菲律宾海西北部岩芯记录的125 ka以来的地磁场强度及其影响因素

沉积物记录的地磁场强度首先提供了模拟地磁场演化的数据约束,其次提供了沉积物的年龄信息. 本文报道了菲律宾海西北部岩芯记录的地磁场相对强度,并结合岩石磁学和沉积学性质探讨了影响强度的各个因素. 除底部红粘土层的局部磁偏角偏转可能揭示了沉积后改造以外,磁化率各向异性和地磁场方向特征表明沉积物为原状沉积. 岩石磁学性质表明沉积物符合磁性均一性,可以记录可靠的地磁场强度. 由于红粘土层及其下部的磁偏角异常,本文讨论其上部约125 ka的结果. 常规归一方法获得的两个地磁场强度参数NRM/ARM(特征剩磁和非磁滞剩磁比值)和NRM/κ(特征剩磁和磁化率比值)与其它记录对比得到时间-深度对比点,对比点之间的年龄为线性内推或者外推. 地磁场强度时间模型上的岩芯氧同位素与全球氧同位素综合曲线一致证明强度结果的有效性和对比的正确性. 磁化率为归一参数的强度大多低于以非磁滞剩磁为归一参数的强度,频谱和相关分析证明NRM/ARM不与ARM和磁性矿物粒度(ARM/κ)相关,也没有轨道周期性,而NRM/κ却与κ和ARM/κ相关,而且有13~12 ka的周期. 由此我们认为NRM/ARM记录的地磁场强度比NRM/κ更好地消除了气候印记. 进一步探讨了超顺磁含量、碳酸钙含量、磁性矿物组成以及磁性矿物粒度变化与地磁场强度差值的关系,发现末次间冰期较高的超顺磁含量和磁性矿物粒度的较大范围变化造成了地磁场强度差值,后者至少造成了90%差异. 中等含量的碳酸钙和较小的磁性矿物组成变化不是磁场强度差值产生的原因. 如何校正磁性矿物粒度变化的影响将是下一步工作的重点.     

基于地磁场相对古强度变化的下蜀黄土年代序列及其古气候意义

分布于宁镇地区的下蜀黄土年代标尺研究薄弱.我们以镇江大港钻孔岩芯的下蜀黄土为例,探讨了下蜀黄土记录地磁场相对古强度的可靠性.岩石磁学的实验显示,下蜀黄土大体上符合估计相对古强度对沉积物的要求.以低频磁化率()作为天然剩磁(NRM300)的归一化因子,我们获得了下蜀黄土记录的地磁场相对古强度变化.通过与邻区和全球的单个及合成曲线的对比,我们发现大港钻孔岩芯的相对古强度记录展现出主要的全球偶极场的变化特征,因而可用于建立下蜀黄土的年代标尺.新的年代标尺表明,大港钻孔的磁化率年代序列与北方黄土无法直接对比,证实了该地点的下蜀黄土磁化率变化机制与北方的不同.大港钻孔下蜀黄土的沉积速率与磁化率相关,低风尘沉积速率对应低磁化率,是降水增加所导致的结果.沉积速率与磁化率年代序列显示,下蜀黄土记录的本区季风变化过程可分为4个阶段.阶段Ⅳ(819～700ka)对应中更新世转型阶段,东亚季风降水较少.阶段Ⅲ(700～412ka)对应中更新世的大间冰期,东亚季风降水最多.阶段Ⅱ(412～197ka)时东亚季风降水减少,较阶段Ⅳ略少.阶段Ⅰ(197～34ka)东亚季风降水最少.因此,中更新世气候转型后,长时间尺度东亚季风降水持续减少,可能受全球温度阶段性降低驱动.     

