Variations in the discharge and organic matter content of stalagmite drip waters in Lower Cave,Bristol

Six drip waters, which were actively depositing stalagmites in Lower Cave, Bristol, were analysed both for discharge and luminescence properties. Drip discharges were determined for two different years, and show a complex response to surface precipitation variations. Inter annual variability in drip discharge is demonstrated to be significantly higher than intra-annual variability, and discharge was demonstrated both to increase and decrease non-linearly with increased precipitation. Drip waters demonstrate a correlation between their luminescence intensity and drip discharge, with increased luminescence in winter as more organic matter is flushed through the aquifer. The strength of the relationship between luminescence intensity and discharge increases with increased discharge. The results presented here have implications for the palaeoenvironmental interpretation of annual growth laminae and the growth rates of stalagmite samples. © 1997 John Wiley & Sons, Ltd.     

Hydrology of cave drip waters at varying bedrock depths from a karst system in southeastern Australia

The study of how cave drip‐water discharge responds to recharge events is fundamental to evaluating the potential of actively forming speleothems as high‐resolution climate archives. Most previous research has focused on caves of the Northern Hemisphere middle latitudes, where recharge is strongly seasonal. Few studies have explored drip‐water behaviour from regions where the expected seasonal rainfall pattern is significantly perturbed on an irregular basis by changing regional atmospheric circulation patterns. Here, we report the results of a 4‐year study of cave drip‐water–climate relationships from two caves in eastern Australia. The discharge of 10 drip sites located beneath bedrock thicknesses of 12, 22 and 45 m was monitored either continuously (using automated infrared sensors) or at discrete approximately monthly intervals and compared with local rainfall and water balance data. The study period traversed two major droughts, including the severe 2002–2003 El Niño. Drips at 12 and 22 m depths responded almost simultaneously to individual recharge events, although the time lag between individual events varied according to the volume of recharge and pre‐event storage. Overall, a steady decline in discharge is evident through the moisture‐deficit period, with increased flows through phases of positive water balance. Speleothems growing at these and similar shallow‐chamber sites have potential for reconstructing palaeo‐rainfall trends at high‐resolution, although the highly variable nature of year‐to‐year recharge would make it difficult to obtain data on a calendrical time‐scale. Drips at 45 m depth did not respond consistently to individual recharge events and displayed hydrological behaviour markedly dissimilar to one another and to the near‐surface drip sites, indicating great complexity in karst architecture and the absence of fissure flow. Although speleothems at this depth may well preserve information on longer‐term rainfall trends, their potential to encode a palaeo‐rainfall variability signal at interannual resolution is poor. Copyright © 2007 John Wiley & Sons, Ltd.     

Epikarst hydrology and implications for stalagmite capture of climate changes at Grotta di Ernesto (NE Italy): results from long‐term monitoring

Grotta di Ernesto is a cave site well suited for palaeoclimate studies because it contains annually laminated stalagmites and was monitored from 1995 to the end of 2008 for microclimate, hydrology and hydrochemistry. Long‐term monitoring highlighted that cave drips show three different hydrological responses to rainfall and infiltration: (1) fast seasonal drips in the upper part of the cave, which are mostly fed by fractures, (2) slow seasonal drips, located at mid‐depth in the cave characterized by mixed feeding and (3) slow drips, mostly located in the deeper gallery, which are fed by seepage flow from bulk porosity with a minor fracture‐fed component. The slow drips display daily cycles during spring thaw. Monitoring also indicated that drip waters are only slightly modified by degassing within the soil zone and aquifer and by prior calcite precipitation. Hydrochemical studies show a clear seasonality in calcite saturation index, which results in most cave calcite precipitation occurring during late autumn and winter with similar amounts of precipitated calcite on most stalagmites, regardless of drip rate (discharge) differences. Drip rate, and drip rate variability, therefore, has a minor role in modulating the amount of annual calcite formation. In contrast, drip rate, when associated with moderate reduction in calcite saturation index, clearly influences stalagmite morphology. Increasing drip rate yields a passage from candle‐, to cone‐ to dome‐shaped stalagmites. Very high drip rates feed speleothems with flowstone morphology. In summary, monitoring provides information about the karst aquifer and how hydrology influences those physical and chemical characteristics of speleothems which are commonly used as climate proxies. Copyright © 2010 John Wiley & Sons, Ltd.     

