Trends in chronic marine oil pollution in Danish waters assessed using 22 years of beached bird surveys

Beached bird surveys provide an important tool for monitoring the level of oil pollution at sea, which is the most significant observable cause of death for a large number of waterbird species and pose a serious threat to wintering seabird populations. Linear regression analyses of oil rates from the Danish 22 year dataset show a decline in the oil pollution level in offshore areas of the eastern North Sea and Skagerrak and in near-shore parts of the Kattegat; but a worsening in the offshore areas of the Kattegat. These results raise concern for species such as common scoter, velvet scoter, eider and razorbill, for which the Kattegat serves as a globally important wintering area. It is recommended that surveillance for oil spills is intensified in inner Danish waters, and that action is taken to make responses towards offenders faster, and penalties for oil seepage higher.     

Eutrophication—The future marine coastal nuisance?

Increased inputs of nutrients to marine coastal areas over the last decades have created a basis for eutrophication of the waters surrounding Sweden. In combination with relatively low water exchange in these vertically stratified and almost non-tidal waters, local and regional effects of increased macro-algal biomass, and decreased oxygen concentrations in bottom water leading to mortalities of benthic animals and decreased fish catches have at times been observed. The effects were first noted in the Baltic, but are now obvious also in Swedish and Danish coastal areas in the Kattegat and the Belt Sea. Similar symptoms have recently also been recorded off the Danish North Sea coast. Other shallow coastal and shelf areas, where stratification occurs, can be regarded as potentially eutrophic risk areas.     

Does the timing of the spawning migration change for the southern component of the Northeast Atlantic Mackerel (Scomber scombrus,L. 1758)? An approximation using fishery analyses

Part of the Northeast Atlantic mackerel population migrates towards the southern spawning area (Cantábrian Sea) at the end of winter. In this seasonal handline fishery targeting mackerel, the most important in the study area that targets this species, the timing of the peak of catches has shifted forward (later) in recent years. This paper presents results pointing to the likelihood that this shift is due to a change in the timing of the spawning migration to the southern area of the Northeast Atlantic mackerel population. Three types of fleet have been identified within this fishery, and in all of them there is a forward shift in time in effort exerted. Moreover, a new model has been defined for the standardization of catch per unit effort (CPUE). The fishing season appears to have shifted forward by 29 days between 2000 and 2006. Nevertheless, changes have been detected neither in the exploitation pattern nor in the duration of the fishing season during the period studied. A shift on this scale has important consequences for the management of the resource, the fleets that exploit it and the resource assessment survey designs that will have to be adapted to this new scenario.     

Quantifying volume transports during SKAGEX with the Norwegian Ecological Model system

A coupled 3-dimensional physical, chemical and biological model system, NORWECOM (the NORWegian ECOlogical Model system), is validated and used to identify and quantify the short-term variability of the different water masses being transported into and out of Skagerrak. The model system is a nesting between a coarse grid model set up for an extended North Sea, and a fine grid defined in the Skagerrak/Kattegat area.Originating from the extensive SKAGEX (SKAGerrak EXperiment) database, several interesting events have been identified and become the focus of the modeling. Through interactive use of the SKAGEX data set and NORWECOM, it is possible to gain a new insight into a very complex hydrodynamic system, an insight that is hard to achieve based on measurements only.     

The distribution of cyclic organochlorines in North Sea sediments

Summary The contamination of North Sea sediments with PCB (as the sum of concentrations of 24 individual components), p, p′-DDE, HCB, α-HCH and Lindane (γ-HCH) was determined in 101 samples taken in early summer 1986. The patterns of individual PCB congeners in the sediments differ between depositional areas and offshore stations: samples from the Kattegat/Skagerrak/Norwegian channel as well as the inner German Bight show higher amounts of highly chlorinated congeners than samples from the central North Sea. The geographical differences in organochlorine contamination were demonstrated on the basis of dry sediments and the content of total organic matter. Concentrations of ΣPCB, p, p′-DDE and HCB reflect the areas of recent deposition of suspended matter in the North Sea. The Ems-Dollard estuary is a source of HCB pollution to the southern North Sea, p, p′-DDE associated to suspended matter from the Baltic Sea presumably accumulates in the Kattegat/Skagerrak/Norwegian channel. Concentrations of Lindane and α-HCH showed only slight gradients or even none in the area investigated.