四万年以来南海西北次海盆地磁场古强度演化及其地球动力学意义

海洋沉积物能够记录较为连续的古地磁信息.对沉积物记录的天然剩磁(NRM)进行归一化处理,可以构建过去较为连续的地磁场相对古强度(RPI)信息,这对于研究地磁场演变与全球记录对比具有重要的科学意义.本文以南海西北次海盆地区L07岩芯作为研究对象,利用等温剩磁(IRM)作为NRM的归一化参数,构建了南海西北次海盆地区37ka以来的RPI曲线.实验结果显示,L07岩芯中载磁矿物的成分较为单一,以单畴(SD)-细粒准单畴(PSD)低矫顽力磁铁矿为主,能够作为古强度记录的载体.此外,在11.5ka处RPI出现峰值.进一步结合东亚地区鄂霍茨克海岩芯的RPI记录以及中国黄土10Be的丰度变化,我们认为该RPI峰值是由于地球非偶极子场影响所致.这说明东亚正磁异常的影响范围可以达到中国南海等中低纬度地区,这为理解东亚地区磁场演化提供了新证据,同时也为该区千年尺度RPI记录变化特征提供了新机制.     

晚更新世以来南海中央海盆沉积物的磁学特征：对物源和东亚季风演化的指示

南海沉积物记录了丰富的高原隆升剥蚀、古海洋、东亚季风和区域构造演化信息,是研究东亚季风和古环境演化的理想材料.但是,由于南海沉积环境复杂,物质来源多样,使得沉积物定年和环境气候探讨的难度加大.为此,本文选取南海中央海盆的SCS-01钻孔作为研究对象,建立其准确的年代框架,综合利用磁学和地球化学分析方法,探讨沉积物物源及其对东亚季风演化的指示.首先,通过对沉积物样品的岩石磁学特征分析,表明沉积物的主要载磁矿物为低矫顽力的假单畴磁铁矿,载磁矿物颗粒大小均一、含量变化小,基本符合建立地磁场相对古强度(Relative Paleointensity, RPI)曲线的“均一性”标准.在此基础上利用磁化率和非磁滞剩磁对天然剩磁进行归一化处理得到RPI,将钻孔的RPI曲线与全球或区域的标准RPI曲线(Sint-200, NAPIS-75和SCS-PIS)进行比较,得到了6个年龄控制点,并结合AMS-¹⁴C测年结果,建立了南海中央海盆75 ka以来的时间框架.SCS-01钻孔的RPI记录和其他全球性观测结果的一致性表明,南海的沉积物记录了全球尺度的地磁场古强度行为模式.综合稀土元...     

南海东北部陆坡天然气水合物分解释放成因的有孔虫碳同位素轻值事件

2013年中国地质调查局广州海洋地质调查局对南海北部实施第二次天然气水合物钻探并成功钻获可视天然气水合物实物样品,共有五个站位获取沉积物岩芯.本文对其中的GMGS2-08站位沉积物开展有孔虫同位素分析研究,以了解天然气水合物地质系统有孔虫的碳同位素特征及其对甲烷释放的响应.GMGS2-08岩芯沉积物中顶空气甲烷浓度最高达到39300μmol L~(-1),气态烃δ~(13)C值在-69.4~-72.3‰PDB,明确指示其为生物成因,根据甲烷δD测试结果(-183~-185‰SMOW)可进一步判别为CO2还原型微生物气.同位素分析结果显示GMGS2-08站位所获得的岩芯中共出现5期有孔虫碳同位素轻值事件,有孔虫δ~(13)C值明显低于南海冰期-间冰期的正常变化区间,底栖Uvigerina peregrina出现-15.85‰PDB的δ~(13)C极轻值,浮游Globigerinoides ruber的δ~(13)C值同样低至-5.68‰PDB.电镜扫描发现δ~(13)C负偏层位有孔虫壳体经历后期成岩改造被自生碳酸盐所充填,有孔虫壳体的成岩矿化程度与埋深并不相关.与有机碳的相关性计算表明有机质的厌氧氧化对底栖有孔虫的δ~(13)C组成影响微弱,意味着有孔虫的δ~(13)C异常负偏可能主要来源于甲烷厌氧氧化成因的次生碳酸盐的叠加影响.GMGS2-08岩芯记录中有孔虫δ~(13)C负异常和δ~(18)O正异常的耦合性是地质历史时期研究区天然气水合物分解释放的重要证据.     