Factors controlling nitrogen and dissolved organic carbon exports across timescales in two watersheds with different land uses

Investigating factors controlling the temporal patterns of nitrogen (N) and dissolved organic carbon (DOC) exports on the basis of a comparative study of different land uses is beneficial for managing water resources, especially in agricultural watersheds. We focused our research on an agricultural watershed (AW) and a forested watershed (FW) located in the Shibetsu watershed of eastern Hokkaido, Japan, to investigate the temporal patterns of N and DOC exports and factors controlling those patterns at different timescales (inter‐annual, seasonal, and hydrological event scales). Results showed that the annual patterns of N and DOC exports significantly varied over time and were probably controlled by climate. Higher discharge volumes in 2003, a wet year, showed higher N and DOC loadings in both watersheds. However, this process was also regulated by land use associated with N inputs. Higher concentrations and loadings were shown in the agricultural watershed. At the seasonal scale, N and DOC exports in the AW and the FW were more likely controlled by sources associated with land use. The Total N (TN) and Nitrate‐N (NO₃^?‐N) had higher concentrations during snowmelt season in the AW, which may be attributed to manure application in late autumn or early winter in the agricultural watershed. Concentrations of TN, NO₃^?‐N, dissolved organic nitrogen (DON), and DOC showed higher values during the summer rainy season in the FW, related to higher litter decomposition during summer and autumn and the fertilizer application in the agricultural area during summer. Higher DOC concentrations and loadings were observed during the rainy season in the AW, which is probably attributed to higher DOC production related to temperature and microbial activity during summer and autumn in grasslands. Correlations between discharge and concentrations differed during different periods or in different watersheds, suggesting that weather discharge can adequately represent the fact that N export depends on N concentrations, discharge level, and other factors. The differing correlations between N/DOC concentrations and the Si concentration indicated that the N/DOC exports might occur along different flow paths during different periods. During baseflow, the high NO₃^?‐N exports were probably derived from deep groundwater and might have percolated from uplands during hydrological events. During hydrological events, NO₃^?‐N exports may occur along near‐surface flow paths and in deep groundwater, whereas DOC exports could be related to near‐surface flow paths. At the event scale, the relationships between discharge and concentrations of N and DOC were regulated by antecedent soil moisture (shallow groundwater condition) in each watershed. These results indicated that factors controlling N and DOC exports varied at different timescales in the Shibetsu area and that better management of manure application during winter in agricultural lands is urgently needed to control water pollution in streams. Copyright © 2013 John Wiley & Sons, Ltd.     

Response of drip water temperature to climate variability: a case study in Xiaoyan Cave,southwest China

Detailed monitoring of surface atmospheric and subterranean microclimatic conditions has provided a new opportunity to interpret drip water temperature changes associated with climate variability. High-resolution multi-index monitoring was conducted in Xiaoyan Cave, Guilin, southwest China, for a period of four years (2011–2014) to identify the processes that control drip water temperature. The results show that variations in drip water temperature are mainly coupled to changes in the cave air temperature unless large drip discharge occurs. The controls on cave air temperature depend on the ventilation modes that eventually affect drip water. The multiple thermal mechanisms are winter ventilation, heat conduction in summer and water flow-induced convection derived from subsurface water percolation into the cave due to fast preferential flow during heavy rain events. Drip water response to extreme temperature anomalies is shown to be sensitive to outside climate.     

Assessing possible changes in flood frequency due to climate change in mid‐sized watersheds in New York State,USA

