Modelling evaporation processes in soils from the Huasco salt flat basin,Chile

The need to understand and simulate hydrological phenomena and their interactions, and the impact of anthropogenic and climate changes on natural environments have promoted the study of evaporation from bare soils in arid climates. In closed Altiplano basins, such as those encountered in arid and hyper arid basins in northern Chile, evaporation from shallow groundwater is the main source of aquifer depletion, and thus, its study is crucial for water resources management. The objective of this work is to understand the mechanisms of evaporation in saline soils with shallow water tables, in order to better quantify evaporation fluxes and improve our understanding of the water balance in these regions. To achieve this objective, a model that couples fluid flow with heat transfer was developed and calibrated using column experiments with saline soils from the Huasco salt flat basin, Chile. The model enables determination of both liquid and water vapour fluxes, as well as the location of the evaporation front. Experimental results showed that salt transport inside the soil profile modified the water retention curve, highlighting the importance of including salt transport when modelling the evaporation processes in these soils. Indeed, model simulations only agreed with the experimental data when the effect of salt transport on water retention curves was taken into account. Model results also showed that the evaporation front is closer to the soil surface as the water table depth reduces. Therefore, the model allows determining the groundwater level depth that results in disconnection of liquid fluxes in the vadose zone. A sensitivity analysis allowed understanding the effect of water‐flux enhancements mechanisms on soil evaporation. The results presented in this study are important as they allow quantifying the evaporation that occurs in bare soils from Altiplano basins, which is typically the main water discharge in these closed basins. Copyright © 2016 John Wiley & Sons, Ltd.     

Building sandstone surface modification by biofilm and iron precipitation: emerging block‐scale heterogeneity and system response

Stone surfaces are sensitive to their environment. This means that they will often respond to exposure conditions by manifesting a change in surface characteristics. Such changes can be more than simply aesthetic, creating surface/subsurface heterogeneity in stone at the block scale, promoting stress gradients to be set up as surface response to, for example, temperature fluctuations, can diverge from subsurface response. This paper reports preliminary experiments investigating the potential of biofilms and iron precipitation as surface‐modifiers on stone, exploring the idea of block‐scale surface‐to‐depth heterogeneity, and investigating how physical alteration in the surface and near‐surface zone can have implications for subsurface response and potentially for long‐term decay patterns. Salt weathering simulations on fresh and surface‐modified stone suggest that even subtle surface modification can have significant implications for moisture uptake and retention, salt concentration and distribution from surface to depth, over the period of the experimental run. The accumulation of salt may increase the retention of moisture, by modifying vapour pressure differentials and the rate of evaporation. Temperature fluctuation experiments suggest that the presence of a biofilm can have an impact on energy transfer processes that occur at the stone surface (for example, buffering against temperature fluctuation), affecting surface‐to‐depth stress gradients. Ultimately, fresh and surface‐modified blocks mask different kinds of system, which respond to inputs differently because of different storage mechanisms, encouraging divergent behaviour between fresh and surface‐modified stone over time. Copyright © 2014 John Wiley & Sons, Ltd.     

A New Operational Paradigm for Small‐Scale ASR in Saline Aquifers

A new operational paradigm is presented for small‐scale aquifer storage and recovery systems (ASR) in saline aquifers. Regular ASR is often not feasible for small‐scale storage in saline aquifers because fresh water floats to the top of the aquifer where it is unrecoverable. In the new paradigm, fresh water storage is combined with salt water extraction from below the fresh water cone. The salt water extraction counteracts the buoyancy due to the density difference between fresh water and salt water, thus preventing the fresh water from floating up. The proposed approach is applied to assess the feasibility of ASR for the seasonal storage of fresh water produced by desalination plants in tourist resorts along the Egyptian Red Sea coast. In these situations, the continuous extraction of salt water can be used for desalination purposes. An analytical Dupuit solution is presented for the steady flow of salt water toward a well with a volume of fresh water floating on top of the cone of depression. The required salt water discharge for the storage of a given volume of fresh water can be computed with the analytical solution. Numerical modeling is applied to determine how the stored fresh water can be recovered. Three recovery approaches are examined. Fresh water recovery rates on the order of 70% are achievable when salt water is extracted in high volumes, subsurface impermeable barriers are constructed at a distance from the well, or several fresh water recovery drains are used. The effect of ambient flow and interruptions of salt water pumping on the recovery efficiency are reported.     