渤海BH08孔磁学参数变化机制与环境指示

边缘海-陆架区是研究海陆交互作用的理想区域,该区沉积物记录了海平面、气候与构造变化的重要信息.渤海作为我国的内海,前人对该区虽然进行了环境磁学方面的研究,但是受复杂的沉积环境影响,渤海沉积物的磁性变化机制十分复杂,因而需要对该区沉积物磁学性质及变化机制进行深入研究.针对这一问题,本文详细研究了渤海BH08孔岩芯沉积物的磁学性质,结果表明：①沉积物中主要载磁矿物是磁铁矿,部分层位含有高矫顽力的矿物;②岩芯整体磁学性质变化复杂,各项磁学参数变化剧烈,其总体波动与S/Cl值、沉积物红度a^*和深海底栖有孔虫δ¹⁸O相关性较好;③在主要的海陆交替边界层位发现胶黄铁矿,表明是富硫的弱还原环境,而快速变化的沉积环境和较高的沉积速率是胶黄铁矿得以保存的重要因素,因而胶黄铁矿可作为沉积环境发生转变的一种特征矿物.这些新认识为深入开展渤海地区,乃至陆架-边缘海区古环境研究提供了新的思路和方法.     

南海南部约80ka以来的古地磁记录

晚更新世以来以一系列地磁漂移事件是区域地层对比和确定沉积物年代框架的重要工具.但是在海相沉积物中,识别这些地磁漂移事件多依赖相对磁场强度(RPI)的变化,在地磁方向异常方面鲜有报到,从而影响对这些事件可靠性的讨论.本文选择南海南部巽他陆架附近重力活塞钻孔BKAS2PC的沉积物,进行系统的岩石磁学和古地磁研究,获得该钻孔沉积记录的RPI和磁倾角变化信息.岩石磁学及扫描电镜结果表明沉积物的原生主要载磁矿物为单畴(SD)和假单畴(PSD)钛磁铁矿.在一些层位,沉积后发生的还原作用形成胶黄铁矿等铁硫化物.磁性矿物的浓度和粒度等参数呈现显著的两阶段变化特征,上部(约220 cm以上)含量低而粒度细,下部含量高但粒度相对较粗,整体上均在一个数量级范围内波动.样品的交变退磁特征显示当交变场超过60 mT时,受胶黄铁矿影响产生旋转磁化,剩磁强度反而上升.因此,在20～60 mT之间确定原生特征剩磁,并把RPI定义为NRM_((20-40)mT)/ARM_((20-40)mT).通过~(14)C限定,并与其他有良好年代控制的相对磁场强度曲线进行对比,建立了钻孔的年代框架.结果显示,钻孔沉积物记录了几次显著的地磁漂移事件,这为联合应用RPI与磁场方向异常构建海相沉积物年代学框架提供了新的依据.     

基于底栖有孔虫转换函数的南黄海近岸古环境演化过程定量重建

利用加权平均偏最小二乘回归方法(WA-PLS)建立了南黄海西北近岸71个表层沉积物样品中的底栖有孔虫组合与夏季底层水盐度(Ss)、夏季底层水温度(Ts)以及冬季底层水温度(Tw)之间的数值转换函数.将3个函数应用于南黄海近岸SY01孔,重建了这一海区3.9 cal.ka BP以来的Ss,Ts以及Tw变化曲线.横向对比结果表明,SY01孔3.9 cal.ka BP以来的Ss和Ts曲线与九仙洞石笋的?18O记录变动基本同步,可以作为东亚夏季风强度变动的可靠指标;而Tw变动曲线与南黄海ZY-2孔的东亚冬季风强度指标也有着良好的对应关系,可以作为冬季风强度变化指标.此次研究结果证实了底栖有孔虫的转换函数是一项具有较大潜在价值的古环境、古气候定量重建工具.     

