO2 column amounts, as well as their temporal variations, agreed reasonably well. The absolute differences （NcMAQ-NGOME） across the domain were between ±3.0×10^15 molecules cm^-2, but they were less than ±1.0×10^15 molecules cm^-2 over the majority （80%） of the domain studied. The overall correlation coefficient between the measurements and the simulations was 0.75. The differences were mainly ascribed to a combination of inaccurate emission data for the CTM and the uncertainties in the GOME retrievals. Of these, the former were the more easily identifiable.     

Flux between soil and atmosphere, vertical concentration profiles in soil, and turnover of nitric oxide: 1. Measurements on a model soil core

A stainless steel soil corer which was filled with homogenized soil was used to measure the flux (J) of NO between soil and atmosphere and the vertical profile of the NO mixing ratios (m) in the soil atmosphere, both as function of the NO mixing ratio (mm _a ) in the atmosphere of the headspace. The NO emission flux decreased linearly with increasing NO mixing ratio and turned into a deposition flux after passage of the compensation point (m _c) at about 400 ppbv NO. Almost the same compensation point was obtained when the turnover of NO was measured in flask-incubated soil samples as function of the NO mixing ratio. The flux (J) of NO at the soil-atmosphere interface was calculated from the production rate (P) of NO and the NO uptake rate constant (k) that were measured in these flask-incubated soil samples using the diffusion model of Galbally and Johansson (1989). The calculated fluxes agreed within <15% with those actually measured. The vertical profiles of NO were fitted to an exponential function and analyzed by Fick's first law of diffusion. The shape of the profiles indicated a net production of NO in the upper 10 cm soil layer when the atmospheric NO mixing ratio was below the compensation point and in a net consumption of NO when the atmospheric NO mixing ratio was above the compensation point. In soil layers below 10 cm depth, the turnover of NO resulted in compensation of production and consumption rates. Measurement of the actual diffusion coefficient using SF₆ showed that gas transport in the soil core was not only due to molecular diffusion but in addition due to a bidirectional gas flow. The experimentally determined diffusion coefficient was smaller than that computed from soil porosities, but resulted together with the additional transport term in NO fluxes that were close (< ±15%) to those measured. This is the first comprehensive study of NO concentration profiles and turnover rates in soil providing a theoretical basis for modelling NO fluxes at the soil-atmosphere interface.     

基于SCIATRAN模型的二氧化氮DOAS 反演敏感性试验

气溶胶和地表反照率是影响星载SCIAMACHY仪器观测数据定量遥感NO2大气柱总量的2个主要因子.文中利用高光谱分辨率大气辐射传输模型SCIATRAN,在考虑分子吸收和气溶胶多次散射影响基础上,精确模拟了气溶胶、地表反照率和NO2气体浓度变化对差分处理前后卫星反射光谱的影响,并定义影响因子f,对3个模拟参数进行综合评价.结果表明:(1)通过剔除卫星反射光谱中慢变光谱变化成分,DOAS方法明显降低了气溶胶和地表反照率对卫星反射光谱的影响;(2)差分处理前,3个模拟参数的影响强弱依次为地表反照率、气溶胶和NO2浓度;而差分处理后,3个模拟参数的影响强弱依次为NO2浓度、地表反照率和气溶胶.在影响趋势上,气溶胶和地表反照率很相似,均体现为宽带效应,在440-450 nm内有水汽强吸收和多次散射复杂相互作用导致的较大峰值;NO2浓度变化对差分处理前后的光谱都呈现气体吸收结构的影响特性;(3)由于吸收和散射相互作用等因素的影响,在基于卫星观测的差分光谱中仍然残留有气溶胶和地表反照率的误差,地表反照率约占18.6%,气溶胶约占6.2%.因此,当前SCIAMACHY遥感的NO2产品在中国区域浓度偏高,需要对气溶胶和地表反照率进行二次精细化的订正.     