Characteristics of thermal radiation of ice covers on water bodies with different mineralization

The microwave brightness temperature of ice cover on fresh and slightly saline noneutrophic water bodies with mineralization varying from 0.1 to 3 g/l is examined. The optimal conditions for the determination of salt concentration in ice cover by radio thermal radiation are identified.     

Small‐Scale ASR Between Flow Barriers in a Saline Aquifer

Regular aquifer storage recovery, ASR, is often not feasible for small‐scale storage in brackish or saline aquifers because fresh water floats to the top of the aquifer where it is unrecoverable. Flow barriers that partially penetrate a brackish or saline aquifer prevent a stored volume of fresh water from expanding sideways, thus increasing the recovery efficiency. In this paper, the groundwater flow and mixing is studied during injection, storage, and recovery of fresh water in a brackish or saline aquifer in a flow‐tank experiment and by numerical modeling to investigate the effect of density difference, hydraulic conductivity, pumping rate, cyclic operation, and flow barrier settings. Two injection and recovery methods are investigated: constant flux and constant head. Fresh water recovery rates on the order of 65% in the first cycle climbing to as much as 90% in the following cycles were achievable for the studied configurations with constant flux whereas the recovery efficiency was somewhat lower for constant head. The spatial variation in flow velocity over the width of the storage zone influences the recovery efficiency, because it induces leakage of fresh water underneath the barriers during injection and upconing of salt water during recovery.     

Modification of the Penman method for computing bare soil evaporation

The Penman equation, which calculates potential evaporation, was modified by Staple (1974, Soil Science Society of America Proceedings 38 : 837) to include in it the relative vapour pressure h_s of an unsaturated soil to predict actual evaporation from a soil surface. This improved the prediction when the difference between the temperature of the soil surface and ambient air is relatively small. The objectives of this study were (i) to revise it further using the actual temperature of the soil surface and air to provide the upper boundary condition in computing evaporative flux from the soil surface and (ii) to determine the range of water content for which the modified form of the Penman equation is applicable. The method adopted was tested by a series of outdoor experiments with a clay soil. The method of Staple (1974) overestimated the rate of evaporation above the water content 0·14 m³ m^?3 (up to 30% deviation), whereas the new method agreed well with the measured rates (maximum 7% deviation). Below 0·14 m³ m^?3 water content, both methods underestimated, but the Staple (1974) method deviated more from the measured values: the deviations were above 70% and around 30% for the Staple (1974) and the new methods respectively. Although the new method provided accurate solutions for a wider range of water content from saturation to the lower limit of the liquid phase of a particular soil, the modification did not respond to the vapour phase of the soil moisture. Therefore, in the dry range (i.e. in the vapour phase in which the flow was entirely as vapour), either resistance models or a Fickian equation should be used. Although the effect of salinity on the measured rates was significant, the model erroneously calculated the same rates for both saline and non‐saline conditions. The effect of soil texture can easily be accounted by defining appropriate matric potential water content ψ_m(θ) and soil relative humidity water content h_s(θ) relationships. Copyright © 2007 John Wiley & Sons, Ltd.     