太湖平原WJ孔矿物磁学特征以及晚第四纪海侵事件

基于古地磁和AMS¹⁴C定年结果,对长江三角洲太湖平原的WJ孔进行岩性特征、矿物磁学、粒度分析及有孔虫化石研究,拟重建WJ孔记录的晚第四纪以来沉积环境演变过程与海侵事件,并探讨环境磁学参数对河口三角洲地区沉积环境演化的指示意义.研究结果表明,WJ孔可以划分为中更新世阶段I、中更新世阶段II、晚更新世、全新世四个阶段,沉积地貌环境分别为:河湖、滨海-阶地、河口坝-河口湾-潮滩与阶地、湖沼平原.WJ孔揭示了三次海侵事件,分别为中更新世晚期海侵,晚更新世MIS5海侵和晚更新世MIS3海侵.其中记录的MIS5e海侵最为强盛,MIS3后期也存在一次海侵加强事件.另外,滨海潮滩-河口坝环境的沉积物磁性特征明显,χ_lf、SIRM、HIRM等为显著高值.     

福州盆地全新世沉积物的磁学性质及其对环境变化的响应

福州盆地位于海陆过渡地带,在海陆变迁过程中,沉积物记录了高分辨率的环境信息,是揭示沉积特征对环境变化响应过程及模式的理想区域.本文选择位于福州盆地的FZ5钻孔进行岩石磁学、环境磁学和古地磁学方面的研究,以期阐明该区域沉积物磁学性质对陆源碎屑输入、海平面变化和成岩作用的响应.岩石磁学结果表明钻孔沉积物以低矫顽力的亚铁磁性矿物为主体,但是在不同的环境变化阶段,磁性矿物的类型有较大变化.在9~3 cal. ka BP的海侵过程中,沉积物中以磁铁矿为主体,存在菱铁矿和铁硫化物等还原性矿物.硫化作用使细粒磁铁矿溶解形成胶黄铁矿和黄铁矿,其峰面随碎屑磁性矿物的浓度变化而迁移.但硫化作用没有完全消除磁铁矿携带的特征剩磁和陆源碎屑输入量以及海平面升降对该阶段沉积物磁性的控制.在~3 cal. ka BP以来随着海平面下降、沉积环境向陆相氧化环境转化,虽然早期还原作用仍然存在,但后期氧化作用使磁性矿物向高矫顽力的赤铁矿等矿物转变,氧化作用基本扰乱了磁铁矿携带的剩磁.沉积及其后期成岩作用过程中,发生在约~8.2、~7.7、~7.5、~2.7、~1.5、~0.5 cal. ka BP六次强烈的古氧化界面反映了福州盆地当时异常干旱或湿热的气候事件.     

Relative paleointensity of the geomagnetic field during the past 200 ka from the West Philippine Sea and its chronological significance

Our rock magnetic analysis of core Ph05 from the West Philippine Sea demonstrates that the core preserves a strong, stable remanent magnetization and meets the magnetic mineral criteria for relative paleointensity (RPI) analyses. The magnetic minerals in the sequence are dominated by pseudosingle-domain magnetite, and the concentration of magnetic minerals is at the same scale. Both the conventional normalizing method and the pseudo-Thellier method were used in conjunction with the examination of the rock magnetic properties and natural remanent magnetization. Susceptibility (χ), anhysteretic remnant magnetization (ARM) and saturation isothermal remnant magnetization (SIRM) were used as the natural remanent magnetization normalizer. However, coherence analysis indicated that only ARM is more suitable for paleointensity reconstruction. The age model of core is established based on oxygen isotope data and AMS¹⁴C data, which is consistent with the age model estimated from RPI records. The relative paleointensity data provide a continuous record of the intensity variation during the last 200 ka, which correlates well with the global references RPI stacks. Several prominent low paleointensity values are identified and are correlated to the main RPI minima in the SINT-200 record, suggesting that the sediments have recorded the real changes of geomagnetic field. Supported by National Natural Science Foundation of China (Grant No. 90411014) and Pilot Project of the Knowledge Innovation Program of Chinese Academy of Sciences (No. KZCX2-YW-211)     