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Die Verteilung von zyklischen organischen Chlorverbindungen in Nordseesedimenten

Zusammenfassung Es wird über die Belastung von 101 fl?chendeckend beprobten Nordseesedimenten mit polychlorierten Biphenylen (24 Einzelisomere), p, p′-DDE, HCB, α-HCH und Lindan (γ-HCH) berichtet. Die PCB-Muster der im Frühsommer 1986 gezogenen Proben unterscheiden sich hinsichtlich Gebiete mit Nettosedimentation und der zentralen Nordsee: in den Mustern der Sedimente des Kattegats, des Skagerraks, der Norwegischen Rinne und der inneren Deutschen Bucht sind hochchlorierte Isomere, in der zentralen Nordsee niederchlorierte Isomere dominant. Geographische Trends in der Schadstoffbelastung werden auf der Basis des Trockengewichts, sowie normiert auf den Gehalt des Sediments an organischer Substanz aufgezeigt. Sedimente der Norwegischen Küste und der inneren Deutschen Bucht sind hoch mit PCBs, p, p′-DDE und HCB belastet. Die Ems emittiert HCB, die Ostsee p, p′-DDE in die Nordsee; Lindan und α-HCH zeigen keine ausgepr?gten Gradienten.

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La distribution des organochlorés cycliques dans les sédiments de la mer du Nord

Résumé La contamination des sédiments de la mer du Nord avec du PCB — (somme de 24 composants différents), p, p′-DDE, HCB, α-HCH et Lindane (γ-HCH) fut déterminée dans 101 échantillons pris au début de l'été 1986. Les types de composants individuels de PCB dans les sédiments sont différents selon qu'ils proviennent de zones de déblais ou de stations offshore. Les prélèvements en provenance de Kattegat/Skagerrak/Norvegian Channel comme ceux de la baie intérieure allemande accusent des montants plus élevés de composants hautement chlorés que les prélèvements provenant du centre de la mer du Nord. Les différences géographiques dans la contamination organochlorée ont été démontrées sur la base de sédiments secs et du volume total de la matière organique. Les concentrations de ΣPCB, p, p′-DDE et HCB reflètent les zones de dép?ts récents de matière suspendue dans la mer du Nord. L'estuaire Ems-Dollard est une source de pollution HCB pour la région sud de la mer du Nord; le p, p′-DDE associé aux matières suspendues en provenance de la mer Baltique s'accumule probablement dans le Kattegat/Skagerrak/Norvegian channel. Les concentrations de Lindane et de α-HCH n'ont pas montré de variation significative dans la zone étudiée.

     

Trace metal levels in coastal sea water investigation of Danish waters

The concentration levels of Cd (25 ng l^?1), Cu (0.45 μg l^?1), Ni (0.48 μg l^?1), Fe (0.2–7.0 μg l^?1), Pb (40 ng l^?1) and Zn (0.80 μg l^?1) have been determined in the Danish Sounds and in the Kattegat. Different sampling techniques have been used and analyses have been carried out separately by two different investigators, both using freon-extraction followed by determination by atomic absorption spectrometry (a.a.s.). Except for iron, found mainly in the particulate phase, the metals are found predominantly in a dissolved and labile (extractable) form. The results are compared with trace metal levels found in the two main water masses entering the Kattegat—the North Sea and the Baltic Sea.     