The frequency of flooding is often presumed to increase with climate change because of projected increases in rainfall intensities. In this paper, using 50‐plus years of historical discharge and meteorological data from three watersheds in different physiographic regions of New York State, USA, we find that annual maximum stream discharges are associated with 20% or less of the annual maximum rainfall events. Instead of rainfall events, approximately 20% of annual maximum stream discharges are associated with annual maximum snowmelt events while 60% of annual maximum discharges are associated with moderate rainfall amounts and very wet soil conditions. To explore the potential for changes in future flood risk, we employed a compound frequency distribution that assumes annual maximum discharges can be modelled by combining the cumulative distribution functions of discharges resulting from annual maximum rainfall, annual maximum snowmelt, and occurrences of moderate rain on wet soils. Basing on a compound frequency distribution comprised of univariate general extreme value (GEV) and gamma distributions, we found that a hypothetical 20% increase in the magnitude of rainfall‐related stream discharge results in little change in 96th percentile annual maximum discharge. For the 99th percentile discharge, two waterbodies in our study had a 10% or less increase in annual maximum discharge when annual maximum rainfall‐related discharges increased 20% while the third waterbody had a 16% increase in annual maximum discharges. Additionally, in some cases, annual maximum discharges could be offset by a reduction in the discharge resulting from annual maximum snowmelt events. While only intended as a heuristic tool to explore the interaction among different flood‐causing mechanisms, use of a compound flood frequency distribution suggests a case can be made that not all waterbodies in humid, cold regions will see extensive changes in flooding due to increased rainfall intensities. Copyright © 2011 John Wiley & Sons, Ltd.     

Integrated cave drip monitoring for epikarst recharge estimation in a dry Mediterranean area,Sif Cave,Israel

Understanding recharge mechanisms and controls in karst regions is extremely important for managing water resources because of the dynamic nature of the system. The objective of this study was to evaluate water percolation through epikarst by monitoring water flow into a cave and conducting artificial irrigation and tracer experiments, at Sif Cave in Wadi Sussi, Israel from 2005 through 2007. The research is based on continuous high‐resolution direct measurements of both rainfall and water percolation in the cave chamber collected by three large PVC sheets which integrate drips from three different areas (17, 46, and 52 m²). Barrels equipped with pressure transducers record drip rate and volume for each of the three areas. The combined measured rainfall and cave data enables estimation of recharge into the epikarst and to better understand the relationship of rainfall‐recharge. Three distinct types of flow regimes were identified: (1) ‘Quick flow’ through preferential flow paths (large fractures and conduits); (2) ‘Intermediate flow’ through a secondary crack system; and (3) ‘Slow flow’ through the matrix. A threshold of ～100 mm of rain at the beginning of the rainy season is required to increase soil water content allowing later rainfall events to percolate deeper through the soil and to initiate dripping in the cave. During winter, as the soil water content rises, the lag time between a rain event and cave drip response decreases. Annual recharge (140–160 mm in different areas in the cave) measured represents 30–35% of annual rainfall (460 mm). Copyright © 2011 John Wiley & Sons, Ltd.     

Intra‐event intermittency of rainfall: an analysis of the metrics of rain and no‐rain periods

The metric or ‘observable’ properties of intra‐event rainfall intermittency (IERI) are quantified using a 10‐year record from arid Fowlers Gap, Australia. Rainfall events were delineated using the minimum inter‐event time (MIT) criterion, using eight values in the range of 1 h – 24 h. Within events, no‐rain periods were defined as corresponding to rainfall rates R < 0.1 mm/h or R < 0.2 mm/h (both less than typical wet‐canopy evaporation rates during rainfall). In this way, rainfall events were subdivided into rain and no‐rain periods. Intermittency was characterised using two measures: the fraction of rainless time within an event, and the duration of the longest rainless period. Events identified using a minimum inter‐event time (MIT) of 24 h included on average 9.4 h of contiguous no‐rain time (47.5% of the mean event duration), and only 6.8 h of contiguous rain. Total IERI averaged 51.1% for these events. Events defined with MIT = 6 h (a value commonly adopted in the literature) exhibited a mean of 1.53 h of no‐rain and 9.04 h of contiguous rain. Total IERI averaged 13.9% for these events for R < 0.1 mm/h, but reached 39.2% if no‐rain periods were taken as those of <0.2 mm/h. The maximum contiguous no‐rain period for events defined using MIT = 6 h was 10.9 h from an event of 12.6 h duration, and this represents 86.5% of the event duration. Results demonstrate that smaller, shorter, and less intense rainfall events tend to exhibit higher IERI than larger, longer, and more intense events. IERI is relevant to the understanding of land surface processes. Information on the metric properties of IERI in different rainfall types (convective and stratiform) and rainfall climates (arid, maritime, and wet tropical) may prove to have significance for diverse studies in land surface hydrology. Copyright © 2015 John Wiley & Sons, Ltd.     