Flux between soil and atmosphere, vertical concentration profiles in soil, and turnover of nitric oxide: 2. Experiments with naturally layered soil cores

Intact soils cores were taken with a stainless steel corer from a sandy podzol and a loamy luvisol, and used to measure the flux (J) of NO between soil and atmosphere and the vertical profile of the NO mixing ratios (m) in the soil atmosphere, both as function of the NO mixing ratio (m _a) in the atmosphere of the headspace. These measurements were repeated after stepwise excavation of the soil column from the top, e.g. by removing the upper 2 cm soil layer. The gaseous diffusion coefficients of NO in the soil cores were either computed from soil porosity or were determined from experiments using SF6. The NO fluxes (J) that were actually measured at the soil surface were compared to the fluxes which were calculated either from the vertical NO profiles (J _c ) or from the NO production and uptake rates (J _m ) determined in the excavated soil samples. In the podzol, the actually measured (J) and the calculated (J _m , J_m) NO fluxes agreed within a factor of 2. In the luvisol, the measured NO fluxes (J) and those calculated from the vertical NO profiles (J _c ) also agreed well, but in the upper 6 cm soil layer the NO fluxes (J _m ) calculated from NO production and uptake rates were up to 7 times higher than the measured NO fluxes. This poor agreement was probably due to the inhomogeneous distribution of NO production and consumption processes and the change of diffusivities within the top layers of the luvisol. Indeed, the luvisol showed a pronounced maximum of the NO mixing ratios at about 6 cm depth, whereas the podzol column exhibited a steady and exponential decrease of the NO mixing ratios with depth. The inhomogeneities in the luvisol were confirmed by incubation of the soil cores under anoxic conditions. This treatment resulted in production of NO at several depths indicating a zonation of increased potential activities within the luvisol profile which may have biased the modelling of the NO surface flux from turnover measurements in soil samples. Inhomogeneities could be achieved even in homogenized soil by fertilization with nitrate solution.     

深对流云输送对于对流层O3、NOx在分析的作用

利用一个冰雹云模式与云化学输送模块耦合而成的三维对流云化学／输送模式, 研究对流云对重要的大气污染物臭氧 （Ｏ３）、氮氧化物 （ＮＯｘ, 包括ＮＯ 和ＮＯ２） 的输送作用。模式较好地体现了一个单体积云的发展过程及其特征。云化学／输送模式的结果表明, 云内强烈的垂直输送能在３０ ｍ ｉｎ 左右, 把低层低体积分数的Ｏ３和高体积分数的ＮＯ２快速、有效地输送到对流层的上部, 造成化学物种的再分布。而在云顶附近, 由于对流穿透了对流层的顶部,造成了上层高体积分数Ｏ３的向下侵入,说明云的对流活动除了能把边界层内的污染物向上输送, 其夹卷作用还可以造成平流层和对流层化学物质的交换。     

Slant Column Measurements of O3 and NO2 During the NDSC Intercomparison of Zenith-Sky UV-Visible Spectrometers in June 1996

In June 1996, 16 UV-visible sensors from 11 institutes measured spectra of the zenith sky for more than 10 days. Spectra were analysed in real-time to determine slant column amounts of O3 and NO2. Spectra of Hg lamps and lasers were measured, and the amount of NO2 in a cell was determined by each spectrometer. Some spectra were re-analysed after obvious errors were found. Slant columns were compared in two ways: by examining regression analyses against comparison instruments over the whole range of solar zenith angles; and by taking fractional differences from a comparison instrument at solar zenith angles between 85° and 91°. Regression identified which pairs of instruments were most consistent, and so which could be used as universal comparison instruments. For O3, regression slopes for the whole campaign agreed within 5% for most instruments despite the use of different cross-sections and wavelength intervals, whereas similar agreement was only achieved for NO2 when the same cross-sections and wavelength intervals were used and only one half-day's data was analysed. Mean fractional differences in NO2 from a comparison instrument fall within ±7% (1-sigma) for most instruments, with standard deviations of the mean differences averaging 4.5%. Mean differences in O3 fall within ±2.5% (1- sigma) for most instruments, with standard deviations of the mean differences averaging 2%. Measurements of NO2 in the cell had similar agreement to measurements of NO2 in the atmosphere, but for some instruments measurements with cell and atmosphere relative to a comparison instrument disagreed by more than the error bars.     