Comparison of particulate matter distribution, in relation to hydrography, in the mesotrophic Skagerrak and the oligotrophic northeastern Aegean Sea

The seasonal vertical distribution of particulate matter (PM) was studied in two contrasting areas: (a) the mesotrophic Skagerrak (in the North Sea); and (b) the oligotrophic northeastern Aegean Sea (eastern Mediterranean). Similarities and differences of the PM distribution in the two areas are assessed with respect to the prevailing hydrographic conditions and the PM composition. Hydrographic conditions in both of the areas are characterised by strong density gradients, resulting from the inflow of low-salinity water, i.e. Baltic Sea water and Black Sea water for the Skagerrak and the northeastern Aegean Sea, respectively.Enhanced primary production and particles mainly of biogenic origin characterise the mesotrophic Skagerrak, whereas five-fold lower particle concentrations appeared in the oligotrophic Aegean Sea. The input of riverine particulates was limited in both of the areas. In the Skagerrak, the strong stratification resulted in particle accumulation on/above the pycnocline and the development of pronounced intermediate nepheloid layers (INLs). The pycnocline-related INLs were formed entirely by dinoflagellates. The pycnocline hindered the vertical movement and sinking rates of particles, thus favouring primary production. Particle horizontal advection along the density discontinuities was probably enhanced. This pattern was not observed in the stratified waters of the northeastern Aegean Sea, probably due to the very low particle concentrations and/or the fact that phytoplankton maxima appeared in deeper waters. Pronounced INLs were identified in the Skagerrak below the pycnocline; these are attributed to accumulated or advected dinoflagellate skeletal remains mixed with clay mineral particles. This was revealed only by means of SEM observations. X-ray diffraction analysis could not provide information on the type of phytoplankton present, because dinoflagellates form their skeletons from organic material. Frontal stations in the northeastern Aegean Sea exhibited pronounced vertical movement of particles towards the deeper waters. Benthic nepheloid layers (BNL) were observed in the Skagerrak; these were related to the resuspended fine-grained surface sediments. In the northeastern Aegean Sea, although near-bottom current velocities were sufficient to resuspend surface sediments, resuspension occurred only episodically. The BNLs here are related mostly to near-bottom phytoplankton growth.     

The termination of the last major phase of aeolian sand movement,coastal dunefields,Denmark

Optically stimulated luminescence (OSL) dating of sand samples from stabilized (or inactive) coastal dunes in Denmark provides information on the age of the termination phase of the last major aeolian activity period. A total of 26 sand samples were taken from four different coastal dunefields around the North Sea, Skagerrak and Kattegat coasts of Denmark. The OSL dates indicate that the last major phase of aeolian activity terminated between ad 1860 and 1905. Most of the dunes examined in this study were active around 1820, during a period documented to have been very stormy. A dune management scheme started around 1792, and this no doubt was a major cause of dunefield stabilization, but an overall decline of storminess, particularly spring and summer storminess, around the end of the 19th century must also have contributed to the increasing inactivity of coastal dunes. The new OSL dates on aeolian sand movement agree well with historical data and data from topographic maps on dune movement. This agreement supports the observation from earlier work that OSL dating of recent aeolian sand movement is accurate over the last few decades to centuries. Copyright © 2005 John Wiley & Sons, Ltd.     

A simple method for confidence rating of eutrophication status classifications

We report the development of a methodology for assessing confidence in ecological status classifications. The method presented here can be considered as a secondary assessment, supporting the primary assessment of eutrophication or ecological status. The confidence assessment is based on scoring the quality of the indicators on which the primary assessment is made. This represents a first step towards linking status classification with information regarding their accuracy and precision. Applied to an existing data set used for assessment of eutrophication status of the Baltic Sea (including the Kattegat and Danish Straits) we demonstrate that confidence in the assessment is Good or High in 149 out of 189 areas assessed (79%). Contrary to our expectations, assessments of the open parts of the Baltic Sea have a higher confidence than assessments of coastal waters. We also find that in open waters of the Baltic Sea, some biological indicators have a higher confidence than indicators representing physical-chemical conditions. In coastal waters, phytoplankton, submerged aquatic vegetation and indicators of physical-chemical conditions have a higher confidence than indicators of the quality of benthic invertebrate communities. Our analyses also show that the perceived weaknesses of eutrophication assessments are due more to Low confidence in reference conditions and acceptable deviations, rather than in the monitoring data.     