Seasonal snowpack dynamics and runoff in a cool temperate forest: lysimeter experiment in Niigata,Japan

Seasonal snowpack dynamics are described through field measurements under contrasting canopy conditions for a mountainous catchment in the Japan Sea region. Microclimatic data, snow accumulation, albedo and lysimeter runoff are given through the complete winter season 2002–03 in (1) a mature cedar stand, (2) a larch stand, and (3) a regenerating cedar stand or opening. The accumulation and melt of seasonal snowpack strongly influences streamflow runoff during December to May, including winter baseflow, mid‐winter melt, rain on snow, and diurnal peaks driven by radiation melt in spring. Lysimeter runoff at all sites is characterized by constant ground melt of 0·8–1·0 mm day⁻¹. Rapid response to mid‐winter melt or rainfall shows that the snowpack remains in a ripe or near‐ripe condition throughout the snow‐cover season. Hourly and daily lysimeter discharge was greatest during rain on snow (e.g. 7 mm h⁻¹ and 53 mm day⁻¹ on 17 December) with the majority of runoff due to rainfall passing through the snowpack as opposed to snowmelt. For both rain‐on‐snow and radiation melt events lysimeter discharge was generally greatest at the open site, although there were exceptions such as during interception melt events. During radiation melt instantaneous discharge was up to 4·0 times greater in the opening compared with the mature cedar, and 48 h discharge was up to 2·5 times greater. Perhaps characteristic of maritime climates, forest interception melt is shown to be important in addition to sublimation in reducing snow accumulation beneath dense canopies. While sublimation represents a loss from the catchment water balance, interception melt percolates through the snowpack and contributes to soil moisture during the winter season. Strong differences in microclimate and snowpack albedo persisted between cedar, larch and open sites, and it is suggested further work is needed to account for this in hydrological simulation models. Copyright © 2005 John Wiley & Sons, Ltd.     

Vapour source and spatiotemporal variation of precipitation isotopes in Southwest Spain

The δ²H and δ¹⁸O composition of 77 precipitation samples collected between January 2014 and April 2019 from two sites across the Guadalquivir Basin, SW Spain, were analysed. The first site is located in an urban area of Seville at 100 km distance to the Atlantic coast and the second site is located in a dune area of the Doñana National Park a few kilometres from the coast. Sampling was performed within intervals of at least 14 days if rain occurred but frequently intervals were longer according to the rainfall incidence. Samples from both sites are available for the period February 2016 to June 2018 with six samples containing identical rain events at both locations. Precipitation weighted averages and local meteoric water lines produced by weighting and non-weighting regression methods are presented for its use in hydrological applications. Results show a remarkably high variability in δ²H and δ¹⁸O values and precipitation weighted average d-excess values of 11.8‰ and 13‰ at the sites Plaza de España and Doñana, respectively. Temperature and amount effects were found to be weak. A significant influence of secondary evaporation for single rainfall events during summer was identified by enriched isotopic signatures with reduced d-excess values plotting close or below the global meteoric water line. Backward trajectory analysis of 115 days with daily rainfall above 3 mm yield a predominant Atlantic Ocean vapour source with negligible Mediterranean influence and therefore, d-excess variability is attributed to the different ocean surface conditions of relative humidity and sea surface temperature. Parallel sampling indicate very similar isotopic signatures at both sites and point to the existence of thermal effects of the Plaza de España site in Seville city during the summer season.     

The droughts of 1996–1997 and 2004–2005 in Amazonia: hydrological response in the river main‐stem

Severe hydrological droughts in the Amazon have generally been associated with strong El Niño events. More than 100 years of stage record at Manaus harbour confirms that minimum water levels generally coincide with intense warming in the tropical Pacific sea waters. During 2005, however, the Amazon experienced a severe drought which was not associated with an El Niño event. Unless what usually occurs during strong El Niño events, when negative rainfall anomalies usually affect central and eastern Amazon drainage basin; rainfall deficiencies in the drought of 2005 were spatially constrained to the west and southwest of the basin. In spite of this, discharge stations at the main‐stem recorded minimum water levels as low as those observed during the basin‐wide 1996–1997 El Niño‐related drought. The analysis of river discharges along the main‐stem and major tributaries during the drought of 2004–2005 revealed that the recession on major tributaries began almost simultaneously. This was not the case in the 1996–1997 drought, when above‐normal contribution of some tributaries for a short period during high water was crucial to partially counterbalance high discharge deficits of the other tributaries. Since time‐lagged contributions of major tributaries are fundamental to damp the extremes in the main‐stem, an almost coincident recession in almost all tributaries caused a rapid decrease in water discharges during the 2005 event. Copyright © 2010 John Wiley & Sons, Ltd.     