Using chlorofluorocarbons (CFCs) and tritium to improve conceptual model of groundwater flow in the South Coast Aquifers of Laizhou Bay,China

The southern coastal plain of Laizhou Bay, which is the area most seriously affected by salt water intrusion in north China, is a large alluvial depression, which represents one of the most important hydrogeological units in the coastal region of northern China. Chlorofluorocarbons (CFCs, including CFC‐11, CFC‐12 and CFC‐113) and tritium were used together for dating groundwater up to 50 years old in the study area. There are two cones of depression, caused by intensive over‐exploitation of fresh groundwater in the south and brine water in the north. The assigned CFC apparent ages for shallow groundwater range from 8 a to >50 a. A binary mixing model based on CFC‐113 and CFC‐12 concentrations in groundwater was used to estimate fractions of young and pre‐modern water in shallow aquifers and to identify groundwater mixing processes during saltwater intrusion. Discordance between concentrations of different CFC compounds indicate that shallow groundwater around the Changyi cone of depression is vulnerable to contamination. Pumping activities, CFC contamination, mixing and/or a large unsaturated zone thickness (e.g. >20 m) may be reasons for some groundwater containing CFCs without tritium. Saline intrusion mainly occurs because of large head gradients between fresh groundwater in the south and saline water bodies in the north, forming a wedge of saline water below/within fresh aquifer layers. Both CFC and tritium dates indicate that the majority of the saline water is from >50 a, with little or no modern seawater component. Based on the distribution of CFC apparent ages, tritium contents plus chemical and physical data, a conceptual model of groundwater flow along the investigated Changyi‐Xiaying transect has been developed to describe the hydrogeological processes. Three regimes are identified from south to north: (i) fresh groundwater zone, with a mixing fraction of 0.80–0.65 ‘young’ water calculated with the CFC binary mixing model (groundwater ages <34 a) and 1.9–7.8TU of tritium; (ii) mixing zone characterized by a mixing fraction of 0.05–0.65 young groundwater (ages of 23–44 a), accompanied by local vertical recharge and upward leakage of older groundwater; and (iii) salt water zone, mostly comprising waters with ages beyond the dating range of both CFCs and tritium. Some shallow groundwater in the north of the Changyi groundwater depression belongs to the >50a water group (iii), indicating slow velocity of groundwater circulation and possible drawing in of saline or deep groundwater that is tracer‐free. Copyright © 2012 John Wiley & Sons, Ltd.     

Evaporation and the subcanopy energy environment in a flooded forest

The combination of tree canopy cover and a free water surface makes the subcanopy environment of flooded forested wetlands unlike other aquatic or terrestrial systems. Subcanopy vapour fluxes and energy budgets represent key controls on water level and understorey climate but are not well understood. In a permanently flooded forest in south‐eastern Louisiana, USA, an energy balance approach was used to address (a) whether evaporation from floodwater under a forest canopy is solely energy limited and (b) how energy availability was modulated by radiation and changes in floodwater heat storage. A 5‐month continuous measurement period (June–November) was used to sample across seasonal changes in canopy activity and temperature regimes. Over this period, the subcanopy airspace was humid, maintaining saturation vapour pressure for 28% of the total record. High humidity coupled with the thermal inertia of surface water altered both seasonal and diel energy exchanges, including atypical phenomena such as frequent day‐time vapour pressure gradients towards the water surface. Throughout the study period, nearly all available energy was partitioned to evaporation, with minimal sensible heat exchange. Monthly mean evaporation ranged from 0.7 to 1.7 mm/day, peaking in fall when canopy senescence allowed greater radiation transmission; contemporaneous seasonal temperature shifts and a net release of stored heat from the surface water resulted in energy availability exceeding net radiation by 30% in October and November. Relatively stable energy partitioning matches Priestley–Taylor assumptions for a general model of evaporation in this ecosystem.     