Decadal long simulations of mesoscale structures in the northern North Sea/Skagerrak using two ocean models

We consider results from two 27-year-long simulation pairs derived using two different ocean models. We focus on the Skagerrak/North Sea area. Each pair consists of the two terrain-following coordinate models ROMS and MIPOM. The first pair utilizes an eddy-permitting grid, that is, a grid in which the Rossby radius is barely resolved. The second pair utilizes an eddy-resolving grid in which the Rossby radius is truly resolved. The goal is to compare the quality of the two models and the two pairs. To this end we derive statistical properties such as probability density functions and compare them with similar statistics derived from observations. Thereby we obtain insight into whether a truly eddy-resolving model is required to realistically capture the mesoscale statistics. We find that eddy resolution is critical to get the mesoscale statistics correct, in particular, the strength of the current jets. Our results also indicate that the improvement gained by employing the eddy-resolving grid is mostly due to a better resolved topography. In particular, we find that this is the case in areas exhibiting prominent topographic features, such as the deep Norwegian Trench cutting into the heart of the northern North Sea/Skagerrak area. The results also highlight the advantage of first performing quality assurance investigations when implementing a new model for a new area.     

Recovery of fish stocks in the Seto Inland Sea

The total amount of fisheries' yield in the Seto Inland Sea in 1999 was 571,000 MT, consisting of 256,000 MT by fishing and 315,000 MT from aquaculture. About 40,000 people engaged in the fishing and aquaculture industries, earned 129 billion yen (1100 million US$) by fishing and 89 billion yen (770 million $US) by aquaculture. The averaged annual catch for the Seto Inland Sea by fishing was 13 MT/km(2). Division into time periods in terms of eutrophication levels can be made: before 1960 when red sea bream were abundant with ecological divergence (before eutrophication), from 1960 to 1990 when the biomass of anchovy was large (during eutrophication), and after 1990 when the jellyfishes were abundant (excessive eutrophication or high N:P ratio). The fish production will decrease in the sea of jellyfishes. Actually, the amount of catch was 462,000 MT in 1982 which decreased 265,000 MT in 1993, corresponding to 43% in twelve years, then keeping the same level. A big reduction was seen in the catches of the spotlined sardine, anchovy, Spanish mackerel, tiger puffer, short-necked clam, sea cucumber and others. The tiger puffer and Spanish mackerel were abundant as predators in the sea of anchovy. The biomass of anchovy was at its maximum in 1986 and decreased to less than one third in 1996. The stocks of tiger puffer and Spanish mackerel greatly decreased because of the higher fishing pressure compared to the anchovy stock. The fishing power of individual fisheries targeting on the tiger puffer and Spanish mackerel increased substantially when fishing vessel and fishing gear improved, resulting in an excessive fishing effort. A large quantity of small immature fishes is usually caught in the Seto Inland Sea, resulting in growth and/or recruitment overfishing for many species. Hence, it is necessary to promote management of the fisheries so as not to reduce the fish stocks, and to allow the Seto Inland Sea to return from being a sea of jellyfishes to a sea of anchovy, with decreased eutrophication levels.     

Future climate impacts on the hydrology of headwater streams in the Amazon River Basin: Implications for migratory goliath catfishes