The impact of storm events on solute exports from a glaciated forested watershed in western New York,USA

This study analysed the importance of precipitation events from May 2003 to April 2004 on surface water chemistry and solute export from a 696 ha glaciated forested watershed in western New York State, USA. The specific objectives of the study were to determine: (a) the temporal patterns of solutes within individual storm events; (b) the impact of precipitation events on seasonal and annual export budgets; and (c) how solute concentrations and loads varied for precipitation events among seasons as functions of storm intensity and antecedent moisture conditions. Analysis of solute trajectories showed that NH₄⁺, total Al and dissolved organic nitrogen (DON) peaked on the hydrograph rising limb, whereas dissolved organic carbon (DOC) concentrations peaked following the discharge peak. Sulphate and base‐cations displayed a dilution pattern with a minimum around peak discharge. End‐member mixing analysis showed that throughfall contributions were highest on the rising limb, whereas valley‐bottom riparian waters peaked following the discharge peak. The trajectories of NO₃^? concentrations varied with season, indicating the influence of biotic processes on the generation, and hence flux, of this solute. Storm events had the greatest impact on the annual budgets for NH₄⁺, K⁺, total dissolved Al, DON and DOC. Storm events during summer had the greatest impact on seasonal solute budgets. Summer events had the highest hourly discharges and high concentrations of solutes. However, NO₃^? and DOC exports during a spring snowmelt event were considerably more than those observed for large events during other periods of the year. Comparisons among storms showed that season, precipitation amount, and antecedent moisture conditions affected solute concentrations and loads. Concentrations of solutes were elevated for storms that occurred after dry antecedent conditions. Seven of the largest storms accounted for only 15% of the annual discharge, but were responsible for 34%, 19%, 64%, 13%, 39% and 24% of the annual exports of NH₄⁺, K⁺, Al, NO₃^?, DON and DOC respectively. These results suggest that the intense and infrequent storms predicted for future climate‐change scenarios will likely increase the exports of solutes like DOC, DON, NH₄⁺, Al and K⁺ from watersheds. Copyright © 2006 John Wiley & Sons, Ltd.     

Fluvial transport of suspended sediment and organic carbon during flood events in a large agricultural catchment in southwest France

Water draining from a large agricultural catchment of 1 110 km² in southwest France was sampled over an 18‐month period to determine the temporal variability in suspended sediment (SS) and dissolved (DOC) and particulate organic carbon (POC) transport during flood events, with quantification of fluxes and controlling factors, and to analyze the relationships between discharge and SS, DOC and POC. A total of 15 flood events were analyzed, providing extensive data on SS, POC and DOC during floods. There was high variability in SS, POC and DOC transport during different seasonal floods, with SS varying by event from 513 to 41 750 t; POC from 12 to 748 t and DOC from 9 to 218 t. Overall, 76 and 62% of total fluxes of POC and DOC occurred within 22% of the study period. POC and DOC export from the Save catchment amounted to 3090 t and 1240 t, equivalent to 1·8 t km^?2 y^?1 and 0·7 t km^?2 y^?1, respectively. Statistical analyses showed that total precipitation, flood discharge and total water yield were the major factors controlling SS, POC and DOC transport from the catchment. The relationships between SS, POC and DOC and discharge over temporal flood events resulted in different hysteresis patterns, which were used to deduce dissolved and particulate origins. In both clockwise and anticlockwise hysteresis, POC mainly followed the same patterns as discharge and SS. The DOC‐discharge relationship was mainly characterized by alternating clockwise and anticlockwise hysteresis due to dilution effects of water originating from different sources in the whole catchment. Copyright © 2011 John Wiley & Sons, Ltd.     