An estimate of late Pleistocene geomagnetic intensity variation from Sulu Sea sediments

Sediments from Site 769 of the Ocean Drilling Program's Leg 124 provide a record of geomagnetic intensity variation over the past 110 ky. Using continous shipboard measurements exclusively, I estimate the variation in the geomagnetic field strength by employing low-field magnetic susceptibility as a normalization parameter for the measured remanence intensity. By calibrating the resultant relative paleointensity record against previously available Holocene age estimates of absolute paleointensity, I derive an estimate of virtual dipole moment since 110 ka. The record obtained from these Sulu Sea sediments is strikingly like that previously obtained from sediments of a similar age in the Mediterranean Basin with distinct intervals of low intensity near 15, 20, 40 and 65–70 ka. The Sulu sediments also indicate a low-intensity feature near 108 ka. Important differences in paleointensity estimates obtained from these different regions for the interval between 30 and 20 ka suggest that a relatively large non-dipolar component of the geomagnetic field might have been present at that time.     

Paleomagnetic record from Academician Ridge, Lake Baikal: a reversal excursion at the base of marine oxygen isotope stage 6

Paleomagnetic and rock-magnetic studies on a hydraulic piston core (Ver98-1, St.6) from Academician Ridge, Lake Baikal showed the occurrence of a reversal excursion at 670-696 cm depth, which is at the base of marine oxygen isotope stage 6. A correlation of X-ray CT values, as a proxy of relative density, to the marine oxygen isotope record provides an age of 177-183 ka for this reversal excursion. It can be correlated with other excursion records from Lake Baikal, found in Core 287-K2 from Academician Ridge [King et al., Russ. Geol. Geophys. 34 (1993) 148-162] and in core BDP93-1 drilled on the Buguldeika saddle [BDP-93, Quat. Int. 37 (1997) 3-17]. We correlate the Lake Baikal reversal excursion with a well documented excursion in the Brunhes Chron, the Iceland Basin event (186-189 ka) from ODP Sites 983 and 984 in the North Atlantic [Channell, J. Geophys. Res. 104 (1999) 22937-22951]. Also the relative paleointensity record agrees well with that from ODP Site 983 [Channell, J. Geophys. Res. 104 (1999) 22937-22951]. The Lake Baikal excursion and the Iceland Basin event correspond to the minimum of relative intensity at 188 ka in Sint-800 [Guyodo and Valet, Nature 399 (1999) 249-252]. We argue that it is distinct from the Jamaica/Pringle Falls excursion, estimated at 205-215 ka [Langereis et al., Geophys. J. Int. 129 (1997) 75-94]. This is supported by the recalibration of the age of another excursion found in Core St.16 in Lake Baikal [Sakai et al., Bull. Nagoya Univ. Furukawa Mus. 13 (1997) 11-22] with an age of ∼223 ka, which is close to the age of the Jamaica/Pringle Falls excursion, as suggested earlier [King et al., Russ. Geol. Geophys. 34 (1993) 148-162]. The VGP path of the reversal excursion (177-183 ka) consists of a southward swing through the North Atlantic, followed by a loop through Africa and the Indian Ocean. The path morphology is similar to that of the Iceland Basin event from the North Atlantic [Channell, J. Geophys. Res. 104 (1999) 22937-22951].     

The geomagnetic field recorded in sediments of the Tuzla section (the Krasnodar Territory,Russia) over the time interval 120–70 ka

Petro-and paleomagnetic methods are applied to the study of the lower part of the Early Pleistocene Tuzla section on the Black Sea coast of the Taman Peninsula, This part of the section is composed of marine and lagoonal sediments deposited over the time interval 120–70 ka. The measured curves of the variation in the geomagnetic field inclination reveal an anomalous direction dated at ～110 ka that coincides with a similar anomalous direction in the Eltigen section (Ukraine) correlating with the Blake paleomagnetic event. The significant correlation between the time series NRM_0.015/SIRM_0.015 (Tuzla section) and the world composite Sint-800 curve indicates that the curve NRM_0.015/SIRM_0.015 in the interval 110–70 ka actually reflects the variation in the relative paleointensity of the geomagnetic field.     