Climate-driven alterations of hydro-meteorological conditions can change river flow regimes and potentially affect the migration behaviour of fishes and the productivity of important fisheries in the Amazon basin, such as those for the continental-scale migratory goliath catfishes (Brachyplatystoma, Pimelodidae). In this study, we investigated hydrologic responses to climate change using a hydrologic model forced with climate inputs, which integrate historical (2001–2010) observations and general circulation model (GCM) projections under the emission scenario Representative Concentration Pathway 8.5. We developed an empirical model to characterize future (2090–2099) climate-change impacts on goliath catfish spawning migrations as a function of river flow depth dynamics at the upstream elevational limit of spawning (250 m) in headwater basins of the Amazon. The model results revealed spatially variable impacts of climate change on the catfish spawning migrations. The Marañón, Ucayali, Juruá, Purus, and Madeira basins had a predicted increase in the annual mean (3–8%) and maximum (1.1–4.9%) spawning migration rate (i.e., the fraction of fish that migrate to the spawning grounds in a day), mainly due to the lengthened rising phase of flow-driven migratory events during wet seasons. The Caquetá-Japurá, Putumayo-Içá, Napo, and Blanco rivers had predicted decreases (3–7%) in the mean migration rate because of decreases in the length of the rising season of flow depth and the frequency of migratory events. The predicted timing of fish spawning migrations (quantified by the temporal centroid of migration rates) was delayed by 7–10 days in the west-central and southwest regions and was 8 days earlier in the northwest and northcentral areas, due to changes in the onset of the rising season. We established a river depth baseline that controls the onset of goliath catfish spawning migration. This depth varies between 0.9–5.6 m across study sites. We found that the estimated depth baseline was most sensitive to uncertainties in river width and cross-sectional channel shape. These results may help inform sustainable adaptation strategies for ecosystem conservation and local fisheries management in the Amazon basin.     

Pelagic tar in the Norwegian Coastal Current

Petroleum particulates were found in 117 of 220 neuston samples collected in the Norwegian Coastal Current during March–August 1975, at an average concentration of 0.11 mg/m². Highest concentrations were observed in the Skagerrak and Barents Sea. Lower densities occurred along the northwest Norwegian coast and in the North Sea.     

Mesoscale activity in the North Sea as seen in ensemble simulations

A set of two simulation ensembles of the ocean circulation in the North Sea, the Skagerrak and bordering seas has been run for the ten year period that started in January 1992. The ensembles differed only in the horizontal grid resolution. The main purposes of this investigation are (1) to quantify the variability that can be expected in multi-year simulations due to noise-like perturbations in the initial fields, and (2) to examine the robustness of model results for mesoscale features that form on the front between the Norwegian Coastal Current and water masses that are of an Atlantic Ocean origin. It is shown that the model resolution has a substantial impact on the ensemble variability, and that the role of small perturbations become more significant as the grid mesh is refined. Nevertheless, it is demonstrated that in a region to the west of the southern tip of Norway, eddies are occasionally found in the same positions at the same time in the results from all members of the ensembles. This is particularly the case in the aftermath of outbreak events of low salinity water masses from the Skagerrak into the North Sea.     

Variation in mercury content of Guillemot feathers over 150 years

The feathers of 277 Black, Common and Brünnich's Guillemot from the Baltic, Kattegat, Faroe Islands and Greenland were analysed for mercury. The levels were found to be higher in the Baltic and the Kattegat compared to the Faroe Islands and Greenland. While the levels were almost constant for the last two areas a substantial increase during this century was found for the Baltic and the Kattegat. In Common Guillemots from the Baltic a decrease was indicated after 1969. In general the mercury levels were higher for Black Guillemots living close to the coast compared to the Uria sp. living off-shore. The inhomogeniety of the mercury load near the shore was indicated by a large individual variation within a colony of Black Guillemots. This variation was reinforced by differences in migration and feeding habits. It has been shown by analysis of individuals recaptured during successive years that the year to year variation of one individual is considerably smaller.It is concluded that chronological series based on feathers from sea birds and museum collections may contribute to the elucidation of the long term trend of mercury pollution at sea.     

An analysis of the salt water inflow into the Baltic in 1975 to 1976

Time series measurements from light vessel and coastal stations in the transition area of the Kattegat and the Baltic Sea are analyzed for the period August 1975 to March 1976. The data consist of daily sampled salinities from different depth levels and daily means of sea levels, surface current, and wind, respectively. The purpose of this paper is to examine the dynamics of the mass- and salt-transport during a major salt water inflow.The principal conclusions of this paper are that

Identification of the environmentally safe fairway in the South-Western Baltic Sea and Kattegat