Estimating daily lake evaporation from biweekly energy‐budget data

Estimates of daily lake evaporation based on energy‐budget data are poor because of large errors associated with quantifying change in lake heat storage over periods of less than about 10 days. Energy‐budget evaporation was determined during approximately biweekly periods at a northern Minnesota, USA, lake for 5 years. Various combinations of shortwave radiation, air temperature, wind speed, lake‐surface temperature, and vapour‐pressure difference were related to energy‐budget evaporation using linear‐regression models in an effort to determine daily evaporation without requiring the heat‐storage term. The model that combined the product of shortwave radiation and air temperature with the product of vapour‐pressure difference and wind speed provided the second best fit based on statistics but provided the best daily data based on comparisons with evaporation determined with the eddy‐covariance method. Best‐model daily values ranged from ?0.6 to 7.1 mm/day over a 5‐year period. Daily averages of best‐model evaporation and eddy‐covariance evaporation were nearly identical for all 28 days of comparisons with a standard deviation of the differences between the two methods of 0.68 mm/day. Best‐model daily evaporation also was compared with two other evaporation models, Jensen–Haise and a mass‐transfer model. Best‐model daily values were substantially improved relative to Jensen–Haise and mass‐transfer values when daily values were summed over biweekly energy‐budget periods for comparison with energy‐budget results.     

Chemical textures on quartz grains: An experimental approach using salts

Two groups of fresh crushed Brazilian quartz grains (0.4–0.6 mm) were placed in 10 ml of various saturated salt solutions (sodium sulphate, sodium chloride, magnesium sulphate, sodium carbonate, and sodium carbonate and soil). One group was placed in an environmental cabinet programmed to simulate summer diurnal temperature and relative humidity values recorded in Wheeler Valley, a dry valley in southern Victoria Land, Antarctica. The other group was allowed to remain at normal laboratory conditions. Quartz grains from both groups were removed at pre-selected intervals for examination using the scanning electron microscope. After 50 hours chemical surface textures were formed on the quartz grains in all but the sodium sulphate solution. At the 140 hour interval all the salt solutions used were producing chemical surface textures on the quartz grains. This paper demonstrates that chemical surface textures can be produced on quartz grain surfaces by saturated salt solutions in a short period of time and may prove to be representative of chemical surface textures produced in a saturated saline environment.     

水面蒸发与散热系数公式研究(一)

根据自1976年以来全国水面蒸发与散热研究协作组在我国各典型地区的原体与室内实验资料和大量水文站历史资料,通过理论分析和统计检验,确定丁影响水面蒸发的诸因子及其非线性相互作用,引入了新的无量纲参数(w_e、Pv、Pe)和公式结构,用实测资料统计确定厂公式中的常系数,得到了用开敞湖面一般水文气象资料计算逐日蒸发和散热系数的公式。经全国各典型气候带内各季节湖泊(水库)和受热污染水体上原体观测和室内专题实验共1860组口平均资料检验,公式的精度高于现有其他公式。全文分两部分,这是第一部分,内容包括:影响水面蒸发的土要无量纲参数;感热输送和大气饱和度对蒸发影响的修正;水面蒸发计算公式的结构及其经验系数。     

Evaporation of water from sand, 2: Diurnal variations

In evaporation tests with moist sand, an evaporation peak was observed just before sunrise. Neither the vapour pressure gradient between water-table and atmosphere, nor the fact that the vapour pressure difference between water-table and atmosphere exceeded the vapour pressure deficit of the air during the night, could fully explain this phenomenon. The temperature difference between that of the water-table and that of the atmosphere correlated well with evaporation during the night and seemed to be a determining factor during that period. It was most probably the factor mainly responsible for the evaporation peak before sunrise.     