Geomagnetic variations for the interval 7000–25,000 yr B.P. as recorded in a core of sediment from station 1474 of the Black Sea cruise of “Atlantis II”

Palaeomagnetic measurements have been carried out on 474 specimens taken at about 2.5-cm intervals along an 11 m long piston core.The magnetic inclination exhibits variations with a period of approximately 2800 yr deduced from five radiocarbon age determinations along the core. The assumption that this period was regular allows “magnetic” ages to be assigned to the core and when these are plotted against depth, two straight lines are obtained indicative of steady rates of deposition of 0.4 mm yr^?1 since about 15,000 yr B.P. and 0.8 mm yr^?1 before then. The radiocarbon ages, except that at 16,800 yr, fit these lines suggesting that the assumption that the magnetic inclination fluctuated with regular period is justified. These swings correlate well, but on a two to one basis, with swings in inclination described for core V10-58 from the Aegean Sea (N.D. Opdyke, D. Ninkovich, W. Lowrie and J.D. Hays, 1972). The extra detail carried by the Black Sea core is possibly explained by the faster rate of deposition.The close correspondence of the periodity of these inclination swings with that observed in declination at Lake Windermere (F.H. Mackereth, 1971) is noted and the possibility that they are both caused by oscillations in intensity of the same geomagnetically active region in the core is discussed.The ratio of NRM intensity to susceptibility varies between about 0.4 and 25 within the banded lutites. This range of values may reflect different magnetic mineralogy in the two types of band, of which there are typically 3–7 per specimen, as well as variations in geomagnetic field intensity.     

The geomagnetic field at the Paleozoic/Mesozoic and Mesozoic/Cenozoic boundaries and lower mantle plumes

The data on the amplitude of variations in the direction and paleointensity of the geomagnetic field and the frequency of reversals throughout the last 50 Myr near the Paleozoic/Mesozoic and Mesozoic/Cenozoic boundaries, characterized by peaks of magmatic activity of Siberian and Deccan traps, and data on the amplitude of variations in the geomagnetic field direction relative to contemporary world magnetic anomalies are generalized. The boundaries of geological eras are not fixed in recorded paleointensity, polarity, reversal frequency, and variations in the geomagnetic field direction. Against the background of the “normal” field, nearly the same tendency of an increase in the amplitude of field direction variations is observed toward epicenters of contemporary lower mantle plumes; Greenland, Deccan, and Siberian superplumes; and world magnetic anomalies. This suggests a common origin of lower mantle plumes of various formation times, world magnetic anomalies, and the rise in the amplitude of geomagnetic field variations; i.e., all these phenomena are due to a local excitation in the upper part of the liquid core. Large plumes arise in intervals of the most significant changes in the paleointensity (drops or rises), while no correlation exists between the plume generation and the reversal frequency: times of plume formation correlate with the very diverse patterns of the frequency of reversals, from their total absence to maximum frequencies, implying that world magnetic anomalies, variations in the magnetic field direction and paleointensity, and plumes, on the one hand, and field reversals, on the other, have different sources. The time interval between magmatic activity of a plume at the Earth’s surface and its origination at the core-mantle boundary (the time of the plume rise toward the surface) amounts to 20–50 Myr in all cases considered. Different rise times are apparently associated with different paths of the plume rise, “delays” in the plume upward movement, and so on. The spread in “delay” times of each plume can be attributed to uncertainties in age determinations of paleomagnetic study objects and/or the natural remanent magnetization, but it is more probable that this is a result of the formation of a series of plumes (superplumes) in approximately the same region at the core-mantle boundary in the aforementioned time interval. Such an interpretation is supported by the existence of compact clusters of higher field direction amplitudes between 300 and 200 Ma that are possible regions of formation of world magnetic anomalies and plumes.