Relationship between Lightning Activity and Tropospheric Nitrogen Dioxide and the Estimation of Lightning-produced Nitrogen Oxides over China

To better understand the relationship between lightning activity and nitrogen oxides(NOX) in the troposphere and to estimate lightning-produced NOX(LNOX) production in China more precisely, spatial and temporal distributions of vertical column densities of tropospheric nitrogen dioxide(NO_2VCDs) and lightning activity were analyzed using satellite measurements. The results showed that the spatial distribution of lightning activity is greater in the east than in the west of China, as with NO_2 VCDs. However, the seasonal and annual variation between lightning and NO_2 density show different trends in the east and west. The central Tibetan Plateau is sparsely populated without modern industry, and NO_2 VCDs across the plateau are barely affected by anthropogenic sources. The plateau is an ideal area to study LNOX. By analyzing 15 years of satellite data from that region, it was found that lightning density is in strong agreement with annual, spatial and seasonal variations of NO_2 VCDs, with a correlation coefficient of 0.79 from the linear fit. Combining Beirle's method and the linear fit equation,LNOXproduction in the Chinese interior was determined to be 0.07(0.02–0.27) Tg N yr~(-1) for 1997–2012, within the range of 0.016–0.384 Tg N yr~(-1) from previous estimates.     

北京奥运会期间NO2浓度降低原因分析

2002～2008年,北京市城区和近郊8月的NO2月均浓度大体呈现逐年下降趋势,其中前5年二者均以每年约10%的降幅下降,2008年发生显著下降,降幅达40%左右。利用嵌套网格空气质量模式系统(NAQPM/IAP),采用敏感性试验方法,评估了气象条件与污染控制措施对北京奥运会期间大气NO2浓度降低的影响,评估不同污染控制措施对NO2浓度降低的作用。研究结果表明,污染控制措施是NO2浓度降低的主要影响因素,其中面源的污染控制措施对于NO2浓度降低的作用最明显。     

Observation of the Stratospheric NO2 Latitudinal Distribution in the Northern Winter Hemisphere

During a series of flights in the winters 1991/92 to 1994/95 total stratospheric NO2 was measured by means of the DOAS (Differential Optical Absorption Spectroscopy) technique on board a C160 (Transall) aircraft. In an area covering 60°W to 60°E, and 16°N to 86°N, the total stratospheric NO2 was observed to vary markedly with latitude and season (winter and spring). In the mid-winter Arctic vortex extremely low total stratospheric NO2 (< 3.1014/cm2) was always found, generally larger amounts of NO2 occurred outside the vortex in winter and towards the spring both inside and outside the vortex. This behaviour of stratospheric NO2 can be explained by the denoxification of the wintertime polar stratosphere. Ambient to the vortex in mid-winter however, sudden increases of total stratospheric NO2 by about a factor of 3 were observed. These sudden increases in stratospheric NO2 coincide with a change in the wavenumber 2 of the geopotential height at 60°N, which indicates that most likely the events are caused by planetary waves efficiently transporting air masses rich in NOx from lower to higher latitudes. The monitoring of stratospheric NO2, during latitudinal traverses ranging from the Arctic (80°N) to the Subtropics (18°N) in spring also unexpectedly showed a large variability in total stratospheric NO2 at mid-latitudes. Since photochemistry almost certainly can be excluded, it is proposed that the observed variability may be due to the planetary wave activity of the stratospheric surf zone, known to dynamically connect the tropical and the polar stratosphere.     

华北地区香河站对流层NO_2的MAX-DOAS光谱仪观测及变化特征分析

利用中国科学院大气物理研究所香河大气探测综合试验站2010年3月至2012年2月(2年)的多轴差分吸收光谱仪(MAX-DOAS)观测数据和32 m高塔常规气象资料,反演了华北地区香河站对流层NO2柱浓度,分析了该区域NO2柱浓度的季节变化特征。研究表明:可见光455~485 nm、紫外330~370 nm都可以作为MAX-DOAS工作波段很好地反演NO2;香河地区NO2柱浓度夏季最低,几乎保持在2×1016 cm–2以下,春、秋季次之,在3×1016 cm–2上下小范围浮动,冬季最高,可达4.5×1016 cm–2;月平均最低值出现在7月,最高值出现在11月。NO2柱浓度与风速、风向密切相关:来自东边唐山方向的风,风速越大时NO2浓度越高,因为唐山是NO2的高值区之一;其它方向风速越大,浓度越低。春、夏两季NO2柱浓度日变化趋势比较平缓,秋、冬两季日变化明显,秋季正午偏高,冬季早晚偏高。