Experimental investigation of injectivity alteration due to salt precipitation during CO2 sequestration in saline aquifers

Injection of CO₂ into saline aquifers causes the geochemical reaction of rock-fluid and salt precipitation due to the evaporation of water as a physical process. Well injectivity is an important issue in carbon capture and storage (CCS) projects because large volumes of CO₂ must be stored for a long time and salt precipitation can significantly reduce injectivity by reducing the permeability. The impact of salt precipitation on the injectivity must therefore be specified in order to maintain the security of CCS projects and enable them to perform at a high level of practicality. The objective of this work is to investigate the influence of the injection rate and brine salinity on injectivity reduction due to evaporation and salt precipitation. In this study, we injected supercritical CO₂ into a sandstone rock sample fully saturated with NaCl brine to characterize the salt precipitation induced by the evaporation process.Evaporation is investigated by mass measurement of the water and vapor produced. The extension in time of salt precipitation and the precipitation profile are analyzed by drying rate measurement, Capillary number and Peclet number. The consequences of salt precipitation on injectivity are specified by permeability and relative permeability analysis. The results show that a high drying rate in the early stage of injection induces rapid salt precipitation. The level of salt precipitation increases with salinity, within a permeability reduction range of 21–66%, and decreases with the injection rate, within a permeability reduction range of 43–62%. The relative permeability of CO₂ is affected by both the injection rate and salinity.     

水面蒸发与散热系数公式研究(二)

根据自1976年以来全国水面蒸发与散热研究协作组在我国各典型地区的原体与室内实验资料和大量水文站历史资料,通过理论分析和统计检验,确定了影响水面蒸发的诸因子及其非线性相互作用,引入了新的无量纲参数和公式结构,用实测资料统计确定了公式中的常系数,得到了用开敞湖面一般水文气象资料计算逐日蒸发和散热系数的公式。经全国务典型气候带内务季节湖泊(水库)和受热污染水体上原体观测和室内专题实验共1860组日平均检验,公式的精度高于现有其他公式。全文分两部分,本文刊出第二部分,内容包括:公式的检验;水文气象要素对α的影响;水面散热系数的计算和结语。     

世界咸水湖的物理与化学特性

本文根据近年来有关咸水湖的研究文献,介绍了咸水湖的概念、地理分布和湖盆的成因。进而从咸水湖的光学特性和热学特性两个方面阐述了湖泊的物理特性;从湖水盐度、蒸发和盐度、盐分来源,湖水的化学成分和类型以及盐湖的演化等方面说明咸水湖的化学特点;最后,从盐类沉积和古气候古环境关系的角度出发,指出咸水湖的古湖沼学研究在过去全球变化历史的重建中具有巨大的潜力,是全球研究体系中不可缺少的部分。     

Effect of Sea‐Level Rise on Salt Water Intrusion near a Coastal Well Field in Southeastern Florida

A variable‐density groundwater flow and dispersive solute transport model was developed for the shallow coastal aquifer system near a municipal supply well field in southeastern Florida. The model was calibrated for a 105‐year period (1900 to 2005). An analysis with the model suggests that well‐field withdrawals were the dominant cause of salt water intrusion near the well field, and that historical sea‐level rise, which is similar to lower‐bound projections of future sea‐level rise, exacerbated the extent of salt water intrusion. Average 2005 hydrologic conditions were used for 100‐year sensitivity simulations aimed at quantifying the effect of projected rises in sea level on fresh coastal groundwater resources near the well field. Use of average 2005 hydrologic conditions and a constant sea level result in total dissolved solids (TDS) concentration of the well field exceeding drinking water standards after 70 years. When sea‐level rise is included in the simulations, drinking water standards are exceeded 10 to 21 years earlier, depending on the specified rate of sea‐level rise.     

Modeling interaction of fluid and salt in an aquifer/lagoon system

To simulate the dynamic interaction between a saline lagoon and a ground water system, a numerical model for two-dimensional, variable-density, saturated-unsaturated, and coupled flow and solute transport (saltwater intrusion by finite elements and characteristics [SIFEC]) was modified to allow the volume of water and mass of salt in the lagoon to vary with each time step. The modified SIFEC allows the stage of a lagoon to vary in accordance with a functional relation between the stage and water volume of the lagoon, and also allows the salt concentration of the lagoon to vary in accordance with the salt budget of the lagoon including chemical precipitation and dissolution of salt. The updated stage and salt concentration of the lagoon are in turn used as transient boundary conditions for the coupled flow and solute transport model. The utility of the modified model was demonstrated by applying it to the eastern Mediterranean coastal region of Turkey for assessing impacts of climate change on the subsurface environment under scenarios of sea level rise, increased evaporation, and decreased precipitation.     