Application of the preventive techniques for the optimisation of fairways in the south-western Baltic Sea and the Kattegat in terms of protection of the coastal regions against current-driven surface transport of adverse impacts released from vessels is considered. The techniques rely on the quantification of the offshore domains (the points of release of adverse impacts) in terms of their ability to serve as a source of remote, current-driven danger to the nearshore. An approximate solution to this inverse problem of current-driven transport is obtained using statistical analysis of a large pool of Lagrangian trajectories of water particles calculated based on velocity fields from the Denmark’s Meteorological Institute (DMI)/BSH cmod circulation model forced by the DMI-HIRHAM wind fields for 1990–1994. The optimum fairways are identified from the spatial distributions of the probability of hitting the coast and for the time (particle age) it takes for the pollution to reach the coast. In general, the northern side of the Darss Sill area and the western domains of the Kattegat are safer to travel. The largest variations in the patterns of safe areas and the properties of pollution beaching occur owing to the interplay of water inflow and outflow. The gain from the use of the optimum fairways is in the range of 10–30?% in terms of the decrease in the probability of coastal hit within 10?days after pollution release or an increase by about 1–2?days of the time it takes for the hit to occur.     

Migration of a volcanic front inferred from K–Ar ages of late Miocene to Pliocene volcanic rocks in central Japan

K–Ar ages have been determined for 14 late Miocene to Pliocene volcanic rocks in the north of the Kanto Mountains, Japan, for tracking the location of the volcanic front through the time. These samples were collected from volcanoes located behind the trench–trench–trench (TTT) triple junction of the Pacific, Philippine Sea, and North American plates. This junction is the site of subduction of slabs of the Pacific and the Philippine Sea plates, both of which are thought to have influenced magmatism in this region. The stratigraphy and K–Ar ages of volcanic rocks in the study area indicate that volcanism occurred between the late Miocene and the Pliocene, and ceased before the Pleistocene. Volcanism in adjacent areas of the southern NE Japan and northern Izu–Bonin arcs also occurred during the Pliocene and ceased at around 3 Ma with the westward migration of the volcanic front, as reported previously. Combining our new age data with the existing data shows that before 3 Ma the volcanic front around the TTT junction was located about 50 km east of the preset‐day volcanic front. We suggest that northward subduction of the Philippine Sea Plate slab ended at ～3 Ma as a result of collision between the northern margin of the plate with the surface of the Pacific Plate slab. This collision may have caused a change in the subduction vector of the Philippine Sea Plate from the original north‐directed subduction to the present‐day northwest‐directed subduction. This indicates that the post ～3 Ma westward migration of the volcanic front was a result of this change in plate motion.     

Anthropogenic nutrient load of the Baltic Sea

The discharge of nutrients is investigated in relation to their sources and effects in two case studies. The reduction of 47% in the phosphorus load from Denmark to marine areas between 1989 and 1993 has resulted in significantly lower phosphorus concentrations in most Danish coastal waters, and tendency to decrease can be seen in the Belt Sea and Kattegat as well. No general changes in nitrogen concentrations have been observed. This is due to the fact that more than 80% of the nitrogen load in Danish waters originate from diffuse agricultural sources.In the Pomeranian Bight strong nutrient gradients are generated by the mixing of Odra river water and coastal water. The spreading of the river plume could be exactly observed especially in winter, when biological activity is low. In general, different types of distribution, transport and modification patterns can be described.The annual input of nutrients from the catchment area to the Baltic Sea was estimated to be around 1000 kt N and 46 kt P. As a result, winter concentrations of phosphate and nitrate are characterized by positive overall trends in the surface layer in all subregions of the Baltic Proper for the period 1969 to 1993. These trends stem mainly from the strong increase in the 1970ies and early 1980ies. Thereafter, the concentrations of both nutrients fluctuate strongly around a high level. The drastic decrease in fertilizer consumption since the late 1980ies mainly caused by the great economic changes in the countries of the former East Bloc is not yet significantly reflected in decreasing winter concentrations, but first signs already have been found in the decrease in averaged phosphate concentrations in winter, especially in the Arkona and Bornholm Seas.