Hydroclimatic controls on dissolved organic matter (DOM) characteristics and implications for trace metal transport in Hwangryong River Watershed,Korea, during a summer monsoon period

Frequent heavy rainfalls during the East Asian summer monsoon drastically increase water flow and chemical loadings to surface waters. A solid understanding of hydroclimatic controls on watershed biogeochemical processes is crucial for water quality control during the monsoon period. We investigated spatio‐temporal variations in the concentrations and spectroscopic properties of dissolved organic matter (DOM) and the concentrations of trace metals in Hwangryong River, Korea, during a summer period from the relatively dry month of June through the following months with heavy rainfall. DOM and its spectroscopic properties differed spatially along the river, and also depended on storm and flow characteristics around each sampling time. At a headwater stream draining a forested watershed, the concentrations (measured as dissolved organic carbon (DOC)), aromaticity (measured as specific UV absorbance at 254 nm), and fulvic acid‐ and protein‐like fluorescence of DOM were higher in stormflow than in baseflow waters. DOC concentrations and fluorescence intensities increased along the downstream rural and urban sites, in which DOC and fluorescence were not higher in stormflow waters, except for the ‘first flush’ at the urban site. The response of DOM in reservoir waters to monsoon rainfalls differed from that of stream and river waters, as illustrated by storm‐induced increases in DOM aromaticity and fulvic‐like fluorescence, and no significant changes in protein‐like fluorescence. The results suggest that surface water DOM and its spectroscopic properties differentially respond to changes in hydroclimatic conditions, depending on watershed characteristics and the influence of anthropogenic organic matter loadings. DOC concentrations and intensities of spectroscopic parameters were positively correlated with some of the measured trace metals (As, Co, and Fe). Further research will be needed to obtain a better understanding of climate effects on the interaction between DOM and trace metals. Copyright © 2006 John Wiley & Sons, Ltd.     

Effect of rainfall uncertainty on the performance of physically based rainfall–runoff models

This paper analyses the effect of rain data uncertainty on the performance of two hydrological models with different spatial structures: a semidistributed and a fully distributed model. The study is performed on a small catchment of 19.6 km² located in the north‐west of Spain, where the arrival of low pressure fronts from the Atlantic Ocean causes highly variable rainfall events. The rainfall fields in this catchment during a series of storm events are estimated using rainfall point measurements. The uncertainty of the estimated fields is quantified using a conditional simulation technique. Discharge and rain data, including the uncertainty of the estimated rainfall fields, are then used to calibrate and validate both hydrological models following the generalized likelihood uncertainty estimation (GLUE) methodology. In the storm events analysed, the two models show similar performance. In all cases, results show that the calibrated distribution of the input parameters narrows when the rain uncertainty is included in the analysis. Otherwise, when rain uncertainty is not considered, the calibration of the input parameters must account for all uncertainty in the rainfall–runoff transformation process. Also, in both models, the uncertainty of the predicted discharges increase in similar magnitude when the uncertainty of rainfall input increase.     

Quantifying the role of the snowpack in generating water available for run‐off during rain‐on‐snow events from snow pillow records

Rain‐on‐snow events have generated major floods around the world, particularly in coastal, mountainous regions. Most previous studies focused on a limited number of major rain‐on‐snow events or were based primarily on model results, largely due to a lack of long‐term records from lysimeters or other instrumentation for quantifying event water balances. In this analysis, we used records from five automated snow pillow sites in south coastal British Columbia, Canada, to reconstruct event water balances for 286 rain‐on‐snow events over a 10‐year period. For large rain‐on‐snow events (event rainfall >40 mm), snowmelt enhanced the production of water available for run‐off (WAR) by approximately 25% over rainfall alone. For smaller events, a range of antecedent and meteorological factors influenced WAR generation, particularly the antecedent liquid water content of the snowpack. Most large events were associated with atmospheric rivers. Rainfall dominated WAR generation during autumn and winter events, whereas snowmelt dominated during spring and summer events. In the majority of events, the sensible heat of rain contributed less than 10% of the total energy consumed by snowmelt. This analysis illustrated the importance of understanding the amount of rainfall occurring at high elevations during rain‐on‐snow events in mountainous regions.     