Evaporation Reduction from Water Reservoirs in Arid Lands Using Monolayers: Algerian Experience

The extremely high rate of evaporation from water surfaces in arid and semi-arid areas greatly reduces optimal utilization of water reservoirs. In Algeria, which is at 80% an arid country, water resources are scarce and renewable due to low annual precipitation. Considering the importance of optimal utilization of renewable water resources, about 70 dams with capacity of 7.4 billion m³ were constructed. One of the biggest problems of water in dams in Algeria is the huge amount of water loss through evaporation due to high evaporation rate. Therefore, applying techniques to reduce evaporation are greatly needed. One of the most recommended techniques for reducing evaporation is the application of a thin chemical film on the surface of the water. The present study aims to investigate the effect of this technique under arid conditions. Experiment was conducted for 20 weeks in Touggourt with three Colorado-type evaporation pans. Fatty alcohol with various doses were used in different pans. First pan was filled with water without adding fatty alcohol while in second pan, fatty alcohols was added with recommended concentration (0.3 kg/10⁴ m²/day) and similarly in third pan fatty alcohol was added with concentration (0.5 kg/10⁴ m²/day). The preliminary results of the study indicated that evaporation rate from surface water was reduced overall up to 16 and 22% in the second pan and the third one, respectively as compared to the non covered pan.     

Estimation of Salt Water Upconing Using a Steady‐State Solution for Partial Completion of a Pumped Well

A new steady‐state analytical solution to the two‐dimensional radial‐flow equation was developed for drawdown (head) conditions in an aquifer with constant transmissivity, no‐flow conditions at the top and bottom, constant head conditions at a known radial distance, and a partially completed pumping well. The solution was evaluated for accuracy by comparison to numerical simulations using MODFLOW. The solution was then used to estimate the rise of the salt water‐fresh water interface (upconing) that occurs under a pumping well, and to calculate the critical pumping rate at which the interface becomes unstable, allowing salt water to enter the pumping well. The analysis of salt water‐fresh water interface rise assumed no significant effect on upconing by recharge; this assumption was tested and supported using results from a new steady‐state analytical solution developed for recharge under two‐dimensional radial‐flow conditions. The upconing analysis results were evaluated for accuracy by comparison to those from numerical simulations using SEAWAT for salt water‐fresh water interface positions under mild pumping conditions. The results from the equation were also compared with those of a published numerical sharp‐interface model applied to a case on Cape Cod, Massachusetts. This comparison indicates that estimating the interface rise and maximum allowable pumping rate using the analytical method will likely be less conservative than the maximum allowable pumping rate and maximum stable interface rise from a numerical sharp‐interface model.     

A simple method for locating the fresh water-salt water interface using pressure data

Salt water intrusion is a key issue in dealing with exploitation, restoration, and management of fresh ground water in coastal aquifers. Constant monitoring of the fresh water-salt water interface is necessary for proper management of ground water resources. This study presents a simple method to estimate the depth of the fresh water-salt water interface in coastal aquifers using two sets of pressure data obtained from the fresh and saline zones within a single borehole. This method uses the density difference between fresh water and saline water and can practically be used at coastal aquifers that have a relatively sharp fresh water-salt water interface with a thin transition zone. The proposed method was applied to data collected from a coastal aquifer on Jeju Island, Korea, to estimate the variations in the depth of the interface. The interface varied with daily tidal fluctuations and heavy rainfall in the rainy season. The estimated depth of the interface showed a good agreement with the measured electrical conductivity profile.