Identifying individual rain events from pluviograph records: a review with analysis of data from an Australian dryland site

Rainfall is routinely reported as falling in ‘events’ or ‘storms’ whose beginning and end are defined by rainless intervals of a nominated duration (minimum inter‐event time, MIT). Rain events commonly exhibit fluctuations in rain rate as well as periods when rain ceases altogether. Event characteristics such as depth, mean rain rate, and the surface runoff volume generated, are defined in relation to the length of the rain event. These derived properties are dependent upon the value of MIT adopted to define the event, and the literature reveals a wide range of MIT criteria. Surprisingly little attention has been paid to this dependency, which limits the inter‐comparison of results in published work. The diversity in criteria also diminishes the usefulness of historical data on event durations, rain rates, etc., in attempts to document changes in the rainfall climate. This paper reviews the range of approaches used in the recognition of rain events, and a 5 year pluviograph record from an arid location is analysed. Changing MIT from 15 min to 24 h (lying within the range of published criteria) alters the number of rain events from 550 to 118. The mean rain rate declines from 2·04 mm h^?1 to 0·94 mm h^?1, and the geometric mean event duration rises from 0·66 h to 3·98 h. This wide variation in the properties of rain events indicates that more attention needs to be paid to the selection and reporting of event criteria in studies that adopt event‐based data analysis. The selection of a MIT criterion is shown to involve a compromise between the independence of widely‐spaced events and their increasingly variable intra‐event characteristics. Copyright © 2008 John Wiley & Sons, Ltd.     

Rainfall partitioning through a mixed cedar swamp and associated C and N fluxes in Southern Ontario,Canada

Partitioning of rainfall through a forest canopy into throughfall, stemflow, and canopy interception is a critical process in the water cycle, and the contact of precipitation with vegetated surfaces leads to increased delivery of solutes to the forest floor. This study investigates the rainfall partitioning over a growing season through a temperate, riparian, mixed coniferous‐deciduous cedar swamp, an ecosystem not well studied with respect to this process. Seasonal throughfall, stemflow, and interception were 69.2%, 1.5%, and 29.3% of recorded above‐canopy precipitation, respectively. Event throughfall ranged from a low of 31.5 ± 6.8% for a small 0.8‐mm event to a high of 82.9 ± 2.4% for a large 42.7‐mm event. Rain fluxes of at least 8 mm were needed to generate stemflow from all instrumented trees. Most trees had funnelling ratios <1.0, with an exponential decrease in funnelling ratio with increasing tree size. Despite this, stand‐scale funnelling ratios averaged 2.81 ± 1.73, indicating equivalent depth of water delivered across the swamp floor by stemflow was greater than incident precipitation. Throughfall dissolved organic carbon (DOC) and total dissolved nitrogen (TDN) averaged 26.60 ± 2.96 and 2.02 ± 0.16 mg L^?1, respectively, which were ~11 and three times above‐canopy rain levels. Stemflow DOC averaged 73.33 ± 7.43 mg L^?1, 35 times higher than precipitation, and TDN was 4.45 ± 0.56 mg L^?1, 7.5 times higher than rain. Stemflow DOC concentration was highest from Populus balsamifera and TDN greatest from Thuja occidentalis trees. Although total below‐canopy flux of TDN increased with increasing event size, DOC flux was greatest for events 20–30 mm, suggesting a canopy storage threshold of DOC was readily diluted. In addition to documenting rainfall partitioning in a novel ecosystem, this study demonstrates the excess carbon and nitrogen delivered to riparian swamps, suggesting the assimilative capacity of these zones may be underestimated.     

Seasonal and storm flow dynamics of dissolved organic carbon in a Mediterranean mountain catchment (Vallcebre,eastern Pyrenees)

To improve understanding of DOC dynamics in seasonal Mediterranean environments, rainfall, soil water, groundwater and stream water samples were taken during a 27-month period in the Can Vila catchment (northeast Spain). Using these data, we characterized DOC dynamics in the different hydrological compartments and analysed the factors affecting them. We also analysed DOC dynamics during storm events and the factors that control DOC delivery to the stream. The results show some seasonality in rainwater and soil water DOC concentrations, while no clear seasonality was observed in stream water and groundwater, where DOC dynamics were strongly related to discharge and water table variations. For storm events with several discharge peaks, the slope of the discharge–DOC concentration relationship was higher for the first peak. The rather similar dynamics of stream water DOC concentration in all floods contrast with the observed diversity of hydrological processes. This raises the question of the origin of the observed rapid DOC increase.

EDITOR M.C. Acreman

ASSOCIATE EDITOR K